Conference Agenda
Overview and details of the sessions of this conference. Please select a date or location to show only sessions at that day or location. Please select a single session for detailed view (with abstracts and downloads if available).
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Location: Studium2000 Building5 V.le San Nicola corner, Via di Valesio, 73100 Lecce LE |
| Date: Monday, 01/Sept/2025 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| 5:15pm - 6:45pm | Poster Session Monday Location: Studium2000 Building5 | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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PO1: 1
Advancing Atmospheric Research in the Eastern Mediterranean: Insights from the Cyprus Atmospheric Remote Sensing Observatory 1Eratosthenes centre of excelence, Cyprus; 2Department of Civil Engineering and Geomatic, Cyprus University of Technology, Limassol, 3036, Cyprus; 3Leibniz Institute for Tropospheric Research (TROPOS), Leipzig, Germany
The Cyprus Atmospheric Remote Sensing Observatory (CARO), a National Facility (NF) for remote sensing of aerosols and clouds, is under evaluation to become an ACTRIS National Research Infrastructure facility for Cyprus. It comprises the Aerosol Remote Sensing (ARS) and Cloud Remote Sensing (CRS) observational platforms. CARO observatory is poised to serve as the reference observatory for the Eastern Mediterranean, North Africa, and Middle East (EMMENA) region.
Situated at a strategic location, CARO provides critical data for understanding atmospheric aerosols, cloud dynamics, and radiative forcing, contributing to regional and global climate studies.
PO1: 2
Assessing the Sources of PM1 Trace Elements in the Marseille-Fos Basin through Rolling Positive Matrix Factorization Crossed-Study 1Aix Marseille Univ, CNRS, LCE, Marseille, France; 2AtmoSud, Regional Network for Air Quality Monitoring of Provence-Alpes-Côte-d’Azur, Marseille, France; 3Univ. Grenoble Alpes, CNRS, IRD, IGE (UMR 5001), 38000 Grenoble, France The Marseille-Fos basin is a critical Mediterranean site characterized by specific meteorological conditions and intensive anthropogenic activities. While organic aerosol sources have been studied, information on the elemental composition of aerosols in this region remains limited. Trace elements from anthropogenic emissions, predominantly in the submicron fraction, pose health risks. This study uses online XRF instrumentation (Xact 625i) to monitor elemental PM1 at two coastal sites: MRS-LCP (urban background) and FOS (industrial). Applying an innovative Rolling PMF approach to Xact datasets, the study identified eight factors at MRS-LCP and nine at FOS, with seven common factors.
PO1: 3
Atmospheric Dry Deposition in the Central Mediterranean Seen from a Single-Particle Perspective 1Institute for Applied Geosciences, Technical University Darmstadt, Germany; 2Department of Mathematics and Physics, University of Salento, Lecce, Italy; 3Institute of Atmospheric Sciences and Climate - Italian National Research Council (CNR ISAC), Lecce, Italy; 4Division of Environmental Management & Planning, Institute of Earth Systems, University of Malta, Msida, Malta; 5Ambient Quality and Waste Unit, Environment and Resources Authority, Marsa, Malta We discuss aerosol dry deposition, a crucial process in the aerosol cycle. We conducted a study focusing on data from Lecce, Italy, and San Lawrenz, Malta. We used a simple sampler to collect dry deposition three times per week for one year, which was then analyzed using electron microscopy. Our study revealed patterns in dust and sea-salt deposition rates, with variations between locations and seasons. We observed dust outbreaks and seasonal patterns, with dust being present in all samples. Dust composition slightly varies between the events. San Lawrenz showed higher and coarser sea-salt deposition due to its proximity to shores.
PO1: 4
Physical and chemical characterization of emissions from biobased renovation materials used for energy upgrade of Cultural Heritage Buildings Chemical Process and Energy Resources Institute (CPERI), Centre for Research and Technology Hellas (CERTH) The CALECHE project will present innovative solutions in various areas, including aesthetically acceptable integration of photovoltaic systems into buildings, advances in insulation materials specifically designed to meet the essential needs of historic buildings in terms of humidity regulation, while promoting resource circularity and reducing the overall carbon footprint. PO1: 6
Characterization of the Atmospheric Microbiome at a high-altitude station in the eastern Mediterranean using Flow Cytometry 1Laboratory of Atmospheric Processes and their Impacts, School of Architecture, Civil & Environmental Engineering, École Polytechnique Fédérale de Lausanne, Lausanne, 1015, Switzerland; 2Center for the Study of Air Quality and Climate Change, Institute of Chemical Engineering Sciences, Foundation for Research and Technology Hellas, GR-26504, Patras, Greece; 3Laboratory of Environmental Remote Sensing Laboratory, School of Architecture, Civil & Environmental Engineering, École Polytechnique Fédérale de Lausanne, Lausanne, 1015, Switzerland; 4Environmental Radioactivity & Aerosol Technology for atmospheric & Climate ImpacT Lab, INRASTER, NCSR Demokritos 15310 Ag. Paraskevi, Attica, Greece Bioaerosols can have important impacts on public health or climate. In this study, a flow cytometer was used to characterize and quantify bioaerosol (n = 67) particles at Mt. Helmos in Greece. A life/dead staining was applied to differentiate between the low and high nucleic acid (LNA and HNA, respectively) and the dead and intact populations. Results showed the presence of the LNA and HNA populations, supported by pictures of the integrated microscope. The LNA population is formed by smaller bioparticles (e.g., dead or bacterial cells) than the HNA population (e.g., potential metabolically active bacteria, fungal spores, or intact pollen)
PO1: 7
Drivers of cloud droplet number using a synergy of remote sensing and in situ instrumentation during the Cleancloud Helmos OrograPhic site experimeNt (CHOPIN) 1Ecole Polytechnique Federale de Lausanne, Switzerland; 2National Technical University of Athens, Greece; 3Foundation for Research and Technology Hellas, Greece; 4National Center for Scientific Research Demokritos, Greece; 5Stockholm University, Sweden; 6Aarhus University, Denmark; 7Finnish Meteorological Institute, Finland We present results from the CHOPIN (“Cleancloud Helmos OrograPhic site experimeNt”) campaign during autumn & spring (October 2024 – April 2025) at Mt.Helmos in the Peloponnese, Greece. In situ and remote sensing measurements distributed at 6 sites along the lee side of the Mt. Helmos, 4 at the Kalavrita ski Center (altitude ~ 1690 m), 1 at the foothills (altitude ~ 1747 m) and the Helmos Hellenic Atmospheric Aerosol and Climate Change station ((HAC)2) at the mountaintop (altitude ~ 2314 m) constrain aerosol-cloud interaction. We focus on the drivers of droplet formation and the degree to which clouds are aerosol- vs. velocity-limited.
PO1: 8
Interactions between urban heat island (UHI) and urban pollution island (UPI) under key atmospheric conditions 1National Research Council of Italy, Institute of Atmospheric Sciences and Climate (CNR-ISAC), Via Fosso del Cavaliere 100, 00133 Rome, Italy; 2Physics Department, Sapienza University of Rome, Piazzale Aldo Moro 5, 00185 Rome, Italy; 3Physics Department, University of Rome Tor Vergata, Via della Ricerca Scientifica 1, 00133 Rome, Italy This study investigates the interaction between nighttime urban heat island (UHI) and daily urban pollution island (UPI) in Rome, Italy, from 2018 to 2024, focusing on three atmospheric conditions: low wind speed, atmospheric stagnation, and heat waves. Under these conditions, statistically significant negative correlations are found for PM10, PM2.5, NO2, and NO, but only in winter, indicating a seasonal dependency. In contrast, the positive correlation between for O3 remains consistent across seasons. The results suggest that both phenomena peak in intensity under the same conditions, emphasizing the need to consider them jointly when assessing urban environmental impacts.
PO1: 9
Long-term aerosol acidity in the urban center of Athens, Greece 1IERSD, National Observatory of Athens, P. Penteli, 15236, Greece; 2ECPL, Department of Chemistry, University of Crete, 70013 Crete, Greece; 3Center for Atmospheric Research, University of Nova Gorica, SI-5000, Nova Gorica, Slovenija Particle water (liquid water content, LWC) and aerosol pH are important parameters of the aerosol phase, affecting heterogeneous chemistry and secondary aerosol formation. In this context, LWC and pH estimates covering a 6-year period was performed for an urban background site in Athens, Greece. High-temporal variability chemical composition derived from an Aerosol Chemical Speciation Monitor is used for SO42-, NH4+, NO3-, Cl- and organics as input for ISORROPIA II, while levels of the remaining ions are obtained from concurrent daily filter analysis. Results show a clear seasonal variability, linked to sources such as biomass burning and mineral dust transportation.
PO1: 10
Do Medicanes promote high dust concentrations in Italy? – A case study on the 2014 Medicane ‘Qendresa’ 1Institute of Atmospheric Sciences and Climate (ISAC), National Research Council (CNR), Bologna, Italy; 2Institute of Atmospheric Sciences and Climate (ISAC), National Research Council (CNR), Lecce, Italy Medicanes are hurricane-like cyclones that occasionally occur in the Mediterranean. Due to their rotation, they can have the potential to move dust loaden air masses from the Saharan desert towards Europe. Measurements on Monte Cimone of the coarse particle concentration showed very high values on the 7th November, 2014, which is the day on which Medicane Qendresa intensified. We used the WRF-Chem model to simulate dust transport from Sahara towards the Mediterranean basin. Early results show that this Medicane is dispersing dust particles around its core, but also releases sea spray particles under strong wind conditions at ocean surface.
PO1: 11
Heavy Metal(loid) fluxes and microbial community associated to Bulk Atmospheric Deposition in the port area of Ancona 1National Research Council, CNR-IRBIM, largo Fiera della Pesca, 2, 60125, Ancona, Italy; 2Department of Life and Environmental Sciences (DiSVA), Università Politecnica delle Marche, via Brecce Bianche, 60131, Ancona, Italy Bulk Atmospheric Depositions were studied inside the Ancona port. Samples were collected from June 2021 to June 2023 and treated differently for Heavy Metal(loid)s (HMs) and Microbiome (MB) analysis. HMs were determined by GF-AAS, AFS, and DMA in soluble and insoluble fractions, separated by filtration. Microbiome community composition was assessed through 16s RNA sequencing. Depositional Fluxes for each HM was evaluated and sources apportionment was performed through Enrichment Factor and multivariate analysis. Intra and interannual differences were observed for HMs and MB. Shipbuilding activities and traffic (maritime and vehicular) resulted to be the principal anthropogenic sources on the area.
PO1: 12
Characterization of the Atmospheric Microbiome in a Semi-Rural Area of Central Europe Using Flow Cytometry 1Laboratory of Atmospheric Processes and their Impacts, School of Architecture, Civil & Environmental Engineering, École Polytechnique Fédérale de Lausanne, Lausanne, 1015, Switzerland; 2Central Environmental Laboratory, School of Architecture, Civil & Environmental Engineering, École Polytechnique Fédérale de Lausanne, Lausanne, 1015, Switzerland; 3Federal Office of Meteorology and Climatology MeteoSwiss, Chemin de l’Aérologie, CH-1530, Payerne, Switzerland; 4Center for the Study of Air Quality and Climate Change, Institute of Chemical Engineering Sciences, Foundation for Research and Technology Hellas, GR-26504, Patras, Greece The characterization and identification of bioaerosols are crucial for understanding their impact on Earth's systems. Flow cytometry is a powerful tool for bioaerosol analysis. We established a protocol to quantify and characterize bioaerosol samples (n = 39) from a semi-rural site in central Europe (Payerne, Switzerland). A live/dead protocol was optimized using two nucleic acid stains: Syto13 for all cells and Propidium Iodide for dead cells. Following acquisition, a clustering algorithm (FlowSOM) identified populations with low and high nucleic acid content (e.g., bacterial cells and dead bioaerosols or fungal spores and protists, respectively).
PO1: 13
Bicycle-based mapping of black carbon across the streets of Milan 1Institute for Atmospheric Sciences and Climate, National Research Council of Italy, CNR-ISAC, Italy; 2EPIGET Lab, Department of Clinical Science and Community Health, Dipartimento di Eccellenza 2023-2027, Università degli Studi di Milano; 3Dipartimento di Ingegneria 'Enzo Ferrari', University of Modena and Reggio Emilia,; 4UOC Qualità dell’Aria, Agenzia Regionale Protezione Ambiente (ARPA) Lombardia Black carbon (BC) in urban areas mainly originates from vehicular emissions, residential heating, and industry. Due to its climate and health impacts, the European Environmental Agency classifies BC as a pollutant of emerging concern. Fixed monitoring stations lack the spatial resolution to capture BC variability, making mobile measurements a valuable alternative. This study, as part of RI-URBANS project, used bicycle-mounted microAeth® devices to measure BC in Milan across four seasons. Results showed higher concentrations near roads, varying by season and time of day. The study aims to develop a street-level land use regression (LUR) model to improve air quality assessments.
PO1: 14
URBAN EMISSIONS FATE TOWARDS SECONDARY AEROSOL FORMATION; A CHAMBER STUDY 1Tampere University, Finland; 2University of Helsinki, Finland Vehicles, cooking emissions & volatile chemical products emit substantial quantities of volatile, semi-volatile & intermediate-volatility organic compounds, which contribute to considerable secondary organic aerosol production. Once VOCs are released into ambient atmosphere, they undergo oxidation, partition between gas & particle phases & ultimately integrate into primary and secondary organic aerosols, thereby introducing uncertainties into health risk assessments. Here, chamber experiments were conducted for various VOC precursors (daytime & nighttime) under different conditions & NOx levels & the biogenic impact factors on aerosol yields and composition. Additionally, a low NOx future scenario was explored, assuming reductions in emissions from incomplete combustion.
PO1: 15
Antibacterial electrospun wound dressing with flame-made Ag/SiO2 nanoparticles 1Department of Microbiology, Tumor and Cell Biology, Karolinska Institutet, Stockholm, Sweden; 2Department of Chemistry, Stockholm University, Sweden; 3Department of Medicine, Karolinska Institutet, Stockholm, Sweden; 4Department of Cell and Molecular Biology, Karolinska Institutet, Stockholm, Sweden Infections significantly hinder wound healing, leading to severe complications and increased healthcare costs. The rise of antibiotic resistance necessitates innovative solutions. We present an approach using antimicrobial nanomaterials, specifically nanosilver, in wound dressings. Our research developed electrospun nanofibrous membranes from polyvinyl alcohol (PVA) and chitosan, infused with Ag/SiO2 nanoparticles via flame spray pyrolysis. These dressings demonstrated potent antibacterial activity against MRSA and P.aeruginosa in ex-vivo and human skin models while maintaining biocompatibility. This novel strategy offers a scalable, cost-effective, and antibiotic-free solution for advanced wound care, addressing a critical need in the medical field.
PO1: 16
Decreasing or increasing pollution in the Mediterranean atmosphere? 16 years of black carbon observations at the Monte Cimone GAW Global Station integrated with FLEXPART and COPERNICUS products. 1Institute of Atmospheric Sciences and Climate – National Research Council of Italy, Bologna, Italy; 2Norwegian Institute for Air Research (NILU), Kjeller, Norway Black carbon (BC) is a key climate-warming aerosol, with its impact varying across space and time. In the Mediterranean, a climate change hotspot, long-term observations are essential to understand BC trends. At Monte Cimone (CMN), BC has been continuously monitored since 2007, revealing seasonal variations with higher summer concentrations. FLEXPART simulations show increased summer biomass burning contributions, while ERA5 data highlight meteorological influences. A long-term decline in BC was observed, though recent trends suggest a reversal since 2016–2017, potentially linked to regional warming. Further analysis will explore how meteorological changes and emissions affect BC variability at CMN.
PO1: 17
Effects of Soil Amendments on Soil Carbon Sequestration Stability and Nutrient Availability in Fukuyama Lettuce: Applications of Biochar and Black Soldier Fly Frass Department of Environmental Engineering, National llan University, Yilan City, 260007, Taiwan, Taiwan This study examines the effects of biochar and black soldier fly frass as soil amendments on Fushan lettuce. Field experiments revealed that optimal application ratios enhance soil carbon sequestration stability and nutrient supply, promoting crop growth. Significant increases in lettuce leaf length and width were observed with these treatments. While total soil nitrogen content increased slightly, total carbon levels decreased, indicating that microbial decomposition released some carbon into the atmosphere, impacting soil carbon content.
PO1: 18
Investigating New Particle Formation and Growth over an Urban Location in the Eastern Mediterranean Weizmann Institute, Israel New Particle Formation (NPF) is a key atmospheric process affecting cloud condensation nuclei and climate. However, the chemical species driving NPF and growth in the Mediterranean Basin remain uncertain. This study conducted high-resolution aerosol, gas, and particulate composition measurements at a semi-urban site in the eastern Mediterranean (Rehovot, Israel) in 2021 and 2023. A hybrid source apportionment analysis identified ammonium sulfate and oxidized organics in daytime nucleation, with semi-volatile species contributing to growth. Nighttime events involved only semi-volatile species and ammonium sulfate. Chemical imaging confirmed internal particle heterogeneity, supporting hybrid PMF findings and highlighting the role of gas-phase photochemistry in NPF.
PO1: 19
The Italian Automated Lidar Ceilometer Network ALICENET: From Near Real-time Monitoring to Long-term Characterisation of Aerosol Vertical Distributions across Italy 1CNR-ISAC, Italy; 2ARPA Valle d'Aosta, Italy; 3CNR-IMAA, Italy ALICENET, the Italian Automated Lidar Ceilometer Network, is a wide cooperative consortium involving several regional environmental protection agencies, universities, research centres and private companies. Through active remote sensing, ALICENET continuously (24/7) monitors aerosol vertical distributions across the country. A key strength of ALICENET is its centralised data processing, which converts raw instrumental data into quality-controlled information on aerosol properties and vertical layering. This contribution aims at presenting the network and its quantitative capabilities, complementing other aerosol measurements and model-based approaches to characterize aerosol processes at different spatial and temporal scales across Italy and Central Mediterranean.
PO1: 20
State of the art of lunar sun-photometry algorithms and application to Izaña 2023 MAPP campaign 1National Research Council, Institute of Atmospheric Sciences and Climate, Rome, Italy; 2Department de Fisica de la Terra i Termodinamica, Universitat de Valencia, Burjassot, 46100, Spain; 3Izaña Atmospheric Research Center, Agencia Estatal de Meteorología (AEMET), Santa Cruz de Tenerife, Spain; 4Physikalisch-Meteorologisches Observatorium Davos, World Radiation Center (PMOD/WRC), Switzerland; 5Group of Atmospheric Optics (GOA-UVa), Universidad de Valladolid, 47011, Valladolid, Spain; 6Deutscher Wetterdienst (DWD), Meteorologisches Observatorium Lindenberg (MOL), Germany; 7National Research Council, Institute of Polar Sciences, Bologna 40129, Italy; 8National Institute of R&D for Optoelectronics, INOE, Magurele, Romania; 9SERCO s.p.a., Rome, Italy; 10Universidad de la República, Rivera 1350, Salto, 50000, Uruguay In this work we present the state of the art of lunar sun- photometry algorithms. We will intercompare the aerosol optical depth values retrieved with the 4 actually available algorithms from measurements taken by the standard instruments of the 3 international sun-photometer networks, SKYNET, AERONET and PFR, simultaneously operating during an international MAPP-EMPIR campaign held in 2023 in the Izaña Observatory in Tenerife, Canary Islands
PO1: 21
Ground-Based Comparison and Validation of ATLID/EarthCARE L2 Aerosol and Cloud Products: Integrating E-PROFILE and AERONET Data 1Andalusian Institute for Earth System Research (IISTA), Univerity of Granada, Spain; 2Applied Physics Department, University of Granada, Granada 18071, Spain; 3Group of Atmospheric Optics (GOA-UVa), University of Valladolid, 47011, Valladolid, Spain; 4Laboratory of Disruptive Interdisciplinary Science (LaDIS), Valladolid, Spain; 5Federal Office of Meteorology and Climatology, MeteoSwiss, Payerne, Switzerland The EarthCARE satellite, a joint ESA-JAXA mission launched in May 2024, aims to improve our understanding of cloud-aerosol-radiation interactions. This study validates aerosol products from EarthCARE’s ATLID lidar using ground-based data from E-Profile and AERONET. Over 800 satellite overpasses have been analyzed, comparing ATLID-derived Level 2 products with direct and GRASP-inverted ground measurements. Key validated parameters include aerosol optical thickness, backscatter/extinction profiles, and PBL height, retrieved using STRATfinder. The synergy between spaceborne and ground-based observations enhances the accuracy of aerosol characterization, contributing to improved climate and atmospheric studies.
PO1: 22
Optical and microphysical properties of local and long-range transport biomass burning aerosols with remote sensing techniques 1University Federico II of Naples, Italy; 2Consiglio Nazionale delle Ricerche, Istituto di Metodologie per l’Analisi Ambientale (IMAA-CNR) In summer of 2017, wildfires near Mount Vesuvius (Italy) and in British Columbia (Canada) led to biomass burning aerosols over the ACTRIS National Facility of Naples. Using lidar and sun-photometer data, a comparison between fresh (local) and aged (transported) particles was carried out. Local aerosols had higher AOD, smaller particles and stronger absorption. Lidar data showed a single layer for local fires and three layers for Canadian fires. The stratospheric layer of Canadian smoke had high depolarization (about 30%). Findings emphasize aging effects on aerosol properties and the importance of multi-instrument observations for complete aerosol characterization.
PO1: 23
Validation of aerosol extinction and mass profiles derived from elastic LIDARs using in-situ measurements 1MeteoSwiss, Switzerland; 2Institut Pierre Simon Laplace, CNRS, France; 3PSI Center for Energy and Environmental Sciences, Switzerland; 4Norwegian Meteorological Institute, Oslo, Norway; 5Laboratory for Air Pollution/Environmental Technology, Empa, Switzerland The E-Profile network can help to fill observational gaps and reduce uncertainties in the global aerosol mass concentration. The V-profile retrieval produce extinction and mass profiles from low-power lidars to quantify the aerosol mass (e.g. dust, ash or biomass burning). This study evaluates the quality of this new product by comparisons with in-situ observations in Switzerland. The 10 years timeseries at Kleine Scheidegg and Jungfraujoch offer in-situ data outside the blind zone of the Lidar, whereas comparison at Payerne are done in well-mixed atmosphere. Improvements of the choice of the lidar ration and the extinction to mass coefficient are described
PO1: 24
Deep-Pathfinder algorithm for ground-based assessment of ATLID/EarthCARE L2 aerosol product 1Andalusian Institute for Earth System Research (IISTA-CEAMA), Granada, 18071, Spain; 2Applied Physics Department, University of Granada, Granada 18071, Spain; 3Federal Office of Meteorology and Climatology, MeteoSwiss, Payerne, Switzerland Understanding the vertical structure of the atmosphere is essential for monitoring clouds and aerosols. The planetary boundary layer (PBL) plays a key role in climate dynamics, and its retrieval benefits from both satellite and ground-based observations. This study evaluates Deep-Pathfinder, a U-Net-based algorithm, for estimating PBL height from ceilometer data. Comparisons with EarthCARE-derived products over Granada show good agreement, with some discrepancies likely due to wavelength differences. Deep-Pathfinder was adapted to be applied on historical data from Granada E-Profile station. Its potential application across the E-Profile network highlights its value in enhancing remote sensing atmospheric profiling capabilities.
PO1: 25
Enhanced Fire Detection in Industrial Complexes Using Scanning LiDAR Technology 1Advanced Institute of Convergence Technology, Korea, Republic of (South Korea); 2Pukyong National University, Republic of (South Korea); 3Gangneung-Wonju National University, Republic of (South Korea); 4Samwoo TCS Co., Republic of (South Korea); 5Sejong University, Republic of (South Korea); 6Korea University, Republic of (South Korea) LiDAR-based fire detection improves real-time monitoring by overcoming limitations of conventional imaging. A dual-wavelength scanning LiDAR was developed, enabling 360° observation and PM concentration analysis. Field tests in Siwha Industrial Complex confirmed its potential for early fire detection.
PO1: 26
Integrating remote sensing and in-situ measurements to assess the impact of PBL dynamics on air pollution in Milan, Po valley (Italy) 1Department of Physics and Astronomy, University of Bologna, Bologna, 40126, Italy; 2Institute of Atmospheric Sciences and Climate, National Research Council of Italy, Bologna, 40129, Italy; 3nstitute of Atmospheric Sciences and Climate, National Research Council of Italy, Rome, 00133, Italy The study investigates the influence of the Planetary Boundary Layer (PBL) on air pollution in Milan, located in the Po Valley, one of the most polluted regions in Europe. Combining remote sensing and in-situ measurements from 2023, it examines aerosol properties and vertical mixing. The mixed aerosol layer height shows a strong anti-correlation with black carbon concentrations, highlighting the role of PBL dynamics in pollutant dispersion. While primary emissions are strongly affected by vertical mixing, secondary aerosols show more complex patterns. By integrating both techniques, the study offers valuable insights into emission, dilution, and atmospheric transport for air quality monitoring.
PO1: 27
Remote Sensing Observations of Aerosol-Cloud Interactions in a Nitrogen Polluted Environment 1Faculty of Civil Engineering and Geosciences, Delft University of Technology, Netherlands, The; 2Climate and Atmosphere Research Center, The Cyprus Institute, Nicosia 2121, Cyprus; 3Meteorology and Air Quality (MAQ), Wageningen University and Research (WUR), the Netherlands; 4Centre for Isotope Research (CIO), University of Groningen, Groningen 9747 AG, the Netherlands Aerosol-cloud interactions (ACI) are a significant source of uncertainty in climate projections. The Cloud-Aerosol Interactions in a Nitrogen-dominated Atmosphere (CAINA) project particularly focuses on understanding how reactive nitrogen influences ACI by bringing together in-situ observations, remote sensing and modelling. This study focuses on the quantification of cloud impacts caused by these aerosol particles by bringing together remote sensing observations and aerosol speciation measurements at the Cabauw Observatory (Netherlands).
PO1: 28
Synergy of PollyXT Lidar & sun/sky photometer to retrieve aerosol properties utilizing GRASP algorithm in Limassol, Cyprus 1Eratosthenes Centre of Excellence, Limassol, 3012, Cyprus; 2Department of Civil Engineering & Geomatics, Cyprus University of Technology, Limassol, 3036, Cyprus; 3GRASP SAS, Villeneuve-d’Ascq, 59650, France Limassol city in Cyprus is strongly influenced by the aerosol transport from neighboring regions. In this study selected cases of different atmospheric conditions will be used to characterize aerosol layers in Limassol by retrieving optical and microphysical properties. The Generalized Retrieval of Atmosphere and Surface Properties (GRASP) algorithm is used for the retrieval of particles’ size distribution, complex refractive index, AOD and the aerosol vertical distribution. Dust, smoke, and marine-dominated cases were analyzed and compared with measurements from the instruments. The synergy of PollyXT Polarization Raman Lidar and the CUT-TEPAK AERONET enables the characterization of fine and coarse mode aerosols.
PO1: 29
Assessment of microplastic particle exposure in indoor football halls by correlative microscopy 1Federal Institute for Occupational Safety and Health, Germany; 2Norwegian Institute of Public Health, Norway; 3Utrecht University, Netherlands A correlative microscopy approach was developed to assess inhalative exposure to micro- and nanoscale plastics (MNP) in complex indoor aerosols. Scanning electron microscopy (SEM) and Raman microscopy were integrated with AI-driven software for precise particle identification and quantification. This method was applied to aerosol samples from indoor football halls in Norway, comparing exposure to particles from natural (olive stone) and synthetic (tyre rubber) turf fillings. The approach enables accurate airborne concentration estimates of MNPs, addressing key challenges in exposure assessment and potential health risks for indoor environments.
PO1: 30
Optimized Flotation Separation for the Characterization of Airborne Microplastics 1Department of Chemistry, University of Rome “Sapienza”, Rome, 00185, Italy; 2Department of technological innovations and safety of plants, products and anthropic settlements, Italian Workers‘ Compensation Authority, Rome, 00143, Italy The European Commission's 2020 Action Plan aims to improve air quality also by reducing airborne microplastics (MPs), which pose health risks, including occupational diseases due to inhalation of plastics like polyvinyl chloride. MPs can also carry toxic contaminants, leached through degradation or abrasion. This study presents an optimized flotation technique for isolating MPs from particulate matter (PM), followed by GC-MS and HPLC-MS/MS analysis for contaminants' characterization. The method was validated using NIST SRM 2585 and applied to airborne PM samples. Results showed that flotation effectively separates MPs, enabling the identification of toxic additives, highlighting the method's potential for exposure studies.
PO1: 31
Inhaled nanoplastics as vectors for benzopyrene: Unveiling a synergistic mechanism of airway toxicity using air-liquid interface exposure 1Unit of Functional and Adaptive Biology, CNRS UMR 8251, Université Paris Cité, Paris, 75013, France; 2Cellular and Molecular Imaging Platform, US25 Inserm-3612 CNRS, Université Paris Cité, Paris, 75006, France; 3CSIC-Instituto de Catálisis y Petroleoquímica. 28049, Madrid, Spain; 4Laboratoire de Chimie et Biochimie Pharmacologiques et Toxicologiques, CNRS UMR 8601, Paris, 75006, France Respiratory diseases have highlighted environmental concerns, with plastics identified as key pollutants due to their interaction with air contaminants. We aimed to assess the toxicity of polyethylene terephthalate nanoplastics (PET-NPs) contaminated with benzo(a)pyrene (BaP). We coated PET-NPs with BaP, and exposed the Calu-3 cell line to single and repeated exposures to the pollutants alone or combined at the air-liquid interface. Transmission electron microscopy showed that PET-NPs were internalized by the cells. BaP and BaP-coated PET-NPs increased cytochrome P1A1 activity, confirming BaP bioavailability when adsorbed onto PET-NPs. Only BaP-coated PET-NPs triggered antioxidant and pro-inflammatory responses, suggesting a synergistic mechanism of toxicity.
PO1: 32
Atmospheric microplastics modelling and quantification using Gibbs sampler 11Institute of Information Theory and Automation, Czech Academy of Sciences, Prague, 18200, Czech Republic; 2NILU, ATMOS, Norway Atmospheric microplastics budget is estimated and associated uncertainties are quantified using microplastics measurement from Brahney et al. (2020). Since the number of unknowns in the domain is larger than the number of measurements, we regularize the space of possible solutions using spatial-temporal patterns from previously reported sources and using source-receptor-sensitivities from FLEXPART 11. The optimization of measurements is based on Gibbs sampling method. We construct a hierarchical Bayesian model whose parameters are optimized using Gibbs sampler. The total estimated emissions are 1336 Gg/y, while the associated uncertainty is almost on the same level as emissions.
PO1: 33
Airborne Microplastic: Dry vs. Wet Precipitation Effects and Morphological Evaluation University of Porto, Portugal This study examines the impact of precipitation on airborne microplastic deposition in Porto, Portugal, by comparing concentrations before and during rainfall. Samples were collected in summer (June-July 2024) and separated into five size fractions for analysis using Raman spectroscopy and SEM imaging. Preliminary results show: wet deposition increases microplastic accumulation by facilitating particle washout, while dry deposition results in slower but prolonged accumulation. Morphological analysis revealed blue microplastics and fibers as the most common colors, likely due to the stability of blue dye. These findings emphasize the importance of standardized monitoring and research on seasonal variability and transport mechanisms.
PO1: 34
Analysis of microplastics in airborne particulate matter (PM) in Krakow, south Poland: Review of separation techniques, in vitro toxicity, and health impacts 1AGH University of Kraków, Poland; 2Oil and Gas Institute – National Research Institute in Kraków, Poland Microplastics (MPs) are widespread pollutants traveling through various pathways, with air being a key vector. Their presence in airborne particulate matter (PM) raises health concerns, particularly regarding respiratory and cardiovascular diseases. This study examines MP separation, identification, and characterization in PM collected in Krakow, Poland, emphasizing in vitro toxicity research. The review explores PM sampling, MP extraction, and analytical methods while highlighting the need for standardized protocols. Potential health effects, including oxidative stress and inflammation, are discussed. This study provides a methodological framework to support further research on MPs' impact on air pollution and human health.
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Indoor and Outdoor Airborne Microplastics in School Settings 1SRI Center for physical sciencies and technolofy, Lithuania; 2Institute of Epidemiology, Helmholtz Zentrum München, 85764 Neuherberg, Germany; 3The Lisbon Council, 1040 Brussels, Belgium; 4Institute for Anthropological Research, 10000 Zagreb, Croatia Indoor air quality in schools is crucial for children's health, as their developing respiratory systems and higher breathing rates make them more vulnerable to pollutants. This study, conducted in a school in Vilnius, Lithuania, examines the presence and characteristics of microplastics (MPs) in indoor air. The results show that MPs in the 100–500 µm size range dominate indoors, comprising up to 60% of total particles, with black and blue being predominant. Outdoors, MPs are generally smaller (50–250 µm) and primarily black and white. Acknowledgment: This project (EDIAQI) is funded by the EU’s Horizon Europe program (Grant No. 101057497).
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Microplastic particles in atmospheric bulk deposition samples in Berlin, Germany 1TU Berlin, Germany; 2University of Bayreuth, Germany Monthly atmospheric bulk deposition samples of microplastic particles were collected for one year in Berlin, Germany, and analyzed to identify polymer types, sizes, shapes and colors of atmospheric MP particles. Bulk deposition rates varied from approximately 300 to 1900 m-2 day-1, with the lowest deposition rates in summer. Precipitation was not well-correlated with deposition rates, indicating a contribution of both dry and wet deposition. Overall, polypropylene (PP) and polystyrene (PS) were the most abundant polymer types, however, the abundance of polymers was seasonally variable. Additionally, differences in polymer types, shape and color were found in different size fractions.
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Quantification of Near Real-Time Tyre Wear Particles in the Ambient PM2.5 Using Online Aerosol Mass Spectrometer 1MRC Centre for Environment and Health, Environmental Research Group, Imperial College, London, W12 0BZ, UK; 2NIHR HPRU in Environmental Exposures and Health, Imperial College, London, W12 0BZ, UK This study presents a novel method for near real-time quantification of tyre wear particles (TWPs) in ambient PM2.5 using an online aerosol mass spectrometer. The method uses cryo-milled tyre particles to create reference mass spectra from ACSM for ambient TWP monitoring. The analysis at an urban London site showed TWP concentrations of 0.22 ± 0.58 µg/m³, highlighting a critical need for updated regulatory measures. This approach fills a significant gap in TWP emissions measurement, aiding policymakers in understanding human exposure risks and developing public health protection strategies.
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Size segregated, highly-time resolved elemental source apportionment at two European transportation hotspots 1PSI Center for Energy and Environmental Sciences, Villigen PSI, 5232, Switzerland; 2Institute of Environmental Assessment and Water Research (IDAEA-CSIC), Barcelona, 08034, Spain; 3Aix-Marseille University, Marseille, 13007, France; 4National Centre of Scientific Research “Demokritos”, Ag. Paraskevi, 15310, Greece; 5Regional Agency for Environmental Protection of Lombardy (ARPA), Milan, 20124, Italy; 6Department of Physics, University of Milan and INFN-Milan, Milan, 20133, Italy The transport sector significantly contributes to elemental emissions in particulate matter (PM), with road traffic and shipping as key sources. This study analyses emissions through two monitoring campaigns using high-time resolution elemental data. Measurements were conducted with an Xact 625i ambient metals monitor in Barcelona and Milan, capturing PM2.5 and PM10 with a switching inlet for size-segregated sampling. SoFi Pro software is used for source apportionment, interpolating between size fractions. This approach aims to differentiate emissions such as traffic, shipping, and industry, revealing distinct patterns in elemental composition based on size, source, and environmental influences at each site.
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Electrical Charging State and Effective Density of Brake Wear Particles 1Department of Ergonomics and Aerosol Technology, Lund University, Sweden; 2Aerosol Physics Laboratory, Physics Unit, Tampere University, Finland; 3Department of Industrial and Mechanical Sciences, Lund University, Sweden; 4Nanolund, Lund University, Sweden Brake wear particles, generated from the pad – disc contact, are a significant contributor to PM10 in urban areas. These particles have recently been suggested to be highly charged, which may have implications on their atmospheric lifetime and deposition in the lung. This work investigates how the charging state of brake wear particles is influenced by brake pad type and braking conditions. We find that brakes produce both positively and negatively charged particles, but that negatively charged particle emissions dominate in all studied cases except one, indicating that both pad type and braking conditions influence brake wear particle charging state.
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Investigations of Gaseous Emissions from Vehicle Braking Process with Chemical Ionization Mass Spectrometry 1Department of Environmental Science, Stockholm University, Sweden; 2Bolin Centre for Climate Research, Stockholm, 11418, Sweden; 3Department of Environmental Science, Stockholm University, Stockholm, 11418, Sweden Here, we focus on the characterization of volatile and semi-volatile organic compounds emitted from the braking process of vehicles. For the first time, we have utilized the pin-on-disc tribometer, combined with the high-resolution time-of-flight chemical ionization mass spectrometer and aerosol size distribution instruments to characterize gaseous emissions and ultrafine particles from the braking process of semi-metallic brake pads used in heavy-duty vehicles. Our results show that as the temperature at the brake pad-disc interface rises, more oxidized volatile organic compounds as well as semi-volatile organic compounds (SVOCs) are released. The SVOCs nucleate and grow into larger particles.
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On-Road Measurements of Wetness, Road Dust and Tyre Wear Particle from Truck 1Chalmers; 2Lunds University; 3RISE Non-exhaust particle emissions are an increasing danger to air quality mainly in urban areas. This study measures both particle concentrations close to a truck wheel in traffic and other parameters during the same occasion that would improve the understanding of those relationships. Due to a commonly wet weather in this part of the world splash and spray from the wheel is analysed by a wetness sensor inside the wheelhouse at all times. The sensor data is then used to start and stop the particle measurements in order to protect the OPS from damage.
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Identification of Non-Exhaust Emissions in Laboratory and Field Measurements 1Department of Mechanical Engineering, Institute of Chemistry and Environmental Engineering, University of the Bundeswehr Munich; 2HDC Blueprints GmbH; 3Department of Mechanical Engineering, Institute of Energy and Power Train Technology, University of the Bundeswehr Munich Vehicle-derived particulate matter (PM) consists of exhaust and non-exhaust emission. Non-exhaust emissions like brake wear particles (BWPs) have gained attention due to their metal-rich composition (Fe, Cu, Ba). Using single-particle mass spectrometry (SPMS), we characterized non-exhaust emissions from a GTR24 inspired brake dynamometer and compared them with ambient measurements near a highway. SPMS identified elevated Ba- and Fe-containing particles as BWP markers. Simultaneous background measurements at a rural site confirmed their traffic-related origin. The mobile SPMS system enables real-time non-exhaust emission detection, providing insights into source apportionment, transport, and transformation, supporting EURO7 regulations on non-exhaust emissions.
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An experimental characterization of PM emissions from railway braking events for the design of sustainable brake pads 1STEMS - CNR, Italy; 2CoFren S.r.L., Italy; 3DICMAPI - University of Naples "Federico II", Italy Non-exhaust PM emissions from transports and particularly from rail transport are steadily increasing over years. The present work reports the application of an experimental procedure for investigating PM emissions produced by railway vehicles brake pads. Different brake pad materials have been tested during tests that simulates the real route of typical trips travelled by suburban trains. Relationships between the main parameters of the brake events and PM10, PM2.5 and PM1 emissions were detected. The results can be useful to develop the optimal brake pad formulations with low-environmental impact and to set specific measures on pads composition for brake-related non-exhaust emissions.
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Chemical and Morphological Characterisation of Particulate Matter from Brake Pads 1Department of Chemistry and NIS Interdepartmental Centre, University of Turin, Italy; 2Raicam Industrie S.r.l., Bruzolo, Italy; 3Institute of Science and Technology for Sustainable Energy and Mobility (STEMS) - CNR, Italy; 4Faculty of Engineering and Environment, Northumbria University, Newcastle upon Tyne, United Kingdom Non-exhaust emissions (NEE) from braking systems contribute to over 50% of vehicle particulate matter (PM). The Euro 7 standards (UN GTR-24) impose a 7 mg/km/vehicle limit, pushing the industry towards low-wear materials. RAICAM Industrie S.R.L. investigates PM10 and PM2.5 emissions from Low Steel (LS) and Non-Asbestos Organic (NAO) brake pads, tested against grey cast iron and coated discs. PM samples were analysed for morphology, chemical composition, number, and mass using SEM-EDS, XRD and other techniques. Results show LS pads emit more PM than NAO. Ongoing research aims to better understand emission mechanisms and develop effective mitigation strategies.
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Chemical composition of brake wear particles – results from two different brake pads 1Finnish Meteorological Institute, Finland; 2VTT Technical Research Centre of Finland, Finland; 3Aerosol Physics Laboratory, Physics Unit, Tampere University, Finland Due to stricter regulations, particulate exhaust emissions from vehicles have been decreasing. As a result, non-exhaust emissions, including those from brakes and tires, contribute more significantly to the total particulate matter concentrations in urban areas. This study focuses on the particulate emissions from two different types of brake pads, with an emphasis on the chemical composition of the emitted particles. Brake particles were produced by using a dynamometer with the WLTP brake cycle. Brake wear particles emitted by both brake pads consisted mostly of Fe. Particles contained also Cu, Zn, Sn and Ba, the composition depending on the tested pad.
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Impact of Brake Pad Composition on Non-Exhaust Particle Emissions Research Centre for Energy, Environment and Technology (CIEMAT), Avda. Complutense, 40, 28040 Madrid, Spain Non-exhaust particle emissions are a significant source of air pollution, particularly those generated by brake wear. This study examines how different brake pad formulations affect particle emissions. Controlled braking tests were conducted to measure the concentration and composition of emitted particles. The results show differences of up to two orders of magnitude in ultrafine particle emissions depending on the formulation, as well as variations in their composition. These findings highlight the influence of friction materials on the quantity and characteristics of the generated emissions.
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Size distributions and black carbon emissions from two comparable brake pads 1Tampere University, Finland; 2Finnish Meteorological Institute, Finland; 3VTT Technical Research Centre of Finland, Finland Brake emissions are a significant part of non-exhaust emissions (NEE), which are not yet regulated. Brake emissions have been found to significantly impact urban air quality especially particulate matter. In our study we measured brake emissions utilizing a brake dynamometer at VTT facilities. WLTP-brake cycle was chosen for the test with variations of it which simulate regenerative braking available on electric vehicles and with extra weight of 300kg. Regenerative braking was found have a significant effect on PM and BC emissions where as importance of extra weight is not as prominent.
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Characterisation and Tribological Performance of Brake Wear Emissions 1Università degli studi di Torino, Italy; 2KTH Royal Institute of Technology, Sweden; 3ITT Friction Technologies, Italy; 4UniTo-ITT JointLab, Italy The study analyzes particulate emissions from brake wear, a major source of urban particulate matter. Using a "Pin on Disc" (PoD) tribometer, three types of brake pads were tested on different discs to measure particle size distribution (10-560 nm), number concentration, and the chemical composition of collected PM10.
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The Effect of Collection Systems in TRWP Measurements: Impacts on Physical and Chemical Characterization 1Department of Physics, University of Milano, Italy; 2Institute of Vehicle Concepts, German Aerospace Center, Germany; 3Institute of Combustion Technology, German Aerospace Center, Germany This study examines impact of collection system design to the physical and chemical properties of tire and road wear particles (TRWP). A controlled roller test bench experiment compared a housing-based system, which encapsulates the tire, to a nozzle-based system, where the tire remains exposed. Identical test conditions were maintained using a novel measurement methodology. Results show that the housing-based system yields 3 to 10 times higher particle number concentrations than the nozzle-based system. Differences in particle size distribution and elemental composition (Micro-XRF) highlight the need for standardized TRWP collection protocols to improve accuracy in environmental impact assessments.
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Evaluating the Repeatability of Tire Wear Particle Measurements in a Novel Housing-Based Collection System 1Department of Physics, University of Milano, Italy; 2Institute of Vehicle Concepts, German Aerospace Center, Germany; 3Institute of Combustion Technology, German Aerospace Center, Germany Accurate and repeatable measurement methodologies are essential for ensuring comparability and reliability in non-exhaust emission assessments. This study investigates the repeatability of a novel housing-based tire road wear particles (TRWP) sampling system under controlled roller test bench conditions. High-resolution particle number concentration (PNC) measurements were conducted across three speed sections of a standardized driving cycle. Results demonstrated increased concentrations and reduced coefficient of variation (CoV) at higher speeds, improving measurement stability and minimizing variability. These findings emphasize the necessity of standardized procedures to enhance TRWP data comparability and facilitate interlaboratory reproducibility.
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High Time Resolution Quantification of PM2.5 Oxidative Potential and Reactive Oxygen Species 1Imperial College London, United Kingdom; 2University of Basel; 3NIHR HPRU in Environmental Exposures and Health, Imperial College London, UK Exposure to airborne PM has been attributed to a wide range of adverse health impacts and millions of premature deaths annually. Recent studies have widely suggested that oxidative potential (OP), defined as the capability of particles to catalytically produce reactive oxygen species (ROS) with subsequent depletion of antioxidants, is key to determining the health effects of PM exposure.In this work, we discuss the deployment of two high time resolution instruments which quantify OP (OOPAAI) and ROS (OPROSI) across London. We reveal the dyanamics of OP as well as the PM components and major source contibutors to OP.
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International intercomparison of methodologies for measuring the oxidative potential of PM using ascorbic acid assay 1University Grenoble Alpes, France; 2European Commission, Joint Research Centre (JRC), Ispra, Italy; 3MRC PHE Centre for Environment and Health, King's College London, UK; 4Institute of Chemical Engineering Sciences, Foundation for Research and Technology Hellas, Patras, Greece; 5Laboratory of Atmospheric Processes and their Impacts, Institute of Environmental Engineering, École Polytechnique Fédérale de Lausanne, Switzerland; 6Institute for Environmental Research and Sustainable Development, National Observatory of Athens, Greece; 7Institute of Environmental Assessment and Water Research (IDAEA-CSIC), Barcelona, Spain; 8IRAS, Division of Environmental Epidemiology, Utrecht University, The Netherlands; 9Division of Environmental Health and Risk Management, Earth and Environmental Sciences, University of Birmingham, UK A new international intercomparison of oxidative potential of PM protocols using AA assay has been launched, as part of a joint RI-URBANS and ACTRIS effort. This work relies on the participation of 28 different laboratories in the world to test a simplified OP-AA protocol protocol with their own equipment. The simplified protocol was elaborated in IGE by testing different key parameters, which differ in the existing protocols. The intercomparison started on March 24th with the shipment of reagents and samples. After gathering the results, data treatment to assess their reproducibility was done anonymously by the EU Joint Research Center.
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Oxidative potential of fine aerosols in sleeping micro-environments: a one-year study in Lisbon area dwellings 1Health & Technology Research Center (H&TRC), Escola Superior de Tecnologia da Saúde (ESTeSL), Instituto Politécnico de Lisboa (IPL), Portugal; 2Centro de Ciências e Tecnologias Nucleares (C2TN), Instituto Superior Técnico, Universidade de Lisboa, Portugal; 3Instituto Politécnico de Setúbal, Escola Superior de Tecnologia de Setúbal, Portugal; 4Faculdade de Engenharia, Universidade Lusófona - Centro Universitário Lisboa, Portugal; 5Department of Environment and Planning, Centre for Environmental and Marine Studies (CESAM), University of Aveiro, Portugal; 6HyLab - Green Hydrogen Collaborative Laboratory, Portugal Recent studies show that indoor air can be more polluted than outdoor air, however sleeping micro-environments are often overlooked in exposure assessments. This study evaluated the Oxidative Potential (OP) of PM2.5 in 30 homes in the Lisbon metropolitan area. Results indicate that in 90% of cases, indoor OP (285±167 pmol.min⁻¹.m⁻³) was higher than outdoor OP (135±101 pmol.min⁻¹.m⁻³). Further research is needed to identify pollution sources affecting OP in fine aerosols to reduce human exposure and mitigate health impacts in sleeping environments.
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Particle Toxicity and its Drivers in India: from Regional to Local Spatial Scales Indian Institute of Technology Bombay, India PM mass concentration may not be an appropriate metric to determine the health effects of particles. Oxidative potential (OP) can be used to assess the ROS (reactive oxygen species)--generating capacity of PM. The present study aims to examine particle toxicity of PM2.5 measured across multiple spatial scales in India through a dithiothreitol assay. Water-extracted PM samples were subjected to acellular Dithiothreitol (DTT) assay for toxicological analysis. Particle toxicity measured through OPDTT ranges from 0.6 - 5.4 nmol min-1 m-3, while the PM2.5 varies between 89 - 446 µg/m3. Carbonaceous and elemental species are the major drivers responsible for ROS generation.
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Global Health Map: Coupling EMAC and KM-SUB-ELF to estimate air pollution health effects using accurate iron soluble fractions 1Max Planck Institute for Chemistry, Mainz, Germany; 2Institute of Energy and Climate Research, Jülich, Germany We present a multi-scale modelling approach to link large-scale atmospheric chemistry-climate models with small-scale multiphase kinetic models to derive a global health map. We use the chemistry-climate model EMAC to derive air pollutant distributions with various time resolutions, and the lung model KM-SUB-ELF to simulate the production of reactive oxygen species, hydroxyl radicals and damage to biomolecules in the human lung.
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Real-Time Oxidative Potential Monitoring: Performance of DTT and FOX-Based Systems 1Center for Energy and Environment, IMT Nord Europe, Institut Mines-Télécom, Université de Lille, Lille, France; 2Pollutants Metrology Department, Institut National de Recherche et de Sécurité (INRS), Vandœuvre-lès-Nancy, France; 3Department of Occupational and Environmental Health, Center for Primary Care and Public Health (Unisanté), University of Lausanne, Epalinges, Switzerland Our study presents on-line methods to measure OP of both particulate and gaseous species and compares the results obtained using two different assays: dithiothreitol (OPDTT) and Ferrous-Orange Xylenol (OPFOX). The comparison was conducted in three main phases : (1) laboratory evaluation of the analytical systems' response using model compounds (e.g., H2O2, Cu2+, 1,4-napthoquinone, welding fumes) ; (2) comparison of the sampling efficiency of both systems and on-line measurement of controlled H2O2 and CuSO4 concentrations and (3) responses of both measurement systems to more complex situations such as welding fumes, gaseous oxidants and secondary organic aerosols generated in controlled conditions.
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Investigating PM2.5 Toxicity: The Initial Comprehensive OP Study in Australia Utilising Various Acellular Assays 1Deakin University, Australia; 2Environment Protection Authority Victoria This study addresses the research gap on PM2.5 oxidative potential (OP) in the Southern Hemisphere by analysing an Australian metropolitan urban environment utilising three acellular assays. Over a year of sampling at two urban lsites, OP values have a weak correlation with PM2.5 mass concentration. DTT had the most variability and seasonal peaks in winter due to wood heating, whereas AA peaks in autumn during hazard reduction burning. OP levels correlated with transition metals (particularly Fe and Cu) and carbonaceous species that make up 60% of local PM2.5. Australian urban air quality management will benefit from these results.
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Buildings located in valley cities : An original study for the characterization of the human exposure to the infiltrated outdoor air with measurements of oxidative potential 1LOCIE, University of Savoie Mont-Blanc-CNRS, France; 2EDyTeM, University of Savoie Mont-Blanc-CNRS, France; 3Research Team BPE, CEREMA, France; 4IGE, CNRS-IRD-University Grenoble Alpes,France Breathable fine particles and black carbon (BC) within the air are known for their important health impacts. Two measurements campaigns have been carried out in winter 2023 and winter 2024 to study the contribution of the infiltrated outdoor air to the human air pollution exposure to PM2.5 and to BC in six public buildings located in valley cities (South-East of France), including schools. The methodology of this study is the characterization of the impact of indoor-to-outdoor air dynamics on air pollutants levels, based on metrics such as i) biological human response to exposure and ii) source apportionment of BC emissions.
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Chemical characterization and Oxidative Potential of fine particulate matter from rural, urban and industrial sites in Sicily within the NOSE 2 project 1Institute of Atmospheric Sciences and Climate (CNR-ISAC), National Research Council of Italy, Bologna, 40129, Italy; 2Institute of Atmospheric Sciences and Climate (CNR-ISAC), National Research Council of Italy, Lecce, 73100, Italy; 3Regional Agency for the Environmental Protection Sicily (ARPA Sicilia), Palermo, 90149, Italy; 4Now at University of Tasmania, Hobart, 7001, Australia Exposure to atmospheric particulate matter (PM) affects human health, especially the respiratory, cardiovascular, and neurological systems, due to excessive reactive oxygen species (ROS) formation; aerosol-induced ROS is defined as aerosol Oxidative Potential (OP). In 2023, PM samples were collected seasonally within NOSE 2 project at three Sicilian air quality stations: Palermo (traffic), Trapani (rural), and Priolo (petrochemical). OP analysis via DTT assay (OPDTT) and OC/EC measurements revealed higher OP values traffic sites and variable levels in Priolo, within the Siracusa AERCA (High Environmental Crisis Risk Area), prompting further analysis on contributions from petrochemical industries.
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PM2.5 oxidative potential at urban and rural sites of the western Mediterranean basin Miguel Hernández University of Elche, Spain PM2.5 samples were collected simultaneously at an urban background station and a rural site located in southeastern Spain during summer and winter. The samples were analysed for a complete characterisation of their chemical composition. Additionally, OP measurements were carried out by the ascorbic acid (AA) and dithiothreitol (DTT) acellular assays. OP values were higher at the urban than at the rural station, indicating a higher oxidative capacity of PM2.5 aerosols in the urban area. Differences were more pronounced for OPAA than for OPDTT, which indicates a lower variability of the DTT activity as a function of the site typology.
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Source apportionment of PM2.5 oxidative potential at urban and rural sites of the western Mediterranean basin Miguel Hernández University, Spain A total of 302 daily PM2.5 samples were collected simultaneously at an urban background station and a rural site located in southeastern Spain during summer and winter. Samples were analysed for OC, EC , water-soluble ions, WSOC, trace metals, levoglucosan and with the dithiothreitol assay (OPDTT). PMF was used to identify PM2.5 sources while the OPDTT apportionment was performed with MLR. At the rural site, biomass burning was the greatest contributor to PM mass and OPDTT. A the urban site, although biomass burning and road traffic were not the highest contributors to PM2.5, they were the main drivers of OPDTT.
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Differences in oxidative potential between rural and urban locations in the Netherlands and related source attributions for PM10 1TNO, Netherlands, The; 2Univ. Grenoble Alpes, CNRS, INRAE, IRD, Grenoble INP, IGE, 38000 Grenoble, France TNO is also focusing on the oxidative potential (OP) of particulate matter, to help steer towards more health relevant policies in the Netherlands. Chemical analysis and OP assays of PM10 are used to compare two locations, urban and rural, in the Netherlands. Subsequently, Positive Matrix Factorization (PMF) was performed on the chemical composition data to identify the contributing sources of PM. The OP values are then linked to the PM10 of source profiles through regression analysis to illustrate the contribution of each source to observed OP levels and thereby identify the most health-relevant sources.
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Field deployment of simultaneous particulate mass and DTT consumption monitoring system for coarse PM and PM2.5 1Japan Automobile Research Institute (JARI), Japan; 2National Institute of Advanced Industrial Science and Technology (AIST), Japan; 3National Institute for Environmental Studies (NIES), Japan; 4Meteorological Research Institute (MRI), Japan Since the mass of particulate matter (PM) in the atmosphere is composed of multiple compounds and particle sizes, and includes both harmless and harmful substances, with large variations in its spatiotemporal distribution, PM is a proxy indicator for understanding the effects on health. In this study, we focused on the oxidative potential of PM, which is also mentioned in the draft European Air Quality Directive (52022PC0542), and deployed a field monitoring system that measures the mass of fine particles (PM2.5) and coarse particles (PMc) and continuously and automatically analyzes their oxidative potential using the dithiothreitol (DTT) consumption.
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Versatile Aerosol-based Nanomaterial Synthesis for Gas Sensing Applications The Cyprus Institute, Cyprus Nanomaterial synthesis by aerosol-based techniques offer a range of advantages including low-cost and continuous production, high reproducibility, good control over the size and composition of the resulting particles, high versatility, as well as minimum or even absence of wastes. In this paper I will present a variety of evaporation-condensation aerosol nanoparticle generators and how these can be used to synthesize nanomaterials for gas sensing applications. The resulting nanomaterials are capable of detecting gases across a broad concentration range, from a few percent down to few ppm. Example results will be presented for hydrogen, methane and nitrogen dioxide.
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Next-Gen Aerosol Tech: SAW-based Aerosol Sources for Industrial Applications 1SONOJET GmbH, 01069 Dresden, Germany; 2Leibniz IFW Dresden e.V., SAWLab Saxony, 01069 Dresden, Germany We commercialize the first compact, integratable SAW-based atomizers and aerosol sources to pave the way towards their industrial application. Our SAW-based aerosol generators do not require any moving parts, orifices, nozzles or meshes, use significantly less power and are suited to produce directed micro- and nanometer-sized droplets with an adjustable narrow size distribution. Furthermore, they exhibit low shear forces and can be used with a broad fluid spectrum from aqueous solutions and organic solvents towards highly viscous particle solutions and inorganic inks as well as biological fluids and cell suspensions.
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Direct Synthesis of Silica-coated Iron (Fe@SiO2) Particles Using an Aerosol Process Hiroshima University, Japan Fe@SiO2 particles were synthesized via a swirler connector-assisted spray pyrolysis method to overcome oxidation challenges in soft magnetic materials. By optimizing the SiO2-to-Fe core ratio, complete FeO reduction was achieved. A precursor solution of Fe(NO3)3·9H2O was atomized, mixed with HMDSO vapor, and processed at 1400°C. Characterization confirmed controlled morphology and enhanced magnetic properties. The optimal ratio (14.3 × 108 SiO2 monomer/Fe core) ensured complete silica coating on Fe, achieving a saturation magnetization of 2.04 T. This study presents a novel, one-step synthesis method for high-purity Fe@SiO2, offering promising applications in inductors and advanced electronic components.
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Light patterns for colorizations School of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, China Faraday 3D print relies on the topologies of electric field for defining the geometries of the nanostructures. The field topologies were basically formed by allowing two differently oriented fields, namely global and local ones, for competition. Generally, the local field was difficult to be manipulated but its sensitivity to structural geometries turned out to be subtle. Here we manage to dynamically alter the local field using light patterns. The nanostructures printed on the selective areas that receive light projection are geometrically different, as compared to those in shadows. The structures also showed instantaneous response to the presence/absence of light.
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Faraday lithography shanghaitech University, China, People's Republic of This work hybridizes Faraday 3D print with etching steps for producing the so-called Faraday lithography (FL). The printed metal features serve as hard masks when performing etching steps, leaving only patterns of substrate materials. The line patterns showed excellent line-edge roughness and their feature size was strikingly reduced to 1/10 to that obtained by photolithography. FL can also make 3D patterns, far exceeding any existing lithographic techniques. This transformative solution is expected to advance semiconductor manufacturing.
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Removal of Sulfur Compounds from Pyrolysis Oil using Cu-MOF Beads 1National Ilan University, Taiwan; 2National Taiwan University, Taiwan This study explores the use of copper-based metal-organic frameworks (Cu-MOF) in adsorption desulfurization to address the challenge of removing thiophene compounds from waste tire pyrolysis oil. Simulation experiments show a 70% adsorption efficiency for sulfur compounds. The Cu-MOF adsorbent is fabricated into bead form to enhance surface area utilization. This technology aims to achieve ultra-deep desulfurization, transforming pyrolysis oil into a cleaner alternative energy source while reducing environmental impact.
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Strategy for the synthesis of size-controlled oxide-free copper nanoparticles and their reactivity Chuo University, Japan Copper nanoparticles, promising alternatives to precious metals, are challenging to synthesize due to oxidation and reduction difficulties. This study explored two strategies: nanosheet surfaces and zeolite pores, to control nanoparticle size and prevent oxidation. Saponite nanosheets, mixed with copper acetate, yielded oxide-free copper nanoparticles upon UV irradiation. Size was controlled by the copper acetate/saponite ratio, demonstrating uniform copper ion adsorption. Copper ions were also introduced into Y-type zeolite pores, forming nanoparticles upon UV irradiation. These nanoparticles exhibited high catalytic activity for benzyl alcohol oxidation, achieving a turnover frequency of 17 h⁻¹, exceeding previous reports.
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Synthesis of TWC Aggregated and Porous Particles via Spray Drying Method: Catalytic Performance and Internal Structure Analysis Hiroshima University, Japan Efficient three-way catalysts (TWCs) are essential for reducing vehicle emissions, but their adoption is hindered by high costs and low-temperature performance limitations. This study investigates spray-dried aggregated and porous TWC particles to optimize structure and enhance CO conversion. Aggregated particles showed increased size with higher concentrations but lower CO conversion due to inefficient catalyst utilization. Introducing a porous structure with PMMA improved CO conversion by enhancing gas diffusion. Higher PMMA concentrations further improved performance by modifying framework thickness and macroporosity. Cross-sectional and 3D elemental mapping confirmed uniform elemental distribution and an interconnected pore network for efficient gas transport.
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MOF induced Perovskite for Cleaner Energy Production 1National Ilan University, Taiwan; 2National Taiwan University, Taiwan This study develops a ZnTiO₃/Cu-BTC composite photocatalyst to enhance hydrogen production. Cu-BTC improves visible light absorption, reduces electron-hole recombination, and lowers the bandgap to 3.78 eV. The 1% Cu-BTC/ZnTiO₃ composite significantly enhances absorption in the 600–800 nm range, achieving 78.63 mmol/g hydrogen yield in three hours. The study also examines the effect of Cu-BTC loading on efficiency, offering insights for renewable energy applications.
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Process Optimization for Repeated CO2 Capture Using Porous MgO adsorbents 1Pusan National University, Korea, Republic of (South Korea); 2Korea University of Technology and Education, Korea, Republic of (South Korea); 3Gyeongsang National University, Korea, Republic of (South Korea) Carbon dioxide (CO2) is a major greenhouse gas for causing climate change. Porous magnesium oxide (MgO) particles have been investigated vigorously as CO2 capture materials through a mineral carbonation. In this study, processes of wet-carbonation and decarbonation for MgO based CO2 adsorbents were optimized by controlling carbonation time and decarbonation temperature. As a result, compared to the previous conservative wet carbonation procedure in the lab., ~40% of the process time was saved. In addition, the decarbonation energy could be saved ~50% compared to the previous decarbonation process in the lab.
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Electrophoretic assisted flame synthesis of hydrophilic carbon nanoparticles film 1Department of Engineering, University of Campania L. Vanvitelli, Aversa (CE) 81031, Italy; 2Department of Chemical, Material and Industrial Production Engineering, University of Naples Federico II, Napoli, 80125, Italy Carbon-based films exhibit tunable wettability, important for surface engineering. This study investigates Electrophoretic-assisted Flame Synthesis (E-ThFS) to enhance carbon nanoparticle (CNP) deposition efficiency and modify film morphology. Using a premixed ethylene/air flame under incipient sooting conditions (C/O = 0.67) , deposition was compared between conventional thermophoretic flame synthesis (ThFS) and E-ThFS. Applying negative voltages (-1 kV, -3 kV) significantly increased deposition rates and altered film roughness. Contact angle measurements revealed metastable superhydrophobicity before stable hydrophilicity. E-ThFS enables controlled film growth and wettability, expanding applications in sensors, coatings, and smart surfaces. These findings advance nanostructured material design.
