3:00pm - 3:15pmID: 174
/ SESSION 6: 1
Type of Contribution: Oral
Topics: WOCSDICE: Other semiconductor devices, WOCSDICE: Theory and ModelingKeywords: multijunction, simulation, HMA, anticrossing, pseudomorphic
Bandgap-Engineered III-V-N Superlattices for Monolithic Tandem Solar Cells Lattice-Matched to Si
Carlos Macías, Ainhoa Orte-Ortega, Jose María Ulloa, Sergio Fernández-Garrido
Instituto de Sistemas Optoelectrónicos y Microtecnología, Spain
We present a theoretical investigation of a previously
unexplored dilute nitride III-V-N short-period superlattice
system, GaPN/GaAsP, designed as a potential top-cell
absorber for monolithic III-V/Si tandem solar cells. This
system exhibits a type-II band alignment. Through
multiband k·p calculations and the envelope function
approximation, we show that an optimal bandgap of 1.7
eV can be achieved while satisfying the strain-balanced,
zero-stress condition over a broad range of dilute
nitrogen compositions. The thicknesses of individual
layers remain well below the critical threshold for plastic
relaxation. We also discuss the experimental feasibility of
realizing such structures, supported by recent progress in
the growth of high-quality GaP buffer layers and precise,
monolayer-controlled incorporation of nitrogen in dilute
nitrides on silicon via molecular beam epitaxy.
3:15pm - 3:30pmID: 169
/ SESSION 6: 2
Type of Contribution: Oral
Topics: WOCSDICE: Other semiconductor devices, WOCSDICE: Electrical and Photonics characterizationKeywords: Transferred DHBT, GaAsSb/InP, power, load pull, 94GHz
13mW/µm² and 24% PAE at 94GHz for 0.44-um Transferred InP/GaAsSb DHBT on Si
Abdelmalek Zemour1,2, Malek Zegaoui1, Yannick Roelens1, Etienne Okada1, Pascal Chevalier2, Mohammed Zaknoune1
1IEMN, France; 2STMicroelectronics, Crolles, 38920, France
We present large-signal load-pull measurements of a transferred InP/GaAsSb double heterojunction bipolar transistor fabricated on a high-resistivity silicon substrate. The tested devices feature an emitter area of 0.44 × 3.9 µm². When biased for highest power, an output power of 13.42 dBm was achieved corresponding to a power density of 12.92 mW/µm² (5.68 W/mm). A peak value of 23.7% was obtained along with a power gain of 5.35 dB when the load impedance was optimized for maximum power-added efficiency (P.A.E). These results highlight the benefits of thermal dissipation improvement in overcoming self-heating effects to achieve high output power.
3:30pm - 3:45pmID: 114
/ SESSION 6: 3
Type of Contribution: Oral
Topics: WOCSDICE: WBG and UWBG material devices, WOCSDICE: Theory and Modeling, EXMATEC: Other semiconductor materialsKeywords: Nickel oxide (NiO), Density Functional Theory (DFT), Defect engineering, Optoelectronic properties, Hybrid functionals
Vacancies in NiO: DFT Study for Optoelectronic Applications
Felipe Bermúdez-Mendoza, Diego J. Ramos-Ramos, Cristian G. Vásquez, David Maestre, Francisco Domínguez-Adame, Bianchi Méndez, Ruth Martínez-Casado, Elena Díaz
Universidad Complutense de Madrid, Spain
This study investigates the effects of Ni and O vacancies on the electronic and optoelectronic properties of NiO using density functional theory (DFT) alongside cathodoluminescence experiments. Computational results obtained with the B3LYP hybrid functional closely match experimental band gaps, validating the reliability of our simulations. Specifically, the introduction of Ni vacancies produces intra-gap states that align well with experimentally observed emission peaks. In contrast, O vacancies demonstrate donor-like behavior, aligning with experimental reports of enhanced n-type conductivity. These findings provide critical insights for defect engineering strategies, bridging theoretical predictions with experimental data to optimize NiO for advanced optoelectronic applications.
3:45pm - 4:00pmID: 130
/ SESSION 6: 4
Type of Contribution: Oral
Topics: WOCSDICE: Other semiconductor devices, WOCSDICE: Theory and ModelingKeywords: Radiofrequency, III-V compounds, PIN diodes
Simulation and Analysis of MOVPE Grown III-V PIN Diodes for RF Applications
Simeon Nikolaev Vladimirov, Iván García, Ignacio Rey-Stolle
Universidad Politécnica de Madrid, Spain
Control elements based on III-V semiconductors are widely used in radiofrequency circuits, especially in the GHz range, as they offer superior high-frequency performance, easy integration, high reliability and compact size. In this context, PIN diodes are one of the most popular choices for limiter and switch applications. However, there is little literature connecting their structure and physical configuration with their circuit response, which hinders further understanding of these devices. In this regard, we present an analysis of the performance of GaAs and AlGaAs/GaAs PIN diodes as possible switches/limiters in X-Band applications, where we have conducted simulations on their high frequency behaviour, employing the Silvaco ATLAS numerical simulation software. Variations in the physical structure of the PIN diodes have been explored, and the resulting changes in their high frequency response have been evaluated. In this communication, we present a sample of the most relevant metrics explored for X-band operation (8-12 GHz), such as as R-I characteristics under forward bias, insertion losses and band structures for all PIN designs.
