12:45pm - 1:00pmFR2-4: 1
Combination of multiway data image analysis for improved characterisation of air pollution
Jonas Sjöblom1, Per Malmberg1, Sara Janhäll1,2, Elias Ranjbari1, Mats Josefson3
1Chalmers university of technology, Sweden; 2RISE – Research Institute of Sweden, Gothenburg, Sweden; 3AstraZeneca, Sweden
Our study presents a novel methodology that integrates multiple high-dimensional imaging techniques to enhance the characterization of air pollution particles. By combining SEM-EDX and ToF-SIMS data with multiway analysis, we address the challenges posed by heterogeneous particle composition and evolving pollution sources. This approach enables more precise source apportionment and a deeper understanding of PM characteristics, particularly in the context of changing vehicle emissions and urban air quality. The results demonstrate the potential of multiway techniques to unlock new insights into air pollution dynamics, paving the way for improved regulatory strategies and pollution mitigation efforts
1:00pm - 1:15pmFR2-4: 2
Optical Properties and Fluorescent Composition of Soluble Brown Carbon in Urban Areas of East Asia
Yueh-Ling Hung1, Yu-Hsiang Cheng2, Ji-Lin Shen3, Yu-Chieh Ting1
1Graduate Institute of Environmental Engineering, National Taiwan University, Taipei, Taiwan; 2Department of Safety, Health and Environmental Engineering, Ming Chi University of Technology, New Taipei, Taiwan; 3Department of Physics, Chung Yuan Christain University, Taoyuan, Taiwan
This study investigated the optical properties of soluble BrC and its impact on climate. Fluorescence analysis was used to obtain the structural characteristics of soluble BrC, contributing to a deeper insight into its composition in urban areas. The findings provide valuable information to support future atmospheric research utilizing fluorescence analysis. Furthermore, this study will employ the PMF model to apportion emission sources and assess their relationship with BrC optical properties. This approach aims to improve our understanding of the contributions of various urban emission sources to climate change.
1:15pm - 1:30pmFR2-4: 3
Chemistry of Aged Atmospheric Bioaerosols; Laboratory Research
Vera Samburova1,2, Palina Bahdanovich1,2, Kevin Axelrod3, Andrey Khlystov1
1Desert Research Institute, Reno, Nevada, United States of America; 2University of Nevada Reno, Reno, Nevada, United States of America; 3York University, Toronto, ON, Canada
Biological aerosol particles, or bioaerosols, represent a significant portion of atmospheric particulate matter (PM) and can profoundly affect the chemical and physical properties of atmospheric aerosols. Interest in atmospheric bioaerosols has increased recently because of the effects bioaerosols have on global climate and human health. In the present study, extracts of common bioaerosols were aged with an oxidation flow reactor (OFR) and with H2O2 under UV-Vis light. The chemical analysis of organic species in fresh and aged bioaerosol samples was performed using Liquid Chromatography Mass Spectrometry (LC-MS) and Nuclear Magnetic Resonance Spectroscopy (1H-NMR).
1:30pm - 1:45pmFR2-4: 4
Unraveling Seasonal Trends in PM10 Organic Aerosols Using Nuclear Magnetic Resonance (NMR) Spectroscopy: A Study from Mumbai, India
Shweta Chandrashekhar Sakpal, Avik Kumar Sam, Rajdeep Singh, Ashutosh Kumar, Harish C. Phuleria
Indian Institute of Technology Bombay, India
This study presents the first NMR-based seasonal analysis of organic aerosols in Mumbai, a tropical coastal megacity. PM₁₀, EC-OC, and NMR-derived functional groups were analyzed using high-resolution diurnal sampling. PM₁₀ peaked in winter afternoons due to meteorological factors, while summer recorded the lowest levels. EC-OC trends indicated biomass burning and secondary aerosol formation. NMR analysis revealed higher hydrocarbons in winter, with aliphatics dominating year-round. Oxygenated species peaked in winter, linked to stagnant conditions. Strong correlations between functional groups and EC-OC suggest seasonal variations in sources and processes. Advanced NMR analysis is ongoing for further insights
1:45pm - 2:00pmFR2-4: 5
Chemical characterization of long-range transported wildfire aerosol plumes reaching Jungfraujoch (3571 m asl, Switzerland)
Leïla Simon1, Benjamin Tobias Brem1, Nora Nowak1, Robin Modini1, David Bell1, Stefan Reimann2, Martin Steinbacher2, Stephan Henne2, Martine Collaud Coen3, Martin Gysel-Beer1
1PSI Center for Energy and Environmental Sciences, 5232 Villigen PSI, Switzerland; 2Laboratory for Air Pollution/Environmental Technology, Empa, 8600 Dübendorf, Switzerland; 3Federal Office of Meteorology and Climatology, MeteoSwiss, CH-1530 Payerne, Switzerland
We characterize the chemical composition of particles from five wildfire plumes that reached the Jungfraujoch in 2023, using TOF-ACSM, AE33 and MAAP measurements. Organic aerosol (OA) dominated all biomass burning (BB) plumes, and the contribution to OA of m/z 60, a levoglucosan tracer, increases for these plumes. We also observe that the contribution of the m/z range 135-200 to OA increases during the BB plumes. A preliminary PMF source apportionment hints at a wildfire-specific BBOA factor in summer. Further work will focus on better separating the air masses and, consolidating the PMF and investigating more BB plumes.
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