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Template-free synthesis of porous metal nitride films from combustion aerosols ETH Zuerich, Switzerland Metal nitrides possess exceptional catalytic properties making them widely used in catalytic-based applications. However, their performance remains limited by poor mass transfer and reduced accessibility of reactive sites when depostied as films with conventional techniques. Here, we demonstrate a template-free method for the design of highly porous metal nitride films with high compositional versatility. These are obtained by exploiting self-assembly of fractal-like metal oxide agglomerates during deposition from aerosols followed by their dry nitridation. This is exploited exemplarily for molecular sensing of NO2 leading to up to a five-fold higher response with faster response time over more compact spin-coated films.
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Effect of the Oxidation State of Copper Nanoparticles on Their Interfacial Interaction with Metallic Substrates Insitute of Particle Technology - Clausthal University of Technology, Germany This study investigates the effects of oxidation on copper nanoparticle collisions using Low-Pressure Impaction (LPI) experiments and Molecular Dynamics (MD) simulations. Unlike studies focusing on oxidation-resistant metals, this work examines an oxygen-affine material to reflect practical scenarios, where the presence of oxygen is often unavoidable. The reactive force field potential (ReaxFF) is used to model oxidation’s impact on adhesion, mechanical properties, and collision dynamics, linking experimental and simulation results to advance nanoparticle research for industrial and scientific applications.
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Electrochemical Sensor for Detection of Oxytetracycline Using ZnO-Modified Carboxylate Multi-Walled Carbon Nanotubes on Glassy Carbon Electrode National Ilan University, Taiwan Oxytetracycline (OTC), a widely used antibiotic, demonstrates broad-spectrum antibacterial activity against Gram-positive and Gram-negative bacteria. Despite its benefits in promoting animal growth, OTC pollution adversely affects soil bacteria, actinomycetes, and microbial populations, with potential risks to human health and the environment, such as allergic reactions and ecosystem disruption. This study aims to develop an electrochemical sensor for detecting OTC, utilizing carboxyl-functionalized multi-walled carbon nanotubes (MWCNT-COOH) on a glassy carbon electrode (GCE) for improved conductivity and charge transfer. The sensor's performance is optimized by comparing different materials and concentrations, targeting low-cost, efficient, and eco-friendly detection.
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Multifunctional and Eco-Friendly EDTA/PEI Aerogels for the Removal of Cu(II) from Aqueous Solutions 1National Ilan University, Taiwan; 2National Taiwan University, Taiwan This study develops a modified chitosan-based aerogel to enhance Cu(II) removal efficiency. Incorporating EDTA and PEI, the aerogel exhibits strong metal ion chelation and abundant amine functional groups, improving adsorption performance. Results show over 90% removal efficiency for initial Cu(II) concentrations up to 30 ppm, reaching 97% at 15 ppm. The aerogel maintains excellent mechanical stability, ensuring structural integrity while offering low density and high surface area. Its easy recovery and reusability minimize secondary pollution, making it an environmentally friendly and highly efficient material for heavy metal removal.
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Synthesis of TiO2 nanoparticle and rGO composite material by flame spray pyrolysis for Li-Sulfur battery cathode creation. University of Eastern Finland, Finland In our current work, we are investigating the possibility of producing TiO2 and reduced graphene oxide (rGO) composite for the craton of Li-Sulfur battery cathode during synthesis of TiO2 by flame spray pyrolysis process. The spherical particles of rGO are produced by the spray drying process and further injected into the flame spray pyrolysis (FSP) rector in the form of dust, which is produced by a fluidized bed aerosol generator. The created material's structural, compositional, and morphological properties are investigated using SEM, EDS, Raman spectroscopy, and TGA techniques. The electrochemical analysis of the effect of different TiO2/rGO ratios is done.
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Deep Spatio-Temporal Neural Network for Air Quality Reanalysis 1LUT UNIVERSITY, Finland; 2Atmospheric Modelling Centre Lahti, Lahti University Campus; 3Univeristy of Helsinki; 4Chinese Academy of Sciences AQ-Net is a spatiotemporal air quality reanalysis model combining LSTM, multi-head attention, and neural kNN. It predicts pollution levels, including for unobserved stations, by filling spatial gaps using limited observation stations. Evaluated on PM2.5 data from northern China (2013–2017), AQ-Net excels in reconstructing spatiotemporal trends. It enhances generalization in urban environments and helps build a comprehensive picture of air pollution for atmospheric chemistry studies.
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Effect of brake friction material on brake particle emissions 1INERIS, France; 2MAT-friction; 3CETIM; 4UTC See the uplooded abstract
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Real-Time Characterization of PAH Derivatives in Bitumen Fume Emissions 1Aix Marseille Univ, LCE, 13331 Marseille, France.; 2MAST/MIT, Université Gustave Eiffel, Allée des Ponts et Chaussées, CS4, 44344 Bouguenais, France.; 3Cerema, Univ Gustave Eiffel, UMR MCD, F-13100 Aix-en-Provence, France.; 4Aix Marseille Université, Avignon Université, CNRS, IRD, IMBE, Marseille, France. Bitumen fumes, classified as potentially carcinogenic by IARC, contain volatile and semi-volatile compounds, including PAHs. While most studies focus on the 16 priority PAHs, recent research highlights the presence of more toxic compounds known as PAH derivatives. A two-week measurment campaign in MIT, Nantes, France, allowed the analysis of bitumen emissions from different bitumen formulations under controlled conditions using advanced real-time instruments (PTR-ToF-MS, HR-ToF-AMS, SMPS). Various PAH derivatives including nitrogenated, sulfurated, oxygenated, and alkylated PAHs were identified and quantified, each exhibiting different toxicological potentials. This study enhances our understanding of bitumen emissions, emphasizing the need for further toxicological assessment.
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A Study on the Distribution Characteristics of Particulate Matter Emissions in Industrial Complex Areas Using Scanning LiDAR 1Advanced Institute of Convergence Technology(AICT), Korea, Republic of (South Korea); 2Metropolitan Environment Management Office, Suwon-si, Gyeonggi-do,16444, South Korea; 3Samwoo TCS Co., Ltd., Chilgok-gun, Gyeongsangbuk-do, 39910, South Korea; 4Sungkyunkwan University Environmental Forensic Lab, Suwon-si, Gyeonggi-do, 16419, South Korea The Sihwa National Industrial Complex has a total of 798 air pollution emission facilities, of which the majority classified as class 4 and class 5. A detailed description of the air pollution emission sites facility is shown in Table 1. Most small factories tend to have insufficient air pollutant emission management, and the government also has insufficient monitoring.In this study, remote sensing LiDAR measurement technology was used to improve the efficiency of illegal emission management of Sihwa Industrial Complex, where small factories are concentrated. The purpose to analyze the characteristics of PM2.5 concentrations in industrial complex areas and identify Hot-spots.
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Evaluation of different causes of air pollution in the Central European Region Czech Hydrometeorological Institute, Czech Republic The paper's area of interest is Moravia, the eastern half of the Czech Republic in Central Europe. The evaluation summarises the main results of two source apportionment studies carried out in this area in 2021 (north-eastern part) and 2023 (central and southern part) in terms of spatial trends, pollution transport and general causes of air pollution. Arrangement to address air quality problems in the northern half of the area of interest should continue to focus on reducing emissions from domestic heating. In South Moravia, the main priority should be to reduce emissions from road traffic.
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Monitoring of radioactive aerosols by two-layer filters in the premises air on low levels of the Shelter Object inside the New Safe Confinement Institute for Safety Problems of Nuclear Power Plants of NAS of Ukraine, Ukraine The results of monitoring of radioactive aerosols (RA) in premises 012/7 (+ 0 м), 012/15 (+ 3 м), 210/7 (+ 6 м) of SO near accumulations of FCM in the New Safe Confinement within 2021 to 2024 are presented. The monthly sampling of RA was carried out by the two-layer filters. The first layer was coarse-fibered FPS-110-0.2, the second layer - fine-fibered FPP-15-1.5. The nuclides 137Cs, 241Am and 154Eu and markers of submicron aerosols 210Pb and 212Pb were detected by gamma-spectrometer (CANBERRA). The proposed approach for sampling RA enables the definition of generation sources of RA.
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Effects of exhaust dilution parameters on characteristics of semi-volatile aerosol emissions from a gasoline internal combustion engine 1Mechanical Engineering, School of Engineering, University of Birmingham, United Kingdom; 2School of Geography Earth and Environmental Sciences, University of Birmingham, United Kingdom; 3School of Biosciences, University of Nottingham, United Kingdom Intermediate/semi-volatile organic compounds (I/SVOCs) are considered to be significant precursors of secondary aerosols. This experimental work focuses on quantifying the effects of varying exhaust dilution parameters on the characteristics of emissions from a modern light-duty gasoline internal combustion engine (ICE). Alongside complementary analyses, the gas and particle phase I/SVOCs are sampled using an in-house adsorption-tube and filter sampler for subsequent extraction and speciation by two-dimensional gas chromatography time-of-flight mass spectrometry. The findings from this work help enhance the understanding of ICE emission factors, dynamics during sampling, abatement strategies, and the repeatability of measurements and speciation considering currently unregulated I/SVOC emissions.
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Exploring the Formation and Toxicity of Secondary Particles in Gasoline Vehicle Emissions 1Laboratory of Applied Thermodynamics, Aristotle University, Thessaloniki, 54124, Greece; 2Laboratory of Animal Physiology, School of Biology, Aristotle University, Thessaloniki, 54124, Greece; 3Aerosol Physics Laboratory, Tampere University, Tampere, 33100, Finland; 4Department of Environmental Science, Stockholm University, Stockholm, 10691, Sweden This study examines secondary particle formation and toxicity from a Euro 6 plug-in GDI vehicle under controlled conditions. Exhaust was diluted and aged in the Tampere Secondary Aerosol Reactor (TSAR) to simulate atmospheric processes. Human epithelial A549 cells were exposed to fresh and aged emissions using an air-liquid interface (ALI) system. Physical characterization showed a substantial rise in small particle concentration after aging.Aged particles significantly increased in number, leading to greater reductions in cell viability and higher LDH release, indicating increased cytotoxicity.
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High secondary aerosol formation from motorcycle exhaust 1Tampere University, Finland; 2Emisia SA, Greece; 3Aristotle University of Thessaloniki, Greece This study investigates secondary organic aerosol (SOA) formation from modern 4-stroke motorcycles and a moped in transient driving cycles by utilizing oxidation flow reactor. Three vehicles were tested: a 50 cc moped, a 300 cc scooter, and a 1200 cc motorcycle. Results showed high SOA formation from the 50 cc and 300 cc bikes. The findings highlight the significant contribution of 4-stroke motorcycles to urban SOA levels, despite regulatory focus on primary emissions.
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The positive impact of burning sustainable aviation fuel on reducing non-volatile particle emissions 1Multi-Physics for Energetics Department, ONERA Université Paris Saclay, F-91123 Palaiseau, France; 2Global Bioenergies, 5 rue Henri Auguste Desbruères, 91000 Evry France One way to achieve carbon neutrality in air transport is to increase the use of Sustainable Aviation Fuels (SAF). These new fuels also positively impact the reduction of emissions of non-volatile particulate matter (nvPM). This study investigates the effect of SAF composition on the nvPM produced by its combustion using a laboratory burner. The SAF examined in this study developed by Global Bioenergies uses a microorganism that converts sugars to isobutene. The results show that the combustion of pure SAF leads to a significant reduction in emissions in terms of both the number and mass of nvPM compared to those from Jet A-1.
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Effect of fuel composition to particles emitted from auxiliary heaters of cars 1Department of Technical Physics, University of Eastern Finland; 2Department of Environmental and Biological Sciences, University of Eastern Finland; 3Aerosol Physics Laboratory, Tampere University; 4Tampere Institute for Advanced Study, Tampere University Effect of fuel composition to particle emissions of fuel operated auxiliary heater (AH) was tested for 95E10 gasoline, ethanol based RE85 and alkylate fuel. Measurements were conducted using an auxiliary heater installed into a specifically designed freezer to allow for control of initial operating temperature. Both direct emissions and aged emissions enable accounting for the effect of secondary particle formation on total emissions. Sample was aged both with oxidation flow reactor and smog chamber. PN emissions of AH were measured along other variables for both cold and warm initial operating temperatures for all 3 fuel types.
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Experimental Investigation of Particle Loss from Sampling Tube Surface Roughness, Tube Coiling, Flow Splitters, and Tube Fittings in Aviation nvPM Sampling Systems 1University of Manchester, United Kingdom; 2Rolls-Royce, United Kingdom Particle losses due to sampling tube surface roughness, tube coiing, flow splitters, and tube fittings were experimentally investigated for representative aircraft nvPM sampling systems parameters. It was observed that no additional particle losses occured when the surface roughness was below 2 µm, but significantly increased as the roughness height increased. For coiled tubes, no additional particle losses occured for turbulent flow, but additional particle losses were oberved for laminar flow. This study showed that surface roughness, tube coiling, and sampling system components have to be carefully considered to reduce nvPM losses and provide more accurate nvPM reporting.
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Roadside emission factors of emerging and unregulated pollutants 1Tampere University, Finland; 2Finnish Meteorolological Institute, Finland; 3Helsinki Region Environmental Services Authority, Finland; 4University of Helsinki, Finland Road traffic emission factors of both regulated and unregulated pollutants, including VOCs, ultrafine particles, and chemical species, were determined from a street canyon site measurements in Helsinki. All the studied 18 aromatic hydrocarbon compounds had a strong correlation with CO2, showing that VOC emission factors can be well determined from roadside measurements. In addition, most alkanes and polycyclic aromatic hydrocarbons correlated well with CO2. Interestingly, some of the biogenic VOCs correlated with CO2, suggesting potential effects of human activity on biogenic VOCs at urban traffic sites that have not been previously considered.
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Real-time monitoring of transport-related air and noise pollution in European cities (Net4Cities): Monitoring plan and approach 1Flemish Institute for Technological Research (VITO), Mol, Belgium; 2Research Institute for Sustainability at GFZ, Potsdam, Germany; 3Institute of Climate and Energy Systems (ICE-3Troposphere), Forschungszentrum Jülich GmbH; 4Airmodus Ltd., Helsinki, Finland; 5ZHAW School of Engineering, Switserland; 6Climate and Atmosphere Research Center (CARE-C), The Cyprus Institute; 7NILU, Norway; 8Technalia, Spain; 9Telraam (Rear Window BV), Leuven, Belgium Net4Cities (Real-time monitoring of transport-related air and noise pollution in European cities) is an EU project. that will expand the air and noise pollution monitoring infrastructure and providing evidence-based support for implementing effective transport policies. Net4Cities will install monitoring devices in 11 cities across 10 European countries, at multiple locations in each city. Measurements include UFP (PNC and LDSA), NH3, VOCs, CH4, N2O, CO2,, and will be complemented with available data of regulated pollutants and BC. Also noise monitors and traffic countser will be installed. Measurements will be performed from 1/4/2025 - 31/3/2027. Set-up and first results will be discussed.
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Exploring Particle Dynamics: Preliminary Investigations in Wear Particle Measurement for Tire and Road Surfaces 1Palas GmbH, Germany; 2Bern University of Applied Sciences This presentation presents ongoing research conducted in collaboration between the BFH (Bern University of Applied Sciences) and PALAS GmbH focusing on the analysis of were particles originating from tire and road abrasion. The impact on Tire and Road Wear Particles (TRWP) is investigated through a progression from laboratory-based tire testing to controlled roller rig experiments and on-road trials, incorporating increasingly diverse influencing factors. The ultimate objective is to develop the capability to directly measure particles from rolling tires using an ISO-kinetic sampling method, enabling precise spatial resolution of particle distribution.
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Particulate emissions from vehicles: a detailed characterization of fine and ultrafine fractions 1ETSI Minas y Energía, Universidad Politécnica de Madrid, Madrid, 28003, Spain; 2Joint Research Centre, European Commission, Italy This study investigates the emissions of micrometric and sub-micrometric particulates from internal combustion engine vehicles, which contribute significantly to air pollution and lung cancer risk. Using Raman spectroscopy, the research analyzes particulate matter from various vehicle types and fuels, identifying black carbon as the primary component, along with defective graphite, iron oxides, sulphates, and nitrogen compounds. Principal Component Analysis has been performed to differentiate emissions by vehicle and fuel type. Additionally, nanoscale carbon structures, including multi-walled carbon nanotubes, were detected using transmission electron microscopy.
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Emissions of particulate matter and pollution control technologies for marine engines operated with green fuels University of Naples Federico II, Italy Waterways shipping is transitioning to green fuels to reduce its carbon footprint, yet emissions of NOx, VOCs, and particulate matter (PM) remain a challenge. This study evaluates emission control technologies—Diesel Particulate Filters (DPF), Wet Electrostatic Precipitators (WESP), and Wet Electrostatic Scrubbers (WES)—for reducing PM and particle number (PN) emissions in marine engines using biogenic and e-fuels. While DPFs are highly effective, their operational constraints limit applicability. WESP and WES offer flexibility but introduce washwater concerns. Proper integration of these technologies can significantly improve air quality and mitigate maritime emissions. Research funded by the EU–NextGenerationEU under PNRR.
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Evaluation of Emissions in a Lab-scale Turbojet Engine Using Fossil and Sustainable Aviation Fuels 1Centro de Investigaciones Energéticas Medioambientales y Tecnológicas (CIEMAT), Madrid 28040, Spain; 2Instituto de Investigación Aplicada a la Industria Aeronáutica (INAIA), Universidad de Castilla-La Mancha (UCLM), Toledo 45071, Spain The aviation sector is a major source of ultrafine particles (UFP) and pollutants. Sustainable aviation fuels (SAF) offer a potential alternative to reduce environmental impact. This study analyzes emissions from a lab-scale turbojet engine (AMT Olympus) using JP8 and a JP8+SAF blend. Results indicate that while SAF does not significantly reduce UFP concentration, it shifts the particle size distribution to smaller diameters and decreases certain volatile organic compounds. These findings highlight the need for further research on SAF under real conditions to improve their accessibility and effectiveness in reducing aviation emissions.
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Ultrafine Particulate Emissions from the Transport Sector: First results from the Net4Cities project 1Institute of Climate and Energy Systems (ICE-3Troposphere), Forschungszentrum Jülich GmbH; 2Research Institute for Sustainability at GFZ, Potsdam, Germany; 3Flemish Institute for Technological Research, Mol (VITO), Belgium; 4Airmodus; 5ZHAW School of Engineering; 6Climate and Atmosphere Research Center (CARE-C), The Cyprus Institute Net4Cities project supports the he EU Green Deal's Zero Pollution Action Plan by implementing advanced aerosol measurment techniques in 11 cities across 10 European countries. The project focus of monitoring emission from both exhaust and non-exhaust sources in urban traffic area, ports and airports. Results will be presented from Düsseldorf, a major metropolitan city in central Europe with key measurments including ultrafine particles, lung deposited surface area. Data will be integrated into real-time models to identify potential pollution sources and inform policies aimed at reducing pollution.
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Fresh exhaust particle emissions from modern passenger cars 1Aerosol Physics Laboratory, Physics Unit, Tampere University, Tampere, Finland; 2BOSMAL Automotive Research and Development Institute Ltd, Bielsko-Biala, Poland; 3Atmospheric Composition Research, Finnish Meteorological Institute, Helsinki, Finland; 4Emission Control and Sustainable Fuels, VTT Technical Research Centre of Finland Ltd, Espoo, Finland; 5The Institute of Experimental Medicine of the CAS, Prague, Czech Republic; 6Czech University of Life Sciences, Prague, Czech Republic; 7PSI Center for Energy and Environmental Sciences, 5232 Villigen PSI, Switzerland Seven passenger cars were driven on a chassis dynamometer in a temperature-controlled test cell according to Real Driving Emissions simulating test cycle. Based on the preliminary results, the fresh exhaust particle emissions of modern passenger cars were relatively low when compared e.g. with their emission standards for solid particles, even though the volatile particles were also included in the EFs. However, the emissions from the PHEVs depended strongly on the used driving mode and the state of charge of the battery. In addition, older conventional cars and a CNG car, that were missing the particulate filters, had clearly higher emissions.
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Portable FTIRs’ capability to measure secondary aerosol precursors from vehicle exhaust 1VTT Technical Research Centre of Finland, Finland; 2Czech Technical University, Prague, Czech Republic; 3Czech University of Life Sciences Prague, Prague, Czech Republic; 4BOSMAL Automotive Research and Development Institute Ltd, Bielsko-Biala, Poland; 5Aerosol Physics Laboratory, Physics Unit, Tampere University, Tampere, Finland; 6Atmospheric Composition Research, Finnish Meteorological Institute, Helsinki, Finland Ambient PM2.5 is formed through atmospheric reactions forming secondary aerosols from gas-phase precursors in the atmosphere under presence of H2O, O2, oxidants and sunlight, and compounds from other sources. For determining the relevant precursor gases, we studied performance of two portable size FTIRs and compared them with laboratory size FTIRs. Exhaust from different fuels were measured using different methods for exhaust gas analyses. The study highlights the strengths and limitations of each device, providing insights into their suitability for various testing situations and their overall performance in capturing accurate and reliable exhaust emission data for potential precursors forming secondary aerosols.
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Influence of Fuel Standards on Vehicular Emissions: Assessing the Impact of Bharat Stage Regulations in Urban Idling Conditions Indian Institute of Technology Delhi, India Vehicular emissions, especially under idling conditions, significantly contribute to Delhi’s air pollution. This study analyzes emission factors (EFs) of CO, CO₂, Black Carbon (BC), and NH₃ from light-duty vehicles (LDVs) and two-wheelers under idle and 2000 rpm conditions. Results indicate that EF decreases with increasing Modified Combustion Efficiency (MCE), with BS VI fuels exhibiting the lowest emissions due to improved fuel quality and advanced emission controls. Findings align with Euro VI and China’s norms, highlighting the importance of fuel quality improvements in reducing emissions and enhancing combustion efficiency.
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Regulated and unregulated pollutants emitted by an inland waterway ship – comparison of traditional fuel with two alternative fuels. 1University Gustave Eiffel, France; 2University Claude Bernard Lyon 1; 3CRMT Freight transport has significantly increased in the last decades, and using ships instead of trucks could lower the CO2 emissions. Alternative fuels could lead to even lower emissions, despite poorly documented atmospheric pollutant emissions. This work presents on-board measurements of regulated and unregulated pollutant emissions from an inland ship, comparing traditional non-road diesel to alternative fuels: gas-to-liquid and biodiesel. Results show that the alternative fuels are effective in reducing emissions of CO2, as well as solid particles, black-carbon, SO2 and certain VOCs. NOx emissions from biodiesel are however high. Additional results were obtained for specific conditions (harbours and locks).
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Chitosan based crosslinked nanoparticles by coaxial electrospraying 1University Rovira i Virgili, Spain; 2Catalan Institution for Research and Advanced Studies, Spain We have demonstrated stable multiplexed coaxial electrospray for a range of aqueous solutions with in-situ crosslinking for the continuous production of uniform chitosan-based nanoparticles with active compounds. A proof-of-concept setup was developed for 8 sprayers in a scalable circular arrangement, capable of mg/h production rates. Field Emission Scanning Electron Microscopy (FESEM) imaging of the nanoparticles revealed relatively homogeneous sizes, under about 200 nm, and globular shapes. The particles collect forming aggregates, suggesting a finite electrical resistivity of the nanoparticulate film.
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Finite Taylor Cone: the impact of the electrospray 1Universidad de Malaga, Spain; 2Universidad Politécnica de Madrid, Spain The parametric range in flow rates and electric field for which the the electrospray regime is stable is still not well understood. In this work, the spray and meniscus interaction is studied by numerical means to shed light on this intricate and complex phenomena that involves numerical singularities and deformable interphases of both the electrode and the envelope of the spray. It serves as a first step towards the understanding of the stability of the electrospray regime.
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Spark Ablation Generation of Metal and TiO2 Nanoparticles for CO2 Hydrogenation 1University of Basel, Department of Environmental Sciences, Basel, Switzerland; 2University of Basel, Swiss Nanoscience Institute, Basel, Switzerland This study focuses on the generation of spark ablated and in situ oxidized Ti(O2) nanoparticles, using a spark generator (VSParticle, Delft, NL) and a high temperature oven for oxidation and modification of particle crystal structure and morphology. Furthermore, metal nanoparticles are generated via spark ablation and coated on either the above described TiO2 particles or nebulized TiO2 particles. Both particle species are then compared in their photocatalytic activities for the CO2 hydrogenation reaction.
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Combined Reduction of NOx and PM Emissions from Small-scale Biomass Combustion with Electrostatic Precipitation VSB-TUO, Czech Republic ESP generates nonthermal plasma that triggers chemical reactions and converts reaction products into aerosols via ion-induced nucleation. This, allows ESP to reduce PM and NOx emissions. To avoid secondary aerosols being released into the atmosphere, the ESP should be designed properly and specific energy input ( SIE J/L) can be helpful. In wood pellet boiler tests, sub-6 nm particle nucleation began at 6 J/L SIE, while higher SIEs (48 J/L negative, 35 J/L positive) achieved 78% NOx removal and reduced particle concentrations to 300 particles/cm³ (0.15 µg/Nm³). ESP systems demonstrate effective dual reduction of NOx and PM from small-scale combustion.
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CFD modeling of a perpendicularly oriented EHDA system in a pressurized lateral gas flow 1NHL Stenden University of Applied Science, Netherlands; 2Delft University of technology, Netherlands; 3Escuela de Ingenierías, Universidad de Málaga, Spain; 4NHL Stenden University of Applied Science, Netherlands Electrohydrodynamic atomization (EHDA) (or electrospray) uses strong electric fields to generate fine droplets with a narrow size distribution, increasing evaporation efficiency in industrial processes such as odorization, combustion, and humidification. This study develops a COMSOL model to analyze droplet motion in a natural gas odorization system. Initial simulations focus on gas flow and droplet transport, with ongoing work incorporating electric field effects and droplet interactions. The results aim to optimize system design by evaluating parameters such as nozzle geometry, duct configuration, and gas flow dynamics to improve the efficiency of EHDA-based odorization.
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Droplet behavior and characteristics in high-flow rate electrospray processes 1Department of Integrated Particulate Matter Management, Kangwon National University, Chuncheon-si, Gangwon State, 24341, Republic of Korea; 2Department of Environmental Engineering, Kangwon National University, Chuncheon-si, Gangwon State, 24341, Republic of Korea Wet scrubbers are widely used for the removal of both particulate matter and gaseous pollutants, although their efficiency in capturing fine particles is limited. Electrospray is a potential method to enhance the collection efficiency of wet scrubbers by introducing charged droplets. This study investigates the droplet characteristics produced by high-flow electrospray and the removal of fine particles in a wet scrubber. Charged droplets were characterized under various electric field strengths, liquid flow rates, and solution conductivities. Additionally, optimum conditions for stable droplet formation and enhanced collection efficiency were identified.
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Spreading aerosol nanoparticles through mobilizing substrates for wafer‐scale nanoprinting Shanghaitech University, China, People's Republic of Due to industrial demand for 3D nanostructures, this work realizes their printing over an entire wafer through mobilizing the substrates to adequately spread aerosol nanoparticles via a printing head. We demonstrated the extreme ability for printing of a drastically great number of periodic nanostructures, 100 million over a 4-inch wafer within just 1 h. Besides, we showed material flexibility for realizing the printing of multimaterials within a single nanostructure. This innovation enables the printing of uniform nanostructures over a virtually infinitely large area with ultra-fast printing speed, upgrading Faraday 3D Printing to match industrial demand.
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Sustainable Aliphatic Polyketone/Nylon6 fibrous Membrane for Emulsion Separation 1Department of Environmental Engineering, National Ilan University; 2Department of Materials Science and Engineering, National Taiwan University Oily wastewater pollution poses a severe threat to humans and marine life due to toxic substances like petroleum hydrocarbons. This study explores electrospun aliphatic polyketone (PK) and nylon 6 (PA6) composite fiber membranes for filtration applications. PK/PA6 membranes exhibited excellent mechanical properties, heat resistance, and reusability, with high separation efficiency. Water flux tests showed PK had high permeability, while pressing reduced pore size for better selectivity. PK, an eco-friendly polymer with a 61% lower CO₂ footprint than PA66, enhances sustainability by reducing fossil fuel dependence, demonstrating the potential of electrospinning in green material manufacturing.
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Volatile organic compounds emission factors for boreal forest surface fires in laboratory experiments 1Department of Environmental and Biological Sciences, University of Eastern Finland, Kuopio, Finland; 2Department of Technical Physics, University of Eastern Finland, Kuopio, Finland; 3Finnish Meteorological Institute, Helsinki, Finland; 4Atmospheric Chemistry Research Group, Chemical Resource Beneficiation, North-West University, Potchefstroom, South Africa; 5Department of Chemistry, University of Eastern Finland, Joensuu, Finland Biomass burning is a major contributor to greenhouse gases, volatile organic compounds (VOCs) and carbonaceous aerosols, into the atmosphere. It is the second largest source of VOCs, yet emission factor (EF) estimates for European boreal wildfires remain limited for VOCs. The aim of this study was to measure VOC emissions from boreal forest surface fires in a laboratory setting for different combustion phases using a proton transfer reaction time-of-flight mass spectrometer (PTR-TOF-MS) and report emission factors for boreal forest surface fires.
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Light absorption dynamics of wildfire-like BrC from wood combustion 1Environmental and Occupation Health Science Institute, School of Public Health, Rutgers University, Piscataway, 08854 NJ, USA; 2Faculty of Aerospace Engineering, Delft University of Technology, Delft, 2629 HS, The Netherlands; 3Institute for Environmental Research and Sustainable Development, National Observatory of Athens, Athens, 15236, Greece; 4Department of Chemistry, University of Crete, Heraklion, 71003, Greece Here, the light absorption of wildfire-like Brown Carbon (BrC) emitted by wood combustion is elucidated using an integrated generation platform coupled with a real-time monitoring and time-integrated sampling instrumentation. The optical properties of Brown Carbon (BrC) are controlled by varying the wood mass and the content of volatile organic carbon, generating particles that can explain the variation between different wildfires in terms of light absorption. The optical properties of BrC obtained here can be interfaced with climate models to determine the contribution of wildfire PM to global warming.
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Condensable PM formation inside the masonry heater and in the emission gases Estonian Environmental Research Centre, Estonia Condensable particulate matter (CPM) emissions from masonry heaters pose environmental and air quality concerns. CPM consists of fine particles that condense into liquid or semi-liquid droplets, influenced by fuel type, combustion conditions, and heater design. Emission measurements vary significantly depending on the sampling method: solid particle (SP) or dilution tunnel (DT). DT captures both solid and condensable organics, preventing underestimation. This study analyzed PM and OGC emissions from the burning chamber of the masonry heater and simultaneously from hot and diluted flue gas, to estimate the condensation processes inside the burning chamber and after the dilution tunnel.
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3D-printed Filters for Particulate Emissions Reduction in Biomass Combustion 1Department of Chemical Engineering, The University of Manchester, M13 9PL, United Kingdom; 2School of Engineering, The University of Manchester, M13 9PL, United Kingdom This study presents a novel soot mitigation method for biomass combustion in domestic stoves, addressing air pollution and health risks. Three 3D-printed filter geometries, (A) straight, (B) 45° rotated, and (C) gyroid, were tested in a stove rig to evaluate their effectiveness in reducing particulate matter (PM). All designs achieved over 50 wt.% PM reduction, with design (B) performing best across all combustion stages. Particle size distribution analysis showed that filters (B) and (C) effectively reduced sub-100 nm particles. No back-pressure build-up was observed, confirming the feasibility of these filters for soot reduction without clogging.
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Electro Hydrodynamic Fabricated Ecofriendly Polymers for PM0.1-0.5 Capture 1National Ilan University, Taiwan; 2National Taiwan University, Taiwan This study develops a transparent fiber filter using polyketone (PK) and polyamide 6 (PA6) via electrospinning for window screens. The filter balances air filtration efficiency and transparency while utilizing natural ventilation. Key parameters, including polymer ratio, spinning time, and hand pressing, were optimized. Results showed fiber diameters decreased from 535 nm to 461 nm with increased PA6 content. Filtration efficiency exceeded 90% before pressing and 98% after, with the highest observed quality factor reaching 0.052 Pa⁻¹. Transparency reached 75.7% under optimal conditions, demonstrating the potential for energy-efficient indoor air purification.
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Field testing of air filters for efficiency of removal aerosol particles in an air handling unit CIOP-PIB, Poland Buildings should be characterized by nearly zero energy consumption, hence there is a risk that the pursuit of energy efficiency may negatively affect IAQ. Hence, it is necessary to properly clean the air using filters in the ventilation units. We perform tests of air filters/filter systems under the conditions of their use in building ventilation units in accordance with the ISO 29462:2022. During the field tests, the installed air filters section system in the air handling unit did not reach the final air flow resistance value of 300 Pa and removed particles below 2.5 µm with an efficiency of 74.11%.
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A Detailed assessment of catalytic reduction of organic emissions from a wood stove using PTR-ToF-MS and FTIR 1University of Eastern Finland, FI-80101, Joensuu, Finland, Finland; 2Department of Environmental and Biological Sciences, University of Eastern Finland, FI-70210, Kuopio, Finland; 3Tulikivi Oyj, Kuhnustantie 22, 83900, Juuka, Finland Residential wood combustion (RWC) significantly contributes to air pollution, prompting stricter regulations. This study evaluates emissions from a modern catalytic wood stove using dual FTIR spectroscopy, PTR-ToF-MS, and gas analyzers. Emissions peaked during cold ignition. The catalyst reduced CO by 37–64% (depending on phase) and total hydrocarbons by ≤34%, with higher efficiency during flaming phases as temperatures rose. Aliphatic hydrocarbons and carbonyls dominated VOC emissions, remaining significant post-catalyst. Despite persistent carbonyls, results highlight the catalyst’s effectiveness in reducing pollutants, particularly CO, supporting its role in mitigating RWC emissions and advancing cleaner residential heating technologies.
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Analysis of pressure drops and dust-holding capacities of nano-micro composite filters during dust loading Kangwon National University, Korea, Republic of (South Korea) The pressure drops and dust-holding capacities of individual filtering layers in a composite filter were experimentally measured during dust loading. The results revealed that the pressure drop of the composite filter was primarily influenced by that of the nanofiber layer, while its dust-holding capacity was predominantly affected by the amount of dust deposited in the microfiber layer. This study provides insights into the role of individual filter layers in optimizing the design of composite filters.
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Development of a High Electric Field Type Electrostatic Precipitator with High Gas Velocity for Diesel Exhaust Particles 1Kanagawa Institute of Technology, Japan; 2Tokyo City University This study investigated an energy-saving in an electrostatic precipitator (ESP) for diesel exhaust particles (DEP), focusing on achieving a collection efficiency greater than 80% at a gas velocity of 10 m/s. Experiments were carried out to clarify the effects of electrode length and gas velocity on the collection efficiency. As a result, it was showed that the collection efficiency achieved 88% at the gas velocity of 2 m/s and 75% at high gas velocity of 10 m/s without energy consumption.
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Effect of reputation frequancy on suspended particle trajectory in nanosecond pulsed discharge with DC bias 1Kanagawa Institute of Tecnology, Japan; 2Polytechnic University, Japan; 3Iwate Univercity, Japan Electrostatic Precipitators (ESPs) are used for indoor air cleaning and exhaust gas treatment. This study examines the effect of repetition frequency on particle trajectories in a wire-to-plate ESP with a DC-superimposed nanosecond pulsed corona discharge. Using COMSOL Multiphysics, particle trajectories were analyzed at 200 pps and 1000 pps. Results show that as frequency increased, particle charge also increased, leading to improved collection efficiency. At 1000 pps, efficiency reached 100%, while at 200 pps, it was only 45%. Charged particles were attracted to the grounded electrode due to electrostatic forces, demonstrating the impact of frequency on ESP performance.
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Application of granular bed theory to predict the filtration performance of porous filters Kangwon National University, Korea, Republic of (South Korea) This study investigates the prediction of the filtration performance of porous filters using granular bed theory. The porous filter is modeled as a hexagonal cell structure, where pores are located at the center, and the surroundung filter medium forms the packing material. The Ergun equation is used to estiimate the pressure drop across the filter, while the log-penetration equation predicts collection efficiency based on single sphere theory, The results demonstrate that these equations can be effectively applied to predict the filtration performance of porous filters.
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Atmospheric Particle Fluxes in the High Arctic Across Three Surface Types 1Chair of Environmental Chemistry and Air Research, Technische Universität Berlin, Berlin, Germany; 2Department of Earth and Environment, University of Leeds, Leeds, England; 3Department of Meteorology, Stockholm University, Stockholm, Sweden; 4Department of Environmental Science, Stockholm University, Stockholm, Sweden; 5Department of Atmospheric Microphysics, Leibniz Institute for Tropospheric Research, Leipzig, Germany This study focuses on turbulent particle flux measurements conducted in the central Arctic during the ARTofMELT research cruise. The measurements aimed to quantify vertical aerosol exchange between open water, sea ice, and the atmosphere. Data were collected from May 9 to June 12, 2023, using two measurement systems: an eddy covariance system with an MCPC mounted on the ship’s foremast and a gradient system with a CPC to measure aerosol concentration, windspeed, and temperature. The results revealed that wide leads exhibited net particle emission, closed ice surfaces exhibited net deposition, and narrow leads exhibited both emission and deposition fluxes.
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Characterisation of Physical and Optical properties of Arctic Dust Aerosols at Villum station 1Department of Chemistry,Aarhus,University,Aarhus, 8000, Denmark; 2Department of Environmental Science, iClimate, ARC, Aarhus University, Roskilde, 4000, Denmark; 3Institute of Meteorology and Climatology, University of Natural Resources and Life Sciences, Vienna, 1180, Austria Arctic dust is emerging as a new type of aerosol in Arctic regions as rapid temperature changes in the Arctic cause snow and ice to melt faster, leading to a larger exposed land area. In this study, we will present optical properties of the aerosols measured during an intense campaign in Greenland, and by combining it with information on local meteorology, back-trajectory analysis and size distributions, discuss emission sources based on the Ångström matrix results, with particular focus on unraveling local dust events.
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Investigating the Impact of heating on Semi-Volatile Organic Species in Cloud Condensation Nuclei Counter 1ETH Zürich, Switzerland; 2Leibniz Institute for Tropospheric Research, e.V. (TROPOS), Permoserstrasse 15, 04318 Leipzig, Germany; 3Aix Marseille Université, CNRS, LCE, Marseille, France; 4Laboratoire de Météorologie Physique, Université Clermont Auvergne, Clermont-Ferrand, 63001, France; 5Univ. Paris Est Créteil and Université Paris Cité, CNRS, LISA, F-94010 Créteil, France streamwise-CCNC developed by DMT Inc., may not accurately capture the co-condensation effect due to particle heating, resulting from the temperature gradient being in the same direction as the sample flow, potentially leading to the evaporation of SVOC's from droplets, underestimating CCN activity. No experimental validation of this effect has been conducted to date. In this study, we examined the impact of heating in a streamwise CCNC on the loss of SVOC's by analysing kappa derived from streamwise CCNC measurements under varying temperature gradients. The results were compared with kappa values obtained from AMS measurements and those predicted by the EAIM-III.
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Chemical characterization of fogs in the hyper arid zone of Namibia 1Aix Marseille Université, CNRS, LCE, Marseille, France; 2Université Clermont Auvergne, CNRS, Clermont-Ferrand, France; 3Université Paris-Est Créteil et Université Paris Diderot, CNRS, LISA, Créteil, France; 4Aix Marseille Université, MIO, La Garde, France; 5Leibniz Institute for Tropospheric Research (TROPOS), Leipzig, Germany; 6North-West University, Unit for Environmental Science and Management, Potchefstroom, South Africa Fog is a vital source of water for local ecosystems in the Namib desert. It forms when the stratocumulus clouds collapse over Atlantic ocean. However, climate change may alter fog occurrence and composition. The chemical composition of fogs at Henties Bay and Gobabeb was studied during the AEROFOG project in 2024. Organic and inorganic parts were analyzed, showing that Henties Bay fogs were marine-influenced, while Gobabeb fogs were influenced by both marine and crustal sources. Organic carbon in fogs was higher than in seawater, with coastal fogs showing volatile DOC that could be linked to microorganisms or surfactant-driven processes.
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Evaluation of different sampling methodologies for the characterization of ice nucleating particle concentration using GRAINS, the new INP spectrometer at the AGORA Observatory 1Andalusian Institute for Earth System Research (IISTA-CEAMA), Granada 18006, Spain; 2Department of Applied Physics, University of Granada, Granada 18071, Spain This work presents the development of the GRAnada Ice Nuclei Spectrometer (GRAINS) at the AGORA Observatory in Southeast Spain, which allows to calculate INP concentrations from 0 to -25°C. GRAINS has been validated with the use of standard samples, such as NX Illite, which shows very good agreement compared to other immersion freezing devices. Different sampling methodologies were carried out at the urban background station of AGORA (UGR, 37.2°N, 3.6°W, 680 m a.s.l.). For that, two different types of filters and three different methods for the analysis in GRAINS were used, showing good agreement in the resulting INP concentrations.
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Intercomparison experiments of two INP spectrometers (INSEKT and GRAINS) at AIDAd chamber 1Andalusian Institute for Earth System Research (IISTA-CEAMA), Granada 18006, Spain; 2Department of Applied Physics, University of Granada, Granada 18071, Spain; 3Institute of Meteorology and Climate Research Atmospheric Aerosol Research, Karlsruhe Institute of Technology, 76021 Karlsruhe, Germany; 4Climate Environmental Research Institute, Korea Institute of Science and Technology, 02792 Seoul, Republic of Korea In this work, we present the intercomparison of two immersion freezing devices: the well-known Ice Nucleation Spectrometer of the Karlsruhe Institute of Technology (INSEKT) and the new GRAnada Ice Nuclei Spectrometer (GRAINS). The comparison of the two devices has been done by evaluating the ice nucleating ability of different minerals and dust particles, such as Arizona Test Dust (ATD) or Soil Dust South Africa (SDSA01), among others. The experiments were conducted at the AIDAd chamber (Aerosol Interaction and Dynamics in the Atmosphere dynamic). INP concentrations obtained with both spectrometers show comparison factors around 2, which is considered as good agreement.
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The Influence of Precipitation on Black Carbon Aerosols 1Research Group of Aerosol Physics and Chemistry, Institute of Chemical Process Fundamentals CAS, Prague, CZ-16500, Czech Republic; 2Department of Atmospheric Physics, Faculty of Mathematics and Physics, Charles University, Prague, 18000, Czech Republic This study investigates the wet removal of Black Carbon (BC) aerosols using long-term (2021–2024) and short-term measurements at rural, urban, and mountain sites. Instruments including Aethalometers (AE33, AE51), a Disdrometer, and a Fog Monitor were used to analyze BC concentration, precipitation, and cloud microphysics. Analysis of 846 rain events at NAOK revealed a 16% reduction in BC and a 9% decrease in particle number concentration (PNC), with the strongest scavenging observed for 50–200 nm particles. Seasonal variations showed lower BC during wet conditions, emphasizing precipitation's role in BC removal. Transient recovery post-rainfall suggests a temporary impact on aerosol levels
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INP parameterization comparison: boundary layer vs free troposphere 1Institute of Chemical Process Fundamentals, Czech Academy of Sciences, Prague, 165 02, Czech Republic; 2Institute of Environmental Sciences, Charles University, Prague, 128 00, Czech Republic As a preliminary study for high-resolution Ice Nucleation Particle (INP) measurements using the online instrument Portable Ice Nucleation Experiment (PINE), we investigate changes in parameterized INP concentration with height at the National Atmospheric Observatory of Košetice (NAOK), a rural background measurement site in Czechia. We use a tall tower facility to measure at 4m and 230m above the ground and the DeMott et al. (2010) parameterization, which is based on the number concentration of particles larger than 0.5 µm and temperature. Our results from December 2024 show higher INP concentration in the free troposphere than in the planetary boundary layer.
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Atmospheric Aerosol Composition and Formation in an Alaskan Boreal Forest 1Institute for Atmospheric and Earth System Research / Physics, Faculty of Science, University of Helsinki, Helsinki, 00560, Finland.; 2Geophysical Institute and Department of Chemistry and Biochemistry, University of Alaska Fairbanks, Fairbanks, AK 99775, USA Boreal forests, covering 27% of the world’s forested area, are key contributors to atmospheric aerosol dynamics through gaseous emissions, which vary by region. North American forests are isoprene-dominant, while European forests, especially in Finland, are more monoterpene-dominant. Observations at Delta Junction, Alaska, since 2023, can provide insights into aerosol processes in this unique environment. During summer 2024, PM2.5 aerosols were dominated by organics, with wildfire events in June–July causing increased concentrations. By August, sulphate and ammonium contributions rose. Further analyses will explore wildfire-related events, new particle formation (NPF), and particle growth dynamics, improving our understanding of boreal forest-atmosphere interactions.
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Atmospheric ions indicating continuous new particle formation in the Mediterranean coastal environment 1University of Crete, Greece; 2National Observatory of Athens, Greece; 3University of the Aegean, Greece; 4University of Helsinki, Finland; 5University of Patras, Greece; 6University of Bremen, German This study examines New Particle Formation at the Finokalia research station in Crete using ion number size distributions from a Neutral Cluster and Air Ion Spectrometer over three-year period (2020-2023). The study revealed that NPF events occurred on 37% of observed days, with seasonal peaks in winter and spring. Negatively charged ions were more reliable indicators of NPF events. Additionally, recent approaches suggest that "Quiet" NPF events, which are not traditionally classified as NPF events, can contribute significantly to particle number concentrations These findings highlight the necessity for a fundamental shift in the classification and analysis of NPF events.
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Composition of air ions during new particle formation events in Cyprus University of Helsinki and The Cyprus Institute, Finland Observations from Cyprus demonstrate frequent NPF in Agia Marina Xyliatos (AMX), with >60% of days exhibiting particle formation (Baalbaki et al., 2021; Deot et al., 2024). The occurrence of NPF events at AMX has been associated with meteorological factors, precursor vapor availability, and air mass history. However, the underlying mechanism driving infrequent NPF during summer remains to be explained. Furthermore, this study will provide novel insights into the role of nucleating vapors and their clusters, such as bisulfate, ammonia, and amines, which could be the primary contributors to NPF formation at our site.
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Contribution of new particle formation events to cloud condensation nuclei concentrations at U.S. observatories 1Andalusian Institute for Earth System Research IISTA, University of Granada, Granada, Spain; 2Department of Applied Physics, Faculty of Sciences, University of Granada, Granada, Spain; 3Department of Atmospheric Sciences, University of Utah, Salt Lake City, UT, United States; 4Atmospheric Sciences Research Center, State University of New York, Albany, NY, United States; 5CIRES, University of Colorado, Boulder, CO, United States; 6Global Monitoring Laboratory, NOAA, Boulder, CO, United States New particle formation (NPF) events contribute to the uncertainty of aerosol-cloud interactions in radiative forcing. To reduce this uncertainty, this work quantifies the contribution of NPF events to cloud condensation nuclei (CCN) concentrations using data from multiple US stations. NPF events are identified and characterized and their impact on CCN is assessed through various methods. The results are compared with model simulations (WRF-CMAQ) that allow the selective inclusion or exclusion of particle nucleation.
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Methanesulfonic acid chemistry and new particle formation : a global model study 1Atmospheric Chemistry Department, Max Planck Institute for Chemistry, Mainz, 55128, Germany; 2Climate and Atmosphere Research Center, The Cyprus Institute, Nicosia, 2121, Cyprus Atmospheric methanesulfonic acid (MSA) originates from the oxidation of dimethyl sulfide (DMS), a key natural sulfur compound released by marine phytoplankton. MSA contributes to aerosol growth and cloud interactions, influencing Earth's radiative balance. However, its role remains underrepresented in climate models. This study evaluates four DMS oxidation mechanisms within the EMAC Earth system model, comparing outputs to field measurements and the impact of MSA new particle formation on the climate. Enhanced MSA production at mid-to-high altitudes, particularly over the Southern Ocean, potentially impacting climate forcing through altered cloud condensation nuclei dynamics.
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Uncertainty Quantification of autoCONSTRAINTS derived Reaction Coefficients with MCMC 1LUT University, Finland; 2University of Helsinki, Finland; 3Atmospheric Modelling Center, Lahti, Finland; 4Pi-numerics This study focuses on quantifying the uncertainty in reaction rate coefficients derived using autoCONSTRAINTS and Markov Chain Monte Carlo (MCMC) methods. VOC autoxidation, a key factor in secondary organic aerosol (SOA) formation, significantly impacts air quality. The autoAPRAM framework, coupled with MCM v3.3.1, models VOC degradation, but reaction rates introduce uncertainties. By constraining rates and identifying sensitive and non-sensitive constants, the study enhances model accuracy and improves atmospheric predictions. Results show how rate sensitivity influences SOA formation, providing insights for targeted experimental validation. Detailed findings will be presented at the conference, with figures illustrating key outcomes.
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Internally Mixed Aerosols in Urban Area of Katowice Conurbation (Poland) 1University of Silesia, Poland; 2University Laboratories of Atmospheric Survey Aerosol particles in the atmosphere often exist as internally mixed particles due to dynamic and chemical transformation processes. As part of ACTRIS facilities, multiple measurement campaigns were conducted over the Katowice conurbation using a mobile laboratory in a manned hot-air balloon. Aerosol samples were collected via an aspirator. Individual aerosol particles were analysed using scanning electron microscopy (SEM) with energy-dispersive spectroscopy (EDS). Internally mixed aerosols may form through cloud processes, including droplet coalescence. Samples collected up to 1900 meters above sea level contained sulfates and chlorides likely formed in situ in the urban atmosphere via gas-to-particle conversion.
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Secondary particle formation in the aqueous phase – Conversion of catechol in the presence of iron Technische Universität Berlin, Germany The role of iron in the multiphase system of the atmosphere remains poorly investigated. Previous studies have demonstrated that ferric iron leads to the formation of secondary brown carbon through its reaction with catechol at pH 3, thus having a direct impact on the Earth's radiative budget. In this study, we observed the formation of insoluble, greyish particles in the presence of both ferrous and ferric iron under dark and light conditions. Furthermore, we found that the presence of hydrogen peroxide fundamentally alters the mechanism.
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Sensitivity Analysis of a New Inorganic Multiphase Chemical Model Institute for Atmospheric and Earth System Research (INAR) of University of helsinki, Finland This study enhances the accuracy of simulating atmospheric particles by integrating multiphase inorganic chemistry into the BoxMART model. The key advancement is the incorporation of physicochemical processes, which more realistically represents the dynamics and interactions of inorganic particles in the atmosphere. Through sensitivity analysis, we explored the impact of various conditions on aerosol formation and evolution. The results indicate that changes in these conditions significantly affect aerosol behavior. This improvement is crucial for understanding of aerosol dynamics and contributes to atmospheric aerosol chemistry. Integrating multiphase chemistry into the model significantly enhances its ability to simulate atmospheric chemical processes.
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Towards automated inclusion of representative autoxidation chemistry in explicit models 1University of Helsinki, Department of Chemistry & Institute for Atmospheric and Earth System Research, P.O. Box 55 (A.I. Virtasen aukio 1), 00014 Helsinki, Finland; 2Univ Paris Est Créteil and Université Paris Cité, CNRS, LISA, 94010 Créteil, France; 3Atmospheric Chemistry Observations and Modeling Lab, National Center for Atmospheric Research, P.O. Box 3000, Boulder, CO 80307, USA; 4Aerosol Physics Laboratory, Tampere University, Tampere FI 3720, Finland We are aimong to develop the most complete and chemically explicit model for RO2 autoxidation that can be achieve with our current knowledge. This model will be included in the existing code Generator for Explicit Chemistry and Kinetics of Organics in the Atmosphere (GECKO-A), and we aim for it to include autoxidation reactions of both the H-shift and C=C ring-closure types. We hope that a complete and explicit code such as ours will be very useful for the modelling community when more specialized truncated models
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Implementation of a particle resuspension model in a Large Eddy Simulation code University of Evry Paris Saclay, France Particle resuspension is an indirect source of pollutant exposure in urban areas. In order to better understand resuspension dynamics in urban environments, a resuspension model has been coupled to a Large Eddy Simulation code. A discretized formulation of the well known Rock'n'Roll model was developped for this specific purpose. This formulation was validated and provides a good foundation to study the sensitivity of the Rock'n'Roll model to its parameters. Our work aims to provide guidelines to create healthier urban environments and understand how evolving transportation technologies will shape pollutant exposure patterns.
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Influence of long-range transport over the sea on submicron aerosol chemical composition 1Center for Physical Sciences and Technology, Lithuania; 2Lund University The study presents investigation of submicron aerosol chemical composition changes during long-range air mass transport events across the Baltic Sea between two sites: Hyltemossa (Sweden) and Preila (Lithuania). Having backward air mass trajectories across Hyltemossa and Preila modelled using HYSPLIT and two sets of in-situ sensors (ToF-ACSM, AE33 in Hyltemossa and Q-ACSM, AE31 in Preila), allowed us to investigate the same air mass before and after crossing over the sea. The proposed classification of the connected flow events enabled us to quantitively assess the net result of atmospheric processes taking place during long-range transport over the sea.
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Optimizing Black Carbon emissions on a global scale using TM5-MP and CTDAS 1Department of Chemistry, University of Crete, Greece; 2Insitute for Environmental Physics, University of Bremen, Germany; 3Institute for Chemical Engineering Sciences, Foundation for Research and Technology Hellas, Greece Black Carbon is a short-lived aerosol that influences air quality and climate warming, along with greenhouse gases.The vast range of its emissions sources play a significant role in the estimation of its fluxes. Accurate estimation and modeling of BC emissions remain challenging. In the study, inverse global modeling, using TM5-MP model integrated with CTDAS , is used to optimize BC emission estimates based on the CMIP6 inventory. Emission corrections are computed regionally using observational data from filter-based techniques and aethalometers, then validated against AERONET measurements to assess model performance improvements.
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Simulating the Effect of Bark Beetle Infestation on Secondary Organic Aerosol (SOA) and Ozone Leibniz Institute for Tropospheric Research, Germany Spruce bark beetle increasingly cause wounding at tree stems, which leads to the release of very high BVOC emissions. A new biotic stress parametrization, which accounts for the exponential spreading of bark beetles along one seasonal cycle and applies increased emission potentials for Norway spruce, was integrated in the CTM COSMO-MUSCAT. The stress parametrization was tested and compared to a reference setup. The increased monoterpene and sesquiterpene emissions led to elevated SOA concentrations on regional and continental scale, with variations between day and night. The ozone concentration was observed to decrease in spruce abundant regions.
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An improved Europe-wide spatiotemporal machine learning modelling for PM2.5 using European open databases University of Wrocław, Poland Our study develops a spatiotemporal machine learning model to improve the accuracy of hourly PM2.5 predictions across Europe from 2021 to 2023, leveraging European open datasets. Key predictors include meteorological, environmental, pollutant, and land use data. The developed Extreme Gradient Boosting (XGBoost) model outperforms existing numerical model-based datasets (such as CAMS Ensemble) in capturing PM2.5 variability, as confirmed by spatiotemporal cross-validation results. Future work will extend the model to 2003–2023, enhancing long-term trend analysis. The publicly available dataset will support air quality research, policy evaluation, and public health assessments by providing high-resolution, accurate PM2.5 estimates across Europe.
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Development and Evaluation of Coupled Climate Simulations Using Machine Learning Enhanced Aerosol Model 1University of Eastern Finland, Finland; 2Foundation For Research and Technology Hellas, Institute of Chemical Engineering Sciences, Greece; 3Finnish Meteorological Institute, Finland Aerosol-cloud interactions occur on a microscopic scale yet affect cloud systems on a scale of kilometers. Accurate modeling on such a large scale requires a lot of computational resources. A simple aerosol model enhanced with machine learning will be developed to solve this problem. Such a model learns to imitate the results of more complex models while remaining computationally lighter. The aerosol model will be integrated into the kilometer-scale climate model Integrated Forecasting System (IFS). The aim is to improve the accuracy of IFS without significantly increasing its computational cost.
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Numerical Simulation Analysis on SO2 and Sulfate Aerosol Source Apportionment in the Tibetan Plateau insititute of earth environment, chinenes academy of sciences, China, People's Republic of This study utilized the source-oriented WRF-Chem model to conduct a thorough source apportionment analysis of SO2 and sulfate aerosols over the Tibetan Plateau from June to September 2012. SO2and sulfate aerosols were categorized into seven groups. The results revealed that the primary non-local contributor of SO2 and sulfate aerosols was the East source, constituting 28.34% and 19.81%. Significant contributions also came from the South source, amounting to 26.20% and 14.96%. The Southeast, West, Central, and Other sources contributed 6.96%, 0.90%, 4.20%, 2.77% and 5.19%, 1.22%, 3.11%, 4.42% to the modeled SO2 and sulfate aerosols, respectively.
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Spatial and temporal variability of ultrafine particle number concentrations and their link to air quality close to Munich airport in 2023 University of Bayreuth, Germany Airports can affect local air quality by emission of ultrafine particles (UFP, <100nm). Here, we analyse the spatial and temporal variability of UFP close to Munich airport for the year 2023 using measurements of particle number concentration, particle size distribution, ozone, nitrogen oxides, meteorological data, and traffic/airport operations. Long-term, seasonal, and diurnal trends reveal distinct behaviours of UFP, including rush-hour peaks and site-specific differences, highlighting the impacts of airport operations, traffic emissions, and atmospheric conditions.
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Impacts of changes in land use and land cover between 2001 and 2018 in winter haze pollution in North China Plain and surrounding areas-A case study Institute of Earth Environment, Chinese Academy of Sciences, China, People's Republic of Combing satellite data and WRF-Chem simulations, we assess LUCC impacts (2001–2018) on PM₂.₅ in North China Plain (NCP). Satellite observations show 5%–20% increased forest cover and up to 25% urban expansion in NCP. Average PM₂.₅ decreased by 5.2 μg m⁻³ (3.9%), with urban reductions of 15.5 μg m⁻³ (14.8%). Urbanization-driven sensible heat flux (HFX) rose by 10.7 W/m² (47.5%), elevating planetary boundary layer height (PBLH) by 54.8 m (13.1%). Enhanced vertical dispersion from PBLH deepening dominated PM₂.₅ mitigation, outweighing wind effects. Results highlight LUCC’s role in modifying boundary-layer dynamics to reduce pollution, supporting LUCC integration into air quality policies.
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Composition, sources and formation process of atmospheric aerosol in marine atmosphere 1Fudan University, China, People's Republic of; 2Karlsruhe Institute of Technology, Germany Our study investigates the sources and interactions of atmospheric aerosols in the coastal regions of China, with a particular emphasis on the impacts of anthropogenic activities and oceanic emissions. It quantitatively analyzes the factors affecting the pH of marine atmospheric aerosols and assesses the contribution of marine biogenic emissions to the total organic aerosol mass. The sources and secondary formation processes of saccharides, organic acids, organic amines, and organic sulfides are discussed, along with their influencing factors. Additionally, the molecular characteristics of marine atmospheric organic aerosols are characterized, and their dynamic evolution processes are discussed.
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A mass-spectrometric study of the formation and aging of organic aerosol from vanillin oxidation 1Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Germany; 2Particle Chemistry Department, Max Planck Institute for Chemistry, Mainz, Germany; 3Institute for Atmospheric Physics, Johannes Gutenberg University, Mainz, Germany; 4Department of Chemistry, Johannes Gutenberg University, Mainz, Germany Biomass burning (BB) significantly impacts air quality, health, and climate, yet the oxidation products and transformation processes of its emitted compounds remain largely unexplored. This study examines the atmospheric aging of vanillin, a BB tracer from lignin pyrolysis, using a potential aerosol mass oxidative flow reactor (PAM-OFR). Oxidation with ozone and hydroxyl radicals generated over 60 reaction products, analyzed via online Orbitrap mass spectrometry, aerosol mass spectrometers, and offline liquid chromatography. A comparison between laboratory experiments and ambient measurements from the Po Valley revealed a substantial overlap for both online and filter measurements.
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First study of the composition of cloud water collected at Monte Cimone observatory during the MC3 campaign in October 2024. 1Laboratoire de Météorologie Physique LaMP, CNRS, Université Clermont Auvergne, Aubière, 63178, France; 2Institut de Chimie de Clermont-Ferrand, Université Clermont Auvergne, CNRS, Clermont-Ferrand, 63000, France; 3Institute of Atmospheric Sciences and Climate, National Research Council of Italy, Bologna, 40129, Italy; 4Observatoire de Physique du Globe de Clermont-Ferrand, UMS 833, CNRS, Université Clermont Auvergne, Aubière, 63178, France New insights on cloud water composition from the sampling campaign (MC3), funded by ACTRIS ATMOACCESS, that took place at Monte Cimone (CMN, Italy) in October 2024. Chemical and microbiological characterization of 26 samples was carried out to study the influence of air mass origin on cloud chemical composition, reactivity, and on the distribution of microorganisms present in the cloud water
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Characterization of PM₂.₅-Associated Dicarboxylic Acids and Sugars: Insights into Biomass Burning and Air Quality Dayalbagh Educational Institute, India This study examines the temporal and seasonal variations of PM₂.₅-bound dicarboxylic acids (DCAs) and sugars in Agra, a highly polluted Indo-Gangetic Plain (IGP) city. Biomass burning, secondary aerosol formation, and meteorological factors drive their concentrations, peaking post-monsoon and in winter. Diagnostic ratios confirm primary and secondary sources, while air mass analysis highlights long-range aerosol transport from northwestern India and other continents. These findings provide critical insights into atmospheric chemistry, climate implications, and air quality regulation. The study underscores the need for targeted mitigation strategies, particularly during high-emission periods, to reduce pollution and its associated health risks.
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Characteristics and levels of carbonaceous aerosols from real-time measurements during Diwali festivity Indian Institute of Technology Bombay, India Carbonaceous aerosols (CA) significantly impact atmospheric processes, including radiative forcing and air quality. CA consists of organic matter and elemental carbon, with brown carbon (BrC) acting as a photosensitizer producing reactive species. BrC's optical variability introduces uncertainties in climate models. A continuous CA measurement system was used in Mumbai during Diwali 2023 & 2024, revealing rapid pollution spikes due to firecrackers and biomass burning. CA sources were categorized, showing SOABrC increased post-Diwali. This first-of-kind study from India gives insights into CA's intricate dynamics, environmental impact and the need for further research on its health risks and atmospheric interactions.
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Emission factors of organic aerosols from a prescribed burning of European boreal forest 1Department of Technical Physics, University Of Eastern Finland, Finland; 2Department of Environmental and Biological sciences, University of Eastern Finland, Finland; 3Finnish Meteorological Institute, Helsinki, Finland Wildfires are one of the largest source of atmospheric aerosols affecting both air quality and the climate system. Due to climate change, the frequency of wildifres have increased drastically in the past decade. Characterizing such biomass burning (BB) emissions is, therefore, crucial for understanding their impact on the atmosphere. In this study, we measured BB aerosols emitted from prescribed burning of boreal forest to obtain the emission factors (EFs). The aerosol mass concentration showed an substantial increase during fire reaching ~1000 times higher than the usual conditions at this location. EFs for the aerosols showed clear dependency on the MCE.