4:00pm - 4:15pmID: 145
/ SESSION 6: 5
Type of Contribution: Indifferent
Topics: WOCSDICE: Other semiconductor devices, WOCSDICE: Electrical and Photonics characterizationKeywords: Colour centres, ion implantation, thermal annealing, quantum technologies
Fabrication and monitoring of quantum emitters in Aluminium Nitride via Al-ion implantation and thermal annealing
Elena Nieto Hernández1,2, Hüseyin Bilge Yağcı3,4, Vanna Pugliese1,2, Emilio Corte1,2, Pietro Aprà1,2, Joseph K. Cannon3,4, Sam G. Bishop3,4, John P. Hadden3,4, Sviatoslav Ditalia Tchernij1,2, Paolo Olivero1,2, Anthony J. Bennett3,4, Jacopo Forneris1,2
1Dipartimento di Fisica, Università di Torino, via Pietro Giuria 1, Torino 10125, Italy; 2Istituto Nazionale di Fisica Nucleare (INFN), Sezione di Torino, via Pietro Giuria 1, Torino 10125 Italy; 3School of Engineering, Cardiff University, Queen’s Building, The Parade, Cardiff CF24 3AA, United Kingdom; 4Translational Research Hub, Cardiff University, Maindy Road, Cathays, Cardiff CF24 4HQ, United Kingdom
Single-photon emitters (SPEs) in wide-bandgap materials, like group III-nitrides, are promising for room-temperature single-photon sources. Recent studies have shown antibunched emission from colour centres in gallium nitride and aluminum nitride (AlN). However, the nature of these defects and optimal formation conditions are still unclear.
In this work, we investigated the effect of aluminum implantation on AlN epilayers, followed by thermal annealing and confocal microscopy. The results showed that the SPEs density increased with fluence, with ensembles forming at the highest implantation fluence and that the use of thermal annealing at 600°C increases the number of individual colour centres for the highest fluences. A second study tracked native and created SPEs in a patterned sample, revealing that both native and fabricated ones were present near the sapphire interface. These findings highlight the importance of vacancy formation for SPEs creation and offer new possibilities for defect engineering in solid-state SPEs.
4:15pm - 4:30pmID: 148
/ SESSION 6: 6
Type of Contribution: Oral
Topics: WOCSDICE: WBG and UWBG material devicesKeywords: silicon carbide; membrane sensor; deterministic ion implantation; counting efficiency; spatial resolution
Novel Ion Detection Strategy for Deterministic Implantation Using an Ultra-Thin Silicon Carbide Membrane Detector
Enrico Sangregorio1, Andreo Crnjac2, Lucia Calcagno3
1National Research Council of Italy - Institute for Microelectronics and Microsystems, Italy; 2Division of Experimental Physics, Ruđer Bošković Institute; 3Department of Physics and Astronomy “Ettore Majorana”, University of Catania
Deterministic single-ion implantation has become a critical focus in the semiconductor field, particularly for its applications in solid-state quantum technologies. The ability to precisely position single dopants in nanostructures is essential for developing quantum devices, driving significant advancements in implantation techniques. Among these, single-ion lithographic methods utilizing scanning probes achieve exceptional nanometer-scale accuracy but are limited by slow processing speeds. Direct ion implantation, by contrast, offers a more rapid and scalable solution, though at the cost of reduced spatial precision and constraints imposed by device architecture.
In this study, a novel approach utilizing an ultra-thin 4H-SiC membrane sensor for single-ion detection is presented. The membrane design enables ion detection by monitoring the energy deposited by the ions as they pass through the active layer of the sensor. With this experimental setup, a 96.5% ion counting confidence was achieved, underlining the potential of SiC membranes as high-fidelity in-beam ion sensors. However, the introduction of the SiC membrane impacts the ion beam trajectory, resulting in ion straggling and increased uncertainty in the dopant’s final position within the target. Using a scanning knife-edge technique and SRIM simulations, we quantified the ion straggling, observing an increase in the beam size from 3.43 µm to 8.15 µm. These findings highlight the trade-off between detection accuracy and spatial resolution, emphasizing the need for further optimization to minimize beam perturbations while maintaining high detection efficiency.
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