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Influence of the anthropic settlements on European Arctic climate in terms of Light-Absorbing Aerosol concentrations and Heating Rate 1GEMMA and POLARIS Centre, Università degli Studi di Milano Bicocca, Milano, 20126, Italy; 2Institute of Atmospheric Sciences and Climate (ISAC), National Research Council (CNR), Roma, 00133, Italy; 3Istituto Nazionale di Fisica Nucleare (INFN), Firenze, 50019 , Italy; 4Department of Physics, Università degli Studi di Milano and INFN, Milan, 20133, Italy; 5Institute of Oceanology Polish Academy of Sciences (IOPAN), Sopot, 81-712, Poland; 6Aerosol d.o.o., Ljubljana, 1000, Slovenia; 7Institute of Polar Sciences (ISP), National Research Council (CNR), Bologna, 40129, Italy The Arctic region is warming faster than the rest of the globe and an important role is played by local concentrations of atmospheric aerosols (e.g. BC) through their indirect and direct effets. Therefore, we took part in two AREX summer campaigns in 2018 and 2019 in order to experimentally determine the surface BC concentrations and their HR over the Arctic Ocean around Svalbard Islands and within the anthropized fjords of Spitsbergen. We found that there are significant differences between the anthropogenic fjords / hotspots considered in this study and the Arctic ocean background due to the role of local sources
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Tethered Balloon Observations of Vertical Aerosol Distributions at Neumayer III, Coastal Antarctica 1Extreme Environments Research Laboratory, École Polytechnique Fédérale de Lausanne, Sion, Switzerland; 2Alfred Wegener Institute, Helmholtz Centre for Polar and Marine Research, Bremerhaven, Germany The Southern Ocean significantly impacts global atmospheric circulation, with Antarctic cloud cover playing a key role in the surface radiation budget. However, poor understanding of aerosol-cloud interactions leads to biases in climate models. During the ORACLES field campaign at Neumayer III, a tethered balloon system was used to measure aerosol properties up to 900 m altitude. Results from 66 flights indicate that the aerosol distribution is strongly influenced by wind direction, with marine aerosols dominating under oceanic airflow, while katabatic winds transport lower concentrations of aerosols from inland. This dataset provides valuable insights into Antarctic aerosol characteristics and cloud interactions.
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Airborne measurements of the spatial distribution and variability of ultrafine aerosol particles in Svalbard during melting season 2024 1Institute of Flight Guidance, Technische Universität Braunschweig, Braunschweig, 38108, Germany; 2Institute for Atmospheric and Earth System Research, University of Helsinki, Helsinki, 00560, Finland; 3Department of Environmental Science, Stockholm University, Stockholm, 11418, Sweden; 4Leibniz Institute of Tropospheric Research, Leipzig, 04318, Germany; 5Physics of the Atmosphere, Alfred Wegener Institute, Potsdam, 14473, Germany Aerosol particles contribute to an incomplete understanding of the Arctic amplification. To improve the comprehension of aerosol processes in the lower troposphere, airborne measurements of ultrafine aerosol particles (UFP) were conducted in Ny-Ålesund, Svalbard, during the melting season from May to June 2024. The occurrence of UFP in the size range of 4-19 nm (N4-19) was observed frequently during the campaign. This presentation focuses on a first case study on 24 May 2024, showing high concentrations of N4-19 exceeding 10,000 particles per cm3, including a high temporal and spatial variability within a few hundred meters.
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Condensation-freezing Ice Nucleating Particles at Ny-Ålesund: seasonality and sources investigated by the Dynamic Filter Processing Chamber 1Institute of Atmospheric Sciences and Climate, National Research Council of Italy, Bologna, 40129, Italy; 2Institute of Polar Sciences, National Research Council of Italy, Bologna, 40129, Italy Ice-nucleating particles (INPs) play a critical role for Arctic clouds, by initiating ice crystal formation, a process that governs cloud phase, optical properties, and lifetime. This study presents atmospheric INP concentration data from Ny-Ålesund (Svalbard), collected over three years (2018-2020), during 6 intensive campaigns, covering three seasons (spring, summer and autumn). Ambient INP concentrations were measured offline, in condensation freezing mode at water saturation ratio of 1.02, by means of the Dynamic Filter Processing Chamber at the activation temperatures of -15, -18 and -22°C.
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Dust sources in Iceland: Insights from the High-Latitude Dust Experiment in 2021/2022 1Institute of Meteorology, Freie Universität Berlin, Berlin, Germany; 2Institute of Applied Geosciences, Technical University of Darmstadt, Darmstadt, Germany; 3Leibniz Institute for Tropospheric Research (TROPOS), Leipzig, Germany; 4Barcelona Supercomputing Centre (BSC), Barcelona, Spain; 5Danish Meteorological Institute (DMI), Copenhagen, Denmark; 6Institute of Meteorology and Climate Research, Karlsruhe Institute of Technology (KIT), Karlsruhe, Germany; 7Institute of Environmental Assessment and Water Research – Consejo Superior de Investigaciones Científicas (IDAEA-CSIC), Barcelona, Spain; 8Center for Atmospheric Research, University of Nova Gorcia, Slovenia; 9INRAE, Bordeaux Science Agro, ISPA, Villenave d’Ornon, France; 10Faculty of Environmental and Forest Sciences, Agricultural University of Iceland, Iceland; 11Faculty of Environmental Sciences, Czech University of Life Sciences, Czech Republic; 12ICREA, Catalan Institution for Research and Advanced Studies, Barcelona, Spain Although research on dust aerosol and related feedback processes has been carried out using a variety of approaches, knowledge of mineral dust particles emitted at high latitudes is still limited, despite its pivotal impact on polar environments. Here, we present results from the high-latitude dust experiment which took place in 2021/2022 in Iceland offering insights in dust emission processes and their controls. Findings from our study shed light on the complex web of interactions that are defined by the variability of dust source characteristics and wind speed distribution, ultimately contributing to the understanding of dust emission in cold climate regions.
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High Gaseous Methanesulfonic Acid in Antarctic Air: Evidence of Evaporation from Particle Surfaces During Katabatic Outflows 1Queensland University of Technology, Australia; 2University of Tasmania, Australia; 3Commonwealth Scientific and Industrial Research Organisation (CSIRO), Australia Dimethyl sulfide (DMS) oxidation in the marine atmosphere produces methanesulfonic acid (MSA) and sulfuric acid (SA), impacting aerosol formation and cloud properties. This study presents high-resolution measurements of gaseous MSA during two Southern Ocean voyages (CAPRICORN-2, 2018; MISO, 2024) using NO3-CIMS. Periods of elevated gaseous MSA were observed at high latitudes and coincided with cold, dry Antarctic outflows, high aerosol acidity (pH ~ -1), and enhanced cloud condensation nuclei (CCN). E-AIM modeling confirms MSA volatilization from aerosols as a key source of gas-phase MSA, linking atmospheric conditions to MSA partitioning and aerosol chemistry.
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High spatial resolution measurements of the aerosol climate-relevant parameters from mid-latitudes to the Arctic, up to 90°N (GAIA) 1National Institute for Nuclear Physics, Florence, Italy; 2Dept. of Physics and Astronomy, University of Florence, Florence, Italy; 3Department of Physics – Università degli Studi di Milano and INFN, Milan, Italy; 4GEMMA Center, Department of Earth and Environmental Sciences, University of Milano-Bicocca, Italy; 5Institute of Atmospheric Sciences and Climate (ISAC), National Research Council (CNR), Rome, 00133, Italy; 6Institute of Polar Sciences, National Research Council (CNR), Bologna, 40129, Italy; 7IOPAN, Institute of Oceanology Polish Academy of Sciences, Poland; 8University of Bremen, Institute of Environmental Physics, Bremen, Germany; 9Alfred Wegener Institut (AWI), 27568, Bremerhaven, Germany GAIA project aims at developing and integrating new experimental and modelling tools to give information on georeferenced climatic impact of different aerosol sources and types in all sky conditions from Mid Latitudes till the Arctic Ocean. During summer 2024 GAIA performed two measurement campaigns on board the German icebreaker Polarstern (AWI), reaching up to 90°N, and the Oceania vessel (IOPAN). Results from these campaigns will be presented.
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Source areas and effect on snow albedo of mineral aerosol deposition on snow in North Western Greenland 1Department of Chemistry “Ugo Shiff”, University of Florence, Florence, I-50019, Italy; 2Istituto Nazionale di Geofisica e Vulcanologia, INGV, Rome, 00143, Italy; 3ENEA, Laboratory of Models and Measurements for Air Quality and Climate Observations, Rome, 00123, Italy; 4Department of Physics, Sapienza University of Rome, Rome, 00185, Italy; 5Department of Earth Physics and Thermodynamics, University of Valencia, Valencia, 46100, Spain; 6Institute of Applied Geosciences, Technical University of Darmstadt, Darmstadt, 64287, Germany In March 2024 a sampling campaign of surface snow was accomplished in North-western Greenland. Snow samples are filtered and analyzed by SEM and for ions and elements. In parallel PM10 samples are collected and chemically characterized. Dry deposition seems the main mechanism of dust deposition on the snow in the considered time range. By combining the measured dust concentration in the surface snow with modelled and measured reflectivity spectra we try to quantify the influence of deposited dust on the snow albedo. Besides, by chemical analysis of aerosol and snow samples, the possible source areas of mineral dust are investigated.
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Zooplankton grazing increases atmospheric primary aerosol production in the high Arctic 1CSIC, Spain; 2University of Plymouth, Plymouth, UK; 3University of Rhode Island, Narragansett, Rhode Island, USA; 4Hokkaido University, Hakodate, Japan; 5Department of Environment & Energy Engineering, School of Smart & Green Engineering, Changwon National University, Republic of Korea; 6Korean Polar Research Institute, Republic of Korea Sea spray aerosol (SSA) particles are a main source of aerosols; they influence cloud formation and cloud properties. Ocean microbiota potentially have an impact on SSA production and flux, but our understanding of the mechanisms is still limited. In this multidisciplinary study conducted in the central Arctic during MOSAiC expedition, air-sea interactions were measured by means of in-situ bubble-bursting experiments. For the first time, we studied the effect of zooplankton grazing on aerosol production. We found that experimental water subjected to zooplankton grazing had a 2-fold increase in SSA production relative to controls without zooplankton.
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Characterizing Particulate Matter Concentrations in Southern Iceland 1Palas GmbH, Germany; 2Environmental Sciences, Agricultural University of Iceland, Reykjavík, 112, Iceland The Copernicus Atmosphere Monitoring Service (CAMS), part of the European Union’s Copernicus Programme, provides high-quality data on air pollution, greenhouse gases, and climate forcing. The CAMS National Collaboration Programme (NPC) in Iceland is intended to improve the country's air quality monitoring systems and increasing public awareness of environmental issues and their wider effects on climate and health. Within the framework of NCP, we installed one AQ Guard Smart Aerosol Spectrometers to observe particulate matter variability in Mýrdalssandur - a newly identified dust source area. We have measured Cn, PM1, PM2.5, PM10, and TSP and meteorological parameters at high temporal resolution.
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Pristine Antarctic Cloud Condensation (CCN) and Ice Nucleating Particle (INP) Concentrations and Properties at Neumayer Station III 1Leibniz-Institute for Tropospheric Research, TROPOS, Leipzig, Germany; 2Alfred-Wegener-Institut, Helmholtz-Zentrum für Polar- und Meeresforschung, Bremerhaven, Germany Since 2019, TROPOS has been carrying out continuous in-situ measurements of cloud condensation nuclei (CCN) and ice nucleation particles (INP) at Neumayer Station III (NM III, 70° 40′ S, 8° 16′ W), located in Atka Bay on the Ekström Ice Shelf, in order to improve the data base and thus the knowledge of the locally important particle formation processes for both. The annual cycle of CCN and INP, characteristics and importance of local sources are presented, together with a parameterisation for Antarctic INP.
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A molecular journey from the Baltic Sea to Svalbard: HRMS on organic aerosols collected on board the Oceania vessel 1Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Frankfurt am Main, Germany; 2Environmental Protection Agency of Lombardy Region (ARPA Lombardia), Milan, Italy; 3POLARIS research centres, University of Milano-Bicocca, Milano, Italy; 4Department of Physics, Università degli Studi di Milano and INFN-Milano, Milan, Italy; 5Department of Physics and Astronomy, University of Florence, Sesto Fiorentino (FI), Italy; 6National Institute for Nuclear Physics (INFN), Florence div., Sesto Fiorentino (FI), Italy; 7IOPAN, Institute of Oceanology Polish Academy of Sciences, Poland; 8National Research Council - Institute of Atmospheric Sciences and Climate (CNR-ISAC), Italy The light-absorbing properties of organic aerosols (OA) are a topic of increasing interest among the scientific community. In this work, we invastigate the molecular composition of MeOH-water soluble OA collected at the bow of the Oceania vessel along its journey from the Baltic Sea to Svalbard. An analysis of potential brown carbon compounds is conducted to assess relationships with light-absorption properties.
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Black carbon in the Arctic (Ny-Ålesund): An Assessment Comparing AE33 and LIDAR Data 1DAIS Department of Environmental Sciences, Computer Science and Statistics, University of Ca’ Foscari, Via Torino 155, 30172 Venezia Mestre; 2GEMMA Centre, Department of Earth and Environmental Sciences, University of Milano-Bicocca, Piazza della Scienza 1, 20126, Milan, Italy; 3National Research Council, Institute of Polar Sciences (CNR-ISP), Via Cozzi 53, Milano, 20125, Italy; 4National Research Council, Institute of Polar Sciences (CNR-ISP), Via P. Gobetti 101, Bologna, 40129, Italy; 5Alfred Wegener Institute, Helmholtz Centre for Polar and Marine Research, Telegrafenberg A 45, 14473, Potsdam, Germany Arctic amplification leads to a rapid warming of the Arctic. Light-absorbing aerosols (LAAs), including black carbon (BC), are key uncertainty factors in this phenomenon. This study analyses BC concentrations and their correlations with meteorological parameters, at Ny-Ålesund in 2022. Continuous BC measurements were performed with an AE33 etalometer, and LIDAR data from MPL and WindCube instruments were analysed. Preliminary results suggest a limited correlation between BC and LIDAR data, highlighting the difficulties in comparing ground and elevation measurements produced by AE33 and LIDAR respectively. A possible solution could be organising tethered balloon launches to perform vertical profiles of BC concentration.
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Chemical Composition of Size-Segregated Aerosols During Second Turkish Artic Scientific Expedition (TASE-II) 1Department of Environmental Engineering, Bolu Abant İzzet Baysal University; 2Institute of Environmental Sciences, Boğaziçi University; 3Department of Environmental Engineering, Bursa Technical University The Arctic region is experiencing warming at an unprecedented rate compared to the rest of the planet, leading to significant changes in sea ice coverage (Smith et al., 2015). Atmospheric aerosols play a crucial role in modifying the energy balance of the atmosphere through various mechanisms. The radiative forcing of aerosols is significantly influenced by their chemical and physical characteristics. Consequently, it is crucial to investigate these properties, especially in Arctic regions. The objective of this study is to determine the chemical composition of aerosols onboard in the Arctic Ocean during the second Turkish Arctic Science Expedition (TASE II).
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Continental river runoff over the Arctic Ocean enhances atmospheric aerosol formation 1University of Birmingham, UK; 2Boston University, USA; 3Aerodyne Research Inc., Billerica, Massachusetts 01821, USA; 4University of Helsinki, Helsinki, 00014, Finland; 5FMI, Finland; 6ICM CSIC, Spain The warming Arctic climate is highly sensitive to the presence of cloud condensation nuclei (CCN). A major source of Arctic CCN is New Particle Formation (NPF), however, the sources of vapours driving NPF are still unclear. The Arctic Ocean—the smallest and shallowest of the world's oceans—receives approximately 10% of global river runoff, which is rich in terrigenous dissolved organic matter (tDOM). Here, we explore the association between a 9-year (2010-2018) record of atmospheric aerosol size distributions taken at Tiksi (Russia) and its overlap with air mass trajectories analysis combined with ocean remote sensing data.
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GAInfrA: A Versatile Mobile Laboratory for Aerosol, Clouds and Radiation Studies in Extreme Environments 1Institute of Atmospheric Sciences and Climate (ISAC), National Research Council (CNR), Italy; 2Department of Physics – Università degli Studi di Milano and INFN, Milan, Italy; 3GEMMA Center, Department of Earth and Environmental Sciences, University of Milano-Bicocca, Italy; 4Institute of Polar Sciences, National Research Council (CNR), Bologna, 40129, Italy; 5University of Bremen, Institute of Environmental Physics, Bremen, Germany; 6Alfred Wegener Institut (AWI), 27568, Bremerhaven, Germany; 7Dept. of Physics and Astronomy, University of Florence, Florence, Italy; 8INFN (Istituto Nazionale di Fisica Nucleare), Florence, Italy The GAIA project developed GAInfrA, a custom mobile laboratory for aerosol, cloud, radiation, and meteorological measurements. Deployed on the German icebreaker Polarstern (June–October 2024), it continuously collected high-resolution data on aerosol properties, radiation budgets, and vertical profiles. Designed for extreme Arctic conditions, GAInfrA features dedicated sampling lines, an integrated power system, and remote access for continuous monitoring. Its design was optimized using SolidWorks simulations. The system proved highly reliable, collecting high-quality data for over 90% of the campaign, providing valuable insights into aerosol-radiation interactions and their role in climate dynamics
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Long-term Trends of Key Chemical Species in the High Arctic and Possible Drivers 1Department of Environmental Science, Aarhus University, 4000 Roskilde, Denmark; 2iCLIMATE Aarhus University Interdisciplinary Centre for Climate Change, Aarhus University, 4000 Roskilde, Denmark; 3Department of Geosciences, University of Oslo, 0371 Oslo, Norway; 4National Research Centre for the Working Environment, Chemistry, Copenhagen, Denmark; 5University of Copenhagen, Department of Chemistry, Copenhagen, Denmark The warming in the Arctic is amplified, especially in winter, which can be up to 4 times higher than the rest of the globe. In this study, we utilize weekly high-volume samples and filter pack samples from Villum research station from 2008 to 2023 to investigate the long-term trends of key chemical species and their potential drivers. Elemental carbon shows the strongest decline in spring. Elemental carbon, sulfate, and lead exhibit stagnation or a slight increase after 2016, a trend also observed in the absorption coefficient at Zeppelin Station. However, the causes behind this shift in 2016 remain under investigation.
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Preliminary Results from the CleanCloud Campain in Greenland – Villum Research Station 1Laboratory of Atmospheric Processes and Their Impacts, School of Architecture, Civil and Environmental Engineering, École Polytechnique Fédérale de Lausanne, Lausanne, Switzerland.; 2Environmental Remote Sensing Laboratory, School of Architecture, Civil and Environmental Engineering, École Polytechnique Fédérale de Lausanne, Lausanne, Switzerland.; 3Laser Remote Sensing Unit, Physics Department, National Technical University of Athens, Zografou, Greece; 4Department of Environmental Science, Aarhus University, Roskilde, Denmark.; 5Leibniz–Institut für Troposphärenforschung, Leipzig, Deutschland.; 6DTU Wind and Energy Systems, Technical University of Denmark, Roskilde, Denmark. Our study focuses on the preliminary results of the CleanCloud campaign, which was based at the Villum Research Station in collaboration with the NASA ARCSIX aircraft mission in 2024. We present the cloud and aerosol microphysical characteristics determed by using a synergy of in situ instruments to obtain the aerosol microphysical characteristics (size distribution, CCN concentrations, and bioaerosol number concentration) and remote sensing instrumentation like lidar systems to determine the aerosol's profile, a Doppler lidar for turbulence and cloud scale dynamics, a radar for the cloud microphysical properties, and satellites to retrieve the spatio-temporal evolution of the clouds.
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Validation of methods for simulating aerosol samples from remote dust sources using a resuspension chamber 1Department of Chemistry, Biology and Biotechnology, University of Perugia, Perugia, 06123, Italy; 2Department of environmental sciences, informatics and statistics, University of Venice, Mestre, 30170, Italy; 3Department of Physics and Astronomy, University of Florence and INFN, Sesto F.no, 50019, Italy; 4Department of Chemistry “Ugo Schiff”, University of Florence, 50019 Sesto Fiorentino (FI), Italy Studying high-latitude dust sources is challenging due to their remote locations, where aerosol samplers cannot be deployed. These sources remain poorly characterized, despite their increasing relevance to climate change. To address this, we simulated aerosol samples from soil materials using a custom resuspension chamber at the University of Perugia. The system resuspended soil particles, which were collected on filters for chemical and physical analysis. The method was validated with certified reference materials and tested with various soil samples to assess the impact of particle size and mineral composition on the digestion process and isotopic analysis (Sr, Pb).
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A Simple Surface-bulk Partitioning Model for Estimating Size-dependent Surface Tension of Deliquesced Aerosol Particles 1Institute of Multidisciplinary Research for Advanced Material, Tohoku University, Sendai, Japan; 2The Institute of Environment, Energy, and Sustainability, The Chinese University of Hong Kong, Hong Kong 999077, China; 3Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, Tokyo, Japan Atmospheric aerosols influence climate by acting as cloud condensation nuclei (CCN), with their activation governed by the Köhler curve. While hygroscopicity is well studied, the impact of size-dependent surface tension on CCN activation remains unclear. This study develops a model based on Langmuir adsorption theory to predict surface tension in surfactant-containing droplets. Model validation using experimental data for NaCl-SDS solutions shows that fitted Langmuir parameters improve surface tension predictions. The results highlight the importance of accounting for size-dependent surface tension when evaluating CCN activity and demonstrate that appropriate adsorption parameters can be determined from microdroplet measurements.
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Cloud Condensation Nuclei properties and variability at Mt. Cimone station 1Italian National Research Council – Institute of Atmospheric Sciences and Climate, 40129 Bologna, Italy; 2Ca’ Foscari University of Venice, Department of Environmental Sciences, Informatics and Statistics, Via Torino 155, 30172 Venice, Italy This study investigates aerosol properties affecting Cloud Condensation Nuclei (CCN) activity in the Mediterranean free troposphere. Based on long-term observations at Mt. Cimone (2165 m a.s.l.) within the ACTRIS framework, it explores seasonal CCN variability and the processes regulating it. Results reveal an overall order of magnitude variation in CCN concentration throughout the year, likely modulated by planetary boundary layer dynamics. Köhler theory is applied to assess aerosol hygroscopicity, considering chemical composition and size distribution. This work provides the first comprehensive characterization of CCN in Italy, improving understanding of Aerosol-Cloud Interactions and their role in global radiative forcing.
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Cloud droplet spectra measurements: comparison in low stratiform clouds 1ICPF CAS CZ, Czech Republic; 2Faculty of Mathematics and Physics, Charles University, Czech Republic; 3IAP CAS CZ, Czech Republic; 4Finnish Meteorological Institute, Finland Atmospheric aerosol (AA) interactions with atmospheric water remain uncertain despite their importance. To enhance understanding, standardized measurement techniques for cloud droplet spectra (CDS) and liquid water content (LWC) are needed. A three-month in-situ campaign at Mount Milešovka, Czech Republic, compared three instruments: Fog Monitor 120, Cloud Droplet Analyzer, and Particulate Volume Monitor. Measurements of Effective Diameter, Mean Volume Diameter, and LWC showed consistency with prior data. Cloud droplet number concentration was also analyzed. Results will be further examined in relation to wind speed, direction, and air mass sources.
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Polysaccharides - Important Constituents of Ice Nucleating Particles of Marine Origin 1Leibniz-Institute for Tropospheric Research, Germany; 2Department of Arctic and Marine Biology, UiT – The Arctic University of Norway, Tromsø, Norway The ice nucleation activity of polysaccharides were investigated and the freezing spectra compared to the ones of marine microorganisms. We could find agreement between the two indicating a major contribution to the freezing behavior in the marine microorganism caused by polysaccharides. A parameterization was derived and applied in a global model. The model data was compared to available observations.
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Can CCN activation of insoluble particles be predicted based on water adsorption measurements? 1Finnish Meteorological Institute, Helsinki, Finland; 2University of Eastern Finland, Kuopio, Finland The CCN properties of water insoluble particles can be characterized using the FHH adsorption activation theory. The theory can in principle be used to predict CCN activation if the FHH parameters are obtained from experimental adsorption isotherms. However, experimental critical supersaturations are often lower than those predicted using the adsorption isotherms. Here we investigate experimentally if the predictions can be improved using information about the surface structure of the cloud nucleating particles. We find that the corrected predictions lead to overestimation of the CCN activity of metal oxides and minerals. Possible reasons for the overestimation are discussed.
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CARGO-ACT – towards a global interoperability for aerosol, cloud and trace gas research infrastructures 1ACTRIS ERIC, Finland; 2Leibniz Institute for Tropospheric Research; 3National Institute of Research and Development for Optoelectronics; 4NASA; 5CIRES, University of Colorado; 6GML, NOAA; 7Finnish Meteorological Institute The overarching goal of the EU HORIZON-funded CARGO-ACT project is to deliver a clear roadmap for sustainable global cooperation between key organisations in Europe and in the United States to provide all users, in the scientific community and beyond, with the best possible services for accessing and using information from monitoring climate- and air quality-relevant properties of aerosol, cloud and trace gases in the atmosphere. As a first step towards global convergence, CARGO-ACT brings together the European Research Infrastructure on short-lived Aerosol, Cloud and Trace Gases (ACTRIS) with four US counterparts (ARM, NOAA-GML, MPLNET and ASCENT).
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Cloud-Aerosol-Interactions in a Nitrogen-dominated Atmosphere (CAINA) – New particle formation, Activation, and Turbulence 1Leibniz Institute for Tropospheric Research (TROPOS), Leipzig, Germany; 2Centre of Isotope research, University of Groningen, Groningen, Netherlands In spring 2024, an international field experiment on the influence of nitrogen on cloud properties will take place on the Dutch coast. The region has very high concentrations of agricultural nitrate near the ground in spring. TROPOS will participate with the helicopter-borne platform ACTOS to collect cloud water and measure aerosol particles and cloud droplets. In detail, the number size distributions of aerosol particles (PNSD), total particles number concentration and cloud droplet size distributions (DNSD) are measured, as well as the total number concentration of particles, the liquid water content and the main meteorological parameters.
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Ice-nucleating particles at a background site in the southeast Tibetan Plateau 1LAEEM/LAGEO, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China; 2Beijing Key Laboratory of Cloud, Precipitation and Atmospheric Water Resources, Beijing, 100089, China The characteristics and possible sources of ice-nucleating particles (INPs) at a background site in the southeast Tibetan Plateau were investigated during a summer campaign in 2023. INP number concentrations near the ground were measured by an on-line instrument, the Portable Ice Nucleation Experiment (PINE), over a temperature range of -19°C~-31°C with a high temporal resolution. It was found that anthropogenic sources brought in INPs active at low temperatures. Filter samples were also collected during the campaign and freezing experiments were conducted, revealing the existence of heat-sensitive INPs at high temperatures.
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Ice-nucleating properties of mineral dust particles from Taklimakan Desert 1LAEEM/LAGEO, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, 100029, China; 2Beijing Key Laboratory of Cloud, Precipitation and Atmospheric Water Resources, Beijing, 100089, China Sand dust samples were collected in the Taklimakan Desert and re-suspended in chamber to investigate their ice-nucleating properties. Off-line analysis by INSEKT showed that those samples had similar ice-nucleating properties in the range of -28°C ~-20°C, but might behave differently at temperatures above -15°C. Other properties of dust particles will also be investigated to generate a dataset of dust properties in arid areas of China, which would improve our understanding on the effects of dust on the environment and the climate.
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Investigations on the cirrus cloud seeding abilities of K-feldspar dust particles Institute for Atmospheric and Climate Sciences, ETH Zurich, Switzerland This study investigates the ice nucleation abilities of K-feldspar mineral dust particles in the cirrus cloud regime to assess their potential for cloud thinning (seeding). Nano-sized aerosol particles were produced from two types of K-feldspar raw samples using a dry-dispersion setup and a wet-atomizer to compare the effects of sample generation methods. Dry-dispersed nano-sized K-feldspar particles actively nucleate ice slightly above saturation conditions (by ~0.15) for temperatures <233 K, while wet-atomized particles show suppressed ice nucleation. These results suggest the potential for using dry-dispersed nano-sized K-feldspar particles for cirrus cloud seeding and climate warming mitigation.
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Synergistic Observations of Aerosol-Cloud Interactions During Long-Range Transported Dust Events 1National Institute Of Research And Development For Optoelectronics - Inoe 2000, Remote Sensing Department, Romania; 2Faculty of Physics, University of Bucharest, Romania Aerosol-cloud interactions during dust events influence cloud microphysics and precipitation, impacting climate models and weather predictions. Dust aerosols serve as cloud condensation nuclei (CCN) and ice nucleating particles (INP), modifying cloud properties. This study examines three dust events at RADO-Bucharest using remote sensing, in-situ measurements, and weather analysis. Multi-wavelength Lidar retrieves dust profiles, CloudNET assesses cloud properties, and ERA5 reanalysis with HYSPLIT tracks dust transport. Cloud properties are analyzed before, during, and after dust events to evaluate CCN availability, cloud phase changes, and precipitation effects. Findings enhance aerosol-cloud interaction parameterizations in climate models and weather predictions.
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Does decreasing of sulphur concentration influence the amount of low clouds? The Czech hydrometeorological institute, Czech Republic Recent studies have tried to find the factors that influence the increase in global air temperature. These factors could be, among others, a reduction of sulphur emission from special ship fuel and reducing of low cloud amount. The probability of results in the current research concerning the interaction between sulphur aerosols and low-cloud formation established the basic hypothesis for this study in central Europe. This study is focused on the long-term measurement of sulphur concentration and the potential connection to low-cloud formation.
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Investigating Marine Aerosol Variability and Climate Feedbacks: A Multi-Site Analysis Using Particle Composition and Size Distribution Data 1Department of Technical Physics, University of Eastern Finland, Kuopio, 70200, Finland; 2Finnish Meteorological Institute, Kuopio, 70200, Finland; 3School of Natural Sciences, Physics, University of Galway, Galway, H91 CF50, Ireland; 4NILU, Kjeller, 2007, Norway This study investigates marine aerosol variability and climate feedbacks across four sites: Graciosa Island, Ascension Island, Mace Head, and Zeppelin Mountain. Using Aerosol Chemical Speciation Monitor (ACSM) data, particle size distribution, and back trajectory analysis, researchers aim to isolate marine-influenced aerosols and examine their interactions with meteorological factors. Preliminary findings highlight temperature’s role in influencing marine organic aerosol concentrations and cloud condensation nuclei availability. The study reveals inter-site differences in aerosol properties, contributing to improved modeling of aerosol-cloud interactions and climate feedback mechanisms. Funded by Horizon Europe, the Academy of Finland, and other agencies.
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10 years of particle number size distribution in the urban supersite of Bologna in the Po Valley (Italy) ARPAE, Italy The particle number concentration and aerosol size distribution (3-800 nm) have been available since 2013 in the Bologna Supersite in the Po Valley (Italy). The present study aims to analyze the evolution of the aerosol size distribution over time and to investigate whether there is a variation in the concentration and number of nucleation events.
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Atmospheric conditions that drive NPF events: a case study Tartu University, Estonia We selected six nearby days in March 2024 with NPF events, characterized by similar meteorological conditions. Still, these NPF events were different, despite the similar conditions, and certain NPF features also depended on the location. We study the reasons of these differences.
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Bi-directional vertical transport of cluster ions during new particle formation Technische Universität Berlin, Germany This study presents the first eddy covariance flux measurements of positive and negative cluster ions during a particle formation event. The fluxes were generally directed oppositely, with positive ions moving downward to the surface and negative ions upward. Thus, the forest canopy acts effectively as a source for negative and a sink for positive ions. Before the particle formation, decreasing ion concentrations and deposition of both ions were observed, suggesting that sink processes were dominant. Additionally, vertical transport velocities due to turbulence, in comparison to due to the electrical field, were dominant for negative and about equal for positive ions.
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Diurnal cycle of new particle formation in the upper troposphere above the Amazon 1Stockholm University, Sweden; 2Bolin Centre for Climate Research, Sweden Recent studies highlight the role of isoprene in new particle formation (NPF) in convective cloud outflows over the Amazon. Using the CloudChem box model, we investigate organic NPF events (transport of precursors + nucleation) in the upper troposphere at different times of the day. Nocturnal convection mainly removes isoprene through mixing. Daytime transport is more complex and involve more mechanisms. Results suggest lower particle concentrations after daytime convection due to possibly larger condensation sinks. Sensitivity to in-cloud OH and further mechanisms require investigation to refine our understanding of diurnal NPF dynamics.
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Atmospheric ions and particles in the Indo-Gangetic Plain 1Centre for Atmospheric Sciences, Indian Institute of Technology Delhi, New Delhi, India.; 2India Meteorological Department, Ministry of Earth Sciences, Government of India.; 3Institute for Atmospheric and Earth System Research/Physics, University of Helsinki, Helsinki, Finland. The Indo-Gangetic Plain (IGP), a highly polluted and densely populated region, faces severe health and climate challenges due to elevated sub-10 nm particles affecting cardiovascular and brain health. This study examines new particle formation (NPF) and aerosol dynamics using year-long (Jan 2023–Feb 2024) data from NAIS and SMPS at IITD Sonipat, an upwind site of Delhi. Results show strong NPF activity in summer, with growth rates of 4–13 nm/h, influenced by boundary layer height and temperature. These findings underscore the need for enhanced monitoring and a deeper understanding of NPF events in the IGP.
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First Determination of New Particle Formation in Istanbul 1Department of Environmental Engineering, Engineering Faculty, Istanbul University-Cerrahpaşa, Istanbul, Türkiye; 2Institute for Environmental Research & Sustainable Development, National Observatory of Athens, Lofos Nymphon, 11810 Athens, Greece; 3Department of Environmental Engineering, Construction Faculty, Yıldız Technical University, Istanbul, Türkiye; 4Department of Environmental Engineering, Engineering Faculty, Hacettepe University, Ankara, Türkiye; 5School of Geography, Earth and Environmental Sciences, University of Birmingham, Birmingham B15 2TT, UK; 6Department of Environmental Sciences, Faculty of Meteorology, Environment and Arid Land Agriculture, King Abdulaziz University, Jeddah, Saudi Arabia Istanbul, a major metropolis with over 16 million inhabitants, faces complex air pollution from diverse sources. New particle formation (NPF) is a key source of ultrafine particles (UFPs). This study is the first in Türkiye to examine particle number (PN) and NPF events. PN size distribution (10–400 nm) was measured using NanoScan SMPS at urban background, urban, and traffic sites. UFP contributions were highest at traffic (89 %), followed by urban (83 %) and background (77 %). NPF events contributed 27 % at urban, 23 % at background, and 12 % at traffic sites.
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New particle formation in urban background conditions in the Po valley 1University of Modena and Reggio Emilia, Italy; 2Istituto Universitario di Studi Superiori IUSS Pavia, Italy; 3Institute of Atmospheric Sciences and Climate, National Research Council of Italy; 4ARPAE Emilia-Romagna, Regional Agency for Prevention, Environment and Energy, , Bologna, Italy We investigate the occurrence and intensity of new particle formation (NPF) in an urban background environment within the Po Valley. We set up the neutral cluster and air ion spectrometer (NAIS) in Bologna, the largest urban agglomeration in the Southern part of the Po valley. The analysis revealed the winter season recorded the highest number concentrations which could be attributed to the more stable low-level boundary layer. Applying the nanoparticle ranking analysis to the number concentrations and pollutants measured alongside revealed that some of the days in higher ranks could be days of high pollution disguised as NPF events.
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Observations of atypical decreasing mode diameter events at a rural background site in Cyprus 1Climate and Atmosphere Research Center (CARE-C), The Cyprus Institute, Cyprus; 2Laboraotry of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland Accurate climate projections are hindered by uncertainties in atmospheric aerosol processes, which modulate radiative forcing and cloud microphysics. Approximately 50% of global tropospheric cloud condensation nuclei (CCN) originate from new particle formation (NPF) events, yet their mechanistic drivers remain insufficiently constrained. Atypical decreasing mode diameter (DMD) events exhibit reverse dynamics to NPF events. During the SPICY campaign (April–May 2024), NPF and DMD events occurred on 52.3% and 13.1% of days, respectively. It appears that malonic acid, nearly an order of magnitude higher during DMD events, may inhibit aerosol nucleation by outcompeting sulfuric acid in cluster stabilization pathways.
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Differences of New Particle Formation in Seoul and Seosan, South Korea 1School of Civil and Environmental Engineering, Pusan National University, Busan 46241, South Korea; 2Department of Earth and Environmental Sciences, Jeonbuk National University, Jeonju, 54896, South Korea; 3Department of Environment and Energy, Jeonbuk National University, Jeonju, 54896, South Korea; 4Department of Environmental Science and Engineering, Ewha Womans University, Seoul, 03760, South Korea; 5Digital Omics Research Center, Korea Basic Science Institute, Cheongju, 28119, South Korea; 6Division of Climate and Air Quality Research, National Institute of Environmental Research, Incheon, 22689, South Korea; 7Institute for Environment and Energy, Pusan National University, Busan 46241, South Korea New particle formation (NPF) is a significant source of secondary particulate matter (PM2.5), which causes severe air pollution in winter in South Korea. Understanding the mechanisms and characteristics of NPF is essential to mitigate the PM2.5 haze problems. Mechanisms and characteristics of NPF in South Korea were investigated through four intensive monitoring campaigns during different seasons in 2020-2022 at Seoul and Seosan sites. Real-time measurements were conducted to obtain physicochemical properties of particles, concentrations of gaseous pollutants in the atmosphere, and meteorological data. Condensation and coagulation sinks, growth, formation, and nucleation rates were calculated from the real-time data.
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Estimation of particle growth rate using cross-correlation University of Helsinki, Finland Particle growth rate (GR) is essential for understanding atmospheric new particle formation (NPF) and can be determined from size-resolved number concentration measurements. Traditional methods, like mode fitting and appearance time methods, require expert-provided initial guesses, making the process subjective and time-consuming. This study presents a simple GR calculation method using cross-correlation between size channels to identify time shifts, eliminating the need for initial guesses. This automated approach enables efficient processing of large datasets and reduces subjectivity in GR analysis.
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Humidity driven spontaneous OH radical-initiated oxidation of organic aerosols 1Université Claude Bernard Lyon 1, CNRS, IRCELYON, UMR 5256, F-69626, Villeurbanne, France; 2Department of Chemistry, University of Toronto, 80 George Street, Toronto, Ontario, Canada M5S 3H6; 3Department of Physical and Environmental Sciences, University of Toronto, Scarborough, 1265 Military Trail, Toronto, ON Canada M1C 1A4; 4Tofwerk AG, Thun, Bern, Switzerland Several studies have reported the spontaneous OH formation at the air-water interfaces of aqueous droplets. In our work we investigated the ability of this chemical process to oxidize organic aerosols containing carboxylic acids. We found that only in the presene of water vapours, the air-water interface that is created upon the water uptake onto the pure organic droplets, initiates the OH radical production and the spontaneous oxidation of the organic. Product formation is negligible in dry conditions. Our findings suggest that spontaneous OH production at the air-water interface of organic nanodroplets may be a significant oxidation pathway, especially during night-time.
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Characterisation of VOC over the Great Barrier Reef 1Queensland University of Technology, Australia; 2Southern Cross University, Australia This study focuses on characterisation of VOC emissions from coral reefs and their potential contribution to the aerosol particle population over the Great Barrier Reef (GBR). We present first-time observations of VOC composition over the GBR based on high time-resolution VOC observations. We focus our analysis on the effect of heat stress and coral spawning on coral VOC emissions.
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Competitive multiphase reactions of deliquesced aerosol particles in the presence of SO2 and NO2 regulated by aerosol pH Chuo University We study multiphase oxidation of SO2 by NO2 (R1) and heterogeneous NO2 hydrolysis (R2) at various aerosol pH values, which produces sulfate and nitrate, respectively. As pH increases from 5.8 to 6.3, sulfate formation rates exponentially increase by ~2 orders of magnitude. Nitrate is observable below pH = 6, and nitrate formation rates increase exponentially with decreased pH by ~2 orders of magnitude. We find that sulfate production dominates over nitrate production at high pH, whereas nitrate production is dominant at low pH (<6), highlighting that reactions R1 and R2 are competitive and highly dependent on pH.
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SOA precursor emissions in and above a forest consisting of beech and Douglas fir and their relation to aerosol particle numbers and composition Karlsruhe Institute of Technology, Germany Biogenic volatile organic compounds play a dominating role in the formation of secondary pollution due to their large emissions and high reactivity. The mechanisms controlling emissions of VOCs, especially monoterpenes, and their influence and contribution to the formation and aging of SOA in forests are still unclear. Therefore, we studied VOC emissions, aerosol particle number concentrations and compositions in a relatively healthy mixed forest consisting of beech and Douglas fir. We will discuss the influence of tree type and environmental parameters on VOC emissions and subsequent SOA formation.
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Growth of coating thickness driving absorption enhancement in the urban city of Barcelona 1Institute of Atmospheric Sciences and Climate – National Research Council of Italy, Bologna, Italy; 2Université Grenoble-Alpes, CNRS, IRD, Grenoble-INP, IGE, 38000 Grenoble, France; 3Institute of Environmental Assessment and Water Research (IDAEA-CSIC), Barcelona, 08034, Spain This study, part of the CAIAC project, examines black carbon (BC) properties in Barcelona during a two-week campaign in July 2021. Measurements of rBC mass concentration, size, and coating thickness show that aerosol absorption is influenced by particle properties and meteorological conditions. The mass absorption cross section increases linearly with mean coating thickness, highlighting the role of internal mixing. Stagnant conditions with higher concentrations correlate with smaller, thinly coated rBC particles, lower external mixing with OC, and lower absorption enhancement. In contrast, more ventilated conditions lead to larger, more coated, externally mixed rBC particles with higher absorption enhancement.
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Impact of Agricultural Emissions on Rural and Urban Air Quality (IMAGE) 1Technological University Dublin; 2Dublin City University; 3University College Cork Air quality is of paramount importance to human health. Many air pollutants are linked with human activity such as agriculture, including secondary particulate matter and ammonia which have been heavily linked with human health concerns and climate impacts.
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CFD and Experimental Investigation of Time-Controlled Aerosol Delivery from a Nebulizer in respiratory airways Brno university of technology, Czech Republic Timed aerosol delivery enhances targeted lung deposition and reduces upper airway losses. This study examines the impact of time-controlled aerosol release from a nebulizer in a realistic 5-year-old child model using CFD and experiments. Large Eddy Simulations with Lagrangian particle tracking were performed to quantify deposition during normal breathing. Aerosol was released during defined inhalation phases to evaluate deposition sensitivity to timing. Experiments used fluorescein-labeled aerosol and a nebulizer with a programmed delay. Results show that upper airway deposition is strongly influenced by release timing and initial particle velocity. CFD–experiment agreement supports phase-targeted delivery for improved inhalation therapy.
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Formation and Aging of Nitrogen-Containing Organic Aerosol Institute of Earth Environment, Chinese Academy of Sciences, Xi’an 710061, China Here, nitrate-mediated photooxidation of some important nitroaromatics in atmospheric aqueous phase under different pH and temperature conditions were investigated. The dynamic changes in light absorption of nitroaromatics were measured, the photolysis rates and oxidation products as well as the aging processes were characterized. Besides, the nighttime formation processes of secondary organic nitrates were investigated based on size-resolved measurements with a soot particle long-time-of-flight aerosol mass spectrometer. Moreover, N-heterocyclic compounds from aqueous-phase reaction of dicarbonyls with amines and ammonium under different pH were also studied. We identified for the first time 155 new N-heterocyclic compounds and their formation pathways were characterized.
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PM10-bacterial infection interaction in A549 cells: A One Health perspective 1Department of Physic, University of León, Campus de Vegazana, León, 24071, Spain; 2Department of Molecular Biology, University of León, Campus de Vegazana, León, 24071, Spain; 3Department of of Environment and Planning, Centre for Environmental and Marine Studies (CESAM), University of Aveiro, Aveiro, 3810-193, Portugal; 4Department of Chemistry, University of León, Campus de Vegazana, León, 24071, Spain; 5Droplet Measurement Technologies, LLC, Longmont, CO, USA Air pollution and antimicrobial resistance (AMR) are critical public health issues. In León (NW Spain), coal combustion contributes to particulate matter (PM10) emissions, potentially influencing bacterial behaviour. This study assessed PM10 effects on human lung cells (A549) and Staphylococcus aureus USA300. PM10 exposure reduced A549 cell viability, while S. aureus infection capacity increased, suggesting enhanced virulence. Although bacterial growth remained unaffected, results indicate PM10 may modulate pathogen-host interactions, potentially promoting AMR. These findings highlight the need for a One Health approach to address the interplay between environmental pollution and bacterial virulence.
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Analysis of PM2.5 concentrations in African countries: findings from 2019 to 2024 1Universidad de León, Spain; 2National University of Equatorial Guinea; 3Droplet Measurement Technologies, LLC, Longmont, CO, USA The study analyzes the annual PM2.5 concentrations recorded between 2019 and 2024 in Algeria, Ethiopia, Uganda, and South Africa. The results show pronounced spatial and temporal variations. Uganda consistently reported the highest concentrations, exceeding 100 µg/m³ in most years. In 2023, a general decline in concentrations was observed in most countries, except for South Africa. The observed concentrations exceed the WHO’s annual guideline of 5 µg/m³. The study highlights the urgent need to strengthen air quality monitoring networks in Africa.
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Atmospheric particles, airborne bacteria and fungi at Akrotiri monitoring station (Crete, Greece) 1School of Chemical and Environmental Engineering,Technical University of Crete, Greece; 2Laboratory of Systems Microbiology and Applied Genomics, Department of Environmental Engineering, University of Patras, Agrinio, Greece Atmospheric particles cover a wide size range with the smaller ones being in the nanoscale while dust particles lie in the micron size range. Their dynamics depend strongly on their size therefore different behaviours and interactions may be observed at different sizes. Besides particles, biological entities such as airborne bacteria and fungi are a significant contributor to the atmospheric environment. Their role in atmospheric interactions is under investigation whilst pathogens are known for their detrimental effects in human health.In this work, airborne particles, bacteria and fungi were measured simultaneously at Akrotiri monitoring station.
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Impact of a bioethanol fireplace on indoor pollutant concentrations under different operating conditions 1Environmental and Planning department, University of Aveiro, Aveiro, 3810-193, Portugal; 2VSB - Technical University of Ostrava, Energy Research Centre, Ostrava-Poruba, 708 00; 3CIMO, LA SusTEC, Instituto Politécnico de Bragança, Campus de Santa Apolónia, 5300-253 Bragança, Portugal Bioethanol fireplaces are increasingly used for their sustainability and design advantages; however, their effects on indoor air quality require further evaluation. This study quantified key pollutants (CO, CO₂, NOₓ, carbonyl compounds, and PM10) under controlled conditions, assessing different burner configurations and bioethanol formulations. Combustion led to significant pollutant increases, with single-chamber burners emitting higher CO and NOₓ levels, while double-chamber burners produced more PM10. Acetaldehyde and formaldehyde frequently exceeded guideline thresholds. Indoor-to-outdoor total carbon ratios consistently exceeded one, indicating potential health risks associated with bioethanol combustion in low-ventilation environments.
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High Resolution Optical Light Scattering Measurements of Atmospheric Particulate Matter in the Proximity of an Industrial Area near Taranto Italy Environment Agency of Apulia, Italy The use of a fine particulate matter monitoring system based on a real-time and dimensional scanning acquisition system has shown interesting potential in the recognition of events of increase in fine particulate matter concentration. The study of the dimensional distribution has allowed us to make some statistical considerations by applying multivariate analysis models that are the basis for further in-depth analysis of source apportionment. Finally, the gravimetric comparison with a dataset consisting of 50 samples acquired between March and May 2024 has highlighted a good correlation even during conditions of Saharan event contributions that occurred in the study period
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Effects of the hygroscopicity and mass scattering efficiency of secondary organic aerosols on light scattering 1Guangzhou Institute of Tropical and Marine Meteorology, China Meteorological Administration, China; 2Institute for Environmental and Climate Research, Jinan University, China In this study, we quantified the dry-state mass scattering efficiencies (MSEs) of both primary and secondary organic aerosol components and organic aerosol hygroscopicity, thus systematically evaluating contributions of SOA factors to aerosol scattering and visibility degradation in ambient air.
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Estimating the growth characteristics of commonly used pesticide (Glyphosate) aerosols IMT Atlantique, Nantes, France, France Glyphosate is a widely used herbicide that persists in the environment due to its low volatility, remaining in the liquid phase and interacting with water vapor. It is one of the most employed herbicides in the last years, and can be part of more than 700 pesticide products.This theoretical study estimates its hygroscopic growth under different humidity conditions, showing that glyphosate can absorb water and potentially influence cloud formation and atmospheric processes. These predictions provide a foundation for comparison with ongoing experimental studies. Understanding glyphosate’s water uptake behavior is important for assessing its role in atmospheric chemistry and climate.
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Study and Identification of Benzene Emission Sources in a Complex Industrial Area in Taranto (Italy) 1ARPA Puglia, Italy; 2Pollution Analytical Equipment, Italy Recent reports have raised concerns about increasing concentrations of benzene in ambient air within Tamburi neighbourhood, in the city of Taranto. Tamburi neighbourhood is located south-east of a significant industrial complex that includes a refinery, an integrated cycle steel plant and thermoelectric power plants. Through intensive monitoring campaigns with transportable instrumentation (micro-GC), main diffuse and fugitive emission sources of benzene were investigated. In the steel plant, the analyses revealed high benzene concentrations associated with the coke production process and the treatment of coke gas and by-products. The novelty of this study lies in the use of intensive monitoring campaigns with transportable instrumentation (micro-GC).
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Characterization and Source Apportionment of Ambient Air Particulate Matter (PM2.5) across Lagos, Nigeria using PMF 1Clarkson University, United States of America; 2EnvironQuest Limited, Nigeria; 3PAS Environmental, LLC, United States of America; 4University of Rochester, United States of America Lagos, Nigeria is a rapidly developing megacity with increasing industrialization and traffic leading to substantial air quality issues. Using PM2.5 compositional data from samples collected at 6 sites over a year from 2020 to 2021, source apportionment results were obtained. Nine source types were identified using elements, ions, organic and elemental carbon and molecular marker concentrations. The sources were identified as ndustrial Metal Processing (17.2%), Soil Dust/Crustal Matter (29.3%), Waste Burning (3.0%), Biogenic Emissions (3.7%), Cooking Emissions (5.8%), Gasoline Vehicle Emissions (4.0%), Diesel Vehicle Emissions (3.5%), Industrial Emissions (21.9%), and Biomass Burning (11.6%).
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Aerosols collection through dynamic fog aggregation: the case of asbestos 1Escuela Politécnica Superior, Universidad de Alcalá, 28805 Alcalá de Henares, Spain; 2Counterfog, SL, 28341 Valdemoro, Spain; 3Materials Science and Engineering Department, IAAB, Universidad Carlos III de Madrid, Leganés, 28911, Spain; 4San Jorge Tecnológicas SL, Valdemoro, 28341, Spain Dynamic fog aggregation has been used to collapse asbestos aerosols. This enables the use of this technology both for sampling and for decontamination and prevention. These results demonstrate that even a simple mild manipulation of asbestos plates causes its aerosolization. Additionally, this technology opens new opportunities to prevent asbestos spreading and to collapse asbestos aerosols from air what is of paramount importance for demolitions and debris removal.
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PM in restaurant kitchen air - preliminary results 1Warsaw University of Technology, Poland; 2Fire University, Poland The chemical composition of respirable particulate matter (PM4) and total particulate matter (TPM) was investigated in the kitchen of a restaurant located in Bytom, Poland. Measurements were conducted over 26 days. The results showed significant differences between indoor and outdoor PM, particularly for PM4. The mass content of organic carbon was lower in ambient PM compared to indood PM, and the mass fraction of water-soluble anions and cations was also lower in kitchen PM. Emissions from indoor sources significantly increased concentrations of the PM components studied, with TPM in the kitchen being 4 times higher than in ambient air.
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Particulate matter in the selected fire station in Poland: concentration and size distribution 1Fite University, Poland; 2Institute of Environmental Engineering, Polish Academy of Sciences The aim of this paper is to determine and compare the mass concentration and size composition of particulate matter (PM) inside and outside selected fire stations in Poland. The findings of conducted analyses substantiate the notion that the concentrations and mass size distribution of PM in the fire station deviates from the concentrations and mass distribution for the urban background, a phenomenon that is attributable to the unique characteristics of the fire station and the prevalence of internal sources within it.
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Water- and methanol-extracted brown carbon in PM2.5 in southwest Europe Miguel Hernández University, Spain This study examines the characteristics of brown carbon (BrC) from biomass burning in southeastern Spain, where residential wood burning is common in winter. A total of 302 daily PM2.5 samples were collected between July 2023 and March 2024. Methanol and water-soluble organic carbon absorption (MSOC and WSOC) were analyzed to determine BrC. The results showed that the contribution of MSOC to organic carbon was similar at rural and urban sites, with a significant correlation between absorption and levoglucosan concentrations, a biomass burning tracer, indicating that biomass burning significantly contributed to brown carbon during the cold period.
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Impact of smoking regime (ISO/HCl) on the emissions of PM and carbonyls of new tobacco products Hellenic Open University, Greece The smoking profile is a parameter that has a high impact on the compounds emitted. This study compares the impact of smoking regime on the emissions of two types of new tobacco products: Heated Tobacco Products and vaping of dry herbal products. These results show that there is a high difference on the emissions of carbonyls and particles from the two smoking regimes, with ISO producing systematically lower emissions. As none of the two regimes can represent the real use of tobacco products, the systematic use of the two regimes in tobacco research can give more comprehensive results.
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First results of airborne pollen grain observations in a coastal location in Crete, Greece 1ECPL, Department of Chemistry, University of Crete, Heraklion, 70013, Greece; 2IERSD, National Observatory of Athens, Lofos Koufou, P. Penteli, Athens, 15236, Greece; 3LSCE, CNRS-CEA-UVSQ, Gif‑sur‑Yvette, F-91191, France; 4Institute of Environmental Physics, University of Bremen, Bremen, Germany; 5CSTACC, ICE-HT, FORTH, Patras, Greece Bioaerosols, especially pollen, affect human health, making monitoring crucial for allergenic risk assessment and climate impact studies. Traditional optical microscopy is time-consuming and requires expertise. This study explores automated digital imaging for pollen identification in Heraklion, Crete, using the NanoZoomer S20 scanner. Airborne pollen was collected over two years (May 2022–July 2024) using a Burkard spore trap. Samples were processed and scanned for qualitative and quantitative analysis. Results were compared with concurrent data from Nicosia, Cyprus, and historical records from Thessaloniki, Greece, assessing seasonal variations and potential biases in traditional methods. Findings enhance Mediterranean aerobiological research.
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A novel approach for spectral-based source apportionment of ambient aerosols: A demonstrative study 1Department of Optics and Quantum Electronics, University of Szeged, 9. Dóm square, Szeged, H-6720, Hungary; 2HUN-REN-SZTE Research Group for Photoacoustic Monitoring of Environmental Processes, Dóm ter 9, H-6720, Hungary We present an alternative, spectral-based source apportionment model for calculating the mass concentration of wood burning and fossil fuel aerosol in the ambient. The model was applied to data collected from a rural area in Hungary during a two-month continuous campaign in the winter period. The proposed model is based on the parallel measurement of the size distribution, absorption response of the ambient aerosols, and the thumb-of-rule relation between the elemental carbon (EC) and total carbon (TC) of fossil fuel and wood-burning aerosols. The proposed model is compared with the traditional Aethalometer model applied to the same dataset.
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Optical and chemical properties of aerosol from on-road experiments of heavy-duty vehicles in India: Key inputs for climate assessment Indian Institute of Technology Delhi, India In on-road transport sector, diesel-powered HDVs are major contributors to light-absorbing black carbon emissions. Previous inventories often rely on emission factors derived from dynamometer studies, which may not accurately represent real-world driving conditions. This study presents emission factors and climate-relevant properties of aerosols emitted from on-road operations of diesel-powered trucks and tractors using the Versatile Source Sampling System (VS3). The emission factors of PM2.5 and BC were estimated as 1.2 – 2.4 and 0.5 – 1.3 gkg-1 respectively. The mass absorption cross section for trucks were observed as 0.9 – 6.5 m2/gPM2.5. This paper also presents organic carbon (OC) emission factors.
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Size-Dependent Dynamics of Urban Aerosols: Correlations Between Chemical Composition, Bacterial Communities, and Antibiotic Resistance Genes Over an Annual Cycle 1Environmental, Water & Agricultural Engineering, Technion-Israel Institute of Technology, Haifa, Israel; 2Dep. of Environmental Engineering, Bolu Abant İzzet Baysal University, Bolu, Türkiye; 3Boğaziçi University, Institute of Environmental Sciences, İstanbul, Türkiye; 4Dep. of Environmental Engineering, Bursa Technical University, Bursa, Türkiye; 5Climate and Atmosphere Research Center (CARE-C), The Cyprus Institute, Nicosia, Cyprus; 6Dept. of Chemistry, University of Crete, Crete, Greece; 7ERSD, National Observatory of Athens, Athens, Greece A year-long study in urban Bolu, Turkey, utilized six-stage size-segregated filters to sample airborne particulates. We profiled biotic components—bacterial community structure via metagenomic sequencing and antibiotic resistance gene (ARG) markers through quantitative PCR—and abiotic constituents—ionic, carbonaceous, and sugar-alcohol compounds by chromatography—across seasons and size fractions. Statistical analyses revealed significant correlations between specific microbial taxa and chemical species. Coarse particles harbored higher abundances of human-associated bacterial genera and ARGs, whereas fine particles were enriched in diverse ionic and carbonaceous compounds. These findings underscore size- and season-driven interactions shaping urban air quality.
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Comparative Characterization of Persistent Free Radicals in PM2.5 and PM10 Aerosols between Subtropical Tainan, Taiwan and Temperate Moscow, Russia 1Chia Nan University of Pharmacy and Science, Taiwan; 2SINP, Lomonosov Moscow State University, Moscow, 119991, Russia; 3Faculty of Geography, Lomonosov Moscow State University, Moscow, 119991, Russia Persistent free radicals (PFRs), as chemically stable yet highly reactive constituents of atmospheric aerosols, are emerging environmental health hazards due to their capacity to induce the formation of reactive oxygen species (ROS) (Chen et al., 2020). Their presence is strongly associated with the chemical composition and sources of aerosols, particularly with combustion-derived particles that exhibit significantly higher PFR concentrations than non-combustion sources. PO1: 226
3D-Printed impactor 1Fraunhofer Institute for Translational Medicine and Pharmacology ITMP, Immunology Infection and Pandemic Research IIP, Munich, 80799, Germany; 2Chair of Analytical Chemistry and Water Chemistry, Laser and Particles Group, Technical University of Munich, Garching, 85748, Germany For the drone-based aerosol sampling, light-weight samplers are needed. We designed an impactor with a 1 micrometer cut-off diameter and printed it on a stereolithography 3D-printer. The printing accuracy was within 5% of the desired nozzle diameter. With a polydisperse test-aerosol, the impactor was sucessfully tested.
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A holistic approach to assess the impact of port activities on air quality: The case of Piraeus Port, Greece 1IERSD, National Observatory of Athens, 15236 P. Penteli, Greece; 2ECPL, Department of Chemistry, University of Crete, Heraklion, 70013, Greece Ship emissions and their impacts on the environment is a key issue for atmospheric research and climate policy. Particles and gases emitted by ships can contribute to various environmental issues such as acidification and eutrophication of water and soil in coastal regions, climate cooling due to the sulfur content of marine fuel as well as climate warming caused by the emissions of greenhouse gases and absorbing black carbon. This study synthesizes findings from multiple measurement campaigns conducted in recent years in the Piraeus Port area to evaluate the impacts of port activities on air quality, pollutant sources, and population exposure.
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Characterization of particulate emissions during asphalt milling and paving in Southern Sweden 1National Research Centre for the Working Environment, 2100, Copenhagen, Denmark; 2Department of Chemistry, University of Copenhagen, 2100, Copenhagen, Denmark; 3Ergonomics and Aerosol Technology, Lund University, SE-22100, Lund, Sweden; 4Division of Occupational and Environmental Medicine, Lund University, SE-22100, Lund, Sweden; 5Department of Occupational and Environmental Medicine, Region Skåne, SE-22381 Lund, Sweden Asphalt is a widely used material. In this study, we investigate key tasks related to road construction: milling, sweeping, paving, and rolling by employing two measurement strategies in the near-field area. Our results show that asphalt milling generates both coarse and fine particles, likely originating from combustion-derived soot, resuspended aged asphalt organics, and surface dust. Asphalt paving lead to bitumen fumes consisting of elevated levels of semi-volatile organic compound, distinct from typical traffic emissions. Such an integrated approach provides detailed insight into occupational exposure to pollution, and will contribute to further identify emission sources.
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Critical analysis of carbonaceous aerosols from residential wood burning using offline and online measurements 1Department of Earth and Environmental Sciences, The University of Manchester, M13 9PL, UK; 2National Centre for Atmospheric Science, The University of Manchester, M13 9PL, UK; 3Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, YO10 5DD, UK; 4Department of Civil Engineering and Management, The University of Manchester, M13 9PL, UK; 5Air Quality and Aerosol Metrology Group, National Physical Laboratory, Teddington, TW11 0LW, UK; 6National Centre for Atmospheric Science, University of York, YO10 5DD, UK This study aims to critically compare multiple measurement techniques for quantifying carbonaceous aerosols, which is challenged by typical UK urban pollutions, and evaluate the uncertainties accordingly. Preliminary results show good agreements between Thermal Optical Analysis and online measurements of total carbon. However significant discrepancies were observed between EUSAAR2 and NIOSH Element Carbon quantification. Lack of significant difference between day and night indicating discrepancies are not driven by sources. Comparisons between online and offline analysis suggests single particle soot photometer calibration factor and Mass Absorption cross-section need to be adjust to better account wood combustion environments.
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Development of an open-source, modernized, airborne optical particle counter instrument University of Leeds, United Kingdom Aerosol size distributions using Optical Particle Counters (OPCs) are a key type of measurement taken during airborne atmospheric measurement campaigns, however some of the most commonly used instruments are aging and therefore difficult to maintain and operate. In this poster we present work on the development of a updated, open-source instrument based on Lorenz-Mie theory light scattering principles, using modern, off-the-shelf components and modular design, and suitable for airborne usage. The motivation is to reduce reliance on aging instruments, and build a community of users around a versatile, adaptable, instrument which can be easily maintained and configured by operators.
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Emerging Dust Sources in the Middle East: Quantifying the Impact of Iraq-Syrian Desert Dust Storms on Air Quality in Eastern Mediterranean 1Department of Earth and Environmental Sciences, University of Manchester, UK; 2National Centre for Atmospheric Research, UK; 3UrClimate, İstanbul, Türkiye; 4Department of Climate and Marine Sciences, Eurasia Institute of Earth Sciences, Istanbul Technical, İstanbul, Türkiye The Iraq-Syrian Desert is emerging as a significant but underexplored dust source affecting the Eastern Mediterranean. We analysed hourly PM₁₀ data (2011–2025) from 34 air quality stations in Türkiye, identifying high-PM₁₀ episodes using statistical peak detection. Satellite observations (MODIS, VIIRS, TROPOMI, CALIOP) and HYSPLIT trajectories confirmed dust origins and transport pathways. WRF-Chem simulations revealed atmospheric structures enabling long-range transport. Some events from the Iraq-Syrian region caused PM₁₀ levels up to 800 µg/m³ in southeastern Türkiye. Results highlight the increasing influence of this region on air quality, with implications for climate and health, urging improved monitoring and regional collaboration.
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In-situ characterization of the optical properties of flame synthesized TiO2 NPs using light emission spectra Laboratory EM2C, CNRS, CentraleSupélec, Université Paris-Saclay, Gif-sur-Yvette, 91190, France Flame Spray Pyrolysis is an emerging flame aerosol technique for synthesizing nanoparticles( NP). Understanding the NP formation process in the flame allows precise tunability of the NP characteristics. In-situ laser diagnostics can provide access to the temporal and spatial evolution of NP characteristics along the flame but is difficult to implement because the NP optical properties evolve along the flame. In this work, the natural emission of Titania (TiO2) NPs in the flame, together with data from laser induced incandescence and CFD simulations, is employed to provide useful insights into the evolution of the NP optical properties during flame synthesis.
PO1: 233
Integrated Strategies for Detection and Manipulation of Ultrafine Particles Using Physical Forces and Fiber-Tip Nanophotonic Sensors Eindhoven university of technology, Netherlands, TU/e Ultrafine particles (UFPs, <100 nm) pose significant health risks but are challenging to detect due to their low mass and high diffusivity. This project develops a fiber-tip nanophotonics sensor for UFP detection based on refractive index changes. Scanning mobility particle sizer serves as the benchmark for sensor validation using controlled polystyrene aerosols. To enable reliable detection within the sensor’s small active volume, we investigate UFP delivery strategies using inertial impactors, electrostatic forces, and acoustic manipulation. Combined with CFD simulations and microfabrication, this multidisciplinary approach offers a compact, high-sensitivity alternative to conventional systems for real-time UFP monitoring.
PO1: 234
New particle formation over the Southern Ocean: insights from long-term measurements in Punta Arenas, Chile 1Leibniz Institute for Tropospheric Research, Germany; 2Leipzig Institute for Meteorology, Leipzig University, Leipzig, 04103, Germany; 3University of Magallanes, Punta Arenas, Chile A long-term atmospheric dataset collected at Cerro Mirador, Chile (2019–2023), revealed clear seasonal patterns in particle number size distributions (PNSD), with higher concentrations in summer and lower in winter. In Summer, four main PNSD types were identified, three of them linked to new particle formation (NPF) processes, under predominantly westerly winds. A persistent presence of 20–30 nm particles suggests frequent regional NPF, while local NPF occasionally occurs in “banana-shaped” patterns. These findings help improve the understanding of aerosols in the Southern Ocean region, where cloud representation in climate models remains a major challenge.
PO1: 235
Parameters controlling the representation of Arctic cloud-forming aerosols in UKESM 1Institute for Climate and Atmospheric Science, University of Leeds, United Kingdom; 2National Centre for Atmospheric Science, Leeds, United Kingdom Enhancing the representation of aerosols in Global Climate Models is important for reducing uncertainties associated with aerosol-cloud interactions. This study identified and examined the dominant parameters controlling cloud-forming aerosols over the Arctic region within the United Kingdom Earth System Model (UKESM). The role of 37 aerosol-cloud-relevant parameters in determining accumulation-mode number concentration and diameter was examined using a Perturbed Parameter Ensemble. Key parameters were identified which controlled number and size properties, which contextualised simulated seasonal biases when compared against size-distribution measurements from Arctic observational sites. This research indicates areas for further model development in constraining physical processes, and natural/anthropogenic emissions.
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Monitoring of UPFs in a site affected by biomass burning ARPAT, Italy This study describes the monitoring results at the LU-Capannori site, affected by a high amount of emissions from biomass combustion. It is observed that during night peaks, the most contributory particulate mode is the Aitkins mode, with a high correlation between PM1 and BC due to biomass combustion. In each of the four campaigns, UFP levels are much higher than the WHO recommended values, both hourly and daily, furthermore the temporal evolution and the correlation with the other pollutants monitored at the site demonstrate that biomass combustion is the factor that mostly contributes to exceeding the threshold.
PO1: 237
Feasibility of an inexpensive single-particle SIBS instrument Tampere University, Finland This work evaluates the feasibility of using spark-induced breakdown spectroscopy (SIBS) for real-time elemental analysis of individual airborne aerosol particles. The SIBS is offering an inexpensive and compact alternative to aerosol mass spectrometry and laser-induced breakdown spectroscopy (LIBS). A cost-effective SIBS system was developed, incorporating an inductive spark generator and spectrometer-based optical detection. In experiments, potassium and sodium were successfully detected in individual multi-salt particles, with a particle-to-spark hit rate of 0.1/s for particles larger than 2 µm. While promising, the practical applications of the prototype are limited by the low plasma temperature (~3500 K).
PO1: 238
Modelling metals (Cu, Fe, Mn) concentrations over Europe 1LISA (UPEC-CNRS-UPC), France; 2IGE, France; 3INERIS, France; 4CITEPA, France; 5LCSQA, France; 6IMT Nord Europe, France; 7ANDRA, France; 8Atmo Grand Est; 9Atmo Auvergne Rhône-Alpes; 10Atmo Hauts de France; 11CSIC, Spain; 12Yokohama Institute for Earth Sciences, Japan Certain metals (Cu, Fe and Mn) are suspected of playing an important role in the health effects of PM. Therefore, it is important to be able to simulate atmospheric concentrations of these metals. We developed European emission inventories for these 3 metals, then simulated their concentrations for over 2 years. Evaluation against observations shows that the model accurately simulates copper, whereas significant biases exist for iron and manganese. Road traffic (abrasion processes) is the predominant source for these metals but the role of other sources such as rail traffic and industry needs, to be investigated.
PO1: 239
Open-pit mine dust aerosol monitoring using MODIS and Sentinel-5p satellite retrievals 1Babeș-Bolyai University, Romania; 2Helmholtz-Zentrum Dresden-Rossendorf, Germany; 3S.C. CupruMin S.A., Romania Mining operations produce dust, impacting air quality, health, and climate. The EU Horizon-funded MOSMIN project uses satellite and ground-based data to monitor such effects. This study applies MODIS MAIAC AOD and Sentinel-5P AI to assess dust activity over two open-pit mines: Roșia Poieni (Romania) and Talabre (Chile). While MODIS offers finer spatial detail, it struggles with bright surfaces and cloud cover. Sentinel-5P detects absorbing aerosols but at a coarser resolution. Combined, they reveal elevated aerosol levels and dust transport beyond source areas. These findings support synergistic EO approaches to enhance mining impact assessment.
PO1: 240
Optical and Compositional Characterization of Carbon Nanoparticle Aggregates in Films Produced via Electric Field-Assisted Flame Synthesis 1University of Naples Federico II, Italy; 2Istituto di Scienze e Tecnologie per l'Energia e la Mobilità Sostenibili, STEMS-CNR, Piazzale Tecchio, 80, Napoli, Italy Optical and Compositional Characterization of Carbon Nanoparticle Aggregates in Films Produced via Electric Field-Assisted Flame Synthesis PO1: 241
Preliminary findings on the adhesion of bacteria to particulate matter in the polluted atmosphere of Gliwice, Poland Faculty of Energy and Environmental Engineering, Silesian University of Technology, Poland This study presents preliminary findings on the adhesion dynamics of airborne bacteria to particulate matter (PM) in the polluted atmosphere of Gliwice, Poland. Airborne bacteria were sampled using a 6-stage Andersen cascade impactor, with particle concentrations simultaneously measured using a particle counter. The results show a strong correlation between coarse PM and larger bacterial particles in the aerosol, suggesting that small, respirable bacteria (≤3.3 µm) may adhere to coarse particles. These findings highlight the need for further investigation to better understand the mechanisms of bacterial adhesion to PM in urban environments.
PO1: 242
Saharan dust Transport Events over Southern Italy: a comprehensive analysis based on model simulations and experimental data 1Institute of Atmospheric Sciences and Climate (ISAC) CNR, Lecce, Italy; 2Technical University of Darmstadt, Institute for Applied Geosciences, Darmstadt, Germany; 3University of Salento, Department of Biological and Environmental Sciences and Technologies, Lecce, Italy; 4University of Salento, Department of Mathematics and Physics, Lecce, Italy During the spring of 2024, two dust storm events were observed over southern Italy, as detected by MODIS/AQUA satellite imagery and the WRF-Chem model. During both episodes, elevated daily mean PM₁₀ mass and particle number concentrations were recorded at the ECO Observatory of Lecce. To characterize the sources of the measured particulate matter, the FLEXPART model and the aerosol vertical profiles were employed. Aerosol dry deposition samples (collected in Lecce site of X Med-Dry network) were analysed by electron microscopy with energy dispersive X-ray to obtain size, shape and elemental composition of single particles.
PO1: 243
Soot nanoparticles: transforming a harmful pollutant into a sustainable nanocomposite-based sensor 1CNR-ICMATE, Milano, 20125, Italy; 2CNR-IPCF, Bari, 70126, ITALY; 3Università degli Studi Di Milano e UdR INSTM di Milano, Milano, 20133, ITALY; 4Università degli Studi di Firenze e UdR INSTM di Firenze, Sesto Fiorentino, 50019, ITALY; 5Università degli Studi Di Bari, Bari, 70126, ITALY; 6CNR-NANOTEC, Bari, 70126, ITALY The aim of this study is to upcycle carbon soot particles produced through hydrocarbon combustion and to explore their potential as electroactive nanomaterials. The soot particles undergo acidic pre-treatment to introduce surface functional groups that facilitate gold deposition. A sustainable colloidal chemical approach is then implemented to decorate the soot (NPs) with gold nanoparticles (Au NPs). The novel hybrid nanocomposites have been fully characterized and their electroanalytical properties were tested in the detection of H2O2, a key biomarker in biological processes, and diclofenac (DFC) drug, a pharmaceutical water contaminant responsible for serious human health and environmental concerns.
PO1: 244
Sub-micrometer urban aerosol analysis by nanoelectromechanical systems-based Fourier-transform infrared spectroscopy (NEMS-FTIR) 1Invisible-Light Labs GmbH, Vienna, 1040, Austria; 2Institute for Sensor and Actuator Systems, TU Wien, Vienna, 1040, Austria; 3TSI GmbH, Aachen, 52068, Germany We demonstrate rapid collection and chemical characterization of sub-micrometer urban aerosols using nanoelectromechanical systems-based Fourier-transform infrared spectroscopy (NEMS-FTIR) with the EMILIE™ (Invisible-Light Labs GmbH). Combined with a mini-MOUDI™ impactor (Model 135-10B, TSI GmbH) and aerosol impactor adapter plate, particles down to 10 nm were sampled for less than 30 minutes and analyzed by different size fractions. Spectral features revealed common organic and inorganic aerosol constituents, including black carbon, whose concentrations were estimated via spectral fitting of a reference spectrum of Diesel soot. Results show clear temporal differences in chemical composition (midday vs. rush hour & size fractions, respectively).
PO1: 245
Tracing textile-origin VOCs in airborne particulate matter: Non-Targeted profiling via HS-SPME GC-Orbitrap. CNR IIA, Italy The CELLOPHAN project investigates the chemical fingerprint of plastic materials from major industrial sectors to support airborne microplastics research. We applied HS-SPME GC-Orbitrap HRMS to characterize VOC emissions from textile blends sampled during industrial operations. Four cotton-based fabrics (with polyester or acrylic) were incubated to simulate emissions under warm conditions. The method enabled the untargeted detection of over 100 compounds, with clear differences among fabrics. Cluster and correlation analyses identified specific emission markers. The workflow was also tested on PM₁₀ filter samples, confirming its potential to trace textile-derived VOCs in complex environmental matrices.
PO1: 246
Towards an improved historical emission dataset for modelling air quality in urban areas during the industrialization 1Leibniz Institute for Tropospheric Research, Germany; 2Faculty of Economics and Management Science, Leipzig University, Leipzig, Germany Is there a link between industrial-era air quality and contemporary socio-economic outcomes in German cities? Answering this question requires spatial data on urban air pollution at the end of the 19th century. The regional chemistry-transport-model ICON-MUSCAT is used to model historical air quality in Germany using an improved emission dataset based on the emissions of the Community Emissions Data System (CEDS). Improvements of the spatial distribution of the sector-wise emissions are performed with the help of population data and historical maps that provide the location of factories etc. within the city, as well as the extent of populated areas. PO1: 247
Comparison of atmospheric PM10 measurements obtained by online and offline ED-XRF instrumentation. 1Institute of Atmospheric Sciences and Climate, ISAC-CNR, Lecce, Italy; 2Department of Engineering for Innovation, University of Salento, Lecce, Italy This study compares online and offline elemental composition measurements of PM₁₀ using the same ED-XRF technique but different sampling supports: Teflon tape for the Xact® 625i analyser and quartz filters for the benchtop ED-XRF. The online system, operating at the ECO observatory with 3-hour time resolution, also records meteorological parameters, allowing source-related interpretations. Daily averages from the Xact are compared with offline measurements to assess agreement and data quality. In addition, we present the first high temporal resolution dataset of elemental concentrations at ECO, focusing on specific tracers of sources such as African dust, biomass burning, road traffic, and fireworks. PO1: 248
CFD simulation of non-exhaust particles dispersion in the wake flow of a passenger car 1Ecole Supérieure des Techniques Aéronautiques et Construction Automobile (ESTACA), France; 2Royal Military Academy (RMA) Non-exhaust emissions (NEE) from tyre and brake wear and resuspended particles are a major source of traffic-related PM, particularly in urban areas. As wheels strongly influence airflow around the vehicle, simulating their motion is essential for accurate predictions. This study uses CFD simulations to assess the turbulent dispersion of brake-wear particles from a passenger car, providing insights into their transport and potential exposure risks. Results show that particles primarily accumulate on both sides of the vehicle due to longitudinal vortices. Inside wheelhouses, larger particles settle quickly on surfaces, while smaller ones remain airborne longer, extending their suspension in the air.
PO1: 249
Integrated measurements of atmospheric aerosol properties over Naples urban area using near surface and remote sensing devices 1Università degli studi di Napoli "Federico II", Italy; 2Consiglio Nazionale delle Ricerche Istituto di Metodologie per l’Analisi Ambientale; 3Università della Basilicata The APINA (Aerosol Properties by Integrated measurements in Naples Area) campaign investigates atmospheric aerosol properties in the urban area of San Giovanni a Teduccio, Naples. Conducted through collaboration between CNR, University of Naples "Federico II," and University of Basilicata, the study combines surface and remote sensing instruments to assess aerosol optical and microphysical properties. The campaign focuses on pollution sources like black carbon from traffic and harbour emissions, as well as long-range transport phenomena. Results aim to improve understanding of urban air quality, seasonal variability, and the environmental impact of anthropogenic emissions.
PO1: 250
Tracing Sources of Elemental PM2.5 in the Sarajevo Basin: Results from the SArajevo AEROsol Experiment (SAAERO) 1Institute of Environmental Assessment and Water Research (IDAEA-CSIC), Barcelona, 08034, Spain; 2University of Nova Gorica, Nova Gorica, 5000, Slovenia; 3Center for Energy and Environmental Sciences, Paul Scherrer Institute (PSI), Villigen, 5232, Switzerland; 4Aix Marseille Université, CNRS, LCE, Marseille, 13007, France; 5Environmental Radioactivity & Aerosol Tech. for Atmospheric & Climate Impacts, INRaSTES, National Centre of Scientific Research “Demokritos”, Ag. Paraskevi, 15310, GreeceNCSR; 6Research and Development Department, Aerosol d.o.o, Ljubljana, 1000, Slovenia; 7Federal Hydrometeorological Institute of Bosnia and Herzegovina, Sarajevo, 71000, Bosnia and Herzegovina The high-resolution Xact 625i data facilitated better identification of complex pollutant sources at the Sarajevo site (BIH) strongly influenced by meteorology. In the frame of the first systematic extended study of fine aerosols in Sarajevo during 2022—2023 (Sarajevo AEROsol Experiment: Composition, Sources, and Health Effects of Atmospheric Aerosol, SAAERO) we identified following winter PM2.5-el. sources: fresh and aged biomass (41%), heavy oil/regional (35%), industrial (17%), traffic (4%), dust (2%) and firework (1%). The study provided valuable insights for developing effective pollution mitigation strategies in this pollution hotspot.
PO1: 251
Chemical characterization of atmospheric aerosols in Antarctica 1Università Politecnica delle Marche, Department of Life and Environmental Sciences; 2Ca’ Foscari University of Venice, Department of Environmental Sciences, Informatics and Statistics; 3National Research Council, Institute of Biological Resources and Marine Biotechnology Aerosols play a crucial role in climate dynamics, yet their sources and distribution in Antarctica remain underexplored. This study analyzes size-segregated elements in Antarctic aerosols to assess seasonal variations and potential sources. Seven samples were collected at Faraglione Camp (November 2019–January 2020) using a cascade impactor. Elemental analysis via ICP-OES, GF-AAS, and DMA revealed distinct seasonal trends influenced by katabatic winds and pack-ice melting. Enrichment factor analysis indicated geogenic and marine contributions, with Cd, Cr, and Hg suggesting anthropogenic influence. These findings underscore the need for continued aerosol monitoring to evaluate long-range pollution transport and environmental impacts.
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Exploring Short-Term Exposure to Traffic-Related Air Pollution during Bicycle Commuting 1UMRESTTE UMRT9405, Université Gustave Eiffel, Université de Lyon, Université Lyon 1F-69675, Bron, France; 2LESCOT, Univ Gustave Eiffel, Univ Lyon, F-69675, Lyon, France; 3Division of Environmental Health & Risk Management, School of Geography, Earth & Environmental Sciences, University of Birmingham, Edgbaston, Birmingham, B15 2TT, United Kingdom Transport-Related Air Pollution (TRAP) poses significant health risks, particularly for active commuters. This study compares TRAP exposure among cyclists using conventional (CvB) and electric-assisted bikes (EAB) in Lyon, France. By measuring pollutant concentrations and inhaled doses on high- and low-traffic routes, we found that UFP and black carbon doses were significantly higher in high-traffic areas. CvB users consistently inhaled more TRAP due to greater physical effort and increased breathing rates. The study is part of a broader project on cognitive effects of TRAP exposure. Further research with additional participants will refine these findings and explore seasonal variations.
PO1: 253
Analysis of Aerosol Absorption Properties through an Integrated Experimental Approach during a Monitoring Campaign at a Central Mediterranean Site 1Department of Engineering, University of Salento, Lecce, Italy; 22Insitute of Atmospheric Sciences and Climate, ISAC-CNR, Lecce, Italy; 3Department of Mathematics and Physics, University of Salento, Lecce, Italy This study examines the carbon fraction of atmospheric particulate matter (PM), focusing on Black Carbon (BC), a byproduct of incomplete combustion with significant climate and health impacts. Sampling took place in Lecce (May–June 2024), with analysis conducted using advanced techniques, including the AE33 aethalometer, OC/EC analyzer, and Isotope Ratio Mass Spectrometry (IRMS). Results show seasonal variability in PM absorption, with BC as the primary contributor to solar radiation absorption. Strong correlations (R > 0.50) were found between PM components and absorption coefficients. Isotopic analysis identified key sources like traffic, biomass burning, and desert dust, supporting air quality mitigation strategies.
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| 5:15pm - 6:45pm | Poster Session Tuesday Location: Studium2000 Building5 | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Switching regimes in fire plumes: regional implications 1School of Chemical and Environmental Engineering, Technical University of Crete, Greece; 2Leverhulme Center for Wildfires, Environment and Society, Imperial College London, London, UK Wildfire events present a rising frequency in recent years, especially in warm climate regions. During such events, the generated fire plume contains a mixture chemical species, driving the chemical processing during the initial and aging stage. Organic aerosols comprise a large portion of the available species and their fate is primarily determined by two competing regimes. In this work we evaluate the conditions of prevalence of each regime. The balance of these two regimes is associated with the black and brown carbon levels; thus, the differentiation of the chemical reactions in the center and at the edges of the plume.
PO2: 2
Photosensitization Induced by Carbonyl Compounds and Its Role in Secondary Aerosols Formation King Abdullah University of Science and Technology, Saudi Arabia Organic photosensitizers from biomass burning can generate oxidants, facilitating the conversion of precursors into secondary aerosols. Chloride ions mix with photosensitizers in biomass burning particles, influencing aerosol oxidative potential. Using SO₂ oxidation to sulfate as an indicator, we found NH₄Cl + glyoxal particles produced sulfate 4–5 times faster than NaCl + glyoxal, especially at low humidity. Adding imidazole-2-carboxaldehyde (IC) increased sulfate production 73-fold compared to NH₄Cl alone. Kinetic analysis revealed chloride ions react with ³IC* at rates ~1000 times higher than in bulk solutions, highlighting the synergistic role of chlorine chemistry and photosensitization in atmospheric oxidation.
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Aerosol composition and gas/particle partitioning in a nitrogen dominated atmosphere 1Wageningen University & Research, the Netherlands; 2Utrecht University, the Netherlands; 3National Institute for Public Health and Environment, the Netherlands; 4Rijksuniversiteit Groningen, the Netherlands Reactive nitrogen has previously been found relevant in new particle formation and growth events, but specific mechanisms are not yet fully understood. The research consortium of CAINA (Cloud-Aerosol Interactions in a Nitrogen dominated Atmosphere) aims to gain new insights into these important interactions. We will present first results of aerosol and gas composition measurements that have started in a nitrogen rich environment in central Netherlands. A MARGA, ACSM and chemiluminescence NOy detector are used to investigate nitrogen speciation across the gas and aerosol phase. The studied mechanisms are informed by thermodynamic equilibrium models (e.g. ISORROPIA2 and E-AIM).
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Chemical formation pathways of secondary organic aerosols in the Beijing-Tianjin-Hebei region in wintertime Yunnan University, China A regional air quality model system (RAQMS) was developed by incorporating an aqueous reaction mechanism for secondary organic aerosol (SOA) formation and primary semi-volatile (SVOC) and intermediate volatile organic compounds (IVOC) precursors to investigate various chemical pathways for SOA formation in the Beijing-Tianjin-Hebei (BTH) region in wintertime. The average contributions from various precursors or chemical pathways to SOA formation during the study period were estimated, in which AVOCs (anthropogenic VOCs), SVOCs, IVOCs, BVOCs (biogenic VOCs), GLY and MGLY contributed 38.4%, 24.9%, 28.4%, 0.2% and 8.1% of SOA mass concentration, respectively, in the BTH region.
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Cross-validation of methods for quantifying the contribution of local (urban) and regional sources to PM2.5 pollution: Application in the Eastern Mediterranean (Cyprus) 1Climate and Atmosphere Research Centre (CARE-C), Nicosia, Cyprus; 2National Observatory of Athens, Athens, Greece; 3Department of Labour Inspection, Ministry of Labour and Social Insurance, Nicosia, Cyprus This work quantifies the contribution of local versus regional PM sources in Cypriot cities by applying two source apportionment methods namely the “Lenschow approach” and Positive Matrix Factorization (PMF) to a comprehensive filter-based PM2.5 chemical composition dataset collected at multisite network consisting of one urban traffic site (NICTRA) and two urban background (NICRES and LIMRES) located within the two largest cities of Cyprus (Nicosia and Limassol), along with one regional background (AMX).The robustness of our conclusions on local versus regional source contributions is demonstrated by strong agreement between the two techniques.
PO2: 6
Black Carbon Trends and Source Apportionment in Berlin: A Multi-Year Analysis 1Forschungsinstitut für Nachhaltigkeit – Helmholtz-Zentrum Potsdam, Germany; 2Climate and Atmosphere Research Center (CARE-C), The Cyprus Institute, Nicosia, Cyprus Black Carbon (BC) is a key air pollutant affecting air quality, climate, and public health. This study analyzes over five years of BC measurements in Berlin using Aethalometer AE33 data, alongside PM₂.₅, PM₁₀, NOx, and CO concentrations to assess source contributions. Traffic-related BC will be estimated using NOx and CO correlations, while biomass burning influences will be evaluated through seasonal trends and, where possible, levoglucosan or Elemental Carbon/Organic Carbon validation. Seasonal, annual, and diurnal variations will be examined, contributing to the Net4Cities initiative. Findings will inform air quality policies, particularly in quantifying fossil fuel vs. non-traffic BC contributions.
PO2: 7
Aerosols from Biomass Burning: A Comparative Study under Controlled and Uncontrolled Combustion Conditions State Research Institute, Center For Physical Sciences And Technology, Vilnius, Lithuania, Lithuania Biomass burning is a major source of atmospheric aerosols, impacting air quality and climate. This study examines the isotopic composition (δ13C) of aerosols from various wood species and coal under controlled and uncontrolled combustion conditions. Two experimental setups were used: one simulating domestic heating in Lithuania and the other in a controlled laboratory environment. Biomass materials (18 types) and coal were combusted, and aerosol samples were collected using a high-flow sampler. δ13C values varied between −24‰ to −30‰ for uncontrolled and −22‰ to −29‰ for controlled conditions. The findings highlight the influence of combustion conditions on aerosol formation and composition.
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Modelling Air Pollution in Coastal Industrial Zones of Chile: A Fuzzy Clustering and High-Resolution Spatial Approach Including the “Gray Zone” Pontifical Catholic University of Chile, Chile Quintero and Puchuncaví are two coastal cities in Chile currently recognized as part of the country's "sacrifice zones" due to frequent air pollution episodes caused by industrial emissions. A key challenge is identifying the spatiotemporal distribution of PM2.5 and SO2 near these sources. We developed a new methodology for source apportionment of industrial emissions using a fuzzy clustering technique to determine the contributions of PM2.5 and SO2 concentrations from industrial complexes in these cities. This approach allows us to isolate industrial impacts from other sources in the study areas, such as traffic and residential emissions.
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Source apportionment analysis of phosphorus in PM2.5 and PM10 in two Greek cities 1ECPL, Department of Chemistry, University of Crete, Heraklion, 70013, Greece; 2IERSD, National Observatory of Athens, P. Penteli, Athens, 15236, Greece; 3CARE-C Research Center, The Cyprus Institute, Nicosia, 2121, Cyprus; 4CSTACC, ICE-HT, FORTH, Patras, Greece; 5Institute of Environmental Physics, University of Bremen, Bremen, Germany Phosphorus (P) is crucial for ecosystems, cycling through land, ocean, and atmosphere. In the eastern Mediterranean, P limits marine productivity, with atmospheric deposition as a key source. This study analyzed PM2.5 (Athens) and PM10 (Heraklion) samples for total and inorganic P, bioaerosol proxies, and chemical components. Results showed peak total P in spring, correlating with bioaerosols. Positive Matrix Factorization identified bioaerosols (31%) as major P sources, followed by anthropogenic emissions (28%) and Saharan dust (19%). These findings highlight the significant role of bioaerosols in atmospheric P cycling, emphasizing their importance in marine nutrient supply.
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Source apportionment of aerosol particles by positive matrix factorization in urban background environment (Vilnius, Lithuania) State research institute Center for Physical Sciences and Technology, Lithuania An aerosol is a suspension of a liquid or solid particles suspended in a gas. Aerosols are a key contributor to environmental issues such as global warming, poor air quality and health. Depending on their nature, aerosols are divided into natural and artificial. Natural aerosols are formed under the influence of natural forces The aim of this study was to determine the sources of aerosol particles using positive matrix factorization in an urban background environment. Measurements were performed from January 2 to December 21, 2019 at the urban background site located at the Vilnius.
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Spatial characterization of Urban Particle Phase Pollution Sources through Mobile Measurements in Sarajevo 1PSI Center for Energy and Environmental Sciences, 5232 Villigen PSI, Switzerland; 2University of Nova Gorica, Nova Gorica, 5000, Slovenia; 3Aix Marseille Univ., CNRS, LCE, Marseille, 13007, France; 4Federal Hydrometeorological Institute of Bosnia and Herzegovina, Sarajevo, 71000, Bosnia and Herzegovina; 5now at: Institute of Climate and Energy Systems (ICE-3Troposphere, Forschungszentrum Jülich, 52428 Jülich, Germany; 6now at: Institute of Environmental Assessment and Water Research (IDAEA-CSIC), Barcelona, 08034, Spain; 7now at: Environmental Radioactivity & Aerosol Tech. for Atmospheric & Climate Impacts, INRaSTES, National Centre of Scientific Research “Demokritos”, Ag. Paraskevi, 15310, Greece; 8now at: NOAA CSL & Cooperative Institute for Research in Environmental Sciences (CIRES), Boulder, CO, USA Air pollution in Sarajevo, Bosnia and Herzegovina, is exacerbated by wintertime temperature inversions and solid fuel combustion, leading to PM2.5 levels comparable to those in Asian megacities. To identify pollution sources, high-resolution mobile and stationary measurements were conducted in January 2023 as part of the SAAERO project. Using Positive Matrix Factorization (PMF), five organic aerosol factors were identified, with oxygenated organic aerosol (OOA) dominating overall. Residential wood burning and cooking were key contributors in different urban areas. These findings provide crucial insights for targeted air quality mitigation strategies in South-Eastern Europe.
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Chemical composition, sources and vertical transport of non-refractory submicron aerosol in Po Valley: simultaneous on-line measurements at Bologna (54 m a.s.l.) and Mt. Cimone (2165 m a.s.l.) 1Institute of Atmospheric Sciences and Climate (CNR-ISAC), National Research Council of Italy, Bologna, 40129, Italy; 2Institute of Atmospheric Sciences and Climate (CNR-ISAC), National Research Council of Italy, Lamezia Terme, 88046, Italy Submicron particulate matter (PM1) impact health, climate, and ecosystems, with Organic Aerosol (OA) being a key component. OA is either directly emitted (POA) or formed through atmospheric processes (SOA), undergoing ageing during transport. Time-of-Flight- (ToF) and Quadrupole- (Q) Aerosol Chemical Speciation Monitors (ACSM) have been measured non-refractory PM1 (NR-PM1) since August 2024, in Bologna (urban) and at Mt. Cimone (remote). Results show OA dominates NR-PM1, with SO4 more abundant at Mt. Cimone and NO3 at Bologna. POA is observed in the lower Po Valley but absent at Mt. Cimone, indicating significant OA ageing, influenced by Planetary Boundary Layer dynamics.
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Comprehensive source apportionment of black carbon at a rural site in Punjab using the aethalometer model and positive matrix factorization (PMF) model 1Department of Mechanical Engineering, Indian Institute of Technology Delhi, New Delhi, 110016, India; 2Department of Chemical Engineering, Indian Institute of Technology Delhi, New Delhi, 110016, India; 3Department of Civil and Environmental Engineering, Virginia Tech, Blacksburg, USA, 24060; 4Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villegen, Aargau 5232 Switzerland Crop residue burning severely impacts air quality and health in India, despite regulations. This study measures black carbon (BC) at a rural stubble-burning site in Punjab and applies source apportionment techniques. The Aethalometer Model (AM), though widely used, identifies only two sources, limiting accuracy. To improve analysis, the Positive Matrix Factorization (PMF) model was also used. BC concentrations ranged from 1.45 to 85.0 µg/m³, averaging 12.6 µg/m³. AM estimated 48.5% BC from biomass burning and 51.5% from fossil fuels, while PMF identified five sources. The study found an average Absorption Ångström Exponent (AAE) of 1.7 ± 0.3.
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Advancing Air Quality and Climate Insights in Lahti, Finland: Investigating Regional Emission Sources 11Institute for Atmospheric and Earth System Research/Physics, University of Helsinki, Finland; 2Atmospheric Modelling Centre Lahti, Finland; 33School of Engineering Science, Lappeenranta-Lahti University of Technology,Finland Air pollution in Lahti is influenced by transboundary transport from Eastern Europe and Russia. This study applied the FLEXPART-SOSAA model to assess pollutant transport and the role of large-scale weather patterns. Results show significant contributions of sulphates, black carbon, and organic aerosols, with seasonal variations driven by coal combustion, biomass burning, and meteorological conditions. Cyclones enhance transport, while anticyclones cause stagnation. Model results align with ground-based observations, highlighting the need for international cooperation and adaptive strategies for air quality management.
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Black carbon source apportionment and air mass transport effects in urban areas across warm and cold seasons 1Institute for atmospheric Physics, University of Mainz (JGU); 2University of Warsaw; 3Center for Physical Sciences and Technology; 4Stiftelsen NILU (former Norwegian Institute for Air Research) This study examines black carbon (BC) sources and aerosol optical properties in Vilnius and Warsaw during the warm (2022) and cold (2022/23) seasons. Aethalometers and Nephelometers were used to investigate BC source contirbution and optical properties, while the FLEXPART model was used to distinguish local and transported BC. Results showed similar BC source distribution in summer but increased coal burning in Warsaw during winter. Optical classification indicated higher contribution of BC-BrC mixtures in winter, though small BC-dominated particles prevailed year-round. Long-range transport significantly influenced BC levels, especially in winter, highlighting its role in urban BC dynamics in Poland and Lithuania.
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Light Absorbing Carbon in Atmospheric Particulate Matter in Lagos 1Clarkson University, United States of America; 2EnvironQuest Limited, Nigeria; 3PAS Environmental, LLC, United States of America; 4University of Rochester, United States of America Light-absorbing carbon (LAC) consisting of black carbon (BC) and brown carbon (BrC) are key compoents of PM2.5 and poses risks to climate, visibility, and human health. LAC was mesured at 6 sites in Lagos Nigeria from 2020 to 2021 using filter and continuous methods. Filters were analysed for LAC with a Multiwavelength Absorption Black Carbon Instrument (MABI) at seven wavelengths (405 nm, 465 nm, 525 nm, 639 nm, 870 nm, 940 nm and 1050 nm) and for EC with a Sunset thermal-optical analyzer. Aethlab MA350s were operated at each site. Differences among sites and measurements will be presented.
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Evaluation of aerosol optical properties of cooking emissions in rural East African homes 1Leibniz Institute for Tropospheric Research, Leipzig, 04318, Germany; 2Atmosfair gGmbH, Berlin, 12059, Germany; 3Safer Rwanda, Kigali, P.B 7301, Rwanda; 4Buana e.V., Hamburg, 22767, Germany The optical properties of aerosol emitted during cooking in rural households in Rwanda were investigated. Participants used traditional cooking methods and improved cookstoves. Aerosol mass concentrations were monitored using portable light absorption photometers. Filter PM10 samples were collected and analysed to determine elemental, organic (OC), and total carbon concentrations. During the use of the stoves, the total absorption decreased by ~50-70% compared with traditional cooking. The largest reductions occurred in the UV due to a significant difference in OC between both methods. The change resulted in different Absorption Ångström Exponent (AAE, traditional cooking = 2,4, new stove = 1,4).
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Optical and Aerodynamic Properties of Solid Aerosol Aggregates in the Context of Potential Stratospheric Aerosol Injection 1Paul Scherrer Institute PSI, Switzerland; 2ETH Zürich, Switzerland This study investigates the optical and aerodynamic properties of solid aerosol aggregates in the context of stratospheric aerosol injection (SAI) for solar radiation management. Through numerical simulations and laboratory experiments, it quantifies the impact of particle coagulation on light scattering and atmospheric residence time, both of which collectively determine the radiative forcing potential of injected aerosols.
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Characteristics of Black Carbon in San Luis Potosi City, Mexico. 1UASLP, Mexico; 2IMAREC, UASLP, Mexico; 3CIACYT, UASLP, Mexico BC is emitted primarily from the incomplete combustion of fossil fuels, biofuels, and biomass burning, therefore, can be classified into two subfractions: fossil fuel (BCff) and biomass burning (BCbb). BC is formally defined as a refractory light-absorbing substance composed of aggregated carbon spherules. San Luis Potosi City is located in central Mexico and is characterized by a huge automotive industry, funding industry, and mining sector. This study presents an evaluation of BC measured by an AE33 Aethalometer, from three different zones and years in San Luis Potosi City, with different characteristics and emission sources.
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Unraveling the Role of PAHs in Shaping Primary and Secondary Brown Carbon Absorption in Eastern India's Semi-Urban Atmosphere 1Indian Institute of Technology, Kanpur, India; 2Indian Institute of Tropical Meteorology, Pune, India This study examines the contribution of PAHs to Brown Carbon (BrC) light absorption at a semi-urban site in Jorhat, India. Using laser reflectance data and the Minimum R2 approach, BrC absorption was determined and apportioned into primary and secondary BrC. PAHs contributed 0.8% to BrC absorption, with high molecular weight PAHs dominating (98.6%). Benzo(g,h,i)perylene was the largest contributor (41.2%). PAH absorption correlated strongly (0.84) with primary BrC but weakly with secondary BrC, highlighting its origin from direct emissions and its significant role in BrC radiative forcing and atmospheric impact.
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Wintertime aerosol chemical composition over the Arabian Sea based on shipboard collected aerosols: Implication to surface water biogeochemical processes 11CSIR-National Institute of Oceanography, Dona Paula, Goa, 403004, India; 22Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India Atmospheric aerosol chemistry is crucial to assess and understand the role of aerosols in controlling the surface water biogeochemical processes. In this context, a cruise-based study is undertaken during northeast monsoon (NE), and aerosol samples were collected for the analyses of their chemical composition in the Arabian Sea. This comprehensive analysis of aerosol composition in the Arabian Sea provides valuable insights into the sources and transformation processes of marine aerosols, emphasizing the influence of continental outflows and secondary aerosol formation. These findings contribute towards the better quantification of aerosols, which plays an important role in understanding the surface water biogeochemistry.
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Spatial and Seasonal Variation in Chemical Composition of Urban Residential Outdoor PM2.5 across four cities in India Indian Institute of Technology Bombay, India This study, part of APEAL, uniquely examines seasonal and spatial variations in PM2.5 chemical composition across four Indian cities. PM2.5 levels were highest in Delhi, especially in winter, exceeding other cities by up to 87%. Overall, major contributors to PM2.5 levels were WSII, OC, and EC. WSII, dominated by sulfate and nitrate, peaked in winter, while summer fractions featured sodium and phosphate. SOC was highest in Delhi (86%), indicating strong photochemical activity, while WSM, mainly zinc, peaked in Mumbai. This spatial and seasonal variability in chemical composition can explain varying impacts rather than PM mass concentration.
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Multiphase Aerosol-Cloud Chemistry and Secondary Aerosol Formation from α-pinene 1Wageningen University & Research, The Netherlands; 2Center for Isotope Research, Rijksuniverstiteit Groningen, The Netherlands; 3Institute for Marine and Atmospheric Research Utrecht, Utrecht University, The Netherlands; 4Institute of Meteorology and Climate Research-Atmospheric Aerosol Research, Karlsruhe institute of Technology, Germany The oxidation of biogenic volatile organic compounds (BVOCs), such as α-pinene, plays a key role in secondary organic aerosol (SOA) formation, particularly in nitrogen-rich atmospheres like the Netherlands. This study integrates AIDA cloud chamber experiments with the F0AM box model to investigate the multiphase chemistry of α-pinene oxidation products. By varying relative humidity and seed composition, we assess their impact on SOA growth and organic nitrogen species formation. Our results improve the mechanistic understanding of gas-aqueous-particle partitioning, enhancing SOA representation in cloud-resolving models and contributing to better predictions of aerosol evolution in regional and global atmospheric models.
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On-line speciation of glyoxal multiphase reactions on deliquesced ammonium sulfate particles 1Aix-Marseille University, France; 2Université Paris Est Créteil and Université Paris Cité, CNRS, LISA, Créteil, France; 3Université Clermont Auvergne, CNRS, OPGC, LaMP, Clermont Ferrand, France; 4Leibniz Institute for Tropospheric Research (TROPOS) Leipzig, Germany This study presents chemical speciation of the gas and the particle phases during the uptake of gaseous glyoxal on deliquesced AS seed particles (RH ≥ 80 %) in the CESAM chamber.
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Playing with bricks: speciation models to depict the interaction among water-soluble components of the atmospheric particulate matter 11Department of Chemistry, University of Turin, Turin, 10125, Italy; 2Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche e Ambientali, CHIBIOFARAM, Università degli Studi di Messina, Messina, 98168, Italy; 3Department of Life and Environmental Sciences, Università Politecnica delle Marche, Ancona, 60131, Italy; 4Regional Environmental Protection Agency of Piedmont, Turin, 10135, Italy A water droplet in air acts as a complex chemical reactor, where various chemical species interact with each other, and many reactions can occur, such as acid-base reactions, photolysis, metal hydrolysis, and complexation. Modelling the chemical species in these droplets helps better understand environmental processes. These processes are influenced by the type and concentration of specific chemical species. Speciation models for water-soluble components of PM10 have been developed. The results highlight the importance of the interaction between Fe and oxalate. More detailed investigation of this interaction was conducted by modeling different conditions to assess the photochemical activity of these systems.
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Results from the first chemical ionization mass spectrometry Intercomparison Workshop at the TROPOS twin chamber setup in ACTRIS CiGas 1Atmospheric Chemistry Department (ACD), Leibniz Institute for Tropospheric Research, Germany (TROPOS); 2Institute for Atmospheric and Earth System Research (INAR) / Physics, University of Helsinki Condensable vapors are precursors of Secondary organic aerosols (SOA). Their improved detection has led to massive progress in the understanding of atmospheric processes, but the large variety of instruments and techniques limits the comparability of the results. In this study, ten NO3-CI-ToFMS instruments took part in an intercomparison workshop at a simulation chamber setup. A unified inlet system was designed to improve the comparability. A series of experiments were performed parallel in both chambers, including gas mixtures of analytical standards, α-pinene oxidation under various conditions and sulfuric acid formation from OH oxidation. Observed differences emphasize the need for further investigation.
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Concentrations of Key Atmospheric Pollutants: BC and PAHs in PM2.5 – Levels, Meteorological Influence, Correlation with Other Pollutants and Health Aspects 1Burgas State University Prof. Dr Asen Zlatarov, Bulgaria; 2National Institute of Meteorology and Hydrology, Sofia, Bulgaria Fine particulate matter is a key air quality indicator influenced by interactions with other pollutants and meteorological conditions. In this regard current study focuses on PM2.5 and associated BC and PAH concentrations at an urban background site in Sofia, where three samplings were carried out during February-March 2022, October-November 2022 and February-March 2023. BC concentrations were analyzed using Multi-wavelength Absorption Black Carbon Instrument, while 19 PAH compounds in PM2.5 were quantified via GC-MS/MS. Present study analyzes correlations between PM2.5, BC, PAHs and other pollutants (PM10, NO2, CO, Benzene) using data from Sofia-Mladost (EEA) and assesses the impact of meteorological factors.
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Effects of hydroperoxy radical heterogeneous loss on the summertime ozone formation in the North China Plain Institute of Earth Environment, Chinese Academy of Sciences, China, People's Republic of Hydroperoxy radical (HO2) is key in NO to NO2 oxidation, contributing to tropospheric O3 formation. While HO2 uptake on wet aerosols is efficient, its impact on O3 remains unclear. Model simulations of a severe O3 pollution episode in the North China Plain (NCP) in 2018 showed that HO2 heterogeneous loss reduced daytime HO2 and MDA8 O3 concentrations by 5% and 1%, respectively. However, decreased HO2 uptake due to reduced emissions from 2013 to 2018 only contributed to a 5% increase in MDA8 O3, indicating it is not a major driver of O3 trends in the NCP.
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Modelling for atmospheric radicals and oxidants on PM2.5 and O3 episodic and non-episodic days in an urban area of Taiwan China Medical University, Taiwan This study aims to characterize the key radicals and oxidants during PM2.5 and O3 episodic and non-episodic days in a Taiwan urban area using a photochemical box model with field constraints. The OH was the dominant radical, peaking at noon and followed by HO2 and RO2, whereas the NO3 peaked in the evening. The production of OH was mainly driven by the HOx cycling between HO2 and NO, whereas the major loss of OH was due to its reaction with VOCs. Nighttime chemistry of NO3 and N2O5 hydrolysis were implicated in elevated PM2.5 in the following morning hours.
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Biomass Burning Organic Aerosols as a Pool of Atmospheric Reactive Triplets to Drive Multiphase Sulfate Formation 1King Abdullah University of Science and Technology, Saudi Arabia; 2City Univeristy of Hong Kong, Hong Kong Biomass-burning organic aerosol(s) (BBOA) are rich in brown carbon (BrC), which significantly absorbs solar irradiation and potentially accelerates global warming. Despite its importance, the multiphase photochemistry of BBOA remains poorly understood. In this study, we explored the photochemical reactivity of BBOA particles in multiphase S(IV) oxidation to sulfate. We found that sulfate formation in BBOA particles is predominantly driven by photosensitization involving the triplet excited states (3BBOA*). Our results highlight that the chemistry of 3BBOA* in particles can greatly contribute to the formation of sulfate. Photosensitization of BBOA will likely become increasingly crucial due to the intensified global wildfires.
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Fast generation of peroxides via particulate photosensitization King Abdullah University of Science and Technology, Saudi Arabia Peroxide species are key oxidants in shaping the atmospheric oxidative capacity, yet their formation pathways remain elusive under high-NOx conditions, where classical gas-phase mechanisms are suppressed. Herein, we report an underappreciated ‘in-particle’ peroxide formation pathway driven by photosensitization reactions in biomass burning organic aerosol (BBOA). This mechanism remains highly efficient even in polluted, high-NOx environments, leading to orders-of-magnitude increase in particulate H₂O₂ concentrations under sunlight—far exceeding levels expected from gas-phase partitioning. These new findings suggest that intensifying wildfires in our warming world, beyond their primary emissions, may significantly reshape atmospheric oxidation chemistry and exacerbate air quality degradation.
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Wildfire chromophores enhance the production of sulfate radicals in Ammonium Sulfate photochemistry 1University of California, Davis, United States of America; 2Central South University, Changsha, China Recent research challenges the assumption that ammonium sulfate (AS) aerosols are photochemically inert. While prior studies used dilute solutions, aerosol liquid water (ALW) contains high ionic strength AS, allowing for the formation of reactive sulfate radicals (SO₄•⁻) under troposhpehric light. Wildfire-emitted chromophores, increasingly common due to climate change, significantly enhanced SO₄•⁻ radical production when added to these AS solutions. To determine the production yield, the radicals were trapped with an organic compound to form organosulfates, and tracked via liquid chromatography coupled with high-resolution mass spectrometry. The findings reveal important implications for atmospheric chemistry, climate models, aerosol-cloud interactions, and health impacts.
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Numerical Analysis of Fuel Injection Control and Its Impact on Aerosol Formation and Transport in Urban Canyons and Open Environments 1Tampere University, Finland; 2Sahand University of Technology; 3University of Helsinki This study employs a numerical modeling approach to analyze pollutant emissions from a combustion chamber and their transformation into aerosols in urban environments. The first phase focuses on optimizing fuel injection control to reduce emissions and improve efficiency, revealing that an increasing oscillatory injection pattern enhances power output while enabling waste heat recovery. The second phase models pollutant dispersion and chemical transformation in street canyons and open areas using CFD and atmospheric chemistry simulations. The findings offer insights into the impact of fuel injection strategies, urban geometry, and meteorological conditions on air quality, supporting better emission control and mitigation policies.
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Dust contribution in the performance evaluation of the FARM dispersion model 1ARPA Puglia, Italy; 2ARIANET srl This work presents the results produced within the framework of The Puglia Regional Air Quality Plan. The reconstruction of PM10 concentrations across the entire regional territory, for a specific emission scenario, was carried out using the modelling system implemented at ARPA Puglia. The emission database was reconstructed for the year 2019 using the INEMAR system. The model performance evaluation was conducted using the DELTA TOOL software, by comparing the modelled PM10 data with the measured data from the 61 monitoring stations of the regional air quality network, taking into account the contribution of Saharan dust.
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Impact of Traffic Emissions on Near-Road Air Quality in the Presence of a Noise Barrier: A PALM-LES Simulation 1Aerosol Physics Laboratory, Physics Unit, Tampere University, Tampere, Finland; 2Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, Finland; 3Helsinki Region Environmental Services Authority HSY, Ilmalantori 1, FIN-00240, Helsinki, Finland; 4Atmospheric Composition Research, Finnish Meteorological Institute, PL 503, FIN-00101 Helsinki, Finland; 5Helsinki Institute of Sustainability Science, Faculty of Science, University of Helsinki, Helsinki, Finland Urban air quality significantly affects public health, with traffic emissions influenced by urban structures. This study investigates how a noise barrier affects traffic aerosol movement using the parallelized large eddy simulation model PALM. Simulations use real-world topographic and also meteorological data to assess conditions with wind flowing perpendicular to the highway. By comparing scenarios with and without the barrier, and validating results with field measurements, the study evaluates its impact on total particle concentrations.
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Radiative Cooling in New York/New Jersey Metropolitan Areas by Wildfire Particulate Matter 1Faculty of Aerospace Engineering, Delft University of Technology, Delft, 2629 HS, The Netherlands; 2School of Public Health, Rutgers University, Piscataway, NJ 08854, USA; 3School of Environmental and Biological Sciences, Rutgers University, New Brunswick, NJ 08901, USA; 4Institute for Environmental Research and Sustainable Development, National Observatory of Athens, Athens, 15236, Greece; 5Department of Chemistry, University of Crete, Heraklion, 71003, Greece; 6Department of Physics, University of Ioannina, Ioannina, 45110, Greece Here, state-of-the-art real time and time integrated instrumentation is used to characterize the physicochemical properties and radiative effects of wildfire particulate matter (WFPM) reaching the highly populated metropolitan areas of New Jersey/ New York during the extreme wildfire incident of summer 2023. The WFPM direct radiative forcing of -352.4 W/m2 derived here based on the light absorption and scattering measured at the peak of this incident explains the observed temperature reduction of about 3 K. Such negative radiative forcings may limit natural ventilation of megacities, increase the residence time of WFPM and other background air pollutants, exacerbating public health risks.
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Monitoring and Analysis of Black Carbon in different cities in Mexico UASLP, Mexico Mexico is number 13 on the list of countries with the largest volumes of CO2 emissions in year 2013. Nevertheless, there are not enough official measurements of BC, especially in most medium-sized cities. Peralta et al. (2019) recompiled all the BC studies measured in Mexico, and pretended to establish a BC Network, but just a few state governments were interested. This study added information from 5 different monitoring sites with different characteristics measured by an AE33 Aethalometer, to have a better understanding of this pollutant to develop mitigation and adaptation strategies, reduce emission precursor sources, and risks in the population.
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Aerosol Model-Measurement Comparison for Improving the Prediction of Aircraft Engine Deterioration 1Institute of Jet Propulsion and Turbomachinery, Technische Universität Braunschweig, Germany; 2Institute of Flight Guidance, Technische Universität Braunschweig, Germany Aerosol particles cause aircraft engine deterioration, adversely affecting flight safety and maintenance costs. The present paper aims to contribute to refining estimates of the amount of aerosols ingested by engines. Therefore discrepancies in model outputs and atmospheric measurements are identified. This is done by comparing atmospheric composition models with in-situ measurements of aerosol particles, which were performed with the research drone ALADINA downwind of the airport Berlin-Brandenburg. The research shows that the aviation community needs observations in airport proximity to obtain more precise estimates of the quantities of ingested contamination.
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Desert dust exposure in sub-Saharan Africa: the case of the city of Cotonou, Benin 1Université du Littoral Côte d'Opale (ULCO), France; 2Université d’Abomey-Calavi, LBBM, Benin; 3Université du Littoral Côte d'Opale (ULCO), CCM, France; 4Université du Littoral Côte d'Opale (ULCO), PFT, France; 5Centre National Hospitalier et Universitaire de Pneumo Phtisiologie de Cotonou (CNHUPP-C), Benin; 6Université Paris Cité, UMR 261 – MERIT, Paris The present work will focus on outdoor air pollution and examines the various factors that contribute to the concentration of PM2.5 in ambient air in Cotonou, Benin. Ambient air quality was monitored over the period from January to May 2024. Statistical analysis tools were used to identify and quantify the contribution of sources to the concentration of PM2.5 in ambient air in Cotonou. Results show that exceedances of ambient PM2.5 concentration occur mainly during the dry season, when the harmattan wind is active. A maximal average daily concentration of 166 µg/m3 was recorded, whereas the WHO recommendation is 15 µg/m3.
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Effects of Urban Form on PM2.5 Concentration Using Explanatory Machine Learning SRI Center for Physical Sciences and Technology (FTMC), Lithuania Air pollution is a major health risk, with PM2.5 exposure causing 253,000 premature deaths in the EU in 2021. Urbanization alters air pollution distribution by increasing built-up areas and reducing green spaces. This study examines how 2D/3D urban form affects PM2.5 in Vilnius, Lithuania, using Spatial Random Forest machine learning. Key factors influencing PM2.5 include built-up volume (BU-Vol), percentage of landscape (PLAND), and largest patch index (LPI), while edge density (ED) is least important. Findings enhance understanding of urban form’s impact on air quality, aiding pollution control efforts.
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Investigating the vertical distribution of sporadic appearance of ultrafine aerosol particles emitted at the airport FRA 1Institute of Flight Guidance, Technische Universität Braunschweig, Braunschweig, 38108, Germany; 2Department of Atmospheric Microphysics, Leibniz Institute for Tropospheric Research (TROPOS), 04318, Leipzig, Germany; 3Institute of Combustion Technology, German Aerospace Center (DLR), Stuttgart, 70569, Germany; 4Institute of Atmospheric Physics, German Aerospace Center (DLR), Oberpfaffenhofen-Wessling, 82234, Germany Ultrafine aerosol particles (UFP) impose significant health risks, especially in the vicinity of airports due to high exposure of emissions. To obtain a profound understanding of the vertical distribution of UFP in the atmospheric boundary layer, the research drone ALADINA was used to measure aerosol particles in the size of 4-19 nm (N4-19) around Frankfurt Airport in October 2024. The results indicate a pronounced appearance of N4-19 close to ground, when air masses originate from the airport plume. In addition, peaks of N4-19 occur in a vertically concentrated altitude of 200-400 m, suggesting horizontal transport during aircraft approach.
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Saharan Dust Transport in the Mediterranean: Circulation Patterns, Air Quality Monitoring, and Chemical Composition Analysis 1Istituto di BioEconomia IBE-CNR, 50145 Florence, Italy; 2ENEA, SSPT-CLIMAR, 40121 Bologna, Italy; 3Consorzio LaMMa, 50019 Sesto Fiorentino, Florence, Italy; 4Department of Chemistry, University of Florence, 50019 Sesto Fiorentino, Florence, Italy; 5I.N.F.N., Florence, Via Sansone 1, 50019 Sesto F.no, Florence, Italy; 6Department of Physics and Astronomy, University of Florence, 50019 Sesto F.no, Florence, Italy In the Mediterranean, Saharan dust transport increases PM10 levels, often exceeding EU limits and impacting human health. Recent years have seen more frequent and intense intrusions, likely due to climate change. The LaMMA Consortium applied a weather classification method to identify circulation patterns linked to these events. Data from the AirQino network helped track PM10 and PM2.5 plumes in space and time. Analyses from 2018-2023 reveal both direct and complex dust transport paths. Chemical analyses of PM10 samples in Tuscany confirmed the desert origin using techniques like ion chromatography, PIXE, and ICP-AES.
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Dust storm dynamics: a study using HYSPLIT and WRF to analyze dust transport patterns in León, Spain 1University of Leon, Spain; 2University of Salamanca; 3Droplet Measurement Technologies We use the regional atmospheric model WRF and the Hybrid Single-Particle Lagrangian Integrated Trajectories model to diagnose the contribution of Saharan dust to the northwest region of Spain. We find that synoptic conditions correspond to an anomalous cut-off low whose center initially sits in front of the Iberian Peninsula and rapidly migrates southwards over northwest Africa and Morocco, exposing air to the central dust source in the region. These dynamic conditions are apt for a strong meridional advection of aerosol, which limits the action of scavenging processes and renders a substantial mass of aerosol deposition in NW Spain.
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The Spectroscopic Multiparameter Particle Analyzer Droplet Measurement Technologies, United States of America An innovative instrument to quantify multple properties of aerosol particles has been developed that integrates technology that images at high resolution, extracts the complex refractive index from spherical particles, identifies organic and bioaerosols from the fluorescence signatures and measures the absorption cross section with thermal analysis. The Spectroscopic Multiparameter Particle Analyzer (SMPA) is the results of years of development at DMT of a suite of ground based and airborne instrument, i.e. the CAPS, WIBS, SP2 and AFN that have been well characterized by users worldwide. Selected featurs from the instruments have now been integrated into a single system, the SMPA.
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Enhancing Air Quality Governance: Results from LIFE SIRIUS in Rome Enviromental Protection Agency of Lazio Region ARPA Lazio, Italy The LIFE SIRIUS project enhances air quality governance in urban areas through integrated assessment methods. In Rome, it evaluated Air Quality Plans, emission scenarios, and mitigation measures. Using a high-resolution dispersion model, it projected air quality for 2030 under "do nothing" (CLE2030) and "with measures" (CLE2030+AQP) scenarios. Findings indicate NO₂ reductions up to 13 µg/m³, PM2.5 drops up to 13 µg/m³, and consistent PM10 improvements. Measures like sustainable transport and renewable energy incentives proved effective. The study highlights the need for coordinated policies, robust emission inventories, and advanced modelling to meet air quality targets and mitigate health risks.
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High-Resolution Modeling of Air Pollution in Poland: Evaluation of EMEP4PL and uEMEP for PM2.5, NO2, and O3 1University of Wrocław; 2Norwegian Meteorological Institute; 3Xi’an Jiaotong-Liverpool University This study compares two chemical transport models – EMEP4PL (4 km x 4 km resolution) and downscaling uEMEP (1 km ×1 km, 500 m × 500 m, and 100 m × 100 m resolutions) – using daily averages of PM2.5, NO₂, and O₃ in 2022. We examined seasonal variability, station/area type effects. The uEMEP model demonstrated significant performance improvements compared to EMEP4PL. The highest accuracy was achieved at 500 m × 500 m resolution. The uEMEP model outperformed EMEP4PL, with improvements at rural stations and weaker performance at urban traffic sites. Seasonal analysis revealed challenges.
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Impacts of urban expansion on meteorology and air quality in North China Plain during wintertime: A case study Institute of earth environment, Chinese Academy of Sciences, China, People's Republic of The North China Plain (NCP) has rapid urbanization, with urban areas increasing from 1.78% in 2000 to 6.70% in 2015. Urban expansion impacts air quality through changes in meteorology and physicochemical processes. WRF-Chem simulations show urbanization raises near-surface temperature by 0.2℃, boundary layer height by 1.6%, and humidity by 0.4%. O3 increases by 2.2%, while PM2.5 decreases by 2.4% overall and 8.9% in urban areas. NO2, SO2, and CO also decline. Despite higher emissions, urban expansion reduces particulate pollution in cities.
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Microscale impact assessment of particulate matter emissions from a large steel plant in Taranto (Italy) 1ARPA PUGLIA, Italy; 2ARIANET Srl, via B. Crespi 57, Milan, 20159, Italy The study assesses the microscale impact of particulate matter emissions from a large steel plant in Taranto, Italy, using Lagrangian particle modeling. The aim is to reconstruct exposure at a microscale level, considering the influence of urban structures and recently built park roofs on pollutant dispersion. Simulations were conducted with the PMSS modeling suite over an 8 km × 8 km domain with a 5 m resolution, divided into 25 communicating tiles to speed up a parallel computation which was performed on a the RECAS HPC Data Center. The abstract presents the modeling setup and preliminary results of the study.
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Preliminary Analysis of Aerosol Size Distribution at Col Margherita 1Institute for Polar Sciences, National Research Council (CNR-ISP), Venice, Italy; 2Department of Environmental Sciences, Informatics and Statistics, Ca’ Foscari University of Venice, Italy.; 3Department of Civil Environmental and Mechanical Engineering (DICAM), University of Trento, Trento, Italy.; 4Stiftelsen NILU, Kjeller, Norway; 5Institute of Marine Sciences, National Research Council (CNR-ISMAR), Italy; 6Department of Health Sciences (DISS), University of Basilicata, Potenza, Italy This study presents a preliminary assessment of aerosol concentrations at the Col Margherita Observatory (2543 m a.s.l.). Data from June 12, 2023, to August 20, 2024, showed a seasonal pattern, with maximum concentrations in summer and late summer, and minimum values in winter. Diurnal trends were generally weak, but particles tended to peak at night and drop during the day, opposite to planetary boundary layer height. These findings suggest distinct sources and processes for different particle sizes and offer insight into aerosol transport in the Dolomites. Further analysis will include LIDAR data from Passo Valles.
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Investigating drivers of recent reductions in PM2.5 concentrations across the UK 1Wolfson Atmospheric Chemistry Laboratories, University of York, Heslington, York, UK; 2National Centre for Atmospheric Science, University of York, Heslington, York, UK Larger than expected decreases in PM2.5 have been observed recently across the UK. This work utilises the AURN and complementary networks to investigate the potential drivers of these recent reductions. The largest reductions of aerosol components were ammonium and nitrate during spring, with larger decreases observed at more southerly sites. Overall, the European source of PM2.5 appears to be weakening during spring, driving reductions in PM2.5 concentrations in the UK. This analysis highlights a complex air quality policy issue. The UK can only control a certain fraction of the PM2.5 concentrations, with the controllable fraction varying across the UK.
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Characterization of Secondary Organic Aerosols formed in Atmospheric Simulation Chambers and Flow Tube with Liquid Chromatography - High-Resolution Mass Spectrometry 1Université du Littoral Côte d'Opale, France; 2IMT Nord europe, Institut Mines-Télécom Secondary Organic Aerosols (SOAs) are formed from the oxidation of Volatile Organic Compounds (VOCs). They present complex chemical compositions. To assess the molecular characterization of them, the Electrospray Ionization – Liquid Chromatography – Quadrupole Time of Flight – Tandem Mass Spectrometry was implemented with simulation chambers/flow tubes for different VOCs precursors emitted by various sources: biomass combustion (furans, methoxyphenols), vegetation (terpenes) and transport (aromatics). These studies demonstrate the usefulness and effectiveness of the technique to characterize oxidation products, oligomers, Highly Oxygenated Organic Molecules... This work is useful for SOA formation understanding, identification of markers to trace sources and toxicological studies.
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Urban vs. Suburban PM10 Organic Aerosols fingerprints in an Eastern Mediterranean medium-sized coastal city 1ECPL, Department of Chemistry, University of Crete; 2CSTACC, ICE-HT, FORTH; 3LAMOS, Institute of Environmental Physics, University of Bremen This study investigates the PM10 (particulate matter of diameter smaller than 10 μm) organic aerosol fingerprints in an urban and a suburban site in Heraklion, Crete, during winter 2024. Liquid chromatography coupled with electrospray ionization Orbitrap mass spectrometry was used to analyze 48 PM10 aerosol filter samples in both positive and negative full MS modes. Principal component analysis revealed a clear separation between urban and suburban samples for positive ion mode features. The majority of significant urban features in positive mode correlated with black carbon and predominantly consisted of relatively high volatility molecules with low O:C ratios indicating fresh emissions.
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Organic and emerging pollutants in indoor suspended particles hospitals before, during and after SARS-CoV2 pandemic. CNR, Italy Four indoor chemical characterisation campaigns were conducted in five Italian hospitals. Measurements were performed before the peak of SARS-CoV2 (autumn 2019), during (spring 2021) and after the lifting of the pandemic restrictions (winter 2022 and 2023). Deposition dust (DD) and its comparison with atmospheric particulate matter (PM) were analysed. In this study, PM samples were collected using an air conditioning filter, which can represent indoor particulate matter. The air conditioning filter has a good effect on particle retention and is contaminated by ultrafine particles, which can be resuspended and follow the air conditioning back into the indoor air.
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Primary emissions and secondary organic aerosol production potential of a large automobile fleet focusing on cold starts at an underground parking facility 1Department of Chemical Engineering, University of Patras, Patras, 26504, Greece; 2Institute of Chemical Engineering Sciences (FORTH/ICE-HT), Patras, 26504, Greece; 3Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, 5232, Switzerland While vehicular emissions are highly regulated, significant uncertainty remains during cold starts as well as their potential to form secondary organic aerosol. To address this gap, a measurement campaign was conducted in an underground parking garage in Patras, Greece, providing a controlled environment to study light-duty vehicular emissions. An oxidative flow reactor was placed in front of a PTR-CHARON-ToF-MS and an AMS to simulate aging of vehicular emissions over timescales ranging from hours to days, allowing characterization of both fresh and aged volatile organic compounds (VOCs) and the fresh and aged organic aerosol.
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Stability of clusters of highly oxygenated organic molecules from alpha-pinene ozonolysis and sulphuric acid oxidation. 1University of Tartu, Estonia; 2CERN, European Organisation for Nuclear Research; 3University of Vienna, Austria; 4Aerodyne Research Inc; 5University of Helsinki; 6Airel OÜ The chemical composition of first-step oxidation products is measured and identified by elemental composition, but molecular structures are only estimated by modeling. Here we add additional measured information about the atmospheric nucleating clusters by measuring the stability of clusters of highly oxygenated organic molecules from alpha-pinene ozonolysis and sulphuric acid oxidation. We use a differential mobility analyzer together with an electrospray and mass spectrometer to generate ions with known composition (ammoniumhalides), fragment them in mass spectrometer and apply the obtained fragmentation energy to unknown sample from CLOUD chamber.
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Chemical aerosol composition of biomass burning emissions exposed to daytime and nighttime oxidation conditions in the EUPHORE chambers 1EUPHORE Laboratories, Fundación CEAM, Paterna, 46980, Spain; 2Aerosol d.o.o., Ljubljana, SI-1000, Slovenia; 3Center for Atmospheric Research, University of Nova Gorica, Ajdovščina, Slovenia; 4AtmosphericPollution Laboratory (LCA-UMH), Miguel Hernández University, Elche, 03202, Spain Biomass burning impacts climate, air quality, and health through aerosol emissions that undergo oxidation under day and night conditions. This study, based on experiments at the EUPHORE simulation chambers, explores daytime photooxidation of emissions, driven by OH radicals, and nighttime aging, dominated by nitrate radicals. Using advanced instrumentation (API-ToF-CIMS+FIGAERO), key compounds found in the particle phase as well as chemical families are identified for each oxidation condition tested. The findings highlight how oxidation processes influence aerosol composition and optical properties, emphasizing their role in climate and air quality.
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Aerosol composition, sources, and their relation to meteorology on the highest mountain in southwest Germany 1Karlsruhe Institute of Technology, IMKAAF, Germany; 2CNR-ISAC, Bologna, Italy; 3Research Institute for Applied Mechanics, Kyushu University, Fukuoka, Japan Aerosol particles influence cloud formation, precipitation, radiative transfer, and air quality, impacting meteorological predictions. From June 15 to July 26, 2023, aerosol measurements were conducted at Mt. Feldberg (1500 masl) in the Black Forest, Germany, using advanced sensors and mass spectrometers. Lidar scanning provided atmospheric structure insights. Data from the Swabian MOSES 2023 campaign showed aerosol variations linked to Saharan dust, Canadian wildfire plumes, and precipitation washout effects. High-resolution mass spectra will help identify aerosol sources for comparison with transport models. This study examines aerosol composition, sources, and their relation to meteorological conditions.
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ATMOMACCS: Predicting atmospheric compound properties. 1Department of Applied Physics, Aalto University, Espoo, 02150, Finland; 2Physics department, School of Natural Sciences, Technical University of Munich, Garching, 85748, Germany; 3Atomistic Modelling Center, Munich Data Science Institute, Technical University of Munich, Garching, 85748, Germany In this contribution, we introduce a new interpretable molecular descriptor, ATMOMACCS, specifically tailored to atmospheric molecules. We demonstrate its competitive performance in predicting various thermodynamic properties, such as saturation vapor pressure, vaporization enthalpy, partition coefficients, and glass-transition temperature, equaling or surpassing published results for four distinct atmospheric molecular datasets. Our molecular descriptor addresses the need for customized and accurate modeling in data-driven atmospheric science. Additionally, the descriptor’s inherent interpretability and strong performance in thermodynamic property prediction, using machine learning, show promise for further research in molecular-level atmospheric science.
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Cheating the path to new molecular tracers: gas-phase ammonia and organic aerosol-driven reactivity Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Frankfurt am Main, Germany In this work, we exposed ambient PM2.5 samples to ammonia (NH3) saturated air in order to identify compounds affected by atmospheric NH3 concentrations. We investigated the molecular composition of the samples after 72 hours of exposure to NH3, water and synthetic air using HPLC-HRMS. The results show an increase in N-containing compounds and in light-absorbance.
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Comparative Analysis of Chemical Composition and Oxidative Potential of PM1.0 and PM2.5 in Seosan, Republic of Korea Mokpo National University, Korea, Republic of (South Korea) Concentrations of carbonaceous components (OC and EC) and increased proportions of levoglucosan and terephthalic acid (TPA), particularly at night. These components are by-products of coal and waste combustion processes, indicating that ultrafine particles formed from combustion activities possess higher toxic chemical characteristics and exhibit prolonged atmospheric persistence. Additionally, the toxicity equivalency factor (TEF) evaluation of PAHs revealed that PM1.0 posed greater carcinogenic and mutagenic risks compared to PM2.5. DTT-OP analysis also indicated that PM1.0 exhibited higher oxidative potential per mass unit. These findings suggest that current policies regulating only ambient PM concentrations are insufficient and highlight the necessity for separat
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Composition and sources of organic particles and vapours in an urban location during wintertime 1Department of Chemical Engineering, University of Patras, Patras, Greece; 2Institute for Chemical Engineering Sciences, ICEHT/FORTH, Patras, Greece Understanding the chemical composition of organic aerosol (OA) and its gaseous precursors is crucial for assessing secondary organic aerosol formation and potential health effects to exposed population. A study in an urban background site in Athens investigated the chemical composition of OA and organic gaseous species, with the use of a Proton Transfer Reaction Mass Spectrometer (PTR-TOF-MS), with simultaneous collection of sorbent tube samples analyzed through gas chromatography (GC-MS). Results were compared to corresponding measurements of the previous year at an urban location in Athens and different compounds were related to sources apportioned through positive matrix factorization (PMF).
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Identification of fine particulate matter and Gaseous Pollution Sources Contributing to Oxidative Potential in a National Petrochemical Industrial Complex: Based on the source apportionment Model Mokpo National University, Korea, Republic of (South Korea) The oxidative potential normalized to QDTT-OP for PM2.5 showed a significant correlation with key emission sources, particularly EC and Pb, likely due to incomplete combustion processes. Effectively managing these emissions is essential for mitigating health risks associated with air pollution. This study provides valuable insights for developing strategies to improve air quality and public health in areas surrounding industrial complexes.
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Impact of Agricultural Activities on PM2.5 Emissions and Oxidative Potential in Rural Areas of South Korea Mokpo National University, Korea, Republic of (South Korea) The study concludes that the oxidative potential of PM2.5 originating from agricultural activities is elevated due to biomass burning, which could potentially increase human health risks. Moreover, the findings provide insight into the emission characteristics of air pollutants according to differences in agricultural practices between rice and dry field farming. By understanding the emission patterns based on the timing of agricultural activities and the characteristics of cultivated crops, this study offers valuable data for predicting emission quantities.
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Long-Range Transport and Airborne Measurements of VOCs Using Proton-Transfer-Reaction Mass Spectrometry Validated Against GC-MS-Canister Data During the ASIA-AQ Campaign Mokpo National University, Korea, Republic of (South Korea) Chlorinated VOCs, such as 1,2-dichloroethane and 1,2,4-trichlorobenzene, display transport behaviors. Their relatively consistent concentrations during long-range transport emphasize the influence of industrial activities, including coal combustion and petrochemical processes, as major sources. The prevalence of chlorinated VOCs in the Chungnam industrial area and during transportation stages further highlights their strong link with industrial emissions rather than urban traffic sources. These observations necessitate the development of integrated air quality management strategies that accommodate both local and transboundary sources of VOCs.
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Monitoring of Nitrated Polycyclic Aromatic Hydrocarbons in the Czech Republic Czech Hydrometeorological Institute, Czech Republic Nitrated polycyclic aromatic hydrocarbons (NPAH) are a group of highly toxic organic pollutants with significant carcinogenic potential. NPAH are persistent in the environment and contribute to mutagenic and genotoxic effects of pollution. This has a negative impact on human health and mortality worldwide. Their long-term continuous monitoring in the Czech Republic is practically non-existent which makes this research unique. This study maps concentration of NPAH in the air and evaluates their relation to concentration of PAH and nitrogen oxides (NOx). Year-round sampling was done in four cities. High-volume sampler equipped with PM10 sampling head inlet was used for collection.
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Saccharides study in aerosol during wintertime over urban sites in Central Europe and Indo-Gangetic Plain 1Indian Institute of Technology Patna, India; 2Indian Institute of Technology Kanpur, India; 3University of Silesia in Katowice Saccharides are vital organic compounds in atmospheric chemistry, acting as tracers for aerosol sources like biomass burning and soil resuspension. This study analyzed saccharides in aerosols from highly polluted regions: Allahabad (India) and Sosnowiec (Poland). Seasonal variations were observed, with higher anhydrosaccharide concentrations in Allahabad due to hardwood and crop residue combustion, while Sosnowiec emissions mainly came from softwood burning. Correlations among saccharides indicated biomass combustion as a major source. Additionally, contributions from soil resuspension and fungal spores were noted. Overall, aerosol saccharide composition varied by location and source, impacting atmospheric processes.
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The impact of open burning of rice straw on PM concentrations and tracer components in eastern Spain Miguel Hernández University of Elche, Spain Two sampling campaigns were carried out in October 2023 and 2024 near the city of Valencia, coinciding with the period when rice straw burning is allowed. During the first campaign PM10 samples were collected, while during the second campaign the sampler was equipped with a PM2.5 inlet. A comprehensive chemical characterisation, including the analysis of levoglucosan and its isomers, was performed. Marked increases in the concentrations of anhydrosugars and other components usually emitted from biomass combustion, such as WSOC and K+, was observed on days impacted by biomass burning, along with increases in OC/EC, Levoglucosan/Mannosan and Levoglucosan/Galactosan ratios.
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Long-term monitoring of carbonaceous aerosols in the UK: Insights form national air quality monitoring network National Physical Laboratory, UK, United Kingdom Carbonaceous aerosols (CA) present significant implications for air quality, climate as well as human health. Understanding long-term trends and variability of CA is of utmost importance for evaluating the effectiveness of air quality policies and assessing their environmental impacts. This work highlights the efforts of the National Physical laboratory (NPL), UK which manages the UK’s Particle Concentrations and Numbers (PCN) and Black Carbon (BC) air quality Network. The results from this Network highlights the significance of sustained monitoring efforts in supporting evidence-based policy development and improving our understanding of aerosol dynamics in a changing environment.
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Nighttime vertical distribution of black and brown carbon from biomass combustion during traditional Burning of the Witches in Central Europe 1Global Change Research Institute of the Czech Academy of Sciences, Brno, 60300, Czech Republic; 2Institute of Chemical Process Fundamentals of the Czech Academy of Sciences, Prague, 16500, Czech Republic; 3Department of Geography, Faculty of Sciences, Masaryk University, Brno, 60200, Czech Republic; 4RECETOX, Faculty of Science, Masaryk University, Brno, 61137, Czech Republic; 5Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, 5232, Switzerland; 6Czech Hydrometeorological Institute, Košetice Observatory, Košetice, 39424, Czech Republic In this study, a 250 m-tall tower was used to investigate the vertical distribution of black (BC) and brown (BrC) during the traditional Burning of the Witches (BoW), the largest open-air biomass burning (OBB) experiment in Central Europe. Carbonaceous aerosol concentrations were significantly higher during the BoW, and the vertical distribution was exacerbated by the low and stable atmospheric boundary layer during the night. The enrichment of the BB smoke in BrC led to a significantly enhanced absorption Ångström exponent, more pronounced at the near-surface level which was mostly influence by local OBB smoke plumes confined within the mixing layer.
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Cross molecular chemical characterization of primary and aged logwood stove emissions using online mass spectrometry 1INERIS, Parc Technologique Alata, Verneuil en Halatte, 60550, France; 2Aerospec, EPFL, Lausanne, 1015, Switzerland; 3Haze Instruments, Ljubljana, Slovenia; 4University of Nova Gorica, Nova Gorica, Slovenia; 5Aix Marseille Univ., CNRS, LCE, Marseille, France Residential wood combustion is a significant source of PM2.5 in winter, emitting volatile and semi-volatile organic compounds that form secondary organic aerosols (SOA). Despite their environmental impact, the SOA formation mechanisms, particularly involving nitrate radicals at night, remain underexplored. This study investigates the chemical transformations of the emissions from a modern logwood stove using advanced online mass spectrometry techniques (CHARON-PTR-ToF-MS and EESI-ToF-MS). Experiments, simulating real-life heating conditions, focused on the day- (OH radicals) and nighttime (NO3 radicals) aging of softwood and hardwood combustion. The study provides real-time molecular characterization of primary and aged emissions, offering insights into their chemical composition.
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Source attribution of carbonaceous fraction of particulate matter in the urban atmosphere based on chemical composition 1AGH University of Krakow, Faculty of Energy and Fuels, Krakow, Poland.; 2AGH University of Krakow, Faculty of Physics and Applied Computer Science, Krakow, Poland; 3Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen-PSI, Switzerland; 4Datalystica Ltd, Park innovAARE, 5234 Villigen, Switzerland; 5Jan Kochanowski University, Institute of Chemistry, Uniwersytecka 7 Street, 25-406 Kielce, Poland; 6Institute for Chemical Technologies and Analytics, TU-Wien, 1060 Vienna, Austria Air quality is of large concern in the city of Krakow. A comprehensive study was launched in which two PM fractions (PM1 and PM10) were sampled during 1‑year campaign, lasting from April 21, 2018 to March 19, 2019. A suite of modern analytical methods was used to characterize the chemical composition of the collected samples. The carbon isotope composition in both analysed PM fractions, combined with an isotope‑mass balance method, allowed to distinguish three main components of carbonaceous emissions in the city: (1) emissions related to combustion of hard coal, (2) emissions related to road transport, and (3) biogenic emissions.
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Carbon content in PM10 and PM2.5 at a rural background monitoring site in the hinterland of Zadar, Croatia Institute for Medical Research and Occupational Health, Croatia The rural-regional background monitoring station in Ravni Kotari, Croatia, continuously monitored PM10 and PM2.5 fractions throughout 2024. Elemental carbon (EC) and organic carbon (OC) were measured using the thermal-optical method, following the EUSAAR_2 protocol and EN 16909 standard. Results showed seasonal variations in carbon fractions, with no significant differences between weekdays and weekends, except for OC and total carbon (TC). While the proportion of secondary organic carbon (SOC) was consistent across PM fractions, primary organic carbon (POC) was 2.5 times higher in PM2.5. Water-soluble organic carbon (WSOC) had a higher contribution in PM10 than PM2.5.
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Carbonaceous Particles from Gasoline and Diesel Vehicles' Exhaust: Chemical and Isotopic Composition 1State research institute Center for Physical Sciences and Technology, Vilnius, Lithuania; 2Institute for Marine and Atmospheric research Utrecht (IMAU), Utrecht University, The Netherlands; 3Centre for Isotope Research (CIO), University of Groningen, Groningen, The Netherlands The chemical composition of exhaust particles from both gasoline and diesel vehicles is complex, comprising a mixture of organic compounds and elemental carbon. In current experimental setup, three different vehicles were used. The fractional contributions of aerosols released at different thermal decomposition temperatures for emissions from one diesel and two gasoline powered vehicles during different operating conditions revealed the differences that will be presented. The isotopic composition (δ13CTC) revealed the difrences of diesel exhaust particles. Detailed chemical and isotopic analysis presented herein may contribute to the broader discourse on air quality management and the development of sustainable transportation solutions.
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Characterization of endocrine disruptors and other organic compounds in gas and particles from outdoor and indoor air in Northern France 1Unité de Chimie Environnementale et Interactions sur le Vivant, University of Littoral Côte d′Opale, Dunkirk, France; 2Atmo Hauts de France, Lille, France; 3Observatoire local de santé, Dunkirk, France The INTERFERENCE project investigates the concentration levels of endocrine-disrupting compounds (phthalates, alkylphenols, and musks), PAHs, and n-alkanes in indoor and outdoor air, considering both gaseous and particulate phases. Sampling was conducted across four sites in Dunkirk, covering industrial, urban, suburban, and rural environments. Seasonal campaigns collected indoor and outdoor air samples, analyzed for target compounds, alongside resident interviews. Results highlight significant differences between sites, influenced by environmental and residential factors. The next phase involves developing an action plan with residents, elected officials, and economic stakeholders through working groups to reduce exposure to endocrine disruptors.
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Mass concentrations of carbonaceous species in PM2.5 between seasons at different monitoring sites Institute for Medical Research and Occupational Health, Division of Environmental Hygiene, Croatia This research examined seasonal variations in atmospheric particulate matter (PM), organic carbon (OC), and elemental carbon (EC) at two monitoring sites in Zagreb. Samples of PM2.5 were collected throughout 2024. The industrial site showed higher mass concentrations of PM2.5, OC, and EC compared to the urban background site. Seasonal variations were noted, with significant differences in EC and OC concentrations. The highest OC concentration was observed in winter at the industrial site (42.4 µg/m³). The OC/EC ratio indicated higher secondary organic carbon (SOC) in summer at both sites.
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Multi-Seasonal Chemical Characterization of Organic Aerosols at Gruvebadet Laboratory 1Department of Environmental Sciences, Informatics and Statistics, Ca' Foscari University of Venice, Italy; 2Institute of Polar Sciences, National Research Council, Italy; 3Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, WA, USA; 4Atmospheric Sciences Program, Michigan Technological University, MI, USA; 5Department of Life, Earth, and Environmental Sciences, West Texas A&M University, TX, USA The Arctic remains critically underrepresented in organic aerosol (OA) records, limiting our understanding of its impacts on the regional and global climate system.
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Physicochemical characterization of soot emissions from combustion of jet fuel blended with pentanol 1Faculty of Aerospace Engineering, Delft University of Technology, Delft, 2629 HS, The Netherlands; 2Institute of Energy & Process Engineering, Department of Mechanical and Process Engineering, ETH Zürich, Zurich, 8092, Switzerland; 3Federal Institute of Metrology METAS, Bern-Wabern, 3003, Switzerland; 4Institute for Environmental Research and Sustainable Development, National Observatory of Athens, Athens, 15236, Greece; 5Department of Chemistry, University of Crete, Heraklion, 71003, Greece Here, soot is produced by enclosed spray combustion of jet fuel blending with pentanol. The physicochemical characterization of the generated soot is obtained using real-time and time-integrated sampling instrumentation. Increasing the pentanol content decreases the mass concentration up to 70 %, as well as the soot graphitization. Most importantly, the concentration of carcinogenic high molar-weight polyaromatic hydrocarbons (PAHs) is reduced due to the pentanol presence in the jet fuel. Increasing pentanol reduces the genotoxic potential of soot considerably. Thus, optimization of the pentanol content in jet fuel could eliminate the genotoxicity of soot and bound PAHs from aircraft engines.
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Rising Role of Secondary Organic Aerosol Amidst Emission Reductions in North China Plain Institute of Earth Environment, Chinese Academy of Sciences, China, People's Republic of Since the implementation of the Clean Air Act in 2013, China's annual average of fine particulate matter (PM2.5) has decreased by over 50%. However, haze episodes continue to affect the North China Plain (NCP) during winter. The formation of secondary organic aerosols (SOA) in light of these emission reductions remains poorly understood. In this study, we conducted a model-assisted analysis of field sampling data in Shijiazhuang, revealing that SOA has surpassed primary organic aerosol (POA) in prominence during the winter haze of 2024 compared to 2014.
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Evaluation of automated online-GC systems for time-resolved continuous measurements of ozone precursor VOCs in laboratory and field application 1Leibniz Institute for Tropospheric Research, Germany; 2Saxon State Office for the Environment, Agriculture and Geology (LfULG) Due to low regulatory requirements, VOC monitoring is only sparsely done in german and EU air quality monitoring networks. A laboratory intercomparison under different sample air humidities of four commercially available online-GC for VOC monitoring was done. Additionally, three of them were tested in a two-month winter field campaign and two of the instruments were deployed for 1 1/2 years in a field test. Due to significant maintenance efforts, caused by a variety of hardware and software issues, only 73-76% of data availability were achieved. Most data quality issues arose from significant peak shifts and thus peak misclassifications.
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Automatic detection of allergenic pollen grains using the Swisens Poleno Jupiter in 2024–2025 (Poland, Wrocław) 1University of Wrocław, Faculty of Earth and Environmental Sciences, Wrocław, Poland; 2Institute of Environmental Biology, Wrocław University of Environmental and Life Sciences Many automatic monitors of airborne bioaerosols are based on machine learning algorithms for classification and allow real-time detection and quantification of allergenic pollen grains. These methods are still under rapid development and require regular evaluation. The objective of this study is to evaluate the performance of the SwisensPoleno Jupiter in Wrocław (Poland) for a two-year period. During this period, two classification models were used: one trained on Switzerland's pollen data and the other adapted to Polish data. Validation has been conducted using pollen concentration data obtained from manual measurements with a Hirst-type pollen trap.
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Characterization of a novel, mid-cost device for ambient monitoring of ultrafine particles 1Laboratory Particles and Aerosols, Swiss Federal Institute of Metrology METAS, 3003 Bern, Switzerland; 2nanoDUST GmbH, 63739 Aschaffenburg, Germany Ambient monitoring of aerosols typically measures mass concentrations resulting in ultrafine particles (< 100 nm) being overlooked despite their potential for increased toxicity relative to larger particles. Here, we characterize a novel, mid-cost device for the ambient monitoring of ultrafine particle number concentration and mean diameter for both total and solid particle fractions. The device performed extremely well when tested with soot areosol with median diameters from 15 - 120 nm. At 200 nm and 10nm, particles were still measured reliably but with reduced counting efficiency. Good agreement was also seen for the particle size at all conditions tested.
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Comparison of ultrafine particle penetration in inertial and diffusional aerosol spectrometers: Nanocol vs. SDI2001 1University of Oviedo, Spain; 2Autorité de Sûreté Nucléaire et de Radioprotection (ASNR) The study compares the penetration efficiency of ultrafine particles in two aerosol spectrometers, Nanocol and SDI2001. Nanocol, designed for high flow rates, significantly outperforms SDI2001, achieving over 70% penetration efficiency for 5 nm particles compared to SDI2001’s 10%. This improvement is attributed to Nanocol’s refined inertial impaction stage, enhancing accuracy in ultrafine particle classification. The findings suggest the need to revise SDI2001 values for better ultrafine particle deposition assessments. Future work will focus on validating diffusion battery channels and refining theoretical models to improve characterization accuracy.
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An Improved Method for Measuring Cyclone Efficiency University of Alberta, Canada Cyclone efficiency data has traditionally been measured using an aerodynamic particle sizer (APS) (Maynard and Kenny, 1995), where aerosol size distribution measurements are taken upstream and downstream of the cyclone. However, “phantom” particle counts in the APS can result in measurement errors. Here the use of an aerodynamic aerosol classifier (AAC) and condensation particle counter (CPC) is explored for this application. The AAC classifies particles by their aerodynamic diameter and has the potential to make cyclone efficiency measurements with a broader range of aerosol sources, without measurement artifacts.
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Improving the accuracy of aerosol concentration measurements of an optical particle counter (UCASS) for balloon soundings 1Institute for Physics of the Atmosphere, Johannes Gutenberg University, Mainz, Germany; 2Institute for Applied Geosciences, Technical University Darmstadt, Germany; 3Particle Instruments & Diagnostics Research Group, University of Hertfordshire, Hatfield, Hertfordshire, AL10 9AB, United Kingdom; 4National Centre for Atmospheric Science, School of Earth, Atmospheric and Environmental Sciences, University of Manchester, Manchester, M13 9PL, United Kingdom We study a passive-flow Universal Cloud and Aerosol Sounding System (UCASS) for measuring aerosol and droplet size distributions during balloon soundings. We introduce an improvement by implementing a thermal flow sensor (TFS) to continuously measure UCASS flow velocities. Our balloon sounding experiments show that significant non-zero angles of attack occur during ascent, emphasizing the need for independent measurements. In-flight comparisons reveal discrepancies between GPS/pressure-derived and TFS-based velocities, leading to potential misestimation of concentrations. We found that TFS velocities are reliable up to 7.5 km altitude in mid-latitude conditions, but may be biased at higher altitudes due to low air density.
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Systematic Investigation of CPC Counting Efficiency for Three Alternative Working Fluids and Five Particle Seed Materials Cut-Offs at 10 nm and 23 nm Graz University of Technology, Austria The counting efficiency (CE) of condensation particle counters (CPCs) depends on factors such as working fluid (WF) properties and particle composition. This study evaluates alternative WFs to minimize material dependence while ensuring safety. Using simulations, experiments, and safety assessments, three WFs - n-decane, propylene-glycol, and HFE-7500 - were compared to n-butanol. Results indicate that n-decane exhibits the lowest material dependency, while propylene-glycol and HFE-7500 show varying influences. Findings suggest n-decane as a promising alternative. These insights contribute to optimizing CPC performance with reduced material influence, particularly at 10 nm and 23 nm cut points.
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Atomically precise determination of cluster structures School of Physical Science and Technology, ShanghaiTech University, Shanghai, 201210, China In this study, we present an online methodology to determine cluster structures in their native states. The collisional cross-sectional area, which is highly correlated with cluster structure, can be easily obtained via DMA-MS system and theoretical approach, both of which exhibit considerable consistency. The developed tool for deriving cluster structures is highly precise and sensitive to a single atom. The results demonstrate the ability of the plasma method to create alloy clusters of arbitrary atom combinations and the versatility of the developed tool to directly obtain cluster structures with single-atom precision.
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Improving the time resolution of a size scanning Particle Size Magnifier 1Airmodus Ltd., Helsinki, 00560, Finland; 2Institute for Atmospheric and Earth System Research, Faculty of Science University of Helsinki, Helsinki, Finland The Airmodus PSM2.0 is an advanced Particle Size Magnifier designed to measure aerosols in the 1–12 nm range. This study enhances its time resolution, reducing scanning time from 2 minutes to 30 seconds to improve measurements in dynamic environments. By optimizing flow geometry and increasing data logging frequency, scanning limits and calibration needs were assessed. Findings enable faster, more accurate size distribution measurements, particularly in nucleation studies and engine exhaust analysis. The results refine ultrafine particle detection methods, supporting atmospheric research and air quality monitoring in real-world applications.
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Measurement of number concentration of nanoparticles in suspension using ES-DMA technique Korea Research Institute of Standards and Science, Korea, Republic of (South Korea) Among various techniques for measuring size and size distribution of nanoparticles, in the study, electrospray scanning mobility particle sizer (ES-SMPS) technique was used. I have focus on sample preparation to determine size and number concentration of nanoparticles.
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Glassy nano-aerosol phase state and viscosity analysis using improved dual tandem differential mobility analyzer technique School of Earth and Atmospheric Sciences, Queensland University of Technology, Brisbane, Australia This research enhances the Dimer Coagulation, Isolation, and Coalescence (DCIC) technique for measuring aerosol particle viscosity, a critical factor influencing climate, atmospheric composition, and human health. Due to the bipolar charging efficiency of particles dropping dramatically with size, having a high PNC at smaller sizes is very challenging. The enhanced technique achieves a higher number concentration of smaller particles, by charging large particles and then evaporating them to smaller sizes. Under heating conditions, a significant shift in particle size distribution was observed. This method enables precise DCIC merge mode measurement down to 30 nm using sucrose as a test case.
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How to quantify the uncertainty of the dilution factor of diluters with internal mixing gas preparation? Topas GmbH, Germany If a dilution system is installed upstream a particle counter or aerosol spectrometer, the dilution ratio contributes linearly to the measured number concentration. Therefore, the uncertainty of the dilution rate is required to quantify the measurement uncertainty of the aerosol concentration for example when measuring the penetration of filters. The contribution discusses the applied method to quantify the uncertainty of the dilution rate and aims on developing a common method to evaluate the uncertainty of dilution systems to enable the comparison of results.
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Emission of airborne particles from 3D printing 1Department of Civil and Mechanical Engineering, University of Cassino and Southern Lazio, Cassino, FR, Italy; 2International Laboratory for Air Quality and Health, Queensland University of Technology, Brisbane, Qld, Australia Exposure to airborne particles in indoor environments is a significant concern for human health, as the presence of indoor particle sources leads to considerably higher concentrations of particles. In recent years, interest in 3D printers has grown exponentially, especially with their increasing use in homes, rising concern among users regarding emissions from these devices. In this work an experimental campaign was carried out to measure particle number concentrations and size distributions while the 3D printer was in operation using TPE and TPU filaments. All the tests performed showed that printing TPE and TPU filaments emit sub-micron particles.
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The Fluidizer - a newly standardized method for dustiness determination 1Federal Institute for Occupational Safety and Health (BAuA), Germany; 2The Cyprus Institute, Cyprus; 3Groep IDEWE, Belgium; 4TÜV Nord, Germany In this work, we present the Fluidizer as a dustiness method currently undergoing standardization at OECD, and its performance in testing several nanomaterials including different fibrous nanomaterials. Dustiness of eleven nanomaterials, from which 5 were fibrous nanomaterials, were assessed in two laboratories. The coefficient of variation per laboratory was generally <35%. CPC and electron microscopy analysis for fibrous materials were in agreement. These results show the robustness of the Fluidizer method and applicability for dustiness determination of nanomaterials with different morphologies.
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Use of a Particle-on-Slide Model for the Collection of Scattered Light, and Application to Multiphase Aerosols in Time-Dependent Systems Particle Instrumentation and Diagnostics, School of Physics, Engineering and Computer Science, University of Hertfordshire, United Kingdom We present the development and use of a particle-on-slide methodology for the generation of light-scattering data on aerosols. This method is validated using simple, well understood model aerosols, however its chief interest is in the study of dynamic systems where it is desirable to gather data on the same particle over a period of time. Where this model is appropriate, it is simpler and more accessible than existing particle levitation methods, and allows for light scattering and microscopy data to be gathered in tandem.
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Expanded Polytetrafluoroethylene Membrane-Based Humidification System for Aerosol Light Scattering Measurements Appalachian State University, United States of America The study at AppalAIR focuses on a new ePTFE tube humidifier designed to improve aerosol humidification. This system addresses challenges from previous designs, like water droplet formation, by using a highly porous membrane to transfer water vapor into a dry sample stream. The humidifier features a water jacket, stainless steel connectors, and a solenoid pump for slow, continuous water transfer. A controlled external heater adjusts the water temperature to regulate relative humidity. Extensive testing showed successful humidification, with the system operating for over two months in the field, demonstrating the design’s effectiveness for aerosol sample humidification.
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The VERT GPF-Retrofit Program for Cleaner Urban Mobility within the HORIZON Europe AeroSolfd Project VERT Association, Switzerland AeroSolfd, a HORIZON Europe project launched in 2022, aims to advance clean urban mobility by developing affordable and sustainable retrofit solutions. This three-year initiative addresses not only tailpipe emissions, but also brake and pollution in semi-closed environments. VERT has developed and tested a TRL 8 GPF-retrofit system. Results demonstrate >99% filtration efficiency on standard and real-world driving cycles. Fifty gasoline vehicles (GDI and PFI) were retrofitted across Europe exhibiting no issues with filter regeneration, increased fuel consumption, or secondary emissions during 6-8 months of operation. Furthermore, a PN-PTI testing campaign of 1000 gasoline vehicle was conducted. Final results are presented.
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Measuring NaCl with the CV-ToF-ACSM Centre for Isotope Research (CIO), Energy and Sustainability Research Institute Groningen (ESRIG), University of Groningen, Groningen, the Netherlands To date, there are few online measurement methods to quantify sub-micron sea spray concentrations. Aerosol chemical speciation monitors (ACSM) are not ideal for sea salt aerosol measurements because the refractory NaCl cannot be fully evaporated. In this study, we show the potential for the ToF-ACSM equipped with a capture vaporizer for detecting and quantifying NaCl aerosol for the first time. Laboratory experiments and controlled chamber experiments showed the potential of the CV-ToF-ACSM to quantitavely measure NaCl. Application of the method to measurements at a coastal site highlighted the ptential of the CV-ToF-ACSM for real-time sea salt aerosol measurements.
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Application of ToF-ACSM for Characterizing NR-PM1 chemical Composition at CIAO observatory in Southern Italy 1National Research Council – Institute of Methodologies for Environmental Analysis (CNR-IMAA), Italy; 2Università degli Studi della Basilicata, Italy Within the European Aerosol, Clouds and Trace Gases Research Infrastructure (ACTRIS), measurements of chemical composition and concentration levels of non-refractory submicron particulate matter (NR-PM1) were performed for the first time at the CNR-IMAA Atmospheric Observatory (CIAO, Tito Scalo – Italy, Laurita et al., 2025) from May to October 2024 using a Time-of-Flight Aerosol Chemical Speciation Monitor (ToF-ACSM). This instrument uses time-of-flight mass spectrometry to continuously analyze air samples, even over extended periods, enabling precise measurements of chemical compositions of NR-PM1, including ammonium (NH4+), nitrate (NO3-), sulfate (SO42-), chloride (Cl−), and organics aerosol (OA).
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Maximizing the output from filter sample analysis: Evolved gas analysis from thermal-optical carbon analysis (TOCA) using photoionization mass spectrometry (PIMS) 1Photonion GmbH; 2University of Rostock, Germany; 3Helmholtz Centre Munich; 4Desert Research Institute, Reno; 5Aerosol d.o.o. Carbonaceous aerosols impact climate and health, comprising 20–50% of PM2.5 mass. Thermal-optical carbon analysis (TOCA) is an established technique for organic and elemental carbon analysis, but enables molecular analysis when coupled with photoionization mass spectrometry (PIMS). We demonstrate TOCA-PIMS for wood type identification in stove emissions, distinguishing birch, spruce, and beech via unique thermal decomposition markers, as well as rapid PAH proxy- analysis from the same filter sample analysis. Moreover, hyper-fast gas chromatography as add-on may resolves isomers. This method expands chemical analysis capabilities, aiding atmospheric chemistry research and integration into routine air quality monitoring.
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A new experimental Bench for Respiratory Droplet Analysis Under Varying Hygrothermal Conditions: Design and Characterization Univ Paris-Est Creteil, France The subject of collecting and analyzing (physically and biologically) respiratory droplets became important since the last COVID-19 outbreak. Indeed, being able to physically characterize droplets (size distribution, emission rates and state) emitted by living beings will help advance our understanding of the transmission of airborne diseases in indoor environments. The main objective of this work is to propose a new experimental bench that allows to isolate and collect respiratory droplets in a controlled hygrothermal environment.
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Generation of aged bioaerosols in the laboratory for training machine-learning algorithms of automatic bioaerosol monitors 1Particles and Aerosols Laboratory, Federal Institute of Metrology METAS, Bern, Switzerland; 2Mycology and Aerobiology, Sciensano, Rue J. Wytsmanstraat 14, 1050 Brussels, Belgium; 3Federal Office of Meteorology and Climatology MeteoSwiss,Chemin de l’Aérologie 1, 1530 Payerne, Switzerland; 4Swisens AG, Emmen, Switzerland Bioaerosols such as pollen and fungal spores are ubiquitous in the atmosphere. Recent advancements in monitoring airborne biological particles using automatic bioaerosol monitors are based on image analysis, fluorescence, and machine learning. These systems provide real-time information on particle number concentration and classification at the taxonomic or species level. However, most studies have only focused on fresh bioaerosols for setting up datasets for machine learning. In ambient air, bioaerosols may change shape and property during aging and transportation, representing a key research gap. For this, we developed a new coupled experimental setup for the continuous generation of aged bioaerosols.
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Quantifying the Impact of Environmental Conditions and Biological Data Variability on the Robustness of Deep Learning-Based Pollen Classification Models 1Federal Institute of Metrology (METAS), Lindenweg 50, Bern-Wabern 3003, Switzerland; 2Federal Office of Meteorology and Climatology MeteoSwiss, 1530 Payerne, Switzerland; 3Swisens AG, 6032 Emmen, Switzerland; 4Environmental Remote Sensing Laboratory, École Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland; 5Extreme Environments Research Laboratory, École Polytechnique Fédérale de Lausanne, Sion, Switzerland The SwisensPoleno Jupiter bioaerosol monitor automates pollen monitoring in Switzerland using holographic images and UV laser-induced fluorescence (UV-LIF) spectra, fed to a deep learning classification neural network. This study tested the robustness of the retrained model from Sauvageat et al. (2020) by sampling various pollen taxa and eliminating data leakages, which occur when training and testing datasets per taxon come from the same experiment. The model performed well for Pinus sylvestris (93% accuracy) but poorly for Betula pendula and Betula utilis (3% to 6%). Ongoing tests and conditioning of pollen grains aim to investigate parameters affecting the model's classification accuracy.
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Bioaerosol and ChAMBRe: methodologies to study the bacterial viability in different atmospheric conditions 1INFN - GENOVA, Italy; 2University of Genoa, Department of Physics, Italy Bioaerosols are airborne particles with biological origin. At the ASC-ChAMBRe, bioaerosol research focuses on the interaction between bacteria and air pollutants. We used different methods for ASC experiments, including monitoring bacteria total concentration with WIBS-NEO and investigating culturable/viable bacteria concentration through different approaches. These include a multi-step protocol using an Andersen impactor, an automatic custom-made tray for collecting bacteria by gravitation on petri dishes and a liquid impinger for bacterial collection on various media depending on the analytical methodology chosen for the subsequent characterization. Here we’ll present the experimental protocols, their characterization and further results.
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Effects on viability, culturability and cell fragmentation of two bioaerosol generators during E. coli bacteria aerosolization 1Department of Physics, University of Genoa, Italy; 2INFN, Division of Genoa, Italy This study compares the performance of two bioaerosol generators: the Sparging Liquid Aerosol Generator (SLAG) by CH Technologies (SLAG CH Tech.) and the 1520 Flow Focusing Monodisperse Aerosol Generator (FMAG) by TSI (1520 FMAG TSI) , focusing on the viability, culturability, and cells fragmentation of E. coli.
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In situ characterization of adsorbates on aerosol nano-aggregates Clausthal University of Technology, Germany This paper presents a new surface-sensitive measurement method for the characterization of aerosol aggregates based on the combination of aerosol photoemission and aerosol UV-vis-extinction. The adsorption of water vapor on TiO2 nanoparticles is considered as a test case.
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Selective detection of aerosolised respiratory droplets in ambient air 1Jozef Stefan Institute; 2Nanotul Ltd, Slovenia The first method for selective detection of respiratory droplets is based on measurement of time-dependent capacitance . When droplets enter the electric field of the sensor, the capacitance is changed due to replacement of air as a part of dielectric field with water. This change is then converted into an electrical signal. The selectivity is explained by much higher dielectric constant of water compared to air, which is not the case for carbon-based particles. The device can detect individual respiratory droplets larger than 100 nm. Measurement of respiratory droplets in lecture hall and in kindergarten will be presented.
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Development of an online instrument for measuring the oxidative potential of atmospheric particulate matter with two complementary assays. 1Univ. Grenoble Alpes, CNRS, INRAE, IRD, Grenoble INP*, IGE, 38000 Grenoble, France*Institute of Engineering and Management Univ. Grenoble Alpes; 2Aix Marseille Univ., CNRS, LCE, UMR 7376, 13331 Marseille, France; 3Univ. Savoie Mont Blanc, CNRS, LOCIE (UMR 5271), 73376, Le Bourget-du-Lac, The ROS-Online device, developed at the IGE laboratory in Grenoble, enables real-time, continuous measurement of the oxidative potential (OP) of atmospheric particulate matter (PM). It uses two complementary assays, OP Ascorbic Acid (OPAA) and OP Dithiothreitol (OPDTT), to assess PM's ability to induce oxidative stress in the lung environment, a key factor in cardiovascular and pulmonary diseases. The device offers higher sensitivity and particle collection efficiency than offline methods, providing reliable data across varying pollution levels. ROS-Online’s performance correlates well with traditional offline methods, demonstrating its potential as an effective tool for air quality monitoring and research.
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Developing an RH-based correction for a PM2.5 low-cost sensor network Queensland University of Technology, Australia The present study aimed at developing an RH-based correction for a PM2.5 low-cost sensor network by using a novel method called "the dual-sensor approach". Two identical sensor boxes with the Plantower PMS7003 were placed before and after the heated inlet. The setup was collocated with the regulatory-grade instrument for one week. The PM2.5 concentration obtained by the sensor with the heater reduced the overestimation of the PM2.5 concentration from 63% to 15%. However, the correction factor varied throughout measurement, meaning that the composition of the PM2.5 changes depending on the wind direction, varying the hygroscopicity of the particles.
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From the EU metrology projects AEROMET I & II to the HE project MI-TRAP – Reliable chemical aerosol analysis by X-ray spectrometry without calibration samples 1PTB, Germany; 2MPI CEC, Germany PTB uses calibrated instrumentation for aerosol elemental analysis and contributed to many aerosol metrology projects: EMPIR AEROMET initiated multiple measurement campaigns and developed reference methods and calibration procedures, the follow-up project AEROMET II focused on traceable measurements and characterisation of aerosols by means of portable instruments, and the current MI-TRAP project aims to establish a network of monitoring stations addressing discrepancies between transport emission standards and ambient air quality limit values. Examples of PM characterization using reference-free quantification of the mass of the deposited material will be given, summarizing methodological findings paving the way to round robin and related activities.
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WALL-E: A New Wall-Free Particle Evaporator for Real-Time Online Particle Composition Measurements 1Tofwerk AG, 3645, Thun, Switzerland; 2Univ Lyon, Université Claude Bernard Lyon 1, CNRS, IRCELYON, F-69626, Villeurbanne, France WALL-E is a newly designed Wall-Free Particle Evaporator enabling real-time aerosol analysis with minimal wall interactions and fragmentation. Integrating a thermal desorber, cooling unit, and CIMS, it optimizes fluid dynamics to reduce thermal decomposition, improving quantification of semi-volatile and low-volatility species. Controlled experiments with authentic standards and oxidized VOCs demonstrate its performance. WALL-E provides high-resolution molecular insights into aerosol composition and volatility, making it a valuable tool for studying atmospheric processes, emissions, and environmental health impacts in both laboratory and ambient environments.
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A New Ground-Based Spectrometer for Improved Microphysical Characterization of Aerosols and Clouds 1Department of Environmental Science, Stockholm University, Stockholm, 11418, Sweden; 2Bolin Centre for Climate Research, Stockholm, 11418, Sweden; 3Droplet Measurement Technologies, Longmont, CO, USA, 80503 Accurately measuring the microphysical properties of clouds and aerosols remains a major challenge due to their complexity and variability. The newly developed Ground-Based Fog and Aerosol Spectrometer (GFAS) advances these measurements by combining forward and backscattered polarized light detection. In addition to measuring particle size (0.4–40 µm EOD), the GFAS provides information on backscattering intensity and polarization changes, helping to distinguish liquid droplets from solid particles such as ice crystals and dust while reducing sizing biases. Its automated wind-alignment minimizes sampling losses. We present first results from laboratory experiments and field deployments, demonstrating the instrument’s capabilities.
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Fine Particulate Matter (PM) Atmospheric Pollution : Monitoring Air Quality Using Plane Tree Barks as Bio-Monitors 1Center of Geosciences and Geoengeneering, Mines Paris - PSL, Fontainebleau, 77300, France; 2Centre de recherche Énergie Environnement, IMT Nord Europe, Institut Mines-Télécom, Université de Lille, 59000, Lille, France; 3Mines Saint-Etienne, Univ Jean Monnet, INSERM, U 1059 Sainbiose, Centre CIS, F-42023 Saint-Etienne, France This study explores the use of Platanus × acerifolia (plane trees) as passive biomonitors for urban air pollution in Paris. Tree bark samples, collected since 2016 through the Ecorc’Air project, provide insights into fine particulate matter (PM) accumulation. Magnetic susceptibility measurements quantify iron-rich particles, while SEM imaging confirms PM trapping. Statistical analysis identifies key urban pollution hotspots. XRF and ICP-MS determine metal compositions linked to vehicular emissions. Ongoing research evaluates potential health risks using oxidative potential and cytotoxicity assays. Funded by CARINGS, the project involves Mines Paris-PSL, IMT Nord Europe, and Mines Saint-Étienne.
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High temporal frequency and online aerosol characterization for source apportionment evaluations. An application to a mixed urban and industrial hotspot. 1Università di Perugia, Dipartimento di Chimica, Biologia e Biotecnologie, Perugia, 06123, Italy; 2Arpa Umbria, Servizio Rete Aria, Perugia, 06121, Italy; 3Orion srl, Veggiano, 35030, Italy Air quality is a major health concern in Europe, with particulate matter (PM) being one of the main pollutants. The recent EU Directive 2881/2024 imposes stricter limits on PM10 and PM2.5 and highlights the need for supersites to enhance monitoring.
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Investigation of DMSO-H2O mixture as working fluid for Condensation Particle Counters 1Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research – Troposphere (ICE-3), Jülich, Germany; 2Institute of Atmosphere and Environmental Research Wuppertal, Germany; 3GRIMM Aerosol Technik GmbH This study investigates the use of a Dimethyl Sulfoxide (DMSO)-water mixtures as a working fluid in Condensation Particle Counters (CPC), as it offers several advantages for CPCs operated in sensitive working environments. It has been shown that the D50-cutoff diameter is dependent on the temperature difference within the CPC operated with pure DMSO, where greater temperature differences result in smaller cutoff-diameters. We will present the behaviour of a CPC operated with mixtures of DMSO and water including a detailed report on the counting efficiency, during various measuring conditions, focusing on the temperature difference between the condenser and the saturator.
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Optimizing UAV methodology with a low-cost sensing system for air quality monitoring in diverse environmental settings 1Centro de Ciências e Tecnologias Nucleares (C2TN), Instituto Superior Técnico, Universidade de Lisboa, Loures, 2695-066, Portugal; 2Faculdade de Engenharia, Universidade Lusófona de Humanidades e Tecnologias de Lisboa, Lisbon, 1749-024, Portugal; 3IN+, Center for Innovation, Technology and Policy Research, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, Portugal; 4Atmospheric Microphysics Department, Leibniz Institute for Tropospheric Research (TROPOS), Leipzig-04318, Germany; 5Department of Geoscience and Remote Sensing, Delft University of Technology (TU Delft), Delft-2628 CN, The Netherlands This study presents an optimized methodology using Unmanned Aerial Vehicles (UAVs) equipped with an integrated system of low-cost sensors (LCSs) to obtain real-time vertical and horizontal pollutant dispersion profiles in three different environmental settings: urban, rural, and industrial. This approach aims to overcome the limitations of traditional methods by enabling high-resolution, near-surface vertical profiling of air pollutants. The methodology involves adapting a monitoring unit, incorporating AQ LCSs previously validated by the authors, to a customized commercial UAV platform (DJI Matrice 210). The UAV is equipped with GPS, a black carbon (BC) instrument (MicroAeth® AE51), and a multi-pollutant monitoring unit (MU).
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Single particle polarization measurement for aerosol characterization and classification Swisens AG, Switzerland Polarized side-scattering measurements enhance aerosol characterization in the SwisensPoleno Jupiter. The system records p- and s-polarized light intensities from particles illuminated by a 405 nm laser. The polarization ratio (PR) is determined by integrating mid-section scattering signals, effectively distinguishing biological particles (e.g., pollen) from water droplets. PR values are consistent across multiple instruments. This method complements holography and fluorescence spectroscopy, improving real-time aerosol identification and atmospheric monitoring accuracy.
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Implementation of a sensor network for the detection of airborne pollutants in a medium-sized city (In the context of the MAMELI project) 1Department of Clinical Sciences and Community Health, University of Milan, Italy; 2Department Science and High Technology, University of Insubria, Italy; 3INES (Institute of Epigenetics for Smiles), University of Milan, Italy; 4Department of Biomedical and Clinical Sciences, University of Milan, Italy The aim of the exposomic is to understand how exposures from environment, diet and lifestyle interact with our genetic background.The MAMELI Project aims to investigate a wide range of environmental factors in an urban population. A network of 16 low-cost real-time air quality monitors was located in the city hosting the living lab (Legnano, Italy). Moreover, three reference grade instruments for the target pollutants have been installed and co-located. The data collected by this network opens several research opportunities in the exposure sciences field because of their high level of detail on the spatial and temporal variability.
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A novel approach for the determination of Total Carbon, Organic Carbon, and Elemental Carbon with Aerosol Magee Scientific Carbonaceous Aerosol Speciation System CASS 1Aerosol d.o.o., Slovenia; 2Centre for Atmospheric Research, University of Nova Gorica, Slovenia Carbonaceous aerosols (CA) are usually the most significant contributor to fine particulate matter (PM2.5). They are frequently separated into Organic Carbon (OC) and Elemental Carbon (EC) based on their volatility using thermal-optical methods. The Aerosol Magee Scientific Total Carbon Analyzer TCA08 is a scientific instrument that measures the Total Carbon ("TC") of suspended aerosol particles in near real-time using a simplified thermal method (Rigler et al., 2020). Combining Total Carbon Analyzer TCA08 and Aerosol Magee Scientific Aethalometer® provides a novel approach for measuring TC, eBC, OC, and EC content of suspended aerosol particles in near-real-time with high-time resolution.
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Understanding Indoor Air Quality Under Various Ventilation Strategies Using Low-Cost Sensors in a Future Home 1Department of Earth and Environmental Science, The University of Manchester, M13 9PS, United Kingdom; 2Energy House 2.0, University of Salford, Salford, M6 6PU, United Kingdom The Future Homes Standard, set for 2025 in the UK, outlines guidelines for "zero-carbon ready" homes by improving energy efficiency, low-carbon heating, and fabric performance. However, these improvements may impact indoor air quality. Ventilation strategies like MVHR and DMEV help mitigate this while maintaining efficiency. To assess their effectiveness, low-cost sensors from Quant AQ and AirGradient were strategically deployed across Bellway’s Future Home at the University of Salford’s Energy House 2.0 and Controlled experiments were performed. PM1 concentrations were measured using these sensors, indicating that DMEV and MVHR reduce aerosol concentrations by up to 99% in future home's various locations.
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Assessing Air Pollution in Irish Towns using a Low-Cost Sensor Network 1University College Cork, Ireland; 2University of Galway, Ireland Residential solid fuel burning is Ireland’s main winter air pollution source. The TownAir project assesses the impact of 2022 solid fuel regulations by identifying PM₂.₅ sources. A field campaign in Enniscorthy (Winter 2024/2025) used regulatory EPA monitors, a low-cost sensor (LCS) network, and advanced instruments. A concentration similarity index (CSI) compared PM₂.₅ across the LCS network, with preliminary results showing higher levels in older residential areas. Source apportionment via PMF will be conducted using a low-cost sensor and will complement chemical characterization. A future campaign in Letterkenny (Winter 2025/2026) will offer comparative insights into regional pollution trends.
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Low cost sensors network for PM and NO2 urban monitoring: initial and ongoing calibration and management 1Department of Environment, Land and Infrastructure Engineering, Politecnico di Torino, Torino, 10129, Italy; 2Laboratoire de Mécanique des Fluides et d’Acoustique, Université de Lyon, Ecole Centrale de Lyon, INSA Lyon, Université Claude Bernard Lyon I, Ecully, 69134, France; 3Institute of Atmospheric Sciences and Climate, CNR, Torino, 10133, Italy; 4Department of Physics, University of Turin, Torino, 10125, Italy; 5ENEA RC-Portici, TERIN-SII-EDS, 80055 Portici, Italy Urban areas are particularly vulnerable to elevated pollution levels. To measure concentrations of pollutants, the spatial and temporal resolution of the measurement are a key factor. Low-cost sensors can be an effective tool in the assessment of exposure to air pollutants. Following a year of experimentation using two LCS stations, a calibration methodology was developed.Ten low-cost micro-sensor stations called MoNiCa were fixed to monitor PM and NO2 in Turin. Throughout the campaign, trends in the concentrations of the pollutants were consistent with the meteo-climatic, traffic and positioning characteristics. Based on this research, LCS proved to be complementary to canonical instrumentation.
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A Source Specific Calibration of Low-Cost Air Quality Sensors Using Machine Learning and Emission Inventories: A Case Study in Fianarantsoa, Madagascar University Gustave Eiffel, France This study develops a machine learning calibration model for a network of low-cost air quality sensors using emission inventory data for source specific corrections. The approach leverages cross-validation among nearby and co-located sensors, enhancing model robustness. A Data Reliability Indicator assesses performance across income group countries, improving reliability and spatial transferability compared to conventional approaches, which lack fine-scale and source specific insights.
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Evaluating the performance of AE51 and MA200 micro-aethalometers during bicycle-mounted field deployment in city streets 1Institute for Atmospheric Sciences and Climate, National Research Council of Italy, CNR-ISAC, Italy; 2EPIGET Lab, Department of Clinical Science and Community Health, Dipartimento di Eccellenza 2023-2027, Università degli Studi di Milano; 3Dipartimento di Ingegneria 'Enzo Ferrari', University of Modena and Reggio Emilia,; 4UOC Qualità dell’Aria, Agenzia Regionale Protezione Ambiente (ARPA) Lombardia Filter-based absorption photometers, particularly aethalometers, are used to measure equivalent black carbon (eBC) concentrations. Portable models like the microAeth® AE51 and MA200 enable high-resolution monitoring for personal exposure and BC mapping. As part of the RI-URBANS project, 13 devices were mounted on courier bicycles in Milan to assess BC spatial variability. The AE51 proved more robust than the MA200, which experienced software crashes due to vibrations. Both devices correlated well with the reference AE33, though MA200 required longer stabilization periods. Noise issues at 1-second resolution required post-processing. Findings help refine mobile BC monitoring methods and assess urban pollution mapping.
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Evaluating the performance of the low-cost black carbon sensor bcMeter at an urban background site 1Department of Earth and Environmental Sciences, Università degli Studi di Milano-Bicocca, 20126, Milan, Italy; 2Landesamt für Natur, Umwelt und Verbraucherschutz NRW (LANUV), Essen, Germany; 3Institut für Umwelt & Energie, Technik & Analytik (IUTA) e.V., Duisburg, Germany Black carbon (BC) is emitted in the atmosphere by incomplete combustion processes and impacts both human health and climate. Traditional BC monitoring methods are expensive, limiting spatial and temporal coverage. The bcMeter is a recently developed low-cost (<300€) BC monitoring device that can facilitate the spatial coverage of BC measurements.The performance of two bcMeter was evaluated at an urban background site in Mülheim-Styrum (Germany) against reference data from an AE33 aethalometer. The bcMeter provided results comparable with a reference aethalometer in daily averages, proving a promising option for future application in monitoring networks, where daily data resolution is sufficient.
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Machine Learning-Driven PM2.5 Mapping and Hotspot Analysis Using a Large-Scale Low-Cost Sensor Network in Bihar, India Indian Institute of Technology Kanpur, India This study develops a novel hybrid approach integrating satellite data and a large-scale low-cost sensor network using machine learning to generate high-resolution PM2.5 maps at a 200m scale over Bihar, India. A dataset from 511 sensors (May 2023–April 2024) was preprocessed, calibrated, and supplemented with ERA5 data. A GNN-based model outperformed previous models, achieving RMSE of 12.35 μg/m³ and Pearson’s r of 0.9. The analysis identified northern Bihar as more polluted due to population clusters and land use. Findings highlight intra-state pollution sources and seasonal variations, aiding policymakers in developing targeted air quality management strategies.
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Miniaturized and Cost-Effective Electrochemical Sensors for Environmental Monitoring Using Additive Manufacturing Dayalbagh Educational Institute, India This study presents an approach towards the development of customized electrochemical sensors using conductive PLA composite via fused filament fabrication (FFF) for electrochemical application. A PLA-based composite reinforced with graphene nanoplatelets (GNP), multi-walled carbon nanotubes (MWCNT), and lithium titanate oxide (LTO) was fabricated and characterized. Electrical conductivity increased by 12,065%, tensile strength by 64.3%, and compressive strength by 103.7% compared to pure PLA. Thermogravimetric analysis showed improved thermal stability (361.54°C). These findings validate the potential of 3D-printed electrochemical sensors as a low-cost, efficient, and scalable alternative for detecting heavy metals and air pollutants in environmental applications.
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Air mass trajectory-based monitoring network for off-line atmospheric aerosol sampling Czech Hydrometeorological Institute, Czech Republic The TRAMONE (Trajectory-based Monitoring Network) research project is being presented. Its aim is to develop a low-cost, intelligent, autonomous system for atmospheric aerosol sampling on filters, utilizing mobile data network control. The system enables sample collection based on near-real-time air mass trajectory calculations. The software controls the samplers based on whether the trajectory corresponds to a predefined path, serving as an alternative to expensive continuous sampling and subsequent filter analysis. The hardware and software will be freely available for public use.
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Air quality PM sensors performances compared to conventional measurement techniques Consiglio Nazionale delle Ricerche - Istituto sull'Inquinamento Atmosferico (CNR-IIA), Italy In the framework of the DivAirCity Project, aimed at improving Air Quality in Cities through Social Inclusion and Nature Based Solutions, an integrated approach to monitoring, in which conventional instruments and both home-built and commercially available sensors, was undertaken.Both Airly sensors and PM conventional measurements by gravimetry were employed. The optical sensors measure PM by light scattering, and physical properties of the particles, which vary with location and season, may influence the accuracy of the results. Anyway the agreement between data obtained by gravimetry and sensor values was quite good (R2=0.89), and the trends recorded are in general comparable.
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Feasibility study of a low-cost miniaturised Bio-OPC for biologically relevant fluorescent particle detection Wolfson Centre for Biodetection Instrumentation Research (WCBIR), University of Hertfordshire, Hatfield, Hertfordshire, AL10 9AB, United Kingdom Real-time and in situ monitoring of bioaerosols using laser-induced fluorescence is promising, but the specialised instruments designed for this purpose are often large, heavy (typically 20–40 kg), and costly. We introduce a newly designed, low-cost miniaturized Bio-OPC and evaluate its feasibility for detecting various bio-fluorophores in the laboratory. We demonstrate its ability to detect bacteria and pollen in different environments. Compounds such as β-NADH (Nicotinamide adenine dinucleotide) at varying concentrations were used as fluorescent materials, and monodispersed aerosols were generated in the lab to test the sensitivity of the instrument.
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Occupational exposure assessment using miniaturized aerosol instruments in different workplace environments 1Fine Particle and Aerosol Technology Laboratory, Department of Environmental and Biological Sciences, University of Eastern Finland, Finland; 2Indoor Environment and Occupational Hygiene Group, Department of Environmental and Biological Sciences, University of Eastern Finland; 3Department of Chemistry, University of Eastern Finland Occupational diesel exhaust exposure levels are not well quantified in many working sectors and new information is also needed on the use of new miniaturized measurement instruments such as micro-aethalometers and ultrafine particle counters for the assessment of occupational exposure. In this study, occupational exposure of bus drivers, mechanics, construction workers and inspection station workers were measured with these instruments. High momentary diesel exhaust concentrations were detected. The correlation between lung deposited surface area and equivalent black carbon indicates that black carbon plays an important role in exposure to fine particles in the studied workplaces.
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Selective detection of NO2 at ppb concentration with small Cu3N-based sensor ETH Zuerich, Switzerland Air quality deterioration is a growing concern due to urbanization, industrial emissions, and transportation. NO2, a harmful pollutant, poses health risks, prompting strict exposure limits. Effective NO2 sensors must be highly sensitive, selective to confounders analytes, and energy-efficient. While chemoresistive metal oxides offer sensitivity and fast response, they lack selectivity and require high temperatures. Metal nitrides, like Cu₃N, show promise due to excellent catalytic properties. A novel method using aerosol deposition and dry nitridation yields highly porous Cu₃N sensors, achieving excellent NO2 detection at low temperatures (few ppb) enabling cost-effective, miniaturized air quality monitoring networks.
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Using low-cost sensors for assessing human exposure and dose 1School of Chemical and Environmental Engineering, Technical University of Crete, Greece; 2Environmental Informatics Research Group, School of Mechanical Engineering, Aristotle University of Thessaloniki, Greece; 3Center of Interdisciplinary Research and Innovation, Aristotle University of Thessaloniki, Greece; 4Laboratory of Atmospheric Physics, Department of Physics, Aristotle University of Thessaloniki, Greece The current study investigates the applicability of low-cost PM sensors for their future use as a reliable instrument for outdoor particulate matter (PM2.5, PM10) measurements. The evaluation of the accuracy and reliability of the sensors was carried out through linear regressions applied between the particulate matter concentrations (PM10, PM2.5) measured by a reference instrument and the concentrations measured by the low-cost sensors. Subsequently, the deposited dose was estimated for each region of the human respiratory tract (HRT) using the corrected PMx concentrations (sensors).
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Comparison of online (Xact) and offline (ICP-MS) measurements for trace elements in particulate matter across the EU 1University of Nova Gorica, Nova Gorica, 5000 Slovenia; 2Institute of Environmental Assessment and Water Research , Barcelona, 08034, Spain; 3Paul Scherrer Institut, Villigen, 5232, Switzerland; 4Federal Hydrometeorological institute of BiH, Sarajevo,71000, Bosnia and Herzegovina; 5Institute for Environmental Geosciences, Grenoble, France; 6Institute for Medicinal Research and Occupational Health, Zagreb, Croatia Trace elements in particulate matter (PM) are crucial for source apportionment due to their health impacts. Their measurement can be done using online (e.g., Xact 625i XRF) or offline (ICP-MS, ICP-OES, XRD) methods. This study compares online XRF and offline ICP-MS/ICP-OES data from four European sites: Deskle (SLO), Sarajevo (BiH), Barcelona (ES), and Nova Gorica (SLO), with differing PM sizes, digestion methods, and sampling periods. Results show strong correlations for S (r² > 0.90) and Cu (r² > 0.80). Correlations for Pb, Zn, and K vary by site and season, influenced by sources, matrix effects, and special events.
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Aerosol monitoring using different measurement platforms – bicycle, tram, tethered balloon, drone, low-cost sensors University of Stuttgart, Germany This study explores the effectiveness of various measurement platforms—bicycles, trams, tethered balloons, drones, and low-cost sensors—in monitoring aerosol concentrations and meteorological parameters. Mobile platforms, such as bicycles and trams, collect high-resolution data along urban transit routes, identifying pollution hotspots. Aerial platforms, including tethered balloons and drones, extend monitoring to vertical profiles, assessing pollutant dispersion. The use of low-cost, real-time sensors has further enhanced air quality studies by enabling widespread and continuous data collection. The talk will compare these platforms, discussing their advantages, limitations, and contributions to air quality investigations.
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Characterization of Photoacoustic Sensors for the Measurement of Soot at Different EC/OC contents and Black Carbon in Comparison to an Aethalometer 1Institute of Electrical Measurement and Sensor Systems, Graz University of Technology, Graz, 8010, Austria; 2Laboratory of Applied Thermodynamics, Aristotle University, Thessaloniki, 54124, Greece; 3AVL List GmbH, Graz, 8010, Austria In this work we present results from a laboratory characterization exercise of three PAS instruments and an aethalometer, for the measurement on black carbon and brown carbon with known EC/OC content. We evaluated the time response and the linearity for different particle size distributions and mass concentrations.
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INITIAL MEASUREMENTS OF ATMOSPHERIC AEROSOL SIZE DISTRIBUTIONS FOR TRAINING A MACHINE LEARNING MODEL TO PREDICT AEROSOL LIQUID WATER AND CLOUD CONDENSATION NUCLEI 1Appalachian State University, United States of America; 2Georgia Institute of Technology, United States of America In the first step of an integrated study of aerosol liquid water content and cloud condensation nuclei spectra, a field campaign collected size distributions and hemispheric backscattering fraction data, among others. This presented us with the unique oppertunity to see how well correlated particle size is to light scattering with practical data instead of simulated. We found these values to be correlated at all 3 wavelengths studied.
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Large-scale Saharan dust episode in March-April 2024: study of desert aerosol loads over Potenza, southern Italy, using remote sensing and in-situ measurements CNR-IMAA, Italy Saharan dust storms can travel thousands of kilometers, impacting air quality, human health, and economies. The CIAO observatory in Potenza, Italy, frequently experiences these intrusions, especially in spring and summer. Between 30 March and 1 April 2024, an extreme Saharan dust event affected the Mediterranean and Europe. At the conference, we will present lidar and in-situ aerosol observations from this episode, highlighting their complementarity. Lidar data reveal dust layer dynamics, while particle size distribution measurements confirm increased fine and coarse particle concentrations, peaking on 31 March when dust was confined to lower altitudes.
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Ultra-high resolution identification methods of organosulfates in atmospheric nanoparticles from the CERN CLOUD chamber experiments 1Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, 60438 Frankfurt/Main, Germany; 2Center for Atmospheric Particle Studies, Carnegie Mellon University, Pittsburgh, PA 15213, USA Organosulfates (OSs) are important compounds in atmospheric aerosols, but their formation and impact on climate and air pollution remain uncertain. This study analyzes offline particle samples from the CLOUD chamber, comparing results with semi-online particle analysis to improve understanding of OS formation pathways and properties.Using high-resolution mass spectrometry, compounds could be accurately assigned. By comparing different methods and chemical compositions, the study aims to enhance the identification of OSs and understand discrepancies caused by factors like aging and sample handling, offering insights into the formation and distribution of OSs in atmospheric aerosols.
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A selective electrochemical sensor for determination of H2O2 in atmospheric samples 1Department of Physical Chemistry, School of Industrial and Aerospace Engineering, Institute of Nanoscience, Nanotechnology and Molecular Materials (Inamol), Universidad de Castilla-La Mancha (UCLM), Toledo, 45071, Spain.; 2Department of Inorganic, Organic and Biochemical Chemistry, Faculty of Environmental Sciences and Biochemistry, Inamol, UCLM, Toledo, 45071, Spain; 3Department of Physical Chemistry, Higher Technical School of Industrial Engineering, Inamol, UCLM, Albacete, 02071, Spain Peroxides play a crucial role in atmospheric chemistry contributing to the mass of secondary organic aerosols (SOA), with important health implications. The fluorescent DCF-HRP method, while useful, lacks selectivity for H2O2. This study presents a selective electrochemical sensor for determining H2O2 in atmospheric samples. Screen-printed carbon electrodes were modified with an conducting polymer and platinum nanoparticles, enabling direct H2O2 measurement via flow injection analysis with chronoamperometric detection. After optimizing instrumental and chemical parameters, the sensor demonstrated selectivity for H2O2 over other commercial peroxides. Finally, it was successfully applied to the analysis of laboratory-generated SOA, comparing favorably with the DCF-HRP method.
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Comparative Study of Aerosol Optical/Chemical Characteristics by ChAMBRe and field Campaigns. 1Department of Physics, University of Genova, Italy; 2INFN, Genova Division Fine particulate matter (PM2.5) and carbonaceous aerosols significantly affect atmospheric radiative balance and air quality due to their optical characteristics. In this study, we present a detailed look at how aerosols affect light and how they absorb light across different regions. Our research specifically investigates combustion aerosols from various urban and industrial sources, studying their absorption characteristics and impact by both in-situ and filter-based measurement methods. Such efforts allow us to study the impact of geographic and climatic factors on aerosol absorption and scattering characteristics, improving climate models and air quality assessment.
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Comparison of different bioaerosol sampling techniques for qualitative analysis of poultry house microbiota using next generation sequencing (NGS) 1Central Institute for Labour Protection – National Research Institute, Poland; 2University of Alcalá, Spain The bacterial and fungal aerosols were sampled at workplace in poultry house using six bioaerosol instruments: six-stage Andersen and single-stage MAS impactors, Coriolis µ and BioSampler impingers, open-face filter cassette, and COUNTERFOG® BIAFTS sampler. The collected microbiota were quantitatively and qualitatively assessed using NGS. Alpha diversity metrics revealed that the highest richness and evenness of bacterial biota was observed in samples collected with Coriolis µ impinger, whereas fungal biota in samples collected with both MAS impactor and Coriolis µ impinger. Beta diversity showed that bioaerosol samples from Coriolis µ impinger were significantly different from those isolated with other tested samplers.
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Ensuring the worldwide equivalence of measurements of nanoparticle number concentration and charge concentration: an international comparison 1National Physical Laboratory (NPL), United Kingdom; 2Physikalisch-Technische Bundesanstalt (PTB), Germany; 3Korea Research Institute of Standards and Science (KRISS), Republic of Korea; 4Federal Institute of Metrology METAS, Switzerland; 5National Institute of Metrology, China; 6National Metrology Centre, A*STAR, Singapore; 7National Metrology Institute of Japan (NMIJ), National Institute of Advanced Industrial Science and Technology (AIST), Japan; 8NRC Canada; 9German Environment Agency (Umweltbundesamt), Germany; 10Leibniz-Institute for Tropospheric Research (TROPOS), Germany A crucial activity to support the Mutual Recognition Arrangement of the International Committee for Weights and Measures is the delivery of formal comparison exercises between National Metrology Institutes and, where appropriate, Designated Institutes and other reference laboratories. Ten laboratories have participated in an experimental campaign for the CCQM-K185/P237 comparison, which measures the particle number and charge concentration of 30 nm and 50 nm monodisperse soot, and 80 nm and polydisperse soot nanoparticles. We present the results from earlier aerosol metrology comparisons, set out the scope and experimental campaign for the CCQM-K185/P237 comparison and highlight some provisional findings from this exercise.
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High-resolution mapping of urban ultrafine particle (UFP) and CO2 fluxes Technical University of Braunschweig, Germany, Institute of Geoecology, Climatology and Environmental Meteorology Cities are major CO₂ and particulate sources. The eddy covariance (EC) method, which relies on tower-based measurements, quantifies emissions on a larger scale but misses fine-scale processes like identifying single emission hotspots. To address this, EC is combined with mobile measurements using the aerodynamical resistance approach to calculate high-resolution fluxes. This approach, applied to CO₂ fluxes, is being expanded to study local particle fluxes in Berlin. Long-term EC measurements and mobile campaigns, using bicycles and cars, identified emission hotspots. These measurements show strong correlations between emissions, traffic, and turbulence, providing valuable data for dispersion models, though methodological deviations are expected.
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Field intercomparison of absorption measurements at the suburban Demokritos station in Athens 1Institute of Nuclear and Radiological Sciences & Technology, N.C.S.R. Demokritos, 15341 Athens, Greece; 2Center for Atmospheric Research, University of Nova Gorica, Nova Gorica, 5270, Slovenia; 3Haze Instruments d.o.o., Ljubljana, 1000, Slovenia; 4Department of Chemistry and Biology, Federal Institute of Metrology METAS, 3003 Bern, Switzerland; 5Atmospheric Microphysics Department, Leibniz Institute for Tropospheric Research, Leipzig, 04318, Germany; 6PSI Center for Energy and Environmental Sciences, Paul Scherrer Institute, 5232 Villigen, Switzerland; 7Physikalisch-Technische Bundesanstalt, Bundesallee 100, 38116 Braunschweig, Germany Several methods for in-situ aerosol absorption measurement exist, including optical light attenuation, photothermal interferometry, photo-acoustic spectroscopy, and extinction-minus-scattering. The STANBC project aims to establish a measurement framework for both the aerosol light absorption coefficient and its conversion to eBC mass concentration, ensuring measurement traceability, consistency, and comparability across different air quality monitoring networks in Europe. This work focuses on the comparison of different techniques for measuring light absorption and black carbon in the field. The campaign took at the at the National Center for Scientific Research “Demokritos” (DEM) monitoring station in Athens, Greece, from 25/09/2023 to 11/10/2023.
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Emissions of cooking stoves and indoor air pollution levels 1University of Eastern Finland, Finland; 2Tribhuvan University, Nepal; 3Kathmandu University, Nepal The study measured emissions and indoor air pollution from traditional and improved Nepalese cooking stoves and from modern camp stoves. The results showed that camp stoves had the lowest fuel consumption and highest efficiency, whereas mud stove and metallic ICS had the highest fuel consumption and lowest efficiency. Emission levels were generally high and indoor air pollution increased significantly during combustion. The metallic ICS showed poor combustion, leading to high emissions. Additionally, the pot itself was found to increase fine particle emissions. These findings highlight the need to improve ICS technology to reduce household air pollution.
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Mass concentration intercomparison of soot generated with Mini-Cast 1ASNR, France; 2ESTACA, France In the context of studies regarding airborne dispersion of soot particles emitted during fire scenarios and characterization of soot emitted by diesel engines, it is important to have a robust measurement of the mass. This study consists of an intercomparison of the mass concentration measurement of soot generated by the Mini-Cast with ex-situ analyses and with real-time measurements using various types of instruments based on different principles. The gravimetric measurement is used as the reference for the mass concentration. In this article, only the results of the MA300 are presented. The whole results will be discussed during the presentation.
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Real-time quantification of refractory brown-carbon “tarballs” using SP2 Metrology Research Centre, National Research Council Canada, Canada Using a custom tarball-generation setup, we measured particle absorption cross-sections at 400 to 900 nm to report mass absorption coefficients (MACs) as a function of tarball annealing temperatures, up to 550 °C. Corresponding SP2 signals are investigated using detailed modelling approaches (Michelsen et al., 2015). Additional experiments using pulsed 1064 nm radiation will also be discussed. Based on this detailed work, we propose simplified setups for quantifying TB concentrations in real-time during field experiments.
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QUANTIFICATION OF PURE LEVOGLUCOSAN AND PHOTOOXIDIZED LEVOGLUCOSAN AEROSOL BY AEROSOL MASS SPECTROMETRY University of Eastern Finland, Finland Levoglucosan is one of the most used molecular markers for biomass burning. The research will investigate the response of aerosol mass spectrometer (AMS) to the pure levoglucosan aerosol particles subject to aging and mixing with other inorganic/organic particles. The combined CE*RIE (where RIE and CE stand for relative ionization efficiency and collection efficiency) for levoglucosan was found to be 1.11. Two marker fragments C2H4O2 (m/z60) and C3H5O2 (m/z73) and two other potential markers C6H4O3(m/z124) and C6H6O3 (m/z126) will be used to quantify levoglucosan in the mixtures with inorganic/organic aerosols and in the photoaging experiments.
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High-Resolution Air Quality Surveillance and Emission Source Tracking with Scanning LiDAR 1Advanced Institute of Convergence Technology (AICT), Korea, Republic of (South Korea); 2Sungkyunkwan University Environmental Forensic Lab.; 3Climate & Environment Division Scientific Environment Surveillance Team, Gyeonggi Provincial Government; 4Samwoo TCS Co., Ltd This study analyzes PM₂.₅ pollution in the Sihwa Industrial Complex using scanning LiDAR. Results reveal seasonal and diurnal variations, with peaks during commuting and lunch hours. Major sources include waste treatment and manufacturing plants. The findings confirm LiDAR's effectiveness in air quality monitoring and emission source identification.
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Long-time-series of high-time resolution carbonaceous aerosol measurements with different in-situ measurement techniques vs. offline analysis at two background monitoring sites in Germany. 1Air Quality Network, German Environment Agency, Dessau, 06844, Germany; 2Air Quality Network, German Environment Agency, Zugspitze, 82475, Germany The German Environment Agency has monitored BC, Elemental Carbon (EC), and Organic Carbon (OC) since 2010 at five background stations with high temporal resolution. A comparison of online (Aethalometer AE33 and MAAP) and offline (thermography with optical correction (transmission)) measurements of two monitoring sites over two years shows a strong correlation, with AE33 slightly overestimating BC. Seasonal trends indicate higher BC levels in autumn and winter. The study also examines correlations with meteorological and chemical parameters and evaluates source attribution methods.
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Understanding the Generation and Removal of Primary Particulate Matter: Insights from Diesel, Oil, and Metal Emissions Inha University, Korea, Republic of (South Korea) The removal of condensable particulate matter (CPM) remains a major challenge due to its complex formation and diverse properties. This study generated and characterized primary particulate matter (PM) from diesel combustion, oil mist, and metal fume, and evaluated their removal by electrostatic precipitators (EP) and fabric filters (FF). FF showed superior removal of sub-100 nm particles compared to EP due to diffusion capture but suffered efficiency loss over time with oil mist. These findings highlight the need for standardized testing protocols and emphasize the importance of particle size distribution in evaluating PM control technologies.
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Aerosol Particle Classification using Single-Particle Mass Spectrometry and Deep Learning for the Detection of Ship Emissions 1Institute for Applied Physics and Measurement Technology, University of the Bundeswehr Munich; 2Institute of Chemistry and Environmental Engineering, University of the Bundeswehr Munich; 3Institute of Chemistry, Division of Analytical and Technical Chemistry, University of Rostock; 4Joint Mass Spectrometry Center (JMSC), Helmholtz Zentrum München The Sulfur Emission Control Areas was established to reduce sulfur emissions from ships. Gas-phase measurement instruments have a limited detection range (few hundred meters). In contrast, particle-phase systems, like single-particle mass spectrometry (SPMS), can extend this range to several kilometers by analyzing aerosol particles that retain source-specific chemical markers. This study utilized SPMS to analyze aerosol particles, achieving over 92% accuracy in classifying 13 particle classes using a convolutional neural network. Notably, particles rich in vanadium, nickel, and iron ions indicate the use of high-sulfur fuels, and combined with wind data and Automatic Identification System information, allow for real-time monitoring.
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Revised IMPROVE-A OC/EC Protocol Permits Gas/Diesel Analyses 1Clarkson University, United States of America; 2University of Rochester; 3University of California-Davis After a change in instrumentation to implement the IMPROVE-A protocol in the thermal-optical analysis of the carbonaceous components of PM2.5, a significant change in several of the OC-EC fractions (OC4, OP, and EC2). These changes produced significant problems in the source apportionment of gasoline and diesel vehicles and aged secondary organic aerosol. After extensive discussions, the operators of the Chemical Speciation Network, the University of California-Davis, made a change in the OC4 step by extending the time to a fixed 580 s. This modification has resulted in OC-EC fraction data that permit source apportionments similar to those using earlier data.
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Online Oxidative Potential Measurements of Soluble and Insoluble Particulate Matter 1Department of Environmental Sciences, University of Basel, 4056 Basel, Switzerland; 2MRC Centre of Environment and Health, Environmental Research Group, Imperial College London, London W12 0BZ, United Kingdom Epidemiological studies show strong correlation between exposure to ambient particulate matter (PM) and adverse human health effects. The oxidative potential (OP) of PM, has been implicated in PM-induced toxicity, however conventional methods for measuring aerosol OP are labor-intensive and may underestimate OP values due to the short lifetimes of certain species. To address these challenges, our research focuses on advancing online instrumentation for real-time quantification of aerosol OP. Our recent work has further expanded to investigate the OP of both soluble and insoluble PM fractions to be able to develop a measurement device that more accurately reflects real-world conditions.
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Motor vehicle exhaust ultrafine particle number (PN) concentration monitor and calibration technology 1Anhui Institute of Optics and Fine Mechanics, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei, 230031, China; 2Environmental Research Institute of Hefei Comprehensive Science Centre, Building E, Phase IV, Electric Park, Shushan Economic and Technological Development Zone, Hefei, China; 3National Institute of Metrology, Beijing, 100029, China; 4Particle Laboratory, Department of Mechanical and Nuclear Engineering, Virginia Commonwealth University, Richmond, VA, 23284, USA In response to the demand for high-temperature and high-concentration ultrafine particulate matter (UFPM) emissions from motor vehicles, this study independently developed an ultrafine particulate number (PN) monitor for motor vehicle exhausts, which is based on the scheme of ‘unipolar diffusion charging - flat plate electrostatic grading - differential microcurrent detection’ . Meanwhile, we have developed a set of calibration equipment for the PN monitor to meet the calibration requirements of the PN monitor.
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Initial results from the first long term integrated study of aerosol liquid water content and cloud condensation nuclei in the southeastern U.S. 1Appalachian State University, United States of America; 2Georgia Tech University, United States of America Two field campaigns were conducted at the NOAA Federated Aerosol Network site at Appalachian State University to develop, train, and evaluate the Random Forest Machine Learning model to predict cloud condensation nuclei spectra and aerosol liquid water content, using only dried and humidified aerosol scattering and backscattering measured by nephelometers. We will next apply the trained ML model retrospectively to the long-term aerosol optical property datasets at APP to examine how and why aerosol hygroscopicity, ALWC, and CCN spectra are changing. The activities represent the first integrated multi-season study of CCN and aerosol hygroscopicity in the SE U.S.
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Electric system’s insulators: a two-year Italian study on saline pollution 1University of Milan, Department of Chemistry, 20133 Milano, Italy; 2RSE S.p.A., Power Generation Technologies and Materials Department, 29122 Piacenza, Italy; 3RSE S.p.A., Sustainable Development and Energy Sources Department, 20134 Milano, Italy In times of energetic transition, the resilience of the electrical system is fundamental. To give support in smartly managing the system servicing, insulators saline pollution phenomenon was studied by mean of a two-year experiment during which insulator chains were exposed outdoor. Unlike the current literature, a complete chemical approach, including Ion Chromatography and Thermal Optical analysis in Transmittance mode, was carried out. Seasonal trends could be linked to the role of the weathering and to thermodynamic evolutions of the deposits. This study represents a novelty for Italy and poses the fundamentals to manage the risk through modelling and alerting systems.
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Assessing the impact of urban greenspaces on PM2.5 spatiotemporal variability in Riga, Latvia, via citizen science and low-cost sensors 1National Observatory of Athens, Greece; 2Riga Planning Region, Latvia; 3International Institute for Applied Systems Analysis (IIASA), Austria Within the Horizon Europe Urban ReLeaf project, a novel PM2.5 monitoring network with low-cost sensors was established in Riga, Latvia, where fine aerosol characteristics remain uncharted. Field-calibrated and validated Purple Air PA-II monitors were deployed at 20 sites (urban green, urban background, traffic). All sites have operated concurrently since September 2024, and by the time of EAC 2025, a full year of measurements will be collected. PM2.5 data are analysed for high-resolution spatiotemporal variations, with emphasis on the role of greenspaces. Contrasts among sites placed in the border zone of greenspaces and those located deeper in their core were observed.
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Improved Aerosol Eddy Covariance Fluxes using the ELPI+ (Electrical Low-Pressure Impactor): Preliminary Road Traffic and Sea-Spray Emission Fluxes 1Department of Environmetnal Science, Stockholm University, Sweden; 2Physical Oceanography Department, Institute of Oceanology, Polish Academy of Sciences, Poland; 3Department of Earth Sciences, Uppsala University, Uppsala, Sweden The Eddy Covariance (EC) method was used for an Electronic Low-Pressure Impactor (ELPI+), Dekati Ltd, to measure vertical fluxes of aerosols. We correct the EC-fluxes for discrete-counting, sampling-line particle and signal losses, limited time-response, density fluctuations, deliquescence errors. With a response time t~ 0.1s for most of the ELPI+ it is faster than most OPCs and CPCs , with smaller errors. With the ELPI+and EC method, for the first time we can study size resolved turbulent aerosol fluxes in the complete size range. This includes the emission from road vehicle traffic in the range where we expect engine-exhaust to dominate.
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Scattering of light with orbital angular momentum from singly trapped spherical particles U.S. Naval Research Laboratory, United States of America We present experimental results confirming the predicted scattering of light with orbital angular momentum (OAM) from single spherical dielectric particles with diameters ranging from 5 µm to 20 µm.
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Synergies between ACTRIS and ICOS: combination of aerosol and GHS's first campaign measurements for the characterization of atmospheric composition at CIAO observatory in Tito, Potenza, Southern Italy 1National Research Council – Institute of Methodologies for Environmental Analysis (CNR-IMAA), Contrada S. Loja, I-85050, Tito Scalo, Potenza, Italy ; 2Università degli Studi della Basilicata—Dipartimento di Ingegneria, Via dell’Ateneo Lucano, 10, I-85100, Potenza, Italy The first measurement campaign at CIAO observatory combines aerosol profiling, chemical composition, and greenhouse gas (GHG) concentrations through the ACTRIS and ICOS research infrastructures. This collaboration aims to enhance the understanding of atmospheric phenomena such as dust intrusions, volcanic eruptions, wildfires, and fossil fuel emissions on both global and local scales. ACTRIS focuses on aerosols and trace gases, while ICOS monitors the carbon cycle and GHGs. By integrating these data, the campaign provides real-time analysis of interactions between aerosols and GHGs, supporting climate monitoring and policy development.
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Two Motion-Correction Approaches for Turbulent Particle Flux Measurements from a Moving Vessel in the Arctic 1Environmental Chemistry and Air Research, Technische Universität Berlin, Berlin, Germany; 2Leibniz Institute for Tropospheric Research, Leipzig, Germany To enhance knowledge about turbulent particle fluxes in the Arctic, this study aims to correct a large particle flux data set collected during the PS131 expedition of the research icebreaker Polarstern which was influenced by the vessel’s motion. As the standard approach of realigning the measurement coordinate system with a fixed frame of reference proved to be challenging due to a lack of information on the offsets between the motion and eddy covariance/MCPC measurement systems, a second approach was taken that uses spectral FFT analysis to remove the influence of the movement, promising a more reliable data correction in theory.
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Update of the Walking in Chamber of the Polytechnic University of Catalonia for ad hoc Aerosols studies 1Universitat Politècnica de Catalunya, Spain; 2Universitat Autonoma de Barcelona, Spain The Radon Studies Laboratory (LER) is equipped with a walking in radon and climate chamber of 21 m³ volume. As part of the RADosis project, funded by the Spanish Nuclear Safety Council, the INTE-UPC radon chamber has been recently upgraded to also generate, measure and control: i) the concentration of airborne particles (between few hundreds up to tens of thousands of pt/cm3); ii) the particles size distribution (between tens to hundreds of nm). These values can be controlled for any desired duration, with temporal variations generally below 10%. The installed instrumentation and the developed methodology will be presented here.
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From Reference Materials to Real Filters: Mapping Water Content in PM Using KF Titration 1Institute of Environmental Engineering Polish Academy of Sciences, M. Skłodowskiej-Curie 34 Str., 41-819, Zabrze, Poland; 2Silesian University of Technology, Akademicka 2a Str., 44-100, Gliwice, Poland Understanding water content in atmospheric particulate matter (PM) is crucial for accurate mass quantification and interpreting aerosol hygroscopicity and health impacts. This study uses programmed temperature-step Karl Fischer (KF) titration to examine water desorption profiles of various PM-relevant reference materials, including salts, metal oxides, carbonaceous compounds, and organics. Samples were heated stepwise (50°C–250°C) to distinguish adsorbed, bound, and constitutional water. Desorption patterns were compared with ambient PM filters and artificial PM mixture to assess matrix effects. Results show some materials, especially hydrates and porous carbon, retain water at high temperatures, highlighting potential biases in PM analysis and aiding protocol refinement.
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Integrated study of δ¹³C-CH₄ and δ¹³C-CO2 signatures and aerosol properties as tracers of Wildfire Events: Insights from the ACTRIS-ICOS CIAO Observatory 1CNR-IMAA, Italy; 2Università degli Studi della Basilicata (Italy) The isotopic footprint of carbon-13 (¹³C) provides a valuable tool for monitoring wildfires and understanding their environmental impacts. This study aims to analyse the variability of the isotopic signatures to identify different sources of CO₂ and CH₄. We will investigate the potential influence of wildfire events on the isotopic composition of these gases and on aerosol properties through an integrated approach, by combining the GHGs (greenhouse gases) measurements with aerosol characterization.
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Global calibration as a possible alternative to conventional collocation calibration strategy for air quality low-cost sensor networks: Review and experience from long-term deployments 1Vidis Centre, Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Belgrade, 11351, Serbia; 2ENEA CR-Portici, Energy Technologies and Renewable Sources Department, Portici, 80055, Italy; 3Federal Institute of Metrology METAS, Switzerland; 4Faculty of Civil Engineering, University of Belgrade, Serbia; 5VTT MIKES, Tekniikantie 1, 02150 Espoo, Finland Low-cost air quality (AQ) sensor networks recently introduced a promising paradigm shift. This shift can, due to its cost effectiveness, increase spatial resolution of AQ monitoring. One possible solution for reducing the cost of calibration is to derive global calibration models (GCMs). In this work we first summarize the performance of several GCMs developed recently, by several research groups that examine GCMs when applied to different types of sensors used in air quality monitoring. Secondly, we compare GCMs for two long-term deployments of sensor networks, our research group has developed using data from Air-Heritage project, and UNICEF pilot school initiative.
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Challenges in interpreting black carbon data from national air quality monitoring in the UK 1Air Quality and Aerosol Metrology Group, National Physical Laboratory, United Kingdom; 2Environment Research Group, Imperial College London, United Kingdom; 3Finnish Meteorological Institute, Finland; 4Department of Environmental Sciences, Jozef Stefan Institute, Slovenia; 5Laboratory Particles and Aerosols, Federal Institute of Metrology METAS, Switzerland; 6Leibniz Institute for Tropospheric Research, Germany; 7Metrology Research Centre, National Research Council Canada, Canada; 8Institute of Aerosol and Sensor Technology, FHNW, Switzerland; 9Institute of Nuclear Technology and Radiation, NCSR Demokritos, Greece; 10Physikalisch-Technische Bundesanstalt, Germany Various air quality monitoring networks assess black carbon (BC) levels as part of their national policies and provide evidence for effectiveness of the mitigation strategies. However, interpreting BC data encounters several challenges, ranging from instrumentation discrepancies to methodological variations. Examples of such networks are the UK’s Particle Concentration & Numbers (PCN) and Black Carbon (BC) Networks, which has expanded in 2024 from 14 to 26 sites with another seven sites to be installed. We will present an overview of the most recent data from the BC Network data together with highlighting and addressing challenges in their interpretation.
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Fast analysis tool for temporal aerosol particle size and fluorescence response data tested with indoor measurements at EAC 2024 in Tampere Swisens AG, Switzerland The SwisensPoleno Jupiter, an airflow cytometer, enables high-throughput characterization of aerosol particles using multiple measurement techniques. Continuous monitoring generates terabytes of data, stored in a fast-access database for analysis. A server-based backend with a web frontend facilitates feature computation, filtering, and visualization. The analysis tool was tested with EAC 2024 data, showing a correlation between particle concentrations and conference activities. Over 95% of particles (>6.8 μm) exhibited fluorescence. Peaks coincided with breaks, indicating human-related bioaerosols, dust, and microplastics. The toolchain enables efficient temporal analysis of fluorescence and holography features, enhancing aerosol research applications.
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Urban Air Quality Monitoring: Measurement Campaigns and Key Findings 1AVL, Austria; 2Office of the Styrian Provincial Government, Austria The findings from this study underline the importance of continuous UFP monitoring for urban air quality assessments, public health risk evaluations, and evidence-based urban planning. Long-term and high time-resolution measurements are essential to improve our understanding of source contributions, and the role of local meteorological and topographical influences on UFP dispersion. To support these efforts, the utilized AVL UltraFine Particle Monitor, provides a reliable tool for capturing both long-term trends and short-term fluctuations in UFP concentrations. Its capability for high-precision real-time measurements makes it well-suited for regulatory applications and scientific research aimed at developing effective air quality management strategies.
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An open toolkit for particle size distribution analysis 1Centre for Atmospheric Sciences, Indian Institute of Technology Delhi, New Delhi, India.; 2India Meteorological Department, Ministry of Earth Sciences, Government of India.; 3Institute for Atmospheric and Earth System Research/Physics, University of Helsinki, Helsinki, Finland This study introduces a user-friendly Graphical User Interface (GUI) toolkit designed to simplify particle size distribution (PSD) analysis. It enables visualization, multimodal log-normal fitting, and calculation of key parameters like growth rates, condensation sinks, and particle number concentrations. Featuring a cluster-initialized least squares fit algorithm and an automated mode determination method, it is universally applicable without location-specific adjustments. Tested against long-term datasets, the toolkit provides visual feedback for quality assurance and supports data-labeling for machine learning. We are continuously upgrading this & Feedback from EAC25 will help in refine and identify additional features needed by the aerosol research community.
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Optical Properties of Black Carbon Aerosols and Their Climate Implications in Guadalajara, Jalisco Tecnologico de Monterrey, Mexico This study examines the optical characteristics of BC using Aethalometer measurements collected at an urban site in the city center of Guadalajara, Jalisco from June 2024 to January 2025. The dataset includes absorption coefficients at multiple wavelengths (babs_1 to babs_7), absorption Ångström exponent (AAE), and mass absorption cross-sections (MAC370, MAC880), which provide insight into the composition and sources of BC aerosols.
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Annual variations and long-term air quality trends in a low-pollution, northern city 1Aerosol Physics Laboratory, Tampere University, Tampere, 33720, Finland; 2City of Tampere, Urban Environment and Infrastructure, Environmental Protection Unit, 33100, Finland; 3Atmospheric Composition Research, Finnish Meteorological Institute, Helsinki 00101, Finland In this study, a dataset from 2005-2024 has been analysed covering both long-term trends and temporal variations for PM2.5, PM10, particle number concentration (PNC), LDSA, ozone and nitrous oxides (NOx) in Tampere, Finland. This is one of the few studies from Nordic countries with such a long measurement period. In conclusion, the air quality in Tampere has improved over time. Still, although Tampere has low pollution levels, the World Health Organization annual guidelines for PM2.5 and NO2 were exceeded several times in the measurement period.
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Chemical, Physical and Microbial Characteristics of PM10 and PM2.5 in Urban Region of India Department of Chemistry, Dr. Bhimrao Ambedkar University, Agra, India. PM is a portion of air pollution comprising tiny particles and liquid droplets categorized by size and continues to be associated with human disease. In present investigation, particulate matter (PM2.5 and PM10), microbial and metal concentration in the ambient environment of the city of Taj, Agra (India) were assessed. Total metal concentration for PM10 at Khandari and Trans Yamuna was found to be 252.93 µg/m3 and 250.70 µg/m3 respectively. In case of bioaerosol, bacterial concentration was higher as compared to fungi. A total of 4 species, Aspergillus Niger, Aspergillus flavus, Penicillium citrinum, and fumigates were isolated at different sampling sites.
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Developing an emissions inventory for metallic aerosols in London, UK 1MRC Centre for Environment and Health, Environmental Research Group, Imperial College, London, W12 0BZ; 2NIRH Health Protection Research Unit for Environmental Exposures and Health, Imperial College, London, W12 0BZ Metallic aerosols are a toxicologically important constituent of particulate matter air pollution, particularly in urban areas. However, measurements of these components are limited spatially and temporally. Here, high-time resolution PM compositional measurements from two London supersites are used to calculate emission factors (EFs) for 15 health and source apportionment related metals. These EFs are specific to the London traffic fleet and will improve emissions estimates from a key urban source. This study demonstrates the importance of high-time resolution measurements to enable insights into the causes of the broad range in EFs observed.
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Simulation and sampling of human respiratory emission in a laboratory environment 1Fraunhofer-Institut ITMP-IIP; 2Technical University of Munich Our breath aerosol test setup aims to preserve microorganism viability during aerosol analysis, crucial for studying viral respiratory emissions. It uses a bubble-bust nebulizer to gently produce microbial particles, minimizing physical stress and desiccation. The nebulizer includes a stainless-steel sintered filter frit, air and liquid media supply, and a sheath air supply to regulate humidity. For sampling, a growth tube and impinger combination is used. The growth tube operates with a positive temperature gradient, allowing particles to grow through condensation, while the impinger collects larger particles directly into culturable or aqueous media, facilitating fast analysis and reducing microorganism damage.
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Assessing Influenza A Virus Aerostability: Insights from a Novel Bioaerosol Technology University of Bristol, United Kingdom Previous studies assessing the impact of environmental factors such as relative humidity (RH), temperature, and CO2 levels on influenza A virus infectivity have yielded incosistent results. Here, we use the novel Controlled Electrodynamic Levitation and Extraction of Bioaerosols onto a Substrate (CELEBS) device to systematically examine how these factors impact IAV infectivity over time. CELEBS enables precise control over monodisperse virus-laden droplets, allowing high-resolution viral decay measurements. Preliminary findings show that the IAV strain A/X31 (H3N2) remains highly aerostable, whereas A/PR/8/34 (H1N1) is less stable at intermediate RHs, suggesting a potential role for surface proteins in airborne stability.
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Predicting the pulmonary toxicity induced by repeated exposures to a mixture of alumina nanoparticles and HClg using in vitro air-liquid interface exposures 1INERIS, MIV / TEAM, Verneuil-en-Halatte, 60550, France; 2IRBA, D.EBR / U.RTE, Brétigny-sur-Orge, 91223, France; 3IRBA, D.PRT / U.I, Brétigny-sur-Orge, 91223, France; 4IRBA, D.EBR / U.RAD, Brétigny-sur-Orge, 91223, France This study compares in vivo and in vitro approaches to assess the pulmonary toxicity of alumina (Al₂O₃) nanoparticles and hydrogen chloride (HCl) mixtures emitted during solid propellant combustion. Wistar rats were exposed via inhalation, while lung cell co-cultures were exposed at the air-liquid interface (ALI). After four days of exposure, pulmonary inflammation was observed in vivo at lower doses than in vitro. Despite these differences, ALI in vitro methods show promise in predicting the toxicity of repeated exposures and could serve as an alternative to animal models for assessing inhalation toxicity of pollutant mixtures.
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Increased PM Levels Enhance Minimum Leaf Conductance and Modify Transpiration Dynamics Through Stomatal Density Adjustments 1Department of Chemical Engineering, Indian Institute of Technology Delhi, Hauz Khas, Delhi, 110016, New Delhi, India; 2Department of Chemical Engineering, National institute of Technology Sri Nagar, 190006, India; 3Department of Mechanical Engineering, Indian Institute of Technology Delhi, Hauz Khas, Delhi, 110016, New Delhi, India; 4School of Environmental Sciences, Jawaharlal Nehru University, New Delhi 110067, India; 5Sibley School of Mechanical and Aerospace Engineering, Cornell University, Ithaca, NY 14853, USA Aerosols influence plant-water dynamics, yet their direct effects remain unclear. This study examines Pusa Sadabahar tomato plants under controlled conditions, exposed to ambient, filtered, and high PM air. Transpiration rate, stomatal density, and leaf hydration kinetics were analyzed alongside microscopic evaluations of wetness formation and aerosol deposition. Findings reveal a 20% increase in stomatal density, altering minimum leaf conductance (gmin and transpiration rates. This study enhances understanding of aerosol-induced physiological changes, highlighting their role in plant stress responses and potential groundwater depletion in North-West India, emphasizing the need for further research on plant-aerosol interactions.
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Alveolar in vitro model at air-liquid-interface 1University of Eastern Finland, Finland; 2A. I. Virtanen Institute for Molecular Sciences, University of Eastern Finland, Finland This abstract presents a study on an optimised in vitro lung cell model to assess airborne pollutant exposure. We employ a small-volume manual liquid-application exposure system at air-liquid interface to investigate dose-dependent effects of ultrafine particles on a tri-culture model mimicking the alveolar barrier. The study addresses challenges in achieving uniform particle deposition and accurate dosing while maintaining particle properties. Results show a dose-dependent reduction in cellular metabolic activity when UFPs are administered in 100 µL of PBS, allowing a homogeneous distribution. This refined exposure technique aims to improve experimental reproducibility and physiological relevance for exposure studies in inhalation toxicity.
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In vitro dioxin- and PAH-like activities of particulate residential wood burning emissions: influence of appliances, combustion conditions and fuel composition 1Ineris, Parc Technologique Alata, Verneuil-en-Halatte, 60550; 2Aix Marseille Univ, CNRS, LCE, Marseille, France Residential wood heating is the main source of polycyclic aromatic hydrocarbons (PAHs) in ambient air. Factors influencing the formation of such toxic compounds during biomass burning remain poorly documented. This study aims to characterize the aryl hydrocarbon receptor (AhR) mediated activities from different heating appliances under varied combustion conditions and fuel compositions. The biological activity of PM-bound dioxin- and PAH-like compounds was assessed in vitro using the human liver cancer cell line (HepG2). By identifying key factors influencing the toxic emissions of PM, the findings will provide valuable insights into mitigating the emissions of PM-bound AhR-active substances into ambient air.
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Oxidative Potential of PM1, PM2.5, and PM10 in Car and Tram Tunnels: Evaluating Public Health Risks 1AGH University of Krakow, Faculty of Energy and Fuels, Krakow, Poland; 2AGH University of Krakow, Faculty of Physics and Applied Computer Science, Krakow, Poland Oxidative potential (OP) assesses the reactivity and environmental impact of airborne particulate matter (PM), assessing health-related exposures. This study quantifies the OP of PM10, PM2.5, and PM1 from Krakow’s car and tram tunnels using ascorbic acid (AA) and reduced glutathione (GSH) depletion assays. PM10 exhibited the highest OP in the car tunnel (23 μg m−3 OPAA, 21 μg m−3 OPGSH), while PM1 showed the highest in the tram tunnel (28 μg m−3 OPAA, 24 μg m−3 OPGSH). Correlations between OP and metal content were generally weak, except for Rb in tram tunnel PM2.5. Findings highlight PM toxicity and health risks.
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Oxidative potential of urban aerosol and related elements in three simulated lung fluids Czech Academy of Sciences, Czech Republic Particulate matter (PM) bound elements are important components of atmospheric aerosols. Heavy metals are known environmental pollutants due to their toxicity, their ability to accumulate in the human body (Mitra et al. 2022). Heavy metals can exhibit toxicological effects even in trace amounts. Oxidative potential (OP) is defined as the potential of aerosol particles to induce the production of reactive oxygen species (ROS). The oxidative potential is influenced by heavy metals that are present in the environment (Charrier and Anastasio, 2012).
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Association between particle-bound reactive oxygen species and in-vitro oxidative responses induced by traffic-related urban nanoparticles 1Department of Public Health and Infectious Diseases, Sapienza University of Rome, Rome, 00185, Italy; 2Institute of Atmospheric Sciences and Climate, National Research Council of Italy (CNR-ISAC), 00133 Rome, Italy; 3Department of Earth and Environmental Sciences, University of Milano-Bicocca, 26126 Milan, Italy; 4National Biodiversity Future Center (NBFC), 90133 Palermo, Italy; 5Institute of Atmospheric Sciences and Climate, National Research Council of Italy (CNR-ISAC), 40129 Bologna, Italy; 6Department of Environmental Biology, University of Rome Sapienza, 00185 Rome, Italy; 7Regional Environmental Protection Agency (ARPA), 00173 Rome, Italy This study explores the relationship between particle-bound reactive oxygen species (PB-ROS) and oxidative stress responses induced by fine particulate matter, based on the RHAPS experiment in the Po Valley (2019). PB-ROS were analyzed using two approaches: a filter sampler and a particle-into-liquid sampler. Oxidative stress was measured in human bronchial epithelial cells (BEAS-2B). Results indicate that transient ROS, which are fresher and linked to traffic emissions, while long-lived ROS species are found in aged aerosols. A positive correlation between transient ROS and oxidative stress gene expression suggests potential health risks from transient ROS in urban environments.
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Anti-oxidant and anti-inflammatory properties of nanoalgosomes in a co-culture of airway bronchial cells and macrophages at the Air-Liquid Interface 1University of Rostock, Germany; 2National Research Council of Italy, Italy Nanoalgosomes, extracellular vesicles from Tetraselmis chuii, show promise for aerosol-based therapeutics due to their biocompatibility and bioactivity. This study evaluated their effects in a human lung co-culture model exposed to nebulized nanoalgosomes, followed by oxidative stress (TBHP) or inflammation (LPS). Nanoalgosomes maintained cell viability, preserved epithelial barrier integrity, reduced oxidative stress, and suppressed LPS-induced pro-inflammatory cytokine release. These findings confirm their anti-inflammatory and antioxidant properties at the air-liquid interface (ALI), supporting their potential for respiratory therapies.
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Ex-Vivo Respiratory Pharmacokinetics Model for Inhaled Therapies Using Negative Pressure Ventilation and Perfusion: A Proof-of-Concept 1Mines Saint-Etienne, Univ. Jean Monnet, UMR INSERM 1059 SAINBIOSE, 42270 Saint‐Priest-en-Jarez, France; 2University Hospital of Saint-Étienne, CHU Saint-Etienne, 42270 Saint‐Priest-en-Jarez, France; 3Department of Thoracic Surgery and Lung Transplantation, Foch Hospital, Suresnes, France; 4Paris-Saclay University, INRAE, UVSQ, VIM, 78350, Jouy-en-Josas, France Respiratory models are crucial for developing and evaluating aerosol-based medical devices. While in-vivo models, particularly human imaging, are most informative, ethical constraints limit their use. In-vitro models are simpler but lack lung complexity. In-silico models offer simulations but struggle with pathologies and have high computational costs. Ex-vivo models, especially with large animal lungs, offer a balance, preserving lung architecture. This study adapts ex-vivo lung perfusion and negative pressure ventilation prototypes, typically used in transplantation, for pharmacokinetic studies. A successful 6-hour perfusion with a pig lung demonstrates the model's potential for characterizing inhaled therapies.
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Exposure of commuters to black carbon air pollution in urban environment, Croatia 1Ruđer Bošković Institute, Zagreb, Croatia; 2Faculty of Science, University of Zagreb, Zagreb, Croatia Air pollution is a critical public health concern, with particulate matter (PM) characteristics significantly influencing adverse outcomes. While regulatory approaches have traditionally focused on PM mass concentrations, recent research highlights black carbon (BC) and oxidative potential (OP) as more reliable indicators of PM toxicity. This study evaluates personal exposure to BC during daily commutes in Zagreb, Croatia, and the OP of various PM size fractions. Two microAethalometers were used along a 10 km route between fixed monitoring stations, providing comparative data on exposure across transport modes (bicycle and tram) and times of day, providing insights into personal exposure patterns.
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PM10 chemical profiling of vehicles emissions in a Lisbon road tunnel (Portugal) 1C2TN / INSTITUTO SUPERIOR TECNICO, Portugal; 2Consejo Superior de Investigaciones Científicas - Instituto de Diagnóstico Ambiental y Estudios del Agua Road traffic has turned into the primary contributor of particles that impact human health and local environments. Road tunnel studies provide a context for assessing traffic emissions, as they capture exhaust and non-exhaust releases, and resuspended dust with limited external pollution influence. A dataset from the Marquês de Pombal Tunnel was used to estimate vehicular emission factors, to develop detailed chemical and carbonaceous profiles. The study found that PM₁₀ concentrations inside the tunnel were significantly higher than those at the background site, highlighting the dominant influence of freshly emitted exhaust pollutants and road dust resuspension on particulate matter levels.
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Seasonal variability of airborne particles in Lisbon during natural phenomena events and a climatic atypical year C2TN / INSTITUTO SUPERIOR TECNICO, Portugal Sampling campaign was conducted in Lisbon (Entrecampos), Portugal, a strategic area with intermodal connections to public transport, to assess urban air quality. The aim was to identify seasonal variations and PM concentration limits in areas under intense road pressure. Natural atmospheric events, such as wildfires, often cause significant air pollution. In September 2024, Portugal experienced severe wildfires, causing smoke clouds and degrading air quality. Dust plumes occurred in autumn 2024, reaching a rare record of 108 μg/m3. The study found that the average seasonal exposure to PM2.5 reaches WHO limits, but several days exceeded the WHO limit for PM10 concentration.
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Aerosolisation of short, medium, and long chain length per- and polyfluoroalkyl substances (PFAS) from contaminated water 1Centre for Agroecology, Water and Resilience (CAWR), Coventry University, Wolston Lane, Ryton-on-Dunsmore CV8 3LG, UK; 2School of Geography, Earth and Environmental Sciences, University of Birmingham, Edgbaston, Birmingham, B15 2TT, UK This study investigates the aerosolisation potential of 21 PFAS, including restricted and new-generation compounds, from contaminated waters under aeration conditions. PFAS-fortified aqueous solutions, at concentrations and pHs representing wastewater treatment conditions, were aerated using an aeration chamber. All 21 PFAS studied showed significant aerosolisation properties, with aerosolisation increasing as the PFAS carbon chain length increased. The pH of the contaminated water affected PFAS aerosolisation. Our results suggest that aeration-intensive processes such as wastewater aeration could act as a source of atmospheric PFAS.
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Investigation of the Internal Flow Dynamics of Conical Diffuser Chambers 1School of Civil and Environmental Engineering, Pusan National University, Korea, Republic of (South Korea); 2Department of Mechanical Engineering, Korea University of Technology and Education, Korea, Republic of (South Korea); 3Institute for Environment and Energy, Pusan National University, Korea, Republic of (South Korea) Conical diffuser chambers are continuous flow reactors commonly used for studying gas/aerosol-phase reactions and pollutant removal processes. However, turbulent flows caused by the design of the chambers hinder understanding the effects of factors on the particle characteristics. In this study, computational fluid dynamics (CFD) simulations and flow visualization experiments were conducted to analyze internal flow dynamics and their impacts on the particle dynamics. Inlet cone angles (15 and 30°), flow rates (0.3 to 1.5 LPM), and static mixer configurations were controlled as design parameters. Internal flow streamlines were visualized by introducing smoke into the chamber and recorded.
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Chemical analysis of limonene secondary organic aerosols under high reactive nitrogen conditions for varying humidities 1Institute for Marine and Atmospheric Research, Utrecht University, Utrecht, 3584 CC, The Netherlands; 2Energy and Sustainability Research Institute, University of Groningen, Groningen, 9747 AG, The Netherlands; 3Institute for Meteorology and Climate Research, Karlsruhe Institute of Technology, Karlsruhe, 76344, Germany; 4Meteorology & Air Quality, Wageningen University & Research, Wageningen, The Netherlands Experiments in the AIDA chamber examined secondary organic aerosol (SOA) formation from limonene ozonolysis under high reactive nitrogen and varying humidities (0%, 45%, 90%). Results show that increased humidity enhances organic nitrate formation while suppressing dimer formation, affecting the SOA composition. Online measurements and filter analyses confirmed the production of highly oxygenated organic molecules that participate in new particle formation and condensation. These findings suggest that humidity significantly influences SOA chemistry, emphasizing the need to refine atmospheric models of reactive nitrogen–VOC interactions.
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Unraveling 2,5-Dimethylfuran Autoxidation by Ozone and OH radical: Experimental Insights from MION Orbitrap Mass Spectrometry 1Aerosol Physics Laboratory, Tampere University, Tampere, 33720, Finland; 2Department of Chemistry, University of Helsinki, Helsinki, 00014, Finland Furans, a group of volatile organic compounds (VOCs) released from biomass burning and biogenic sources, significantly impact atmospheric chemistry, particularly in wildfire plumes, where furan makes up about 30% of VOCs. Beyond its natural occurrence, furan is considered a potential biofuel due to its high energy density, raising concerns about its potential atmospheric emissions. This study investigates the O₃ and OH-initiated autoxidation of 2,5-DMF, providing crucial insights into the formation of Highly Oxygenated Molecules (HOM) and their role in secondary organic aerosol (SOA) formation. The research aims to advance our understanding of furans' role in atmospheric chemistry.
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Peroxy radical and oxidation product formation in monoterpene oxidation by nitrate radicals: insights from free-jet flowtube experiments 1Institute for Atmospheric and Earth System Research, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland; 2State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing 100029, China; 3College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing 100049, China Aerosols influence global radiation and human health, with secondary organic aerosol (SOA) forming largely through highly oxygenated organic molecules (HOMs). While HOM formation from ozone (O3) and hydroxyl radical (OH) oxidation is well-studied, the role of nitrate radical (NO3) remains less understood. Using a free-jet flowtube with controlled reaction times, we investigate peroxy radical and product formation from NO3-initiated monoterpene oxidation. In alpha-pinene ozonolysis, adding NO2 (as NO3 source by reacting with O3) suppresses peroxy radicals C10H15O8,10, favoring the closed-shell product C10H14O7. Future experiments will use amine-CIMS to identify less oxygenated species and further explore NO3-driven oxidation mechanisms.
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Photochemical degradation of gaseous naphthalene/benzene and secondary organic aerosol formation for typical atmospheric conditions 1Department of Chemistry, University of Copenhagen, 2100, Copenhagen, Denmark,; 2National Research Centre for the Working Environment, 2100, Copenhagen, Denmark; 3School of Chemistry and Environmental Research Institute, University College Cork, Cork, T12 YN60, Ireland; 4School of Physics and Environmental Research Institute, University College Cork, Cork, Ireland; 5Luper technologies, 5656 AE Eindhoven, Netherlands The atmospheric degradation of key species, naphthalene (Nap) and benzene (Bz), emitted from asphalt plants has been investigated in the Irish Atmospheric Simulation Chamber with a focus on reactivity, oxidation products, and secondary organic aerosol formation (SOA) potentials. A total of 24 experiments have been conducted investigating eight reaction mixtures of the OH-initiated oxidation of the species, both individually and together, under different NOx, SO2 and RH conditions. The initial results show that SOA formation occurs only when OH and Nap are present and that the evolution of aerosols from Nap + OH is highly dependent on other compounds present.
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Current chemical ionization mass spectrometry (CIMS) techniques for measuring early generation peroxy radicals from monoterpene ozonolysis are prone to mischaracterization due to an artifact 1Tampere University, Finland; 2University of Helsinki, Finland Current chemical ionization mass spectrometry (CIMS) techniques for measuring early generation peroxy radicals from monoterpene ozonolysis are prone to mischaracterization due to an artifact. In this study, a computational analysis is performed to analyse the possibility of ozonolysis derived peroxy radicals, such as from cyclohexene and α-pinene, losing an O2 during the ionization process. According to the results, this artefact may affect ionization products of many prominently employed reagent ions. Therefore, precaution is required in interpreting measured spectra from alkene ozonolysis experiments.
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Computational study on HOM formation from 2,5-Dimethylfuran oxidation initiated by ozone and OH radical 1Tampere university, Physics Unit, Tampere, Finland; 2University of Helsinki, Chemistry Department, Finland This study explores the formation of Highly Oxygenated Organic Molecules (HOMs) from the oxidation of 2,5-Dimethylfuran (2,5-DMF) by OH radicals and ozone (O₃). 2,5-DMF, a VOC emitted from biomass combustion, is a potential fuel alternative, making its atmospheric impact crucial to study. OH and O₃ reactions produce radicals that undergo autoxidation, leading to HOMs, which influence air quality and climate. Using quantum chemical methods, the study provides a detailed mechanistic understanding of these processes. Supported by the European Research Council, the research utilizes computational tools to refine oxidation pathways, contributing to atmospheric chemistry and air pollution modeling.
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Theoretical Investigation of the Reactivity of Organosulfates with OH Radical Univ. Lille, CNRS, UMR 8523– PhLAM – Physique des Lasers Atomes et Molécules, F-59000 Lille, France Organosulfates (OSs) are key components of atmospheric aerosols, yet their oxidation by hydroxyl radicals (OH) remains poorly understood. This study uses quantum chemistry to investigate the aqueous-phase reactivity of anionic OSs with OH, mimicking aerosol water conditions. Conformational analysis (CREST) and DFT (M06-2X/6-311++G**) with SMD solvation model determine reaction pathways, refined by CCSD(T) calculations. Rate constants are obtained via transition state theory with tunneling corrections. Comparisons with experimental data clarify OS oxidation kinetics and fragmentation into key products, improving understanding of their atmospheric fate.
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The Atmospheric Autoxidation of Mesitylene 1Tampere University, Finland; 2University of Helsinki, Finland Mesitylene is an atmospherically abundant aromatic hydrocarbon. It is found in coal tar and used in industrial solvents and as a jet fuel additive. Mesitylene reacts in the atmosphere with OH in a reaction chain that results in the formation of a bicyclic peroxy radical (BPR). After that its reaction mechanism is relatively unknown despite measurements showing that it produces molecules with up to 11 oxygens. In this study, molecular rearrangement reactions, and subsequent autoxidation reactions, are studied for the mesitylene BPR using quantum chemical methods and master equation simulations, providing a more complete atmospheric autoxidation mechanism for mesitylene.
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The Atmospheric Autoxidation Process of Pseudocumene 1Aerosol Physics Laboratory, Tampere University, Finland; 2Department of Chemistry, University of Helsinki, Finland Pseudocumene (C9H12) makes up significant portion of anthropogenic aromatic emissions. Aromatics have been shown to rapidly autoxidize and produce highly oxygenated organic molecules (HOMs). The oxidation of aromatics leads to formation of a bicyclic peroxy radical (BPR), which through bimolecular reaction can form a bicyclic alkoxy radical (BAR). The ring-opening of the BPR has been shown to be a source of HOMs. Additionally, the ring-open products of the BAR have been suggested to produce HOMs. In this study both the peroxy and alkoxy routes are examined via quantum chemical computations to see their potential for producing HOMs.
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Predictions of homogeneous nucleation rate in laminar and turbulent flows 1School of Mechanical Engineering, National Technical University of Athens, Athens, 15780, Greece; 2National Center for Scientific Research “Demokritos”, Agia Paraskevi, 15341, Greece; 3School of Chemical and Environmental Engineering, Technical University of Crete, Chania, 73100, Greece In applying Classical Nucleation Theory (with or without correction formulas) to calculate the homogeneous nucleation rate, correction factors are required and must be constantly recalibrated as physical conditions change. Homogeneous nucleation related experiments in the literature are scarce, and DBP (dibutyl phthalate) is the only species with data available for both turbulent and laminar flow. In our study, we simulate two DBP experiments—one for laminar flow and one for turbulent flow. Our goal is to accurately predict the order of magnitude for both cases using a single set of correction factors. A diagram of the preliminary data is provided.
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Microbial Ice Nucleation in Polar and Atmospheric Environments: Insights from Antarctic Precipitation and Metagenomic Datasets 1CIIMAR - Interdisciplinary Centre of Marine and Environmental Research, Porto, 4450-208, Portugal; 2Department of science, University of Porto, Porto, 4169-007, Portugal Ice nucleation proteins (INPs) facilitate cloud ice formation at high sub-zero temperatures and are found in diverse microorganisms inhabiting cold environments. These proteins are particularly important in Antarctica and high-altitude ecosystems, where microbial communities influence atmospheric ice formation and climate processes. In this study, we identified INP sequences from newly assembled genomes of potential novel bacterial species isolated from rain and snow at King George Island, Antarctic Peninsula, along with metagenomic datasets from polar and atmospheric environments. Using a custom DIAMOND database of known INPs, we performed BLASTx searches, filtering high-confidence hits based on sequence identity and coverage.
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A DLCA methodology for simulating Brownian agglomeration of nanowire aerosols 1IMDEA Materials Institute, Spain; 2Department of Applied Physics, Universidad Autónoma de Madrid, Spain We present a DLCA model for unidimensional particles with size-dependent translational and rotational diffusivities. The model simulates the aerosol phase agglomeration of nanowires produced by FCCVD and is intended to measure agglomerate growth, kinetics and percolation. The goal of the study is to predict the conditions of gelation for a given population of aerosol-synthesized nanowires. By simulating different monodisperse populations of nanowires of variable length and diameter, as well as populations with lognormal distributions of length and diameter, we conclude that nanowire populations of high aspect ratio and low polydispersity will have increased tendency to form aerogels.
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Single-droplet techniques for analysis of evaporation kinetics and particle morphology in spray dryers 1School of Chemistry, University of Bristol, Bristol, BS8 1TS; 2Danone Research & Innovation, Uppsalalaan 12, 3584 CT Utrecht, the Netherlands Understanding the impact of droplet drying kinetics on the morphology of resultant dried particles is crucial to improve the spray drying process. Experiments in spray dryers have struggled to monitor the drying of the individual droplets directly, whereas SDD experiments have been shown to be successful in relating the drying behaviour of single droplets to the resultant particle morphology. We present novel investigations into the drying kinetics of a range of fat free, dairy-based powders, the impact of their drying behaviour on the final particle morphology and comparative generation of particles in an SDD technique against a small-scale spray dryer.
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Controlling the Morphology of Microparticles Formed by Evaporation of Aerosol Droplets Containing Polymer Nanoparticles 1University of Bristol, United Kingdom; 2University of Sheffield, United Kingdom Control over the morphology of particles formed in spray driers is highly desirable; the morphology affects the material’s chemical and physical properties. In this work aqueous, nanoparticle-laden aerosol droplets were probed using an electrodynamic balance and scanning electron microscopy to determine the effect of relative humidity and the nanoparticle’s mechanical strength on the final microparticle’s morphology. Lower relative humidities increased the evaporation rate and increased the buckling seen in the final particles. Lowering the glass transition temperature of the nanoparticles in the droplets increased the degree of buckling of the final microparticle, but had no impact on the evaporation kinetics.
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Roles of Mucin and Albumin in Exhaled Respiratory Droplet Evaporation and Rehydration: Implications for Airborne Disease Transmission 1Karlsruhe Institute of Technology, Germany; 2University of Heidelberg, Germany Our results highlight the significant roles of different proteins in affecting the physicochemical properties of exhaled respiratory droplets during evaporation and rehydration. The organic content of respiratory fluids varies depending on the region of the respiratory tract where it is produced. Virus-laden respiratory droplets generated in areas with higher organic content may form a more robust shell under dry conditions, thereby enhancing the virus's environmental survivability by protecting it from factors such as temperature, humidity, and ultraviolet radiation.
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New cleaning model to predict the removal efficiency of 10-130 nm contaminant particles on Si wafers using microdroplet impaction Pusan National University, Korea, Republic of (South Korea) We developed a Monte Carlo model to bridge the gap between existing cleaning models and actual cleaning experiments. This MC model was successfully validated through a series of cleaning experiments for 10-130 nm particles on Si wafer surface, using on a two-fluid supersonic nozzle to control the impact velocities of sprayed microdroplets. More importantly, we demonstrated for the first time the significance of cleaning time duration, showing that continued droplet spraying after a liquid film forms on the surface has a negligible effect on particle removal efficiency. Here, we proposed a cyclic repetition of droplet spraying and surface drying.
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Sea spray aerosol emissions (1940-2023) subject to climate change: trends and variation, based on new source parameterizations, the cases of the North Sea and the Baltic Sea 1Department of Environmental Sciences, Stockholm University, Stockholm, Sweden; 2Bolin Centre for Climate Research, Stockholm University, Stockholm, Sweden Sea spray aerosol (SSA), as a dominant natural source of aerosols, is influenced by multiple factors such as sea surface temperature (SST), salinity (S), wind speed (U), ice coverage (I), etc., especially in the Anthropocene. To parameterize SSA emission flux and understand its correlation with key factors, this study developed an SSA source function for both mass and number emissions, incorporating the factors mentioned above. The results show a high similarity in variation compared with satellite-based observations. SSA emissions correlate with these factors differently, exhibiting varying time-lagging relationships.
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Stiff kinetics parameter estimation using neural ordinary differential equation and collocation training 1Institute for Atmospheric and Earth System Research (INAR), The University of Helsinki, Helsinki, 00014, Finland; 2Atmospheric Modelling Centre Lahti, Lahti University Campus, Lahti, 15140, Finland; 3School of Engineering Sciences, Lappeenranta-Lahti University of Technology LUT, Lahti, 15110, Finland The work propose a data-driven approach to estimate reaction rate coefficient of autoxidation reactions. We validate our approach is fast and stable on a synthetic stiff atmospheric chemistry kinetic problem.
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Using digital PCR targeting the respiratory microbiome to quantify respiratory aerosol within complex spaces 1Queensland University of Technology, Australia; 2McGill University, Canada; 3University of New South Wales, Australia; 4University of Maryland, United States We developed a digital PCR targeting normal respiratory microflora
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Development of a particle categorization for the broad representation of atmospheric measurement data with the SwisensPoleno Jupiter GeoSphere Austria, Sonnblick Observatory, Austria We develop a simple particle classification scheme to broadly represent ambient data measured by the SwisensPoleno Jupiter. The plausibility and usefulness of this approach is discussed with respect to data obtained at the Sonnblick Observatory, a high alpine research station.
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Experimental study of homogeneous nucleation in bismuth vapor University of Duisburg-Essen, Germany The homogeneous nucleation of bismuth vapor in the gas phase was investigated to evaluate the impact of various experimental parameters (e.g. evaporation temperature and rate, choice of carrier gas, volumetric flow of carrier gas) on the properties of the resulting particles and their nucleation rate. After careful study of measures required to guarantee an oxygen-free carrier gas, online measurements were carried out using a 1 nm-scanning mobility particle sizer, while ex situ analyses were performed with STEM. Furthermore, experimental results were compared with predictions of homogeneous nucleation to assess the accuracy and predictive capability of the nucleation theory.
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Iron’s impact on SOA formed from Monoterpenes. PSI Center for Energy and Environmental Sciences, Switzerland Secondary organic aerosol (SOA) forms when volatile organic compounds(VOCs) oxidize, producing low-volatility compounds that partition into particles. SOA impacts climate, health, and ecosystems, with biogenic VOCs like terpenes being major sources. SOA can mix with inorganic particles containing metals (e.g., Iron [Fe]), altering its properties. Garner et al. (2024) showed Fe increased mass and dimer formation in α-pinene SOA. We investigated SOA from terpenes using (NH4)2SO4 or Fe-containing seeds at varying humidities. Oxidation products were analyzed via SMPS and EESI-TOF. Results show differing SOA compositions without Fe. We explore how Fe affects β-pinene and limonene SOA, especially at high RH.
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Carbonaceous fine aerosol in Sarajevo, Bosnia and Herzegovina: Elevated concentrations and highly polluted winter episodes 1University of Nova Gorica, Ajdovščina, 5270, Slovenia; 2Aix Marseille Univ., CNRS, LCE, Marseille, 13007, France; 3Research and Development Department, Aerosol d.o.o, Ljubljana, 1000, Slovenia; 4Center for Energy and Environmental Sciences, Paul Scherrer Institute (PSI), Villigen, 5232, Switzerland; 5Institute of Environmental Assessment and Water Research (IDAEA-CSIC), Barcelona, 08034, Spain; 6Aerodyne Research, Inc.45 Manning Rd, Billerica, MA 01821, USA; 7Federal Hydrometeorological Institute of Bosnia and Herzegovina, Sarajevo, 71000, Bosnia and Herzegovina This study represents one of the first fine aerosol study including carbonaceous source apportionment in Sarajevo, Bosnia and Herzegovina, embedded in the Sarajevo AEROsol Experiment (SAAERO) project. The aim is to characterise fine aerosol loadings and sources with special interest on winter stagnation episodes, when fine aerosol concentrations can exceed 200 µg·m-3. For that purpose, we deployed an ACSM and an aethalometer AE33 to characterise the concentrations of fine aerosol components and sources of the carbonaceous aerosol at the Sarajevo-Bjelave site. The main sources of carbonaceous aerosol found are traffic, solid-combustion, and secondary OA.
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Temperature effects on toluene SOA properties 1Democritus University of Thrace, Greece; 2Aarhus University, Denmark In this work we studied the effects of temperature on toluene SOA physicochemical properties. SOA formation took place in the AURA smog chamber at different temperatures (-15, 0 and 20oC). After the completion of SOA production, the temperature was either increased or decreased by 15-20oC. Both the particulate and gas phase were analyzed using online, high resolution state-of-the-art instrumentation. We found differences in the SOA density, collection efficiency and O:C ratio at different SOA formation temperatures. When the temperature changed during the experiment, SOA density remained approximately constant, but in some cases O:C ratio and CE changed.
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Research on IoT and Deep Learning-Based Monitoring and Prediction Technology for Biological Hazards in Indoor Air Sundosoft Co., Ltd., Korea, Republic of (South Korea) This study developed an IoT-based system integrated with deep learning to monitor and predict biological hazards in indoor air. The network measured airborne bacteria and mold in real time, collecting data alongside environmental parameters. GIS was utilized for spatial analysis by facility type and region. Both time-series and non-time-series prediction models were compared, with the time-series model showing superior performance for data influenced by preceding concentrations. A missing data correction model enhanced continuous data usage. Finally, a web GIS platform enabled real-time responses to indoor air quality changes, promising improved management in multi-use and vulnerable spaces.
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On the impact of Saharan dust on ice nucleating particles at high-mountain and urban environments in Southern Europe 1Andalusian Institute for Earth System Research (IISTA-CEAMA); 2Department of Applied Physics, University of Granada Atmospheric aerosols act as ice nucleating particles (INPs), influencing cloud microphysics, radiative balance, and precipitation. However, their impact remains uncertain. This study examines INP variability from June 2024 to May 2025 at two AGORA stations: UGR (urban) and SNS (high-mountain). INP concentrations samples were analyzed using GRAINS (GRAnada Ice Nuclei Spectrometer). SNS showed higher summer INP activity due to mineral dust, while UGR showed higher activity during autumn and winter, highly linked to anthropogenic aerosol. A correlation between INP and optical properties suggests human influence on dust INP activity. Future chemical and mineralogical analyses will further explore INP composition.
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Ecotoxicity of PM10 from heating appliances using different biomass fuels in two dwellings 1Centre for Environmental and Marine Studies (CESAM), Department of Environment, University of Aveiro, 3810-193, Aveiro, Portugal; 2National Institute of Nuclear Physics (INFN), Sesto Fiorentino, Florence 50019, Italy; 3Centre of Natural Environmental Sciences, University of Pannonia, Egyetem str. 10, 8200, Veszprém, Hungary.; 4CIMO, LA SusTEC, Instituto Politécnico de Bragança, Campus de Santa Apolónia, 5300-253 Bragança, Portugal; 5Technical University of Ostrava, Centre for Energy and Environmental Technologies, Energy Research Centre, 17. Listopadu 2172/15, 70800, Ostrava, Poruba, Czech Republic The transition to a low-carbon economy is a key EU strategy, promoting woody biomass for residential heating. This study analyzed the chemical composition and ecotoxicity of PM10 in two Portuguese dwellings using a pellet stove (modern) and a wood stove (older system). Indoor PM10 concentrations were higher for the wood stove, frequently exceeding WHO guidelines. Ecotoxicological assays classified all pellet stove samples as “toxic” and 98% of wood stove samples as “very toxic.” Strong and significant correlations (r²>0.8) were found between PM10-bound elements and toxicity, highlighting the greater environmental and health risks associated with the older heating system.
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Determination of the initial concentration of aerosols and chemical agents at the portable air purifier test site CIOP-PIB, Poland People spending time inside and outside buildings in urban areas are exposed to inhalation of chemical substances (vapors, gases and suspended dust). Unfavorable conditions inside buildings can result in serious health problems in humans manifested by SBS. In order to ensure adequate IAQ, especially in urban areas, proper air purification is required. CIOP-PIB undertook to build a research stand based on the ANSI/AHAM AC-1:2020 method. In our tests for the presence of aerosols and chemical substances in the air of the laboratory chamber, APS 3321 and SMPS 3938 measured techniques and GC/MS and HPLC/UV analytical techniques were used.
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Automatic classification of electrohydrodynamic atomization modes based on machine learning 1NHL Stenden University of Applied Science, Netherlands, The; 2Department of Chemical, Materials and Industrial Production Engineering, University of Naples Federico II, Naples, Italy; 3Federal University of Minas Gerais, 31270-901, Brazil; 4Department of Mathematics and Physics, University of Campania, Caserta, Italy This study builds on the method of Verdoold et al., proposing a machine learning-based system to classify EHDA modes (dripping, intermittent, cone-jet and multijet). The system generates “mode maps” in real time and uses data from more than 10 solutions to train models. Testing algorithms such as XGBoost, we achieved 93.76% accuracy. This approach improves EHDA automation, increasing its potential for industrial applications.
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Evaluation of Ultrafine Particle Abatement Systems in a 125 kW Biomass Pellet Boiler 1Centro de Investigaciones Energéticas Medioambientales y Tecnológicas (CIEMAT), Madrid 28040, Spain; 2CEDER-CIEMAT Autovía A-15 salida 56, 42290 Lubia (Soria), Spain; 3CURVADOS QUINTÍN S.L. Polígono Bakiola 35B 48498 Arrankudiaga (Vizcaya), España; 4Universidad Complutense de Madrid (UCM), Madrid 28040, Spain Biomass combustion is a sustainable alternative to fossil fuels but generates ultrafine particles (UFP) with environmental and health impacts. This study evaluates UFP abatement systems in a 125 kW biomass boiler operating in condensation mode. Different technologies were analyzed using real-time measurements and isokinetic sampling. Results show that appropriate retention devices significantly reduce particle concentration without affecting combustion efficiency. An innovative inertial system developed by CIEMAT achieved the highest UFP reduction. These findings contribute to improving air quality and minimizing health risks.
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Thin continuous polytetrafluoroethylene coatings by electrospray 1University Rovira i Virgili, Spain; 2Catalan Institution for Research and Advanced Studies, Spain In this poster contribution, we provide methodological details and results for implementing the electrospraying of a suspension of polytetrafluoroethylene (PTFE) nanoparticles in acetone, without the addition of surfactants. The collected particulate films were heat treated to melt the particles, and were analyzed by Scanning Electron Microscopy to evaluate porosity or compactness. Both the top views and fracture sections of the films revealed structures that relate to PTFE crystallinity. The water contact angle was around 135 degrees, showing hydrophobicity. Also, the PTFE coatings prevent the outer wetting of the capillary in electrospraying of polystyrene in MEK and PVP in ethanol.
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Particle emissions from the use of tobacco products Hellenic Open University, Greece The scope of this work is to compare particulate emissions from CCs, e-cigs and HTPs. In a first step, an extended bibliographic search was performed in Scopus and Pubmed databases. This search resulted to more than 370 publications concerning CCs, 113 for e-cigs and 69 for HTPs. The presence of particles was studied both in mainstream emissions and in a room or chamber. High heterogeneity was found in the experimental settings among the researchers. In a second step, a number of tobacco products are tested under different experimental conditions to determine the emissions of particles.
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Formation of trioxy acid via OH-initiated aldehyde oxidation in the atmosphere 1Department of Chemistry, University of Helsinki, Helsinki, 00041, Finland; 2Institute for Atmospheric and Earth System Research, University of Helsinki, Helsinki, 00014, Finland; 3Aerosol Physics Laboratory, Tampere University, Tampere, 33720, Finland Hydrotrioxides (ROOOH), once thought unstable, were directly observed in atmospheric reactions between peroxy (ROO) and hydroxyl (OH) radicals. This study explored similar reactions involving acyl peroxy radicals (APR), formed during aldehyde oxidation. Using a flow tube and mass spectrometry, researchers detected trioxy acids from benzaldehyde-derived APR reacting with OH. Quantum calculations confirmed their stability. In contrast, APRs from heptanaldehyde and acetaldehyde followed different paths, showing either rapid internal rearrangements or intermediate trioxy acid formation. These findings highlight the importance of -OOOH group chemistry in understanding atmospheric processes and secondary organic aerosol formation under varying environmental conditions.
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A case study of the strengths and limitations of using the isotopic composition of Carbon (d13C) and Nitrogen (d15N) to partition the sources of C and N in Particulate Matter collected over Naples (Italy) 1Università della Campania "Luigi Vanvitelli", Italy; 2Istituto di Scienze dell’atmosfera e del clima, Centro Nazionale delle Ricerche, Via Piero Gobetti, 101, 40129 Bologna, Italy; 3Dipartimento di Scienze e Tecnologia, Università Parthenope, Centro Direzionale Isola C4, 80134 Napoli, Italy; 4Departamento de Física, Universidad de Córdoba, Edificio "Einstein", Planta Baja, Campus de Rabanales, 14071 Córdoba, Spain; 5Laboratory of Ion Beam Physics, Institute for Nuclear Research, Hungarian Academy of Sciences (MTA Atomki), H-4026, Debrecen, P. O. Box 51, Hungary We measured isotopes of C (d13C) and N (d15N) in Particulate Matter (PM2.5 and PM10) collected over Naples in May 2016 and November 2016 - January 2017, together with the concentration of major ions (NH4+, K+, Ca2+, Na+, Mg2+, NO3-, SO42-, C2O42-, Cl-) that of total C and N, as well as the origin of air masses (wind direction, speed and backtrajectories – Hysplit). 1) CPM10 showed an important fraction (up to 44%) from carbonate C 2) CPM2.5 was predominantly derived from C3/fossil 3) NPM10 showed a shift from volatilization to combustion sources 4) NPM10 was mainly from combustion
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Transport and air pollution exposure around schools UK Health Security Agency, United Kingdom We conducted an updated analysis of air pollution concentrations (PM2.5 and NO2) at school locations in England, UK and associations with socio-economic inequalities. Previous analysis showed that air pollution outside schools is likely to be compounding existing childhood socio-economic disadvantage. We also reviewed transport and planning policies in urban areas, particularly those implemented around schools, that can have beneficial impacts on the environment and health and may offer other co-benefits. Mitigating air pollution in and around schools and during travel has the potential to reduce children’s exposure to harmful pollution and potential associated health risks.
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Additive Fingerprints of Micro- and Nano-plastics in PM10 from Occupational Environments National Research Council, Italy This study investigated around 70 organic additives as potential tracers of micro- and nanoplastics (MNPs) in airborne PM10 collected from three occupational environments. Using GC-MS analysis, distinct additive profiles were observed at each site. The tire repair shop showed the strongest correlation, with high levels of phthalates, benzothiazole, and homosalate in both raw materials and air samples. Weaker links were found in the bottling plant and textile facility. Overall, the findings suggest that workplace materials contribute to airborne MNPs and that specific additives may serve as useful markers for tracing their presence in indoor environments.
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Characterisation of Long-Range Transported Aerosols at Barbados during EUREC4A: Insights from Single-Particle Mass Spectrometry 1Department of Earth and Environmental Sciences, The University of Manchester, UK; 2National Centre for Atmospheric Research, Manchester, UK Saharan mineral dust influences climate and marine ecosystems, with effects shaped by particle composition and mixing state, which evolve during transport. In situ data, especially over oceans, are scarce. We present high time-resolution single-particle measurements from Ragged Point, Barbados (EUREC4A-UK, Jan–Feb 2020), capturing a major dust intrusion. Instruments revealed silicate-rich particles internally mixed with nitrate, sulphate, CaCl, organics, and sea salt—distinct from externally mixed dust observed nearer the source (e.g., Cape Verde). These findings suggest substantial chemical aging during transatlantic transport, enhancing hygroscopicity and modifying cloud-forming potential, highlighting complex interactions between dust and marine aerosols in the boundary layer.
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Characterization of aerosol microphysical properties and transport mechanisms to the Alps 1Institute of Polar Sciences –National Research Council, Milan, Italy; 2Institute of Atmospheric Sciences and Climate –National Research Council, Bologna, Italy; 3Institute of Environmental Geology and Geoengineering – National Research Council, Milan, Italy; 4Regional Environmental Agency Valle d’Aosta, Aosta, Italy; 5Milan Research Area - National Research Council, Milan, Italy; 6Institute of Geosciences and Earth Resources – National Research Council, Torino, Italy; 7Department of Earth System Sciences and Environmental Technologies – National Research Council, Rome, Italy Observations of atmospheric aerosols at high elevations play a crucial role in monitoring changes in atmospheric background composition, evaluating the effects of both anthropogenic and natural aerosols at a regional scale, and enhancing our understanding of aerosol-cloud interaction mechanisms. However, high-altitude observations are limited due to environmental and technical challenges. We will present the first aerosol measurements collected at the Testa Grigia Observatory, at 3,480 m in the Italian Alps from September 2021 to May 2023.
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Comparative characterisation of indoor aerosols from salt atomisation and pan frying: size distribution and ventilation impact in a naturally ventilated townhouse Atmospheric Chemistry Research Group, School of Chemistry, University of Bristol, Bristol, United Kingdom Indoor air quality is shaped by source emissions, ventilation conditions, and spatial airflow patterns. We compare behaviour from two indoor sources in a naturally ventilated terraced house: 5% NaCl aerosols, generated via atomiser, and aerosols from frying bacon. Measurements were performed using two Grimm Scanning Mobility Particle Sizes, placed in the kitchen and the upstairs bedroom. NaCl aerosols exhibited stable unimodal distributions (~80–90 nm) with low variability and moderate concentrations, bacon frying resulted in bimodal distributions (60–120 nm) with higher concentrations, exceeding 7000 particles cm⁻³. Concentrations were elevated in the upstairs bedroom, demonstrating vertical transport and inter-room persistence.
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Development and characterisation of a new aerosol sampling system and preliminary investigations regarding the composition of organic aerosol Johannes Gutenberg-Universität Mainz, Germany Organic aerosols (OA), formed from reactions between gaseous precursors like biogenic VOCs and oxidants such as ozone, significantly impact climate and health. Understanding OA's chemical composition is crucial for identifying their sources and transformations. A novel aerosol sampler, designed for high flow and ease of use, employs a radial impeller and a 3D-printed filter tray. Calibration involved atomizing sodium chloride and sulfate solutions. The Orbitrap mass spectrometer is essential for non-target analysis, providing the high resolution and mass accuracy needed to identify unknown compounds. This study enhances the understanding of OA's sources, transformations, and impacts.
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Development and Evaluation of a Fanless In-Vehicle Electrostatic Precipitator for Urban PM Reduction Department of Urban Environment Research, Korea Institute of Machinery and Materials, Korea, Republic of (South Korea) This study introduces a grille-mounted electrostatic precipitator (ESP) designed to reduce road PM concentrations by utilizing vehicle motion. The system consists of a charging unit, collection unit, and uses passive airflow generated by driving or the radiator fan, eliminating the need for a dedicated fan. The ESP was installed on a real vehicle and tested under actual driving conditions. Results showed that collection efficiency increases with vehicle speed, enabling estimation of clean air delivery rate (CADR) during driving. This approach offers a novel, energy-efficient method to collect particulate matter before it disperses into the urban environment.
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Effects of Chamber Configurations on the Nanoparticle Output of Spark Discharge Generators: A Combined CFD, Particle Tracing and Experimental Study 1University of Szeged, Hungary; 2Lund University, Sweden; 3Chalmers University of Technology, Sweden Spark ablation offers a chemical-free route to produce nanoparticles with controlled properties. This study investigates how spark discharge generator chamber geometry affects nanoparticle yield and transport efficiency. Experiments with various inlet/outlet configurations producing palladium nanoparticles in nitrogen carrier gas were complemented by CFD and Particle Tracing simulations. Results show that modified geometries increase local gas velocities, shorten residence times, and reduce losses. After normalizing for spark energy and frequency, experimental yields aligned well with simulations, except where the residence time exceeded the sparking period. These findings underscore that inlet/outlet placement strongly affects yield, while chamber volume has a marginal effect.
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LOAC-S, a new space-borne OPC for planetary aerosols 1CNRS, France; 2CNES, France Aerosols play an essential role in our understanding of planetary atmospheres, being involved in many chemical processes within them as well as affecting the planet's radiative budget. While remote sensing can provide an initial estimation of aerosol composition, in-situ measurements allow for a deeper understanding of aerosol granulometry, concentration, and typology. To address these issues, we propose a novel spaceborne optical particle counter (OPC) to measure light scattering by aerosols in planetary atmospheres (e.g. Mars or Venus). The instrument is based on the LOAC (Light Optical Aerosol Counter) concept and redesigned for space conditions improved performance to meet scientific requirements.
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Temporal Variation of Tire Wear Particles in Ambient Air: Development of Analytical Techniques and Seasonal Trends Strasbourg University, France Tire wear is a growing source of non-exhaust particulate matter (PM), especially PM10 and PM1, which pose serious health risks. This study developed and validated a high-sensitivity HPLC-MS/MS method to quantify 21 tire-related compounds, including phenylenediamines, benzotriazoles, and triazines. Air samples from Strasbourg were collected seasonally and extracted using Accelerated Solvent Extraction. Eight compounds were consistently detected, with the highest concentrations in winter and PM10 levels exceeding PM1. The method showed excellent linearity, low detection limits, and high precision. These findings highlight tire wear as a key pollutant and support its inclusion in air quality regulation and health assessments.
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The Angstrom coefficient (Aerosol) evaluation through wide-field stellar photometry 1Institute of Physics of the Czech Academy of Sciences, Czech Republic; 2Institute of Theoretical Physics, Faculty of Mathematics and Physics, Charles University, V Holeˇsoviˇck´ach 2, 180 00 Prague, Czech Republic We developed a non-invasive atmospheric monitoring method for CTAO ( Cherenkov Telescope Array Observatory) and Pierre Auger Observatory site locations- the difference between the measured magnitude and the catalog magnitude of a star is equal to the atmospheric extinction. Data is obtained from the FRAM (F/Photometric Robotic Atmospheric Monitor) telescopes using B, V, and R standard Johnson-Cousins filters and the Gaia DR3 catalog as a reference. However, the Angstrom coefficient calculated by the three combinations of VAOD value in the B, V, and R filters (B-V, V-R, R-B) is not the same and also negative for B-V and B-R combinations.
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Using online chemical ionisations high-resolution mass spectrometry for the characterisation of size-dependent reactions in aerosol particles 1Johannes-Gutenberg University Mainz, Germany; 2IRCELYON, Universite Claude Bernard Lyon, France Reactions within organic aerosols significantly impact climate and industrial processes. Understanding these reactions is vital for accurate climate modeling and optimizing chemical applications. A novel setup, combining a Chemical Ionization Orbitrap inlet with an aerosol inlet, enables high-resolution analysis of aerosol particle reactions. This setup allows for the observation of particle size-dependent reaction speeds, enhancing our comprehension of complex processes. By testing various reactant gases and investigating different reaction types, researchers can access a broader range of reactions, ultimately improving climate models and industrial efficiency across sectors like chemical, pharmaceutical, and environmental engineering.
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LungVis 1.0 – AI-enhanced 3D imaging for spatially resolved dosimetry and biokinetics of inhaled nanoparticles throughout the entire murine lung 1Institute of Lung Health and Immunity (LHI), Helmholtz Zentrum München, Comprehensive Pneumology Center (CPC-M), Member of the German Center for Lung Research (DZL), Neuherberg/Munich, 85764, Germany; 2Helmholtz AI, Helmholtz Zentrum München, Neuherberg/Munich, 85764, Germany; 3Helmholtz Imaging, Applied Computer Vision Lab, Division of Medical Image Computing, German Cancer Research Center (DKFZ), Heidelberg, Germany; 4Institute of Epidemiology, Helmholtz Zentrum München, Neuherberg/Munich, 85764, Germany Understanding the dynamic process of spatially resolved aerosol deposition and subsequent transport of (nano‑)particles in the lung is of utmost importance for toxicological research and therapeutic (nano‑)particle applications. Here we present first results from our LungVis1.0 imaging ecosystem, which combines AI enhanced image processing of light sheet fluorescence microscopy (LSFM) images for holistic 3D co-mapping of lung morphology and aerosol deposition and pulmonary biokinetics with cellular resolution in non-dissected murine lungs. These data demonstrate hot spot features in bronchial and alveolar aerosol deposition at a resolution suitable for validation of computational fluid dynamics (CFD) models of aerosol-lung deposition.
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New particle formation from alpha pinene and trace sulfuric acid 1CERN, Switzerland; 2University of Vienna, Austria; 3Faculty of Sciences of the University of Lisbon, Portugal; 4Goethe University Frankfurt, Germany; 5University of Helsinki, Finland; 6University of Tartu, Estonia; 7University of Innsbruck, Austria; 8Ionicon Analytik Ges.m.b.H., Austria; 9The Cyprus Institute, Cyprus; 10Max Planck Institute for Chemistry, Germany New particle formation (NPF) produces about half of global cloud condensation nuclei, often via sulfuric acid–ammonia nucleation. Oxygenated organic molecules (OOM) from terpenes like alpha-pinene can also drive NPF without sulfuric acid. This study examines alpha-pinene-driven NPF in the presence of trace sulfuric acid under cool, clean atmospheric conditions using the CERN CLOUD chamber. Measurements included gas-phase species, clusters, and aerosol size distributions. A new parametrisation of nucleation rates based on OOM and sulfuric acid concentrations was developed and integrated into the EMAC atmospheric model to enhance global representation of NPF processes.
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Particulate Matter: multi-sample analysis protocol for Oxidative Potential determination 1Istituto di Scienze dell'Atmosfera e del Clima (ISAC) - CNR, Lecce, 73100, Italy; 2Dipartimento di Ingegneria dell'Innovazione, Università del Salento, Lecce, 73100, Italy; 3Dipartimento di Scienze e Tecnologie Biologiche ed Ambientali DiSTeBA, Università del Salento, Lecce, 73100, Italy The Oxidative Potential (OP) of particulate matter (PM) reflects its ability to generate reactive oxygen species (ROS), so it is proposed as a proxy for toxicity. We optimized the most widely used DTT and AA acellular assays for OP determination, using a microplate spectrophotometer. These protocols were applied to PM2.5 samples collected in Lecce during TOX-IN-AIR project monitoring compaigns. Samples were extracted in ultrapure water from quartz filters, and both assays were used to evaluate PM redox activity. The different sensitivities of DTT and AA provide a broader view of PM components by measuring reagent consumption over time.
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Particulate-loaded filters analysis via Laser-Induced Breakdown Spectroscopy 1CNR-ICMATE, Institute of Condensed Matter Chemistry and Energy Technologies, Italy; 2Department of Mechanical and Industrial Engineering, University of Brescia, Italy; 3CNR-IPS, Institute of Polar Sciences, Italy Laser-Induced Breakdown spectroscopy (LIBS) is a powerful tool for qualitative and quantitative elemental analysis of solid samples or aerosols. In the condition of extremely low analyte concentrations, the LIBS application o aerosol is not straightforward. An alternative approach involves the collection of atmospheric particulates onto a filter and the analysis without any sample pre-treatment. In this work, particle aerosol is collected on a 3 mm diameter filter to build the calibration curve and single-shot LIBS measurements are carried out. As a case study, this indirect analysis is implemented to analyze impurities in snow samples collected on Cordillea Blanca glaciers, Peru.
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Quantifying short-term intervention-associated source contributions to air quality using a causal machine learning approach College of Environmental Science and Engineering, Nankai University, Tianjin 300350, China Abrupt source emission changes from natural or human interventions often cause unexpected air quality variations. These short-term source emission shifts are difficult to identify and apportion using conventional factor analysis, which relies on chemical covariance. We train a machine learning model on routine air quality data and emission proxies to establish a baseline representing business-as-usual conditions. Deviations during interventions allow causal quantification of source contributions. Applied to the Chinese Spring Festival and a mandatory airport closure, this approach revealed distinct air quality variation patterns and demonstrated its effectiveness in quantifying short-term emission impacts, complementing traditional receptor models.
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Seasonal variability of PM2.5 major chemical components and source tracers in the Mediterranean urban background atmosphere 1School of Chemical Engineering, National Technical University of Athens, Greece; 2Environmental Radioactivity & Aerosol Technology for Atmospheric and Climate Impact Lab, NCSR Demokritos, Greece The present study focuses on levels and seasonal trends of urban background aerosol and its chemical components, in the Mediterranean, a region displaying significant anthropogenic and natural sources and already visible impact from climate change. 24h PM2.5 samples were collected on a daily basis during 2024, at the Demokritos Urban Background Station in Athens, Greece. They were by X-Ray Fluorescence for major and trace elements. In addition, near-real time elemental (EC) and organic carbon (OC) concentrations in PM2.5 were recorded on a 3h basis, by the thermo-optical transmittance (TOT) method.
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Source apportionment of PM in Campania during high tourist season: an integrated analytical and modeling approach 1University of Campania “Luigi Vanvitelli”, Department of Mathematics and Physics, 81100 Caserta, Italy.; 2Department of Physics, University of Córdoba, 14071 Córdoba, Spain.; 3ARPAC - Region Campania Agency for the environment protection, 80143 Naples, Italy.; 4Laboratory for Heritage Science (HSLab), Institute for Nuclear Research, Hungarian Academy of Sciences (MTA Atomki), H-4026 Debrecen, Hungary. A study on atmospheric particulate matter (PM) conducted in Campania (southern Italy) collected high tourist season by the A.R.P.A.C air quality monitoring network. As part of this research activity, elemental characterization, morphological analysis, statistical and atmospheric modeling techniques were applied on PM10 and PM2.5 fraction in order to identify major emission sources of PM and quantify the contribution of each source on measured concentration levels.
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The Effect of Explicit Many-Water Molecules on Dimethyl Sulfide Oxidation University of Helsinki, Finland Theoretical investigations were conducted to examine the gas-phase hydrogen abstraction reaction between hydroxyl radical and dimethyl sulfide, in the presence of explicit water molecules (one until three water molecules). The calculations employed density functional theory with a dispersion correction. The energy of the hydrated transition state with one water molecule is lower compared to that of the non-hydrated counterpart, i.e. 6.07 kcal/mol. To evaluate the atmospheric relevance of these hydrated-oxidation reactions, reaction rate coefficients of the complexes are also calculated.
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Understanding the sources of PM10 and PM2.5 in an underground train station in Ile de France (Paris metropolitan area) 1Particle Vision GmbH, Switzerland; 2SNCF, France; 3Gradiom Sàrl, Switzerland; 4Université Grenoble Alpes, CNRS, IRD, INP-G, INRAE, IGE A combination of advanced bulk and single particle analysis coupled to machine learning classification based on morpho-chemical predictors achieved a detailed estimation of the share of the different particle types/sources within PM10 and PM2.5 in an underground train station. These results give insights into the relative contribution of specific sources even though they are dominated by one main activity (railway traffic). The knowledge gained by this detailed PM characterization contribute to a better understanding of the degree of pollution derived by the different train components (brake pads, railway line, pantograph). And hence determine the most promising fine dust abatement measures.
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Characterization of PM2.5 and its oxidative potential in three regions of the South Italy 1Institute of Atmospheric Sciences and Climate - ISAC-CNR, Lecce, 73100, Italy; 2Clinical Pathology and Microbiology Unit, Vito Fazzi General Hospital, Lecce, 73100, Italy The oxidative potential (OP) of atmospheric aerosol (PM) is proposed as a metric to assess the PM exposure health effects, with OP indicating the PM ability to induce oxidative stress in biological systems. The Dithiothreitol assay is the most used for determining OP-PM. Considering the Mediterranean basin, the number of studies concerning OP of PM is limited. This study focused on the PM2.5 OP measured in a semirural site in Basilicata region (south Italy), evaluating the impact of sources to the PM2.5 concentration and to its OP, comparing the results with those obtained from two other regions of south Italy.
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The Impact of COVID-19 Restrictions on Airborne Concentrations of Contaminants of Emerging Concern in Milan (Italy): The Case of Cocaine 1Università Ca' Foscari di Venezia, Italy; 2Institute of Polar Sciences, Italian National Research Council,; 3ARPA Lombardia, Unità Operativa Qualità dell’Aria The work regards illicit drugs (IDs), which are Contaminants of Emerging Concern, and their presence in the atmospheric urban aerosol. European studies indicate cannabis is the most consumed drug, followed by cocaine, amphetamines, and opioids. Italy follows the same trend. The research examined the airborne concentration of IDs in Milan prior, during, and after the Covid-19 period, revealing significant levels of cocaine. Results suggest the pandemic had little impact on airborne IDs, in agreement with European trafficking trends. The study contributes to understanding the use of drugs as social behavior indicators and their potential impact on tourism.
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Data-Driven Modeling of Ultrafine Particles in Northern France: An XGBoost Approach Using ATOLL Observations University of Lille, France Ultrafine particles (UFPs, <100 nm) present serious health risks and arise from both anthropogenic sources like traffic and natural processes such as nucleation events. Due to limited monitoring and complex behavior, modelling UFPs is challenging. This study applies a machine learning approach using XGBoost to predict UFP concentrations based on data from the ATOLL station in Northern France. An 80/20 data split, 10-fold cross-validation, and hyperparameter tuning via grid search and Bayesian optimization were used. NO₂ served as a traffic proxy. SHAP analysis provided model interpretability. The best-performing XGBoost model achieved an R² of 0.84 on the test set.
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| Date: Thursday, 04/Sept/2025 | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
| 5:15pm - 6:45pm | Poster Session Thursday Location: Studium2000 Building5 | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Using low-cost sensors to monitor particulate matter in classrooms of a Portuguese high school 1Centro de Ciências e Tecnologias Nucleares, Instituto Superior Técnico, Universidade de Lisboa, 2695-066 Bobadela LRS, Portugal; 2HyLab - Green Hydrogen Collaborative Laboratory, Central Termoeléctrica, 7520-089 Sines, Portugal; 3Instituto Politécnico de Setúbal, Escola Superior de Tecnologia de Setúbal, 2914-508 Setúbal, Portugal Recent advancements in low-cost sensor (LCS) and Internet of Things (IoT)-based solutions have enabled real-time monitoring of PM and other pollutants, addressing the limitations of traditional monitoring methods. However, calibration with reference equipment is essential. This study conducted a monitoring campaign in nine classrooms (171 monitored classes) at a high school in inland Portugal. LCS-equipped monitoring boxes measured PM2.5, PM10, CO2, VOCs, temperature, and relative humidity. The results demonstrate that LCS technology can provide extensive and successful air quality monitoring without disrupting teaching, and highlight that PM thresholds are often exceeded in this microenvironment.
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Solid fuel combustion as the dominant wintertime PM2.5 source in Irish towns: insights from the TownAir project 1Centre for Climate and Air Pollution Studies, Physics, School of Natural Sciences, University of Galway, University Road, Galway H91 CF50, Ireland; 2School of Chemistry & Environmental Research Institute, University College Cork, College Road, Cork T12 YN60, Ireland The TownAir project investigates air pollution in two Irish towns, where fine particulate matter (PM2.5) from domestic heating, traffic, and industry poses health risks. In Enniscorthy, winter monitoring revealed frequent exceedances of WHO guidelines, with concentrations up to 200 μg/m3. Using an ACSM and aethalometer, we identified organic aerosols (OAs, 52%) and equivalent black carbon (17%) as major PM2.5 components. PMF analysis attributed most OA to residential combustion, while traffic emissions and secondary formation contributed smaller fractions. A follow-up campaign near Northern Ireland and comparisons with Dublin aim to inform strategies to reduce emissions and improve air quality in Ireland.
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Characteristic of water-soluble inorganic ions in size-segregated aerosols of a typical industrial and mining city in central China Hubei Polytechnic University, China, People's Republic of Water-soluble inorganic ions (WSIIs) were determined in HS atmospheric aerosols across nine size fractions. Both PM and WSIIs reached peak concentrations in winter, with autumn and winter concentrations higher than those in spring and summer. Individual WSIIs exhibit distinct size distribution characteristics The size distribution patterns of WSIIs highlight their crucial role in PM formation and suggest that both natural and anthropogenic sources contribute to their presence in the atmosphere. The seasonal variations in size distribution underscore the importance of meteorological conditions and emission sources in shaping aerosol characteristics.
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High Optical and Temporal Resolution Investigations into Non-Ideal Resuspension Phenomena 1University of Bristol, United Kingdom; 2Defence Science and Technology Laboratory, United Kingdom A novel methodology is employed to investigate the impact of particle-specific features on resuspension, partnering a quadrupole electrodynamic trap for controlled particle fabrication and deposition with a small-scale 3D printed wind tunnel. The resuspension behaviour of two distinct particle morphologies featuring cubic structures were investigated and the resulting resuspension efficiencies demonstrate the challenges of resuspending non-spherical particles. Additional high optical and temporal resolution measurements of particle detachment were recorded with high frame rate imaging to analyse particle orientation, particle-surface contact and particle rotation during resuspension. Together these two methodologies advance our understanding of non-ideal resuspension phenomena.
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On the origins of atmospheric secondary organic aerosol (SOA): Double bonds facilitate rapid functionalization to aerosol precursors 1Department of Chemistry, University of Helsinki, Helsinki, 00014, Finland; 2Aerosol Physics Laboratory, Tampere University, Tampere, 33720, Finland We have performed flow reactor investigations of three cyclic hydrocarbon autoxidation reactions under several short reaction times. A rich variety of oxidation products were recorded with several chemical ionization mass spectrometric methods.
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Flavor-Induced Inflammation and Cytotoxicity in Human Aortic Smooth Muscle Cells: Implications for E-Cigarette Safety 1Mines Saint Etienne, France; 2CHU de Saint Etienne
E-cigarettes are marketed as safer than tobacco, but their cardiovascular effects remain unclear. Our study examined the impact of e-liquids and aerosol condensates with different PG/VG ratios, nicotine levels, and flavors (cinnamon, menthol, tobacco) on human aortic smooth muscle cells. Cytotoxicity (LDH release) and pro-inflammatory response (IL-8 production) were measured. Aerosol condensates, especially with cinnamon and high power settings, induced significant cytotoxic and pro-inflammatory effects.
E-liquids had milder effects, suggesting that thermal degradation amplifies toxicity.
These findings highlight the role of flavors and their degradation products in the cardiovascular risks of e-cigarettes.
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Review of the mass absorption cross-section literature for mixed atmospheric black carbon 1Finnish Meteorological Institute, Finland; 2Metrology Research Centre, National Research Council Canada, Ottawa, Canada; 3Laboratory Particles and Aerosols, Federal Institute of Metrology METAS, Bern, 3003, Switzerland; 4University of Applied Sciences and Arts Northwestern Switzerland, CH-5210 Windisch, Switzerland; 5Air Quality and Aerosol Metrology Group, National Physical Laboratory, Teddington, TW11 0LW, UK; 6Atmospheric Microphysics Department, Leibniz Institute for Tropospheric Research, 04318 Leipzig, Germany; 7Center for Atmospheric Research, University of Nova Gorica, Nova Gorica, 5270, Slovenia; 8Haze Instruments d.o.o., Ljubljana, 1000, Slovenia; 9Department of Environmental Sciences, Jozef Stefan Institute, Ljubljana, 1000, Slovenia; 10Institute of Nuclear Technology and Radiation, NCSR Demokritos, Paraskevi, Attiki, 15310, Greece; 11Physikalisch-Technische Bundesanstalt, 38116 Braunschweig, Germany We compile more than 200 MACBC values from 63 studies and explore the effects of sampling location, study duration, instrumentation (photometers, photoacoustic; mass concentration (CBC) from thermal-optical analysis, or SP2), measurement wavelength, thermal–optical protocol. The data show that photoacoustic measurements of MACBC were consistently higher in remote relative to urban environments, indicating Eabs>1 in remote environments, as expected. This trend was not evident for filter-based measurements, and few other clear trends could be identified in general. Notably, wavelength-dependent trends were not evident. Our results do not support the use of simplistic generalizations or assumptions about MACBC in the atmosphere.
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Atmospheric New Particle Formation Enhanced by Tricarboxylic Acids Aarhus University, Denmark This study investigates the role of tricarboxylic acids in new particle formation (NPF) within secondary organic aerosols (SOA). Using quantum chemical methods, we examined three tricarboxylic acids - carboxyheptanoic acid (CHA), 3-methyl-1,2,3-butanecarboxylic acid (MBTCA), and pinyl diaterpenylic ester (PDPE). The results suggest that these acids can act as organic nucleators in combination with sulfuric acid (SA) and bases like ammonia or amines. Our results show strong clustering interactions, indicating that acid-base interactions remain crucial even with organics present. Further research using the Atmospheric Cluster Dynamics Code will explore the importance of these tricarboxylic acids for NPF in more depth.
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Coagulation of combustion-generated carbonaceous nanoparticles of ethylene and ethylene/ethanol flames in an atmospheric simulation chamber 1STEMS-CNR, Italy; 2INFN, Italy; 3DICMAPI, Italy; 4Dipartimento di Fisica "Ettore Pancini”, Unina, Italy; 5Dipartimento di Fisica, Unige and INFN, Italy Biofuels can emit ultrafine particles with distinct features compared to conventional fossil fuels. In this work, coagulation of soot nanoparticles was experimentally and numerically investigated using an atmospheric simulation chamber. Nanoparticles were produced in a laboratory flame of ethylene and ethylene/ethanol mixtures. Simulations based on Smoluchowski equation show that ethylene-flame particles coagulate with an enhancement factor β=2.2, while a larger β=2.6 is found for ethanol-doped flame. Fractal dimension optimization with a fixed β=2.2 also shows good agreement with experiments. These differences point to distinct surface functionalities potentially impacting particle-particle interaction or differences in particles' fractal properties to be further investigated.
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Effect of gas absorption on evaporation of acoustically levitated slurry droplets at constant and falling rate periods of drying 1Ben-Gurion University of the Negev, Israel; 2Otto von Guericke Universität Magdeburg The process of drying suspension droplets includes two stages. The first stage starts when a slurry droplet is injected into a drying chamber, while the second stage begins when solid particles form an agglomerate. In this study, we developed models of convective heat and mass transfer of an acoustically levitated slurry droplet that evaporates in an atmosphere of air, water vapor, and soluble gas. It has been shown that the drying rate increases in the presence of active gas. We also found that drying time increases with increasing frequency and decreases with increasing sound pressure of the applied acoustic field.
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Personal dose during cardiovascular exercise School of Chemical and Environmental Engineering, Technical University of Crete, Greece People usually practice outdoors, thus exercising in the ambient environment becomes another proxy for human health hazard. It is generally accepted that there is a trade-off between air pollution and exercise, which relates to a threshold beyond which the benefit of exercising becomes negative.Τhe present work investigated the personal dose received by trainees during exercise in the outdoor environment. Dosimetry simulations were performed for different levels of physical exertion and particle mass concentrations for males and female trainees.
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Photooxidation of Biomass Burning Emissions: Secondary Organic Aerosol Formation under varying NOx levels 1Leibniz Institute of Tropospheric Research e.V., Germany; 2Institute of Physical Chemistry, Polish Academy of Sciences, Poland; 3New Mexico State University, United States of America Biomass burning (BB) contributes significantly to atmospheric aerosol through primary emissions and secondary organic aerosol (SOA) formation during aging in the atmosphere. One crucial parameter for SOA formation and properties is the availability of NOx. Thus, the OH oxidation of BB emissions was studied under varying NOx levels. Burning experiments of different fuels were performed in a residential heating stove and the resulting emissions were diluted and introduced into an atmospheric simulation chamber. Aerosol mass spectrometry was used for a detailed analysis of the organic aerosol phase, showing changes in aerosol oxidation state and composition at different NOx levels.
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Time-resolved measurements reveal the evolving oxidative potential of indoor-generated aerosols under simulated photochemical ageing 1Department of Environmental Sciences, University of Basel, 4056 Basel, Switzerland; 2Centre for Atmospheric Science, Department of Earth and Environmental Sciences, University of Manchester, Manchester M13 9PL, United Kingdom; 3Joint Mass Spectrometry Center (JMSC) at Comprehensive Molecular Analytics (CMA), Helmholtz Zentrum München, Munich, 85764, Germany; 4Division of Cardiovascular Science, School of Medical Sciences, Faculty of Biology Medicine and Health, University of Manchester, Manchester Academic Health Science Centre, Manchester M13 9PL, United Kingdom; 5Lydia Becker Institute of Immunology and Inflammation, Faculty of Biology, Medicine and Health, University of Manchester, Manchester Academic Health Science Centre, Manchester M13 9PL, United Kingdom; 6MRC Centre of Environment and Health, Environmental Research Group, Imperial College London, London W12 0BZ, United Kingdom Exposure to indoor-generated aerosols is a public health concern, yet they remain underexplored compared to ambient pollution. We performed smog chamber experiments at the Manchester Aerosol Chamber to investigate how photochemical ageing influences the oxidative potential (OP) of aerosols from cooking, cleaning, and candle burning. Using high time-resolution instruments for measuring OP, we found that photochemical ageing elevates aerosol mass and OP on both a per-volume and per-mass basis. Once photochemistry ceased, OP decreased by about 40% within an hour, revealing the rapid decay of short-lived OP-active species and underlining the dynamic toxicity of indoor-generated aerosols.
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Agricultural fire impacts on brown carbon during different seasons in Northeast China Harbin Institute of Technology, China, People's Republic of Brown carbon (BrC) aerosols were explored in the northernmost megacity in China during two agricultural-fire-impacted seasons. Agricultural fires resulted in distinct peak in BrC's light absorption spectra at 365 nm, and enhanced the mass absorption efficiency of brown carbon (MAE). The enhancement was more efficient by fires with higher combustion efficiencies. After taking CE into consideration, Fire impacts on MAE showed converged patterns for different seasons. The presence of the ∼365 nm peak also complicated the determination of absorption Ångström exponents (AAE). The ~365 nm peak became much less significant during the day, likely due to photobleaching of the relevant chromophores.
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Characteristics and source apportionment of water-soluble inorganic ions in TSP during the lockdown episode for epidemic outbreak of COVID-19 in Wuhan, 2020 1School of Environmental Science and Engineering, Hubei Polytechnic University, Huangshi, 435003, China; 2State Key Laboratory of Biogeology and Environmental Geology, China University of Geosciences, Wuhan, 430074, China; 3Department of Earth Sciences, Environment and Resources, University of Naples Federico II, Naples, 80125, Italy The lockdown held due to the COVID-19 PO3: 16
Climatology of aerosol optical properties in Cyprus based on aerosol type classification from AERONET and Lidar data 1Eratosthenes Centre of Excellence, Cyprus; 2Department of Civil Engineering and Geomatic, Cyprus University of Technology, Limassol, 3036, Cyprus A model for aerosol typing based on optical AERONET measurements is presented. It uses two main optical properties retrieved at several wavelengths by CIMELs of the network: the Single Scattering Albedo and the Angstrom Exponent. It is obtained by a Machine Learning methodology. It is then applied to the data of CIMEL in Limassol (Cyprus). we found the relative presence of various aerosol types in there. To cross-validate the ML method we use the optical data of a collocated depolarization Raman Lidar. the two have also been used to obtain a climatology of other optical properties from AERONET and Lidar.
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Distinguishing the air quality impact from different types of stove for residential heating in central Italy 1Regional Environmental Protection Agency; 2Spanish Research Council (CSIC); 3Sapienza University of Rome In Italy, domestic heating uses often wood (17%) and pellets (7.3%) and in most cases (about 70%), conventional fireplaces or stoves are still used. This study investigates the impact of different types of stoves on local air quality in two different areas of Lazio Region in central Italy (Rome and Sacco Valley) analyzing existing datasets of PM chemical characterization. The results highlight the importance of the role of different types of biomass heating systems and suggest that further investigations can provide important information for adopting best practices to reduce harmful effects on health and environment.
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Eulerian model of dilute suspensions of electrified particles Universidad Politécnica de Madrid, Spain We present an analysis of the suspension of small, electrified solid particles in a gas.
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Evaluating the impact of thermal conditions on emissions from tobacco heating systems CERTH, Greece This study evaluates the impact of thermal conditions on emissions from heated tobacco products (HTPs) using a custom experimental heating device. HTPs operate below combustion temperatures (~300 °C), but combustion onset and soot formation were observed at 400 °C under ambient conditions. A catalytic stripping (CS) system was used to isolate solid particles from volatile emissions. Advanced measurement techniques analyzed particle number, soot mass, and gas concentrations. Results confirm that thermal degradation dominates below 400 °C, while combustion occurs above this threshold. These findings enhance understanding of HTP emissions and inform strategies to minimize harmful byproducts in tobacco heating systems.
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Inflammatory effects of Saharan dust in co-cultures: the role of microbial constituents 1IUF – Leibniz Research Institute for Environmental Medicine, Düsseldorf, Germany; 2Leibniz Institute DSMZ - German Collection of Microorganisms and Cell Cultures, Microbial Genome Research Braunschweig, Germany We investigated the role of microbial components in the inflammatory potency of Saharan dust (SD). On the basis of the microbial composition of SD microbial cocktail, composed of Gram-positive and Gram-negative bacteria and fungi were prepared. The SD was then tested in a co-culture model of A549 lung epithelial cells and THP-1 macrophages in quasi air liquid interface exposure conditions. Heat-inactivation of SD abrogated the increased secretion of IL‑1β and IL-8, and this could be restored upon addition of microbial mixtures to the heat-inactivated SD. Our results support importance of microbial constituents in the inflammatory effect of SD.
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Influence of the acceleration of the flow on microparticle resuspension 1OPAALE Research Unit, INRAE, Rennes, 35044, France; 2GEPEA, CNRS, IMT Atlantique, Nantes, 44300, France This study inverstigates the resuspension of microparticles submitted to accelerated flows. Existing study on particle resuspension usually omit the transient phase needed to reach the velocity of interest, yet it was shown that resuspension starts before reaching the steady phase. Moreover, turbulence usually appears during the acceleration phase and the onset of turbulence depends on the acceleration parameter. We investigate experimentally how the acceleration affects the flow and thus how it affects resuspension using smooth glass microparticles.
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Investigation of particle collisions in air-flow resuspension phenomena with 4000Hz frequency acquisition camera 1Autorité de Radioprotection et de Sûreté Nucléaire, France; 2UMR CNRS 6614 CORIA, France In present work the key role of particle collisions effect during particle resuspension by turbulent airflow for monolayer deposit is investigated using high speed camera and image processing. The experiments are realised in a dedicated wind tunel for velocities between 1 and 3.5 m/s and particle median diameter of 36 µm. Set of particle trajectories are determined to calculate collision frequencies according to surface concentration and particle size distribution.
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Long-term characterization of Lung Deposited Surface Area of Ultrafine Particles in Athens, Greece 1National Observatory of Athens, Greece; 2Department of Environment, University of the Aegean, Mytilene, Greece Ultrafine particles (UFPs, ≤0.1µm) pose significant health risks due to their deep penetration into the lungs, yet they are often overlooked in studies of air pollution. 7-year data from Athens, Greece is analyzed to calculate the lung deposition surface area (LDSA), using measured PNSD and ICRP/MPPD models. The majority of UFPs are deposited in the alveolar region, highlighting the potential impact on health. PMF source apportionment identified vehicular traffic as the main contributor (60%) to LDSA. Long-term trends provide insight into urban aerosol exposure, emphasizing the need for targeted mitigation strategies to reduce the health risks associated with UFPs.
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Measurements of Surrogate Respiratory Sessile Droplet pH and Implications for Exhaled Respiratory Aerosol and Airborne Disease Transmission 1School of Chemistry, University of Bristol, Bristol, BS8 1TS, United Kingdom; 2Institute for Atmospheric and Climate Science, ETH Zürich, CH-8092, Zürich, Switzerland; 3Physical and Theoretical Chemistry Laboratory, South Parks Road, OX1 3QZ, United Kingdom The respiratory aerosol pH (above 9) has been proposed as a major driver for the infectivity loss of SARS-CoV-2 viruses and influenza A virus in exhaled aerosols, thus affecting the airborne transmission of respiratory diseases. Despite several studies utilising Raman spectroscopy to quantify atmospherically relevant aerosol pH, there is limited understanding of the kinetics of CO2 partitioning and pH variability within respiratory fluid-relevant droplets. In this work, a method to investigate the HCO3-/CO32- equilibrium in a surrogate respiratory fluid system within sessile droplets is proposed to elucidate the pH evolution of exhaled respiratory aerosol.
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Modeling Road Traffic Contributions to PM2.5 and Particle Number with LOTOS-EUROS TNO, Department of Air quality and Emissions Research, Utrecht, the Netherlands Road traffic significantly contributes to ultrafine particles and PM2.5. The impact of volatile organic compounds (VOCs), especially intermediate (IVOC) and semi-volatile (SVOC) organic compounds, on particle mass and number is uncertain due to incomplete emission inventories and simplified chemistry-transport model parameterizations (CTMs). The EASVOLEE project updated the LOTOS-EUROS CTM to better represent organic aerosol (OA) formation and particle size/number from road traffic. This includes the CB7 chemistry scheme, VBS scheme, and SALSA2 module. Future steps involve coupling organic vapors with SALSA2 and using new road emission data to assess road transport's contribution to particle concentrations and PM2.5 over Europe.
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Modelling Atmospheric Cluster-to-Particle Transition Aarhus University, Denmark The point at which a given assembly of molecules represents a molecular cluster, or a particle
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Multi-year gradient measurements of sea spray fluxes over the Baltic Sea and the North Atlantic Ocean 1Institute of Oceanology Polish Academy of Sciences, Poland; 2Department of Environmental Science, Stockholm University, Stockholm, Sweden; 3University of Milano-Bicocca, Milan, Italy; 4Bolin Centre for Climate Research, Stockholm, Sweden; 5Baltic Sea Centre, Stockholm University, Stockholm, Sweden; 6Uppsala University, Uppsala, Sweden Ship-based measurements of sea spray aerosol (SSA) fluxes (0.5–47 µm) from 2009–2017 in the Baltic Sea and North Atlantic Ocean revealed lower SSA emissions in the Baltic. Elevated chlorophyll-a levels, indicating higher biological activity, reduced SSA fluxes, especially under strong winds. Wind speed, wave dynamics, and wave age were key factors, with younger Baltic Sea waves generating more SSA. Temperature and atmospheric stability showed weaker correlations. This study provides the first detailed comparison of SSA emissions between these regions, highlighting the need for region-specific models to predict aerosol fluxes and their climatic implications. Markuszewski P. et al. ACP, 2024. https://doi.org/10.5194/acp-24-11227-2024
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Size Ratio Dependent Enhancement Factor of Ultrafine Aerosol Coagulation Rates by Van der Waals Potential The University of Texas at Dallas, United States of America Unequal-size nanoparticle coagulation plays a crucial role in atmospheric aerosol processes, influencing cloud condensation nuclei formation, aerosol growth and scavenging through coagulation. This study examines the impact of van der Waals (VDW) forces on coagulation enhancement factors using NaCl as a model aerosol. Theoretical modeling and chamber experiments show that enhancement factors vary with particle size and the size ratio of the coagulating pair, deviating from continuum and free molecular models. Assuming a size ratio-independent enhancement factor introduces minimal error (<15%) when nanoparticles coagulate with larger ones rather than smaller ones. These findings enhance the accuracy of coagulation rate predictions in aerosol modeling.
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Size-resolved PM Composition and sources in Saxony, Germany: A Decadal Comparison (2013/14 vs. 2023/24) Leibniz-Institut für Troposphärenforschung e.V. (TROPOS), Germany PM2.5 and PM10 remain key air pollutants in Europe, often exceeding WHO air quality guidelines despite emission reductions. This study investigates size-resolved PM concentrations, chemical composition and PM sources at three sites in Saxony, Germany, comparing 2023/24 data to 2013/15. PM10 levels were lower across all sites, particularly with eastern air masses, suggesting reduced anthropogenic contributions. Carbonaceous aerosols at the traffic site decreased significantly, reflecting changes in the local contribution of this PM source from direct exhaust emissions. These findings provide insights into long-term air quality trends. Detailed source apportionment will help determine changes in the contribution of each sector.
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Sparsity introduction in Bayesian Autocorrelation Matrix factorization for organic aerosol source apportionment 1Center for Atmospheric Research, University of Nova Gorica, Ajdovščina, 5270, Slovenia; 2Atmospheric Composition Research, Finnish Meteorological Institute, 00101 Helsinki, Finland; 3Faculty of Computer and Information Science, Tržaška Cesta 25, 1000 Ljubljana, Slovenia; 4Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen PSI, Switzerland; 5School of Ecological and Environmental Sciences, East China Normal University, 200241, Shanghai, China The Positive Matrix Factorisation (PMF) algorithm (Paatero and Tapper, 1994) has been the most widely used receptor model for a long time and has only recently been challenged with new methodologies. The novel Bayesian auto-correlated matrix factorisation method (BAMF, Rusanen et al. 2024) integrates an auto-correlation term emulating real-world pollutant sources time evolution has produced higher accuracy compared to PMF. However, both PMF and BAMF struggle to provide well-separated profiles manifested as mixed time series contributions. This work aims to introduce an sparsity prior called horseshoe regularisation (Piironen and Vehtari, 2017) on BAMF in order to improve profile unmixing.
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Spatial variability of aerosol optical properties in the European Arctic 1Department of Environmental Sciences, Informatics and Statistics, Università Ca’ Foscari, Mestre, 30100, Italy; 2Institute of Polar Sciences, National Research Council, Milan, 20156, Italy; 3Department of Environmental Science, Stockholm University, Stockholm, 10691, Sweden; 4Institute of Polar Sciences, National Research Council, Bologna, 40129, Italy; 5Norwegian Institute for Air Research, Kjeller, 2027, Norway This study examines the vertical variability of aerosol optical properties from 2018 to 2023 near Ny-Ålesund, Svalbard, using observations at two sites: Gruvebadet (61 m) and the Zeppelin Observatory (475 m). Scattering coefficients were measured using an integrating nephelometer, while absorption coefficients were obtained using MAAP, PSAP, and AE33. Seasonal trends reveal that both coefficients are enhanced during the cold season due to Arctic haze from mid-latitude pollution. Radiosonde data indicate that in winter thermal inversions, Zeppelin experiences higher scattering coefficients. In the warm season, Gruvebadet consistently shows higher scattering and absorption when Zeppelin is cloud-surrounded due to scavenging effect.
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Using clustering approaches to dynamically determine the number of sources of organic aerosol in PMF analyses 1MRC Centre for Environment and Health, Environmental Research Group, Imperial College London, London, W12 0BZ, UK; 2Datalystica Ltd., Park innovAARE, Villigen, Aargau 5234, Switzerland; 3PSI Center for Energy and Environmental Sciences, Paul Scherrer Institute, 5232 Villigen, Switzerland; 4NIHR HPRU in Environmental Exposures and Health, Imperial College London, UK PMF is widely used to apportion aerosol sources, while current PMF techniques still struggle to adapt to changing source profiles over time. This study proposes a new method that combines PMF with machine learning to dynamically determine the number of sources, leading to more accurate source identification and quantification. Tested on European datasets, the method showed potential to improve PMF results via better-separating sources like cooking activities, and biomass burning. Wider adoption of this approach promises to enhance air quality models, health assessments, and policymaking by providing a clearer picture of PM2.5 sources in diverse environments.
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Atmospheric reactive nitrogen and its dry deposition regimes under emission reduction: Insights from intensive and long-term monitoring in Switzerland 1Laboratory of Atmospheric Processes and their Impacts (LAPI), Ecole Polytechnique Fédérale de Lausanne (EPFL), Lausanne, Switzerland; 2Empa, Swiss Federal Laboratories for Materials Science and Technology, 8600 Dübendorf, Switzerland; 3PSI Center for Energy and Environmental Sciences, 5232 Villigen PSI, Switzerland Fifteen years of long-term measurements at an agricultural site in Switzerland revealed trends in nitrogen deposition and aerosol chemistry, complemented by high time-resolution observations. Aerosol pH was lower in summer due to meteorological factors, while NH₃ buffering prevented an expected pH increase despite declining SO2 emissions. HNO3 partitioned into particles at night, whereas NH3 remained in the gas phase, regulated by high aerosol pH. Seasonal variations in dry deposition showed faster nitrate removal in summer, while ammonium consistently deposited rapidly. These findings highlight the complex interactions governing nitrogen deposition and aerosol acidity, informing strategies for air quality management.
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Comparative genome copies reduction of MS2 and T4 Bacteriophages Using UVA and UVC in a Controlled Atmospheric Chamber: Implications for Indoor Air Hygiene 1Leibniz Institute for Tropospheric Research e.V. (Leibniz-Institut für Troposphärenforschung e.V.), Germany; 2UFZ, Department of Environmental Microbiology, Helmholtz Centre for Environmental Research, Permoserstrasse 15, 04318 Leipzig, Germany; 3Institute of Virology, Faculty of Medicine, Leipzig University, Johannisallee 30, 04103 Leipzig, Germany Our results show that conducting experiments in a 19 m3 atmospheric volume comparable to real-world indoor environments, combined with the use of a mucin mixture to simulate human respiratory emissions, significantly increases the required UV dose for effective genome copy reduction compared to studies using small-scale reactors. These findings are crucial for designing effective UV-based air disinfection systems, as they provide more realistic dose requirements necessary for mitigating airborne virus transmission in indoor spaces.
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Evaluation of the PM mitigation using a green barrier in a high traffic site 1RSE S.p.A., Italy; 2University Milano-Bicocca, Italy; 3Fondazione Lombardia per l’Ambiente, Italy The study investigates air pollution mitigation using a green barrier along Viale Fulvio Testi, a high-traffic area in Milan, within the “TESTI” project framework. Preliminary data collection measured PM10, PM2.5, PM1, black carbon, and gaseous pollutants using various instruments. Results showed peak pollution levels during rush hours, with a PM2.5/PM10 ratio of 0.65 due to traffic-induced resuspension. Vertical and horizontal particle profiles indicated a 20% reduction in ultrafine particles (≤50 nm) behind the vegetation. These findings highlight the potential of urban greenery in reducing airborne pollutants and provide insights for designing effective green barriers in urban environments.
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Gaining insights into filter-based measurements of the aerosol absorption coefficient: an integrated approach 1Department of Physics – Università degli Studi di Milano and INFN, Milan, Italy; 2Department of Physics – Università degli Studi di Genova and INFN, Genoa, Italy; 3Department of Physics and Astronomy, University of Florence and INFN - Florence, Sesto F.no (FI), Italy In this work we performed sensitivity tests on a free parameter needed to obtain aerosol light absorption measurements by on polar photometry. We tested aerosol emitted by a moto-generator in an atmospheric simulation chamber and collected in parallel on different types of filters (both fibre and membrane filters). Light-absorption characteristics of emissions by different fuels were investigated (i.e. diesel and HVO available in petrol stations). After measurement optimisation, the role of particle size distribution on Ångström Absorption Exponents (AAE) was experimentally investigated and the results were corroborated using discrete dipole approximation simulations considering different geometric assumptions.
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Giant Particle Size Distribution and Composition Near and In Dust Sources 1Technical University Darmstadt, Institute of Applied Geosciences, Darmstadt, Germany; 2Karlsruhe Institute of Technology (KIT), Institute of Meteorology and Climate Research, Troposphere Research (IMKTRO), Germany; 3Freie Universität Berlin, Institute of Meteorology, Berlin, Germany; 4Barcelona Supercomputing Center (BSC), Barcelona, Spain; 5Danish Meteorological Institute (DMI), Copenhagen, Denmark; 6Institute of Environmental Assessment and Water Research – Consejo Superior de Investigaciones Científicas (IDAEA-CSIC), Barcelona, Spain; 7Agricultural University of Iceland, Environmental Sciences, Reykjavik, Iceland; 8Catalan Institute for Research and Advanced Studies (ICREA), Barcelona, Spain Mineral dust is one of the key players in the Earth’s atmosphere. Dust spans a large size range of particle diameters from 100 nm to more than 100 µm. Owing to the negligence and difficulty in measurement, few information is available on the super-coarse and giant dust size range. We collected deposition samples from field campaigns inside Saharan, Arabian and Arctic dust sources and analyzed them by electron microscopy for size and composition. We present size distributions along with particle composition, e.g. minor compositional differences between Arabian and Saharan dust, or coarser particles particular in the Arctic.
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FROM BIOMASS PELLETS TO AIR POLLUTION: HOW FUEL QUALITY DETERMINES EMISSIONS 1Institute of Environmental Engineering, Polish Academy of Sciences in Zabrze, M. Skłodowskiej-Curie 34 St, 41-819 Zabrze, Poland; 2University of Silesia in Katowice, Faculty of Natural Sciences, Będzińska 60 St, 41-200 Sosnowiec, Poland; 3Indiana University, Indiana Geological and Water Survey, 1001 E. 10th St, Bloomington, IN 47405, United States; 4Centre for Biomass Energy Research and Education, University of Silesia in Katowice, Będzińska 60 St, 41-200 Sosnowiec, Poland In light of climate goals, biomass pellets are promoted as renewable energy sources, yet their combustion may emit harmful pollutants. This study assessed 30 wood and non-wood pellets sold in Poland, revealing major quality inconsistencies—even among certified products. Many failed key standards due to high ash content, poor durability, or contamination. Emission tests showed that especially agro-pellets release excessive levels of PM, CO, NO₂, H₂S, NH₃, Cl₂, SO₂, and HCHO. Statistical models linked emission levels to pellet properties. The findings underscore the need for stricter certification, better labeling, and advanced quality control to ensure cleaner biomass energy and protect public health.
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Spatial variability of air pollution from residential heating in a small settlement in the Czech Republic Czech hydrometeorological Institute, Czech Republic Detailed air quality monitoring in a small settlement Rožďalovice was conducted in February 2024. Measurements were carried out simultaneously at four locations throughout February. The aim of the study was to assess the spatial variability of benzo(a)yrene (BaP) and PM10 concentrations in small municipalities during the heating season. A preliminary evaluation of the data reveals significant differences in PM10 and BaP concentrations between the monitoring sites. The findings provide valuable insights into the limited representativeness of measurements in areas influenced by local heating sources, also known as 'village hot spots.
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Investigation of coating thickness and black carbon mass absorption cross-section variation during winter campaign in Ljubljana (Slovenia) 1University of Nova Gorica, Slovenia; 2Haze Instruments d.o.o., Slovenia; 3Aerosol d.o.o., Slovenia; 4Finnish Meteorological Institute, Finland An ambient measurement campaign was conducted in an urban background site in Ljubljana (Slovenia) during winter 2024/2025. The aim was to determine the influence of coating on absorption enhancement of black carbon and to investigate the factors influencing the generation of coating. The coating thickness was measured by selecting particle mass using CPMA and measuring rBC with SP2-XR. Photothermal interferometer PTAAM-2λ was used to measure aerosol absorption. First results show a varying mixture of moderately and highly coated particles.
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Long-term composition and optical properties of Amazonian aerosols measured at the ATTO tower 1Institute of Physics, University of Sao Paulo, Brazil; 2Multiphase Chemistry Department, Max Planck Institute for Chemistry, 55128 Mainz, Germany In central Amazonia, aerosol sources, weather, and chemical processes create a highly variable aerosol population. This study connects aerosol optical measurements from the Amazon Tall Tower Observatory (ATTO), at 60 and 325 m heights, to particle composition and sources, characterizing different aerosol populations, assessing their vertical gradients, and associating them with the influence of various emission sources and atmospheric processes. TSI SMPS, AE33 Aethalometers, Ecotech nephelometers, and Aerodyne ACSM monitors were continuously operated at 60 and 325 meters in height. The results show a complex mixture of biogenic sources with organic aerosols from VOC oxidation.
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Physico-chemical characterization of indoor airborne particulates emitted in plastics processing workplaces 1C.N.R. Institute of Atmospheric Pollution Research, Monterotondo St., Rome, 00015, Italy; 2University of Cassino and Southern Lazio Dep. of Civil and Mechanical Engineering, Cassino (FR), 03043, Italy; 3Italian Workers‘ Compensation Authority, Rome, 00143, Italy Through the CELLOPHAN project indoor airborne particulate matter (PM) with special focus on micro-nano particles (MNP) emitted by different workplaces has been investigated and analysed by different techniques. Optical particle counters (OPC) were employed to detect particle concentrations, whereas filter PM samples were analysed by Electron microscopy and microanalysis (SEM-EDS). Three different site types were considered for each workplace in order to represent different exposure conditions (direct emission, average exposure, office). Results of particle size and number concentration obtained with different techniques were cross-compared and some preliminary results are reported in this contribution.
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PM10 and PM2.5 variability over Italy (2021–2023): Data-driven mapping and causal inference analysis CNR-ISAC, Italy This study proposes high-resolution daily maps of PM2.5 and PM10 concentrations covering the Italian territory from 2021 to 2023 at ~1 km spatial resolution. The work uses machine learning models trained on data from over 300 monitoring stations combined with spatial and spatiotemporal predictors such as land cover, human presence, elevation, atmospheric state, and aerosol optical depth. Among the evaluated models, Ensemble Bagged Trees explained up to 67% of PM variance. The SHAP analysis identifies key predictors impacting the PM variations. These findings improve air quality assessments and policymaking by increasing understanding of PM variability and its underlying causes.
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Predicting the influence of the Planetary Boundary Layer at the Helmos Hellenic Atmospheric Aerosol & Climate Change (HAC)2 station using a combination of in-situ measurements and remote sensing techniques 1Environmental Radioactivity & Aerosol Tech. for Atmospheric & Climate Impacts, INRaSTES, National Centre of Scientific Research “Demokritos”, Ag. Paraskevi, 15310, Greece; 2LAPI, School of Architecture, Civil and Environmental Engineering, École Polytechnique Fédérale de Lausanne, Lausanne, Switzerland; 3Institute for Chemical Engineering Sciences, Foundation for Research and Technology, Patras, Greece; 4Department of Environmental Science, Stockholm University, Stockholm, Sweden; 5Finnish Meteorological Institute, Kuopio, FI-70211, Finland; 6Laser Remote Sensing Unit, Physics Department, National Technical University of Athens, GR-15780 Zografou, Greece The Helmos Hellenic Atmospheric Aerosol and Climate Change ((HAC)²) station in Greece (2314 m a.s.l.) is the only high-altitude station in the eastern Mediterranean, suitable for climate change-related studies. Two intensive campaigns with the scope of unravelling aerosol-cloud interactions took place at (HAC)2 station; the CALISHTO campaign during autumn-winter 2021-2022 and the CHOPIN campaign during autumn-winter 2024–2025. This study establishes a set of metrics for identifying the influence of Planetary Boundary Layer at (HAC)2 by a synergy of in-situ and remote sensing measurements and applying a statistical model to test their effectiveness.
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Source assessment of atmospheric lead reaching Ny-Ålesund (Svalbard) University of Genoa, Italy PM10 has being sampled in Ny-Ålesund (Svalbard, Norwegian Arctic) since 2010 to assess sources, transport pathways and seasonal variations of pollutants. The latest findings (2022-2024) are here presented. Samples were analyzed for lead content and isotopic composition, evaluating the potential source areas of aerosol. The main contribution of Pb was anthropogenic, with a relevant seasonal trend both for concentration (higher in winter-spring) and geographical origin (Russia in winter-spring, with North American contributions in summer). Preliminary results from the analysis of wet depositions and surface snow samples highlighted the influence of Rain-On-Snow events on the local environment.
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Volatility of molecular components of Pinene SOA modulated by inorganic seed composition 1PSI Center for Energy and Environmental Sciences, Paul Scherrer Institute (PSI), 5232 Villigen, Switzerland; 2Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, United States; 3Environmental Chemistry and Air Research, Technische Universität Berlin, 10623 Berlin, Germany The Log C*eff of a molecule represents an important atmospheric variable. The oxidation of volatile organic compounds creates a complex mixture, making C* determination challenging. Furthermore, SOA can be mixed with inorganic salts, impacting the non-ideality of the aerosols. We have generated SOAs in an atmospheric simulation chamber and determined the C*eff’s of the underlying SOA with either ammonium sulfate or iron/ammonium sulfate seed aerosols. The presence of iron in the seed exhibits non-ideal interactions resulting in ~x10 decrease in C*, which indicates that knowing the underlying seed composition is important for understanding C*eff.
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A new approach for source apportionment of Black Carbon from Raman Spectroscopy 1Department of Environment, Land and Infrastructure Engineering (DIATI), Polytechnic of Turin,; 2Department of Applied Science and Technology (DISAT), Polytechnic of Turin; 3Department of Economics and Statistics “Cognetti de Martiis”, University of Turin Black Carbon is a major contributor to air pollution and climate change. Current techniques using an Aethalometer can differentiate biomass burning and fossil fuel combustion aerosols, but their accuracy is limited by assumptions and BC properties. This study explores using Raman spectroscopy, statistical analysis and machine learning to improve BC source apportionment, considering more BC emission sources: diesel, gasoline, and biomass burning. Preliminary results indicate over 95% accuracy in classifying BC sources, providing a promising innovative method for effective air quality management.
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Developing an algorithm to determine woodsmoke events Environmental Modelling Sensing and Analysis, TNO, Petten, The Netherlands It is challenging to distinguishing woodsmoke from other sources. Levoglucosan (specific marker of woodsmoke) is determined on 24-hour filters, lacking high temporal resolution. In this study, we developed an algorithm to automatically identify woodsmoke events from measured black carbon and particulate matter concentrations. The ACSM (estimating levoglucosan from m/Q channel 60) was used to verify the algorithm showing that it performed very well. In an ongoing campaign, we assess whether woodsmoke events can be distinguished by combining BC and PM sensors. By integrating spatially resolved measurements, we aim to provide actionable insights into localized pollution patterns, enabling targeted interventions.
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Distinguishing Total and Solid Particle Emissions from Household and Office Devices using a Catalytic Stripper 1Catalytic Instruments GmbH & Co.KG, 83026 Rosenheim, Germany; 2Stanford University, Department of Engineering, Stanford, CA 94305, United States; 3Minnesota State University, Mankato, MN 56001, United States People spend most of their time indoors where they are exposed to a very complex mixture of aerosol. Especially household appliances which produce heat, like toasters, hair driers, and also printers, are prone to generate a large number of particles. Here we present various studies on household and office devices, like a printer, where we used a Catalytic Stripper in combination with other particle measurement techniques to determine the concentration and size of solid and semi-volatile particles. This information could help to develop new mitigation strategies and foster future particle emission regulations for household and office devices.
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Elevated NOx concentration in urban plumes increases volatility of secondary organic aerosol over the suburban region 1South China Institute of Environmental Sciences, China, People's Republic of; 2Guangdong Provincial Academy of Environmental Science; 3Jinan University In this study, we investigated how increased NOx level within urban plumes affect the evolution of OA volatility at a downwind site. Source analysis was performed on the thermogram data of organic compounds measured by a FIGAERO-CIMS. Increasing NOx levels mainly affected the SOA formation through gas-particle partitioning, suppressing the formation of low-volatile organic vapors, and thus promoting the formation of relatively high volatile OA. The rise in FIGAERO OA volatility in the afternoon was predominantly driven by high-NOx-like pathway, especially during the urban air masses period.
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Characterizing Aerosol Optical Properties at the Payerne Monitoring Site Using Polarimetric Observations 1PSI Center for Energy and Environmental Sciences, 5232 Villigen PSI, Switzerland; 2Federal Office of Meteorology and Climatology, MeteoSwiss, Payerne, Switzerland Polarimetric light scattering measurements enhance understanding of aerosol optical properties, improving aerosol classification and remote sensing validation. However, in situ observations remain scarce. This study presents in situ aerosol polarimetric measurements at Payerne using the IMAP-100 polarimeter to analyze scattering phase functions and polarization-resolved data at different cut-off sizes. Laboratory calibration ensured accurate data processing, and retrievals were performed using the GRASP algorithm. Preliminary results reveal temporal variations in light scattering coefficients and aerosol size distributions. Future work focuses on refining retrievals, integrating multi-instrument datasets, and advancing aerosol characterization techniques to better connect in situ and remote sensing observations.
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Organic and emerging pollutants in indoor suspended particles hospitals before, during and after SARS-CoV2 pandemic. CNR, Italy Four indoor chemical characterisation campaigns were conducted in five Italian hospitals. Measurements were performed before the peak of SARS-CoV2 (autumn 2019), during (spring 2021) and after the lifting of the pandemic restrictions (winter 2022 and 2023). Deposition dust (DD) and its comparison with atmospheric particulate matter (PM) were analysed. In this study, PM samples were collected using an air conditioning filter, which can represent indoor particulate matter. The air conditioning filter has a good effect on particle retention and is contaminated by ultrafine particles, which can be resuspended and follow the air conditioning back into the indoor air.
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Germicidal effects of UV irradiation on viral aerosols 1Helmholtz Centre for Environmental Research GmbH - UFZ, Germany; 2Leibniz Institute for Tropospheric Research - TROPOS, Germany; 3Leipzig University - Faculty of Medicine, Germany; 4German Environment Agency - Section Microbiological Risks, Germany COVID-19 highlighted the impact of infectious particles on daily life. We explored UV-light-based methods for indoor air disinfection. Therefore, we have tested their efficiency on phages and feline coronaviruses-loaded aerosols, exposing them to UVA and UVC radiation. Thereafter, the aerosols are sampled and quantified genome equivalents (qPCR) and recovered viruses (microscopy). The survivability of all viruses is reduced even with UVA light (53.15 J/cm²) and a clear reduction in genome equivalents is observed under UVC irradiation. Based on that, we outlined currently ongoing experiments focusing on microscopic visualization and the application of UV disinfection in real-world environments.
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Hunting for the sources of rural air pollution: waste burning 1HUN-REN Centre for Energy Research, Hungary; 2Eötvös Loránd University, Hungary; 3Aerosol d.o.o., Slovenia This study investigates air pollution from waste burning and wood combustion, focusing on rural Hungary. Waste burning, particularly in uninformed communities with poor waste management, emits high levels of particulate matter and toxic pollutants, exacerbating respiratory diseases. Two winter measurement campaigns used advanced aerosol spectrometers and filter analysis to monitor PM and black carbon emissions. Results show extreme pollution levels, however based on the measurement results, it was possible to distinguish between dry wood combustion and illegal waste burning. This research enhances emission source apportionment, supporting targeted air quality mitigation strategies and sustainable pollution management.
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Investigating the viable to total respiratory particles concentration ratio using a BioTrak in various indoor environment configurations Univ Paris-Est Creteil, France Viable particles refer to biological particles, such as bacteria, viruses, fungi, or spores, that are capable of growing, reproducing, or causing infections under the right conditions. In the context of bioaerosols, these particles can remain airborne and potentially spread diseases or impact indoor air quality. Characterizing the viability of airborne particles is therefore very important to accurately analyze infection risk in indoor environments.In this study, we propose a new approach in the real time physical characterization of viable particles in indoor environments with a focus on respiratory particles
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Investigation of Optical Properties of Different Fuels Diesel Exhaust by an Atmospheric Simulation Chamber experiment 1PM_TEN Srl, Genoa, 16123, Italy; 2INFN, Genoa Section, Genoa, 16146, Italy; 3Department of Physics, University of Genoa, Genoa, 16146, Italy; 4BEES Srl, Genoa, 16121, Italy; 5SIGE Srl, Genoa, 16161, Italy Carbonaceous aerosols, comprising 20% to 50% of total aerosol mass, significantly impact climate and human health. This study examines the optical properties of aerosols from different fuel combustion processes, analyzing emissions for particle size distribution and carbon content. Experiments in the ChAMBRe chamber at Genoa University/INFN used a propane-fueled soot generator and a diesel engine running on conventional diesel and HVO. Diesel combustion produced the most light-absorbing particles, with MAC values up to 9.4 m² g⁻¹. Findings highlight the need for accurate correction factors in optical measurements and support real-time monitoring for environmental and workplace safety.
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ML analysis for absorption measurements correction schemes – A test study 1University of Nova Gorica, Slovenia; 2Nextail Labs SL, 28006 Madrid, Spain; 3Haze instruments d.o.o; 4Andalusian Institute for Earth System Research (IISTA-CEAMA), University of Granada, Granada, Spain; 5Institute for Atmospheric and Earth System Research (INAR), Faculty of Science, University of Helsinki, Finland; 6Institute of Environmental Assessment and Water Research (IDAEA-CSIC), Barcelona, Spain The absorbing properties of aerosols is typically measured using instruments like filter photometers, with the aethalometer AE33 being the most widely deployed. However, FPs are sensitive to scattering, which can lead to measurement errors, especially at high scattering levels. A correction scheme to address this was proposed but requires scattering data, often unavailable in networks. To overcome this, we are testing Machine Learning algorithms using a gradient boosting regressor on a 2023 summer campaign in Granada, yielding accurate compensation results. The model is being expanded to 23 European sites to validate and refine the algorithm and cross-validate with other instruments.
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Optical properties and size distributions of particulate matter produced by diesel B7 and Hydrotreated Vegetable Oil combustions in an atmospheric simulation chamber 1University of Genoa, Italy; 2INFN, Division of Genoa, Italy; 3Università degli Studi di Milano and INFN, Milan, Italy; 4National Institute for Nuclear Physics, INFN-Florence, Sesto Fiorentino, Italy Here we present the results of several experiments, performed at ChAMBRe (Chamber for Aerosol Modelling and Bio-aerosol Research) with the aim to measure the optical properties and size distribution of aerosol generated by combustion of HVO (Hydrotreated Vegetable Oils) and diesel B7 (conformed to EN590).Results in terms of size distribution (NanoMoudi), optical properties (MWAA and BLAnCA) and EC/OC ratio (thermal-optical analyses) at each stage of fresh and aged aerosol will be presented at the conference.
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PM10 Source assesment in rural olive areas of Spain: Implications for 2030 Air Quality Standards University of Huelva, Spain This study analyses PM10 and CO levels from June 2018 to June 2024, as well as the chemical composition of PM10 from 2021 to 2023, to determine source apportionment using the US-EPA PMF5 model. After discounting North African dust apportionment, a 25% reduction in combustion emissions is required to meet the 2030 directive’s target. Therefore, it is crucial to maintain, until at least 2030, the measures outlined in the Air Quality Plan of Villanueva del Arzobispo by the Junta de Andalucía, specifically targeting biomass combustion emissions.
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Source Apportioned Particle Number Concentrations during Winter Season before COVID19 lock in the City Center of Belgrade, Serbia Vinca Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade This study apportioned the sources of PNSDs by analysing the data collected between January 20th and March 9th 2000., during the winter season period of 40 days before COVID19 lockdown. Source profiles, obtained by application of EPA PMF5 software, were interpreted considering the potential regional sources, local sources and the fact that level of air pollutant including PM fractions are variable over the time and depend from a combination of source emission rates and meteorological conditions. It is investigating the influence of on ultrafine particle (UFP) sources to determine the success of the mitigation strategies and to plan future actions.
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Submicrometric aerosol using Q-ACSM and Positive Matrix Factorization at remnants of the Atlantic Forest in Metropolitan Area of São Paulo (MASP) 1Institute of Astronomy, Geophysics and Atmospheric Sciences, University of São Paulo; 2Laboratoire des Sciences du Climat et de l’Environnement, CEA, CNRS, Gif sur Yvette; 3Centre for Energy and Environment, IMT Nord Europe, Institut Mines-Télécom, Université de Lille; 4Université Clermont Auvergne, Laboratoire de Météorologie Physique (LAMP/CNRS); 5Institute of Physics, University of São Paulo; 6Institute of Agricultural Sciences, Federal University of Uberlândia Air pollution has become a major problem in large urban conglomerates, particularly in megacities. The objective of this study was to investigate the chemical composition of the submicrometric aerosol particles during the intensive campaign of the “BIOgenic emissions, chemistry and impacts in the MASP: BIOMASP+” project. The BIOMASP+ took place at two sites the Matão-IAG (urban forest site) and Reserva Morro Grande (RMG, Atlantic Forest site) from April 22 to May 22, 2023. The PM1 (18 and 5.2 µg.m-3) measurements were performed a using the Quadrupole Aerosol Chemical Speciation Monitor (Q-ACSM). Positive matrix factorization was performed on the organic fraction.
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Three-wavelength Lidar for aerosol optical and microphysical properties characterisation at Mount Etna (Italy): system upgrades and first measurement results 1Department of Physics “Ettore Pancini” University of Naples “Federico II”, I-80126 Napoli, Italy; 2IMAA-CNR Istituto di Metodologie per l’Analisi Ambientale, I-85050, Tito Scalo-Potenza, Italy; 3Istituto Nazionale di Geofisica e Vulcanologia, Osservatorio Etneo, Piazza Roma 2, 95125 Catania, Italy Lidar measurements have become essential for near-real-time atmospheric monitoring. At Mount Etna, within the VULCAMED project, lidar observations of volcanic aerosols have been conducted since 2010, initially with a single-wavelength prototype and later with an advanced multi-wavelength system developed. Originally designed to operate in the UV and IR spectral regions, the system was upgraded with VIS channels, improving aerosol characterization. It now acquires elastic and Raman signals at multiple wavelengths, enabling measurements of aerosol optical and microphysical properties. Calibration and validation procedures are required to optimize performance; the implementation and preliminary measurement results will be presented.
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Optimizing Uncertainty Reduction in Air Pollution Health Impact Assessments: A Tradeoff Analysis Using Information Entropy University of Notre Dame, United States of America We study how estimates of the relationship between air pollution and mortality may be improved with more information on air pollution concentrations or death records, and compare the impacts of improved air pollution data alone versus improved death data alone. We also study the effect of social inequalities by comparing what happens when there is missing data in the majority demographic. Because different groups face different pollution levels, minority data is statistically more informative, offering insights unavailable from majority data alone. This highlights the importance of inclusive data for accurate environmental health assessments.
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Black carbon emission factors of household wastes co-burned with firewood in stoves 11HUN-REN–PE Air Chemistry Research Group, University of Pannonia, Veszprém, 8200, Hungary; 2University of Pannonia, Veszprém, 8200, Hungary The combustion of household waste in fireplaces negatively affects air quality, among other factors, due to the increased emission of soot. In this work, various plastic waste types were co-burned with firewood, and legal fuels were also burned separately in a fireplace under controlled conditions. The emission factor of soot was calculated and discussed for the burning of specific waste types.
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Black carbon pollution and sources in gas-heated Moscow megacity: Upgrade to European phenomenology 1Moscow State University, Russian Federation; 2Aerosol d.o.o., Research & Development Department, Ljubljana, Slovenia Major peculiarity of BC pollution and sources are highlighted in Moscow, largest northernmost European megacity, with gas-fueled heating system and absence of residential biomass burning. Upgrade to European phenomenology supports the harmonization of BC measurements allowed for comparisons between cities; two and a half-year mean BC in Moscow urban background is found significantly less than in France, Spain and Greece, and no difference with UB sites in Northern, North-Western, Eastern Europe, and in Netherlands, Germany. Annually average Moscow monthly eBC concentrations characterized by increased values in August and September, different from European UB with prominent winter SF residential heating impact.
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PFAS monitoring in Flanders, Belgium VITO, Belgium In response to elevated PFAS concentrations in soil, water and air in the wider Antwerp region, the Government of Flanders decided in June 2021 to map out the problem and to initiate a coordinated approach and perform extensive monitoring campaigns on a regular basis throughout Flanders. This contribution reports about the results from air monitoring campaigns that were conducted at a range of monitoring sites including industrial, urban residential and rural sites in Flanders, with the purpose to survey and assess the PFAS concentrations and fingerprints in ambient air and deposition.
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A Multi-year Characterization of Black Carbon at Regional, Urban, and Urban Background Locations in Qatar Qatar Environment and Energy Research Institute, Hamad Bin Khalifa University, Qatar This study analyzes black carbon (BC) concentrations in Qatar from 2022 to 2024 across urban and background sites. BC levels were highest near traffic-heavy areas and declined over time due to improved urban management post-2022 FIFA World Cup. Seasonal peaks occurred during the hot-humid months, while diurnal patterns followed traffic trends, with morning and nighttime peaks. The ΔBC/ΔCO ratio confirmed diesel vehicles as a dominant source. Comparisons with SO₂ and NOₓ indicated BC's traffic-related origin, while SO₂ peaks suggested industrial contributions. These findings provide insights into BC pollution trends and influencing factors in Qatar's environment.
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Analysis of the spatial-temporal variability of chemical-physical properties of PM2.5 in two sites of Southern Italy 1NationalCouncilofResearch(CNR), Italy; 2Department of Chemistry, University of Bari, Italy; 3Department DISTEBA, University of Salento, Lecce, Italy. Two measurement campaigns were performed, in cold and warm periods, simultaneously at two sites, urban and suburban background, about 4.3 km apart, in the area of Lecce (Southern Italy). Daily PM2.5 samples were collected simultaneously on quartz and Teflon substrates by a dual-channel low-volume (2.3 m3/h) automatic sampler. Additional measurements were particle number concentration in the range 0.3-10 μm, using two optical particle counters (OPC), and size distributions in the range 0.01-0.8 μm using two scanning mobility particle sizers (SMPS). Meteorological data were also collected at both stations. Chemical characterization included elemental composition analysis by energy dispersive X-ray fluorescence (ED-XRF).
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Assessing indoor and outdoor air quality interactions in urban environments: a case study in Bologna within the ECOSISTER Project 1Institute of Atmospheric Sciences and Climate, National Research Council of Italy, Bologna, 40129, Italy; 2Dept. of Engineering ‘Enzo Ferrari’, University of Modena and Reggio Emilia, Modena, 41125 Italy; 3Proambiente S.C.r.l., Bologna, 40129, Italy; 4Institute for the Study of Nanostructured Materials, National Research Council of Italy, Bologna, 40129, Italy; 5now at Dept. of Statistics, University of Bologna, Bologna, 40126, Italy Indoor air quality (IAQ) is crucial globally and in Europe, where people spend 90% of their time indoors. It is influenced by internal emissions (activities, materials) and outdoor air quality (OAQ), depending on ventilation rates. The ECOSISTER project studies IAQ in a Bologna’s district using low-cost sensors to monitor indoor and outdoor CO₂, PM, VOCs, NOₓ, O₃, and meteo parameters. Preliminary results show a strong impact of outdoor pollution on indoor PM levels and the predominance of indoor VOC sources. The study aims to develop smart solutions to reduce human exposure to pollutants while optimizing indoor comfort and energy efficiency.
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BC concentrations and spectral absorptions at regional background stations in Greece 1Department of Chemistry, University of Crete; 2Department of Chemical Engineering, University of Western Macedonia; 3Department of Mechanical Engineering, University of Western Macedonia; 4Institute for Environmental Research and Sustainable Development, National Observatory of Athens This study examines the seasonality of BC and its components related to fossil fuel combustion and biomass burning (BCff, BCbb), as well as the spectral absorptions related to BC and Brown Carbon (BrC) at two regional-background sites in Greece. The first site is at Finokalia, Crete, a well-known measuring station for atmospheric composition in the eastern Mediterranean and the second is located at a continental background site in NW mountainous Greece (ZEP, Kozani). Both stations are mostly affected by regional-background aerosol plumes of different optical and physico-chemical characteristics (continental vs. marine), and are sensitive in detecting long-range transported aerosol plumes.
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Brown carbon characterization and impacts of absorbing aerosol in Eastern Mediterranean 1IESRD, National Observatory of Athens, I. Metaxa and Vas. Pavlou, 15236, P. Penteli, Athens, Greece; 2Climate and Atmosphere Research Center (CARE-C), The Cyprus Institute, Nicosia, 2121, Cyprus; 3ECPL, Department of Chemistry, University of Crete, P.O. Box 2208, 71003 Heraklion, Greece Absorbing atmospheric aerosol constitutes an essential contributor to Earth’s climate system, since it possesses the ability to absorb solar radiation, affecting radiative forcing. The area of Europe constitutes a scarce context for the investigation of absorbing aerosol, since it is characterized by a vast diversity of emission sources and atmospheric conditions. The current research utilizes a multi-faceted approach, employing ground-based observations combined with chemical analyses, to quantify aerosol properties. The results indicate that absorbing aerosol demonstrates pronounced seasonal and temporal variability, while high absorption coefficients of BC and BrC, appear to be associated with intense biomass burning and residential heating.
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CAPE-k CHEM: Precursors vapors and chemical composition of the Southern Ocean aerosols at Cape Grim Queensland University of Technology, Brisbane, Australia As part of the larger Clouds and Precipitation Experiment at kennaook (CAPE-k) campaign, CAPE-k CHEM performed online measurements of aerosol precursor vapors using state-of-the-art aerosol instrumentation deployed for the first time at kennaook/Cape Grim. This abstract describes the motivation, purpose, methodology, and show first results. CAPE-k CHEM ultimately aims to elucidate the sources, transformations, and fate of natural aerosols in the Southern Ocean as well as their effects on cloud properties by incorporating air mass back trajectory analysis, meteorological reanalysis data, and satellite products as well as utilizing statistical tools such as Positive Matrix Factorization (PMF) and machine learning.
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Characterization of a Novel Laminar-Flow Oxidation Reactor for Simulating Atmospheric Multiple-Day Oxidation IONICON Analytik GmbH, Austria The newly developed Laminar-Flow Oxidation Reactor (ILOx), with a total internal volume of 8 liters, enables the simulation of multi-day atmospheric oxidation processes within minutes. Depending on the total flow, typical residence times range from 2 to 16 minutes. A surrounding 480 W UVA LED lamp (365 nm) provides direct irradiation over 72% of the reactor's surface. The outlet is optimized for simultaneous sampling of VOCs and particles. We will present a comprehensive characterization of the ILOx Reactor, highlighting its oxidation potential. The results will be validated through comparison with the F0AM-4.3 model.
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Characterization Of Gas and Particle-Phase Chemistry from Rice Straw Burning and Aerosol Aging Under Light and Dark Conditions in EUPHORE Chambers 1Fundación CEAM. EUPHORE Laboratories, C/ Charles R. Darwin 14, 46980, Paterna, Spain; 2Department of Chemistry, Drexel University, Philadelphia, PA, USA Biomass burning (BB) significantly impacts air quality, health, and climate by emitting gases and particulate matter. In the Valencian Community (Spain), around 60 kt of rice straw is burned annually, raising environmental concerns. A recent campaign at EUPHORE chambers (Jan–Feb 2025) investigated gas- and particle-phase chemistry and aerosol aging from rice straw combustion under light and dark conditions. Using advanced instruments like HR-ToF-CIMS, the study identified degradation pathways, including the formation of phenolic, furanic, nitrogen-containing compounds, and other BB tracers such as levoglucosan. This ongoing research provides new insights into BB pollutant chemistry.
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Collision rates of multiply-charged aerosol particles in the CERN CLOUD chamber 1CERN, European Organisation for Nuclear Research, 1211 Geneva, Switzerland; 2Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, 60438 Frankfurt, Germany; 3Faculty of Physics, University of Vienna, 1090 Vienna, Austria; 4Faculty of Sciences of the University of Lisbon, 1749-016 Lisbon, Portugal; 5Institute of Physics, Faculty of Science and Technology, University of Tartu, 50411 Tartu, Estonia; 6Paul Scherrer Institute, 5232 Villigen PSI, Switzerland Results of experiments conducted at the CERN CLOUD chamber to study the interactions of unipolar small ions and multiply-charged small particles (<10 nm diameter) with large aerosol particles in the CCN size range (50-100 nm). We will report new insights into the impact of electric charge on particle-particle and particle-ion collision rates in unipolar environments.
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Comparison of the Four-Wavelength Photoacoustic Spectrometer PAAS-4λ and Aethalometer AE33 for Long-Term Measurements in Rural Northern and Southern Finland 1University of Wuppertal, Germany; 2schnaiTEC GmbH, Wuppertal, Germany; 3Finnish Meteorological Institute, Helsinki, Finland; 4University of Tokyo, Japan; 5University of Helsinki, Finland This study presents long-term measurements of light absorption by atmospheric black carbon (BC) in Northern and Southern Finland, using the PAAS-4λ four-wavelength photoacoustic aerosol absorption spectrometer. The data were compared with MAAP and Aethalometer AE33 measurements to evaluate their accuracy in determining BC mass concentrations (eBC). The study identifies periods influenced by long-range transported combustion aerosols and investigates the variability of the Aethalometer multi-scattering correction factor, C, and its relation to source regions. Further analysis explores BC’s mixing state using light scattering and single scattering albedo (SSA). These findings enhance understanding of BC’s impact on the Arctic climate.
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Comparison of ultrafine particles volatility at a traffic site and a suburban station in Athens, Greece N.C.S.R. ‘Demokritos’, Greece Human exposure to the ultrafine fraction of particulate matter, (UFP), has serious health effects due to their ability to penetrate deep into the lungs. Traffic exhaust emissions are a major source of particulate matter in urban environments. Volatility is one of the most important physical properties of aerosol particles, as it can provide real-time information on the particle mixing state for UFPs. This work aims to study the volatility of aerosol particle number. The measurement campaign took place at a traffic site in Athens and compared with those recorded at a suburban research station located at the N.C.S.R. ‘Demokritos’.
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Contamination of the soils with dust fallout from a smelting site in Lubumbashi city, RD Congo 1IMT NORD EUROPE, France; 2UNILU FACULTE DE POLYTECHNIQUE, RD Congo The bioaccumulation of metals can increase human health risks through several pathways, including particle inhalation, etc.This study aimed to distinguish lithogenic metal sources from anthropogenic soil contamination caused by dust fallout from smelting operations. Topsoils (28), soil profiles (5), dust fallout (17), total suspended particles (TSPs) (10) were collected around the mining site. Mass concentration of metals (Co, Cu, etc.) associated with smelting activities in the topsoil exceeded their background value found in the deeper layer, indicating anthropogenic contamination. In addition, enrichment factors showed that TSPs reflect recent contamination, while dust fallout and top soils show contamination integrated over time.
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Determination of the relative contributions of the disc and pad to the particles emitted by mechanical braking 1Center for Energy an Environment, IMT Nord Europe, Institut Mines-Télécom, Université de Lille, Lille, France; 2University of Lille, CNRS, Centrale Lille, UMR 9013, LaMcube, Lille, France; 3Alstom Flertex/Flertex Sinter, Gennevilliers, France; 4Alstom, Saint-Ouen-sur-Seine, France Particles emitted by the mechanical braking of commuter trains are part of the non-exhaust particles. The concentrations of these metallic particles with potential adverse health effects are high in confined underground train stations. It is therefore important to understand which component of the braking system, pads or disc, contributes mostly to the emission of particles, in order to design low-emission materials. To this purpose, a mass balance approach has been applied to metals, tracers of the friction materials. The results are discussed and compared to independent measurements of the volume loss of the materials.
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Cytotoxicity, intracellular oxidative stress, and acellular oxidative potential of PM2.5: a study in South Italy 1Department of Environmental and Biological Sciences and Technologies (DISTEBA), University of Salento, Lecce, 73100, Italy.; 2Institute of Atmospheric Sciences and Climate (ISAC), National Research Council of Italy, Lecce, 73100, Italy; 3Department of Engineering for Innovation, University of Salento, Lecce, 73100, Italy The study investigates the toxicity of fine particulate matter (PM2.5) sampled at two sites (urban and urban background) in South Italy, focusing on oxidative stress and cytotoxicity. Both acellular assays (ascorbic acid and DTT) and cellular assays based on A549 cells were used. Most samples showed cell viability inhibition below 20%, some between 20%-50%, none exceeded the 50% value. A correlation between oxidative stress and reduced cell viability was observed. Urban PM2.5 induced higher oxidative stress than suburban samples. The results suggest that the chemical composition of PM2.5, rather than its mass concentration, plays a crucial role in its toxicity.
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Detection and 23-year climatology of Saharan dust at the high-altitude site Jungfraujoch 1MeteoSwiss, Switzerland; 2PSI Center for Energy and Environmental Sciences, Switzerland; 3Laboratory for Air Pollution/Environmental Technology, Empa, Switzerland Different methods to detect Saharan dust events (SDE) based on in-situ aerosol optical parameters or size distribution and on FLEXPART back trajectories are evaluated and compared to CAMS dust products at the high-altitude site Jungfraujoch. The method based on negative single scattering albedo exponent is more efficient in winter but depends on the type of nephelometer and absorption photometer. The method based on the size distribution is more efficient in summer. A 24 years climatology of the SDE hours and mass allows to see a trend toward more dust influence since 2020.
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Determining source specific organic aerosol and black carbon emission rates by coupling source apportionment and atmospheric dynamics 1Center for Atmospheric Research, University of Nova Gorica, SI-5000 Nova Gorica, Slovenia; 2Aerosol d.o.o., SI-1000 Ljubljana, Slovenia; 3Center for Energy and Environmental Sciences, Paul Scherrer Institute, 5232 Villigen, Switzerland This study focuses on determining emission rates of source-specific black carbon (BC) and organic aerosol (OA) using a combination of source apportionment and atmospheric modeling. Measurements were conducted in Nova Gorica, Slovenia, using an Aerosol Chemical Speciation Monitor (ACSM) and an aethalometer over three months in 2024. A box model approach estimated emission rates by incorporating atmospheric dynamics through planetary boundary layer height inferred from radon measurements. Results showed distinct diurnal patterns for traffic and biomass burning emissions, while secondary OA can be linked to photochemical production and long-range transport.
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Evaluating ALI Cell Exposure in Transient Driving Cycles in CNG vehicle 1CERTH; 2LAT/AUTh; 3School of Biology/AUTh This study examines the health impact of ultrafine particle (UFP) emissions from a Compressed Natural Gas (CNG) passenger vehicle, despite CNG being considered a cleaner alternative to gasoline and diesel. A Euro 6 CNG taxi was tested under two real-world driving cycles using a chassis dynamometer, with emissions analyzed through Air-Liquid Interface (ALI) in-vitro cell exposure. A549 human epithelial cells were exposed to diluted exhaust, revealing cell mortality, increased cytokine production, and inflammatory responses. The mRDE driving cycle had a significantly stronger impact, indicating that different driving conditions influence emission toxicity and potential health risks.
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Evaluation of the toxicological effects of primary and aged logwood stove emissions on alveolar cells exposed at the air-liquid interface 1INERIS, Parc Technologique Alata, Verneuil en Halatte, 60550, France; 2Univ. Littoral Côte d'Opale (ULCO), France; 3Univ. Lille, Lille Neurosciences & Cognition - UMRS 1172, France; 4Univ. Aix Marseille, CNRS, LCE, France Experiments were conducted following the beReal test protocol to simulate real-world combustion conditions. A comprehensive physicochemical characterization of gaseous (VOCs, CO, NOx) and PM phases (mass, size, number, morphology, BC, EC-OC, ions, metals, molecular composition) was conducted, alongside an extended analysis of toxic species (PAHs, nitro- and oxy-PAHs, nitrophenols, carbonyls). For toxicological assessment, cells were simultaneously exposed to primary and aged emissions. Particular attention was given to determining the PM mass deposited on the cells.Inflammatory markers (Nrf2, NFkB, TNF-a, IL-1b, IL-6, IL-8) and oxidative stress (carbonylated proteins), cell membrane damage (4-HNE), and DNA oxidation (8-OHdG) were assessed.
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Experimental determination of the Atmospheric Heating Rate due to Light Absorbing Aerosols at the Jungfraujoch high altitude remote station 1GEMMA and POLARIS Centre, Università degli Studi di Milano-Bicocca, Milano, 20126, Italy; 2Federal Office of Meteorology and Climatology, MeteoSwiss, Payerne, 1530, Switzerland; 3PSI Center for Energy and Environmental Sciences, Villigen, 5232, Switzerland; 4Department of Environmental Sciences, Computer Science and Statistics (DAIS), University of Ca’ Foscari, Available observations suggest that some mountain regions (including Alps) are experiencing seasonal warming rates that are greater than the global land average. The reasons behind the magnitude of climate change in mountains are not entirely clear. However, there are some known mechanisms that can produce enhanced warming rates.In particular light absorbing aerosol absorbs solar radiation and warms the mid-troposphere. Therefore, we carried out a measurement campaign from 1/05 to 31/10 2023 at the Jungfraujoch facility in order to experimentally determine the atmospheric LAA HR in the free troposphere. Preliminary results showed an average value of 0.035 ± 4*10-4 K/day.
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Exploring the chemical aging of urban organic emissions: Results from the POSEIDON campaign 1Institute for Chemical Engineering Sciences, ICEHT/FORTH, Patras, Greece; 2Department of Chemical Engineering, University of Patras, Patras, Greece; 3Institute for Environmental Research and Sustainable Development, National Observatory of Athens, Greece The POSEIDON campaign, conducted in September 2024 on Poros, a Greek island downwind of Athens, the capital of Greece, aimed to study the chemical aging of urban emissions. Advanced instruments measured aerosol and gas phase pollutants, while additional measurements were conducted in Athens for comparison. Organic aerosol (OA) accounted for 52% of PM₁, with more-oxidized OA comprising 64%. Aged biomass burning OA (15%) was associated with the more-oxidized OA factor. The study analyzed air mass trajectories, VOC ratios, and OH concentrations to assess oxidation processes. These findings provide valuable insights into the atmospheric transformation of urban emissions.
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Firefighter exposure and health risks: linking exposure concentrations to health outcomes 1Institute of Environmental Assessment and Water Research – Spanish Research Council (IDAEA-CSIC), Barcelona, Spain; 2PhD program of Analytical Chemistry and Environment, University of Barcelona, Barcelona, Spain; 3Pollution Prevention Unit, Spanish Ministry for the Ecological Transition, Madrid, Spain; 4Center for Environmental Medicine, Asthma, and Lung Biology, University of North Carolina at Chapel Hill, North Carolina, United States Firefighters face health risks from air pollutants in fire smoke, classified as carcinogenic. A study in Catalonia (2022–2024) measured exposure using PM2.5, black carbon (BC), and PAHs. Biological samples (urine, nasal mucosa, dried blood) assessed short-term health effects. Torch operators had higher BC and PAH exposure, while line operators faced lower doses but sometimes stronger immune responses. IL-8 levels indicated inflammation, varying by task. Findings suggest task-dependent immune effects and individual susceptibility. Further research on blood and urine samples aims to clarify the link between wildfire smoke exposure and health impacts.
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Fractional Soaring of Bacteria and Fungi Aerosols in a Chicken Farm 1Escuela Politécnica Superior, Universidad de Alcalá, Spain; 2Counterfog SL, Valdemoro, Spain; 3Department of Chemical, Aerosol and Biological Hazards, Central Institute for Labour Protection, Poland A new paradigm for transport channel-resolved failure mode biosecurity assessment is under research in HE-FARM project. Among the potential channels for transportation of pathogens, aerosols play a key role. In this context the new Counterfog® BIAFTS method (del Álamo, 2022) has been used to sample bioaerosols in a chicken farm at two different heights. Culture of active bacteria and fungi from these samples shows a variation of predominance and ratios of the different species evidencing a fractional soaring of the species. This demonstrates the strong interaction of air dynamics with the aerosolization processes and an example of spatial heterogeneity.
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Glycolic Acid Sulfate Formation in Aqueous Aerosols Analyzed with Hydrophilic Interaction Liquid Chromatography-Mass Spectrometry Aarhus University, Denmark Glycolic acid sulfate, the sulfate ester of glycolic acid, has been detected across many locations in the atmosphere, though its formation mechanism remains unclear. This study develops a method for quantification using ultra-high performance liquid chromatography with a HILIC column coupled to Orbitrap mass spectrometry. Atomizer experiments with glycolic acid and sulfuric acid show that glycolic acid sulfate only forms in the aerosol phase, and not in the bulk phase. Further atomizer experiments and chamber studies aim to shed light on its formation mechanisms and potential relevance to the formation of other organosulfates.
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Impact of War on Air Quality: PM2.5 Aerosol Composition in Beirut During the 2024 Conflict 1National Institute for Nuclear Physics (INFN), Section of Florence, Sesto Fiorentino (FI), 50019, Italy; 2Department of Physics and Astronomy, University of Florence, Sesto Fiorentino (FI), 50019, Italy; 3Lebanese Atomic Energy Commission - National Council for Scientific Research (CNRS-L), Beirut 11-8281, Lebanon This study examines air pollution caused by the September-October 2024 war in Lebanon. PM2.5 samples collected in Beirut showed a threefold increase in particulate matter near the conflict zone compared to pre-war levels (2018–2021). Gravimetric and PIXE analyses revealed high concentrations of toxic metals (Pb, Zn, Cu, Ni) from weapon fumes and debris, as well as increased sulfur and chlorine from combustion. These findings highlight severe air quality deterioration due to warfare.
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In vitro toxicological evaluation at the air-liquid interface of aerosols generated by POD vaping device using nicotine salts Mines Saint-Etienne, Univ Lyon, Univ Jean Monnet, INSERM, U1059, SAINBIOSE, Centre CIS, F -42023 Saint- Etienne France Electronic cigarettes (EC) have gained popularity, with the introduction of fourth-generation devices based on e-liquids containing nicotine salts that promise a smoother vaping experience than freebase nicotine. However, the toxicological effects of nicotine salts are still largely unknown. Human lung epithelial cells were exposed to undiluted aerosols of e-liquids containing various ratios of solvents, freebase nicotine, organic acids, nicotine salts, and flavoured commercial e-liquids. Cytotoxicity, inflammation, and oxidative stress, were assessed 24 h after exposure. Results showed that aerosols from fourth-generation devices can cause different toxicological effects, the nature of which depends on the chemical composition of the e-liquid.
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Influence of NOx on the physical and chemical properties of isoprene SOA 1Democritus University of Thrace, Greece; 2Barcelona Supercomputing Center, Spain In this work we studied the effects of NOx concentration on isoprene SOA density, oxygen-to-carbon ratio (O:C) ratio, volatility, volatility distribution and vaporization enthalpy. Dark ozonolysis or photo-oxidation experiments of isoprene were conducted in an environmental chamber at varying NOx concentrations. The particulate phase was analyzed using an Aerodyne High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) and a Scanning Mobility Particle Sizer (SMPS). A thermodenuder system was used for the SOA volatility characterization.Our results indicate that RO2 chemistry has a non-linear effect on SOA density, O:C ratio and volatility.
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Investigation of the properties and factors affecting concentrations and size distribution of ultrafine aerosol particles in the city of Zagreb, Croatia 1Division for Marine and Environmental Research, Ruđer Bošković Institute, Zagreb, 10000, Croatia; 2School of Earth and Atmospheric Sciences, Queensland University of Technology, Brisbane, 4001, Australia This study presents the first investigation of UFP in Zagreb, Croatia. We studied the influencing factors on physical and chemical properties of UFPs, using the scanning mobility particle sizer during two contrasting seasons (winter and summer 2024). On-line black carbon (eBC) concentrations were measured by aethalometer, while particle size fractions (13 stages; from 10 nm to 32 μm) were collected with an MOUDI impactor and analysed for mass and organic carbon content. Data were correlated with meteorological parameters, biomass burning (BCbb) versus fossil fuel (BCff) contributions to eBC, and NO2, SO2, and O3 concentrations
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Key Factors Affecting Indoor PM2.5 in New Dwellings in London 1Imperial College London, United Kingdom; 2UK Health Security Agency This study investigates indoor PM2.5 in new London flats. High indoor emissions, particularly cooking, cause sharp peaks (up to 600 μg/m³), while non-emission periods stay below 50 μg/m³. Outdoor PM2.5 averages15 μg/m³ with moderate infiltration (0.4–0.5), rendering outdoor contributions negligible. Seasonal variations in ventilation, cooking patterns, and weekend occupancy further influence pollutant levels. Open-plan layouts yield strong coupling between kitchens and lounges, with bedrooms showing relatively lower levels (max 60 μg/m³ even when kitchens peak at 300 μg/m³). Building airtightness also modulates infiltration. Future work will expand to TVOCs and CO2 for a comprehensive assessment of indoor air quality.
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Molecular-Scale Mechanism of Adsorption and Ice Nucleation on the Copper Oxide (CuO) Surface 1Finnish Meteorological Institute, Finland; 2Laboratory of Atmospheric Process and their Impacts, ENAC, Ecole Polytechnique Fédérale de Lausanne, Switzerland; 3Office féderal de météorology et de climatologie MtoSuisse, Chemin de l'Aérologie 1, 1530 Payerne; 4Institute of Chemical Engineering Sciences, Foundation for Research and Technology Hellas, Patras, Greece; 5Department of Applied Physics, University of Eastern Finland, Kuopio, Finland This study explores ice nucleation on copper oxide (CuO) surfaces using Grand Canonical Monte Carlo (GCMC) and molecular dynamics (MD) simulations. Findings reveal that water adsorption is initially dominated by chemisorption at Cu-O sites, followed by multilayer physisorption. Adsorption isotherms and energy calculations (~8.23 eV) confirm strong surface-water interactions, influencing ice formation. Reactive MD simulations highlight dissociative and molecular chemisorption, with water clustering around active sites. These insights improve atmospheric modeling and material design. Future research will refine adsorption models and integrate experimental validation to enhance understanding of heterogeneous ice nucleation and surface wettability engineering.
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Particulate air pollution in the heart of the European Union: lessons learned from SAFICA 2017-2018 and SAAERO 2022-2023 projects 1Paul Scherrer Institute, Switzerland; 2Datalystica Ltd., Switzerland; 3National Centre of Scientific Research “Demokritos”, Greece; 4Faculty of Science, University of Sarajevo, Bosnia and Herzegovina; 5Federal Hydrometeorological Institute of Bosnia and Herzegovina, Sarajevo, Bosnia and Herzegovina; 6Institute for Public Health of the Sarajevo Canton, Bosnia and Herzegovina; 7Mechanical Engineering Faculty, University of Sarajevo, Bosnia and Herzegovina; 8Institute for Medical Research and Occupational Health, Zagreb, Croatia; 9Technical University of Vienna, Austria; 10Rudjer Boskovic Institute, Zagreb, Croatia; 11Institute for Environmental Geosciences, Grenoble, France; 12University of Bern, Switzerland; 13University of Belgrade, Serbia; 14Academy of Applied Studies Šabac, Serbia; 15University of Nova Gorica, Slovenia; 16Aerosol d.o.o., Ljubljana, Slovenia; 17Jozef Stefan Institute, Ljubljana, Slovenia; 18Aerodyne Research, Inc., Billerica, MA, United States of America; 19University of North Carolina at Chapel Hill, NC, United States of America; 20Urban Emissions, New Delhi, India; 21Institute of Environmental Assessment and Water Research, Barcelona, Spain Particularly during winter, urban areas of the Southeast Europe (SEE) are experiencing some of the poorest air quality globally. It imperative to understand SEE urban air pollution, 1st locally (emission sources, processing, and the adverse health effects) and 2nd regionally (transboundary outflow). This presentation will give the results of two major projects centered at supersite in Sarajevo, Bosnia and Herzegovina (BiH). Sarajevo, BiH is an excellent case study for the SEE urban air pollution: it is situated in a basin surrounded by mountains, and during cold winter months, topography and meteorology cause trapping of the pollutants in its basin.
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Physico-optical properties of atmospheric aerosols over North-East India Dibrugarh University, India The study analysed atmospheric particulate matter in North-East India during the post-monsoon season of 2023, using SEM-EDX and FTIR to assess morphology, elemental composition, and different functional groups. Particles ranged from 1 to 70 μm, with major elements like C, O, Si, and hazardous elements such as Cr and Fe. Sources were identified using Enrichment Factor, Pearson Correlation, and PCA, revealing dust aerosols are the dominant species. Optical properties were simulated using DDSCAT-7.0, showing higher extinction and scattering efficiencies at shorter wavelengths for non-spherical particles. Shape significantly influenced optical properties, with rectangular particles exhibiting higher light attenuation than spherical ones
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Ship emissions profiles from ambient measurements in Dublin Port 1University of Galway, Ireland; 2Chinese Academy of Sciences, China; 3Hong Kong Polytechnic University, China; 4University College Cork, Ireland; 5Imperial College London, UK; 6SRI Center for Physical Sciences and Technology, Lithuania Emissions profiles of commercial ships are changing and new studies are needed to quantify and trace these ship emissions from new alternate marine fuels. A research project, PortAIR, took place in the Dublin port area. The analysis of aerosol chemical speciation monitor data using combined organic and sulfate ion positive matrix factorization. idenitified three types of ship fuel emissions: sulfate-rich (S-Ship), organic-rich (O-Ship), and Marine Gas Oil (MGO). Overall, S-Ship and O-Ship plumes were observed frequently and contributed to at least 28%-47% of PM1, but MGO were somewhat 'invisible' to the scientific and regulatory mass measurements, posing a problem.
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Site-selectivity of Phl p 5 modifications and their influence on the inflammatory potential 1Multiphase Chemistry Department, Max Planck Institute for Chemistry, Mainz, 55128, Germany; 2Division 1.5 Protein Analysis, Federal Institute for Materials Research and Testing (BAM), Berlin, 12489, Germany Over the past three decades, pollen allergies have increased, possibly due to air pollutants like ozone and nitrogen dioxide modifying allergens such as Phl p 5. These modifications, including dityrosine and nitrotyrosine, influence the allergen's interaction with the TLR4 receptor, a receptor central in inflammation. Ozone exposure only leads to dityrosine formation, increasing TLR4 activity. Nitrogen dioxide exposure results in both nitrotyrosine and dityrosine, also increasing TLR4 activity but less than Phl p 5 after ozone exposure alone. The reaction with peroxynitrite, also causing both modifications, significantly increases TLR4 activity, highlighting the impact of site-specific tyrosine modifications on TLR4 activity.
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Source Apportionment of wide range particle number concentration during summertime in Istanbul 1Istanbul University-Cerrahpasa, Turkiye; 2Istanbul Technical University; 3Hacettepe University; 4Bogazici University; 5University of Birmingham Istanbul is one of the major metropoles in the world with more than 16 million inhabitants, providing access through motorway, maritime and air transportation between Asia and Europe. These activities represent different pollution sources causing a complex air pollution profile across the province. This is the first study on measuring a wide range of particle number size distribution (10 nm to 10 um) conducted in Istanbul and measured at the urban background, urban and traffic sites in Istanbul using a NanoScan SMPS and Palas for 20 days in summer. Source apportionment analysis showed the main source of particles is traffic.
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Urban particulate matter SRM 1648 as a reference material for Oxidative Potential determination 1Centro de Ciências e Tecnologias Nucleares (C2TN), Instituto Superior Técnico, Universidade de Lisboa; 2Instituto Politécnico de Setúbal, Escola Superior de Tecnologia de Setúbal; 3HyLab - Green Hydrogen Collaborative Laboratory Given its importance in assessing the health impacts of PM, OP, aligned with information from the sources and composition of PM, can be of extreme importance in creating new directives on air quality. However, the lack of a standard method makes it difficult to compare results and effectively create new legislation. This study aims to test a reference standard for the OP analysis, providing a useful tool for quality assurance and results comparison.
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A Novel Breath-Taking Hood for COVID-19 1Institute of Environmental and Occupational Health Science, College of Public Health, National Taiwan University; 2Department of Occupational Safety and Health, Chung Hwa University of Medical Technology From the perspective of engineering control hierarchy, source control is always the most cost-effective option compared to pathway and receptor control. A novel breath-taking hood has been developed to completely capture respiratory aerosols exhaled by infected people to protect the environment. It could replace negative pressure wards, remove the need for isolation and quarantine, and make city or national lockouts redundant. The source control device demonstrated in the study could revolutionize infection prevention and control.
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Analysis of aerosol optical properties using aethalometer and nephelometer over 3 years in an urban and suburban places 1Department of Physics, University of León, Campus de Vegazana, 24071, León, Spain; 2Centre for Environmental and Marine Studies (CESAM), Department of Environment and Planning, University of Aveiro, Aveiro 3810-193, Portugal; 3Department of Biodiversity and Environmental Management, University of León, 24071 León, Spain; 4Droplet Measurement Technologies, LLC, Longmont, CO, USA Understanding aerosol optical properties is essential for assessing their climate and air quality impacts. This study characterizes aerosol absorption and scattering in León, Spain, based on a three-year sampling campaign (2021–2024). Measurements were conducted at urban and suburban sites using an AE33 Aethalometer and an Aurora 3000 nephelometer. Extreme absorption and scattering values were recorded during Saharan dust intrusions and fossil fuel emissions. Findings highlight the relevance of combining optical coefficients to identify aerosol sources, contributing to improved climate models and air pollution management strategies, particularly in urban environments.
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Assessing human exposure to air pollution in microenvironments using portable Low-Cost Sensor units 1Centro de Ciências e Tecnologias Nucleares (C2TN), Instituto Superior Técnico, Universidade de Lisboa, Loures, 2695-066, Portugal; 2Faculdade de Engenharia, Universidade Lusófona de Humanidades e Tecnologias de Lisboa, Lisboa, 1749-024, Portugal; 3ESTeSL-IPL - Escola Superior de Tecnologia da Saúde de Lisboa, Instituto Politécnico de Lisboa, Lisboa, Portugal; 4Health & Technology Research Center (H&TRC), Escola Superior de Tecnologia da Saúde (ESTeSL), Instituto Politécnico de Lisboa (IPL), Portugal; 5IN+, Center for Innovation, Technology and Policy Research, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, Portugal; 6Centro Europeu do Sono, Clínica São João de Deus, Lisboa, Portugal; 7Centro Cardiovascular da Universidade de Lisboa, Faculdade de Medicina da Universidade de Lisboa, Sleep Unit, Lisboa, Portugal; 8HyLab - Green Hydrogen Col Presenting author laborative Laboratory, Portugal This work focuses on the HypnosAIR project approach to assess and reduce air pollutant exposure during sleep, integrating daily AQ exposure characterization (indoor and outdoor microenvironments), and exposure-response analysis. The methodology chosen involves 80 volunteers. A key component of this study was the deployment of portable low-cost sensor monitoring units (MUs) to monitor real-time AQ parameters to characterize the daily human exposure to air contamination. The results obtained so far confirm previous findings from studies conducted by the authors (Ramos et al., 2022), which demonstrate that some IAQ parameters may influence the sleep quality of the individuals.
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Assessment of children’s exposure to airborne microorganisms indoors 1Hellenic Mediterranean University, Greece; 2Technical University of Crete, Greece; 3N.C.S.R. “Demokritos”, Greece Measurements of viable, cultivable, airborne bacteria and fungi using passive sampling and culture-based analysis were performed in different indoor environments where children spend their time to assess their airborne microbial exposure. The presented results allow to assess that the airborne microbial contamination indoors depends mostly on different environmental conditions (such as temperature, relative humidity), as well as on activities, such as occupancy and cleaning rates, and ventilation conditions. The bacterial contamination indoors is related to the occupancy rates and the ambient temperature. As the ambient temperature decreases, a reduction in bacterial contamination was observed inside schools.
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Biomonitoring polycyclic aromatic hydrocarbon levels in domestic kitchens using commonly grown culinary herbs 1University of Pannonia, Hungary; 2ELGOSCAR 2000, Hungary PAH emissions from cooking significantly affect indoor air quality. In our study a one-month biomonitoring was carried out in Hungarian kitchens using basil (Ocimum basilicum), rocket (Eruca sativa), parsley (Petroselinum crispum) and chives (Allium schoenoprasum). The two main objectives were to follow PAHs accumulation pattern in the kitchen vegetables, and to find out if this pattern can be associated with the different cooking habits (methods: deep fry, pan fry, oven baking, boiling; used materials: lard, butter, oil).
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Characterization of physical, chemical, and toxicological properties of fine Particles emitted from pork and mackerel Grilling Gwangju Institute of Science and Technology (GIST), Korea, Republic of (South Korea) This study examines fine particles (PM2.5) from grilling pork and mackerel, focusing on composition and toxicity. Mackerel grilling emitted more PM2.5, while pork grilling had higher organic carbon (OC). Both generated toxic aerosols, with mackerel showing higher oxidative potential and pork inducing stronger inflammatory responses. Findings provide insights for air quality and health policies.
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CHEMICAL COMPOSITON AND SOURCE APORTIONMENT OF PM10 IN TRAFFIC MONITORING STATIONS IN THE CITY OF SEVILLE University of Huelva, Spain This study analyzes the levels and chemical composition of PM10 at two monitoring stations of the Air Quality Network of Andalusia in the city of Seville (684k population): Torneo and Príncipes, both significantly influenced by traffic emissions. Sampling was performed between 2021 and 2023. Based on the chemical composition, source apportionment study to PM10 were determined using PMF5. Simultaneously, a study on vehicle flux near both stations under varying weather conditions (primarily wind and rain) was correlated to daily traffic apportionment in order to calculate que equivalence of concentration of PM10 and number of vehicles every day.
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CIAO - CNR-IMAA Atmospheric Observatory: the first year of aerosol in-situ measurements CNR-IMAA, Italy The CIAO atmospheric observatory at CNR-IMAA in Southern Italy has been upgraded with an aerosol in-situ observational component, complementing over two decades of remote sensing studies. Located in a Mediterranean-influenced mountainous region, CIAO is ideal for studying natural aerosols like desert dust and volcanic particles. In February 2024, it was accepted as an ACTRIS National Facility, enabling advanced aerosol measurements. Continuous monitoring, starting November 2024, will enhance aerosol characterization, support improved typing methods, and contribute to understanding particle transport. The first-year data will be presented at the conference.
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Comparison of oxidative potential and composition of fine (PM2.5) and ultrafine (PM0.1) particles at an urban and a background site in Greece 1Institute of Chemical Engineering Sciences, (FORTH/ICE-HT), 26504 Patras, Greece; 2Department of Chemical Engineering, University of Patras, 26504 Patras, Greece; 3Laboratory of Atmospheric Processes and their Impacts, EPFL, 1015 Lausanne, Switzerland Fine and ultrafine particles affect human health through oxidative stress. This study examines how PM2.5 and PM0.1 composition influences oxidative potential (OP) using aerosol samples from two field campaigns (summertime and wintertime) in Greece. The water-soluble OP of PM2.5 and PM0.1 were compared and linked to their composition and sources. Initial results showed that wintertime PM0.1 composition is strongly influenced by calcium and sulfur, with refractory black carbon contributing 10% of PM0.1. PM0.1 concentration exhibited strong temporal correlation with potassium, indicating significant contribution from combustion-related emissions. Further statistical analysis is needed to clarify these associations and their contribution to OP.
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Contamination of the atmosphere with size segregated PMx in selected seaports of northern Europe and on transects between them 1University of Gdansk, Poland; 2University of Brest, France The aim of the research was to determine the air quality in terms of aerosol pollution in selected ports of northern Europe and on transects between them. During the research cruise from Gdynia (Poland) to Bodø (Norway) in the period from June 5 to July 2, 2024, size segregated aerosols samples were collected using the Tisch Environmental TE-6000 high-flow impactor. Aerosol samples were collected in 3 seaports (Bergen and Bodø in Norway and Malmö in Sweden) and at 12 stations located on transects between ports. The aerosol research was supplemented with the analysis of meteorological parameters and air mass trajectories.
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Cytotoxicity assessment of ambient air aerosol using a novel “Cells-on-Particles” in vitro model 1Kaunas University of Technology, Lithuania; 2Department of Regenerative Medicine, Centre for Innovative Medicine, Lithuania Air pollution poses serious health risks, necessitating improved toxicity assessment methods. This study evaluates a novel "Cells-on-Particles" in vitro model for cytotoxicity testing of ambient air aerosols. The nanofibrous polycaprolactone (PCL) platform efficiently captures fine particles while providing a cell-friendly surface. Samples were collected near a high-traffic street, and exposure doses were normalized to platform surface area. BEAS-2B cell viability decreased in a dose-dependent manner, with significant cytotoxicity at 50 µg/cm². The LDH assay confirmed cell damage only at the highest concentration (50 µg/cm²). This platform enables direct cell exposure, providing a rapid and representative assessment of aerosol toxicity.
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Enhancing Air Quality through Stricter Regulations on Ship Fuel Oil in East China 1The Hong Kong Polytechnic University; 2Shanghai Academy of Environmental Sciences; 3The Hong Kong University of Science and Technology (Guangzhou) In this study, a long-term online field measurement (from 2016 to 2019) of shipping emission tracers, i.e., vanadium (V) and nickel (Ni), was carried out at a downwind sampling site (i.e., the Dian Shan Lake (DSL) supersite) which is ap-proximately 50 km from the Shanghai waters. Despite the long distance, the decreasing trend in V concentrations from the phase of DECA 1.0 (5.1 ng m-3) to DECA 2.0 (2.4 ng m-3) reflected a positive response due to the strengthened emission control.
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HIGH-TEMPORAL AND SPATIAL RESOLUTION MONITORING OF VOLATILE ORGANIC COMPOUNDS (VOCs) IN THE COMPLEX INDUSTRIAL AND PORT AREA OF TARANTO (ITALY) University of Bari "Aldo Moro", Italy Volatile Organic Compounds are airborne pollutants of concern extensively investigated by the International scientific community for the potential adverse effects on human health and environment. The present study based on the development and validation of a sensor network for high temporal resolution monitoring of total VOCs and BTEX concentration at selected sites nearby the industrial and port area of Taranto allowed to discriminate the contributions of the multiple emission sources, to identify short-emission events not otherwise detectable through the application of conventional methodological approaches and to raise the issue of the inhalation exposure of the population living in the surroundings.
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Impact of residential biomass burning emissions on the wintertime particulate pollution in the Guanzhong Basin, China: a case study 1Institute of Earth Environment, Chinese Academy of Sciences, China, People's Republic of; 2CAS Center for Excellence in Quaternary Science and Global Change, China It remains elusive about the effect of residential biomass burning (RBB) emissions on the particulate matters (PM) pollution and regional climate. The results oof WRF-Chem model simulations of persistent air pollution episodes show that the total contribution of RBB emissions to the near-surface PM2.5 mass concentration during the simulation period is around 29.2% (18.4 μg m-3) averaged over the GZB, with an average contribution of 52.6% to the SOA, suggesting that the RBB emissions should be considered in the air pollution control strategies for further alleviation of the wintertime PM pollution in the GZB under current conditions.
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Neural Network Interatomic Potentials for Atmospheric Chemistry 1Department of Applied Physics, Aalto University, Espoo, 02150, Finland; 2Department of Physics, TUM School of Natural Science, Technical University of Munich, Garching, Munich Atmospheric aerosols influence climate and air quality, but their molecular formation is not well understood. Computational methods can provide insights into molecular-level dynamics but are limited by system size. An alternative is machine learning interatomic potentials (MLIPs). We trained an MLIP using active learning on atmospheric organic molecules from the GECKO-A dataset. The model achieves good predictive performance for small to medium molecules but shows higher errors for larger accretion products. These errors can be addressed with further training and transfer learning. This MLIP offers an alternative to quantum chemistry, enabling studies of larger systems and advancing aerosol research.
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Particle number and black carbon concentrations in Helsinki – spatial variation and trends 1Air Quality Unit, Helsinki Region Environmental Services Authority (HSY), Finland; 2Aerosol Physics Laboratory, Tampere University, Finland; 3Atmospheric Composition Research, Finnish Meteorological Institute, Finland We studied the spatiotemporal variation of particle number (PN) and black carbon (BC) concentrations in Helsinki, Finland, using annual datasets from 20 sites (2009-2024). In addition, the trends of PN, PN size distribution, BC and other pollutants were analyzed at a traffic supersite. The highest PN levels were at the airport terminal, highway and street canyon sites. At traffic sites, BC and NOx levels have decreased rapidly and PN more slowly. Annual mean BC concentrations are currently similar in busy traffic sites and detached housing areas with wood burning. Wood burning significantly impacts BC but has less impact on PN.
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PM10 Composition in an African Megacity: Weekly and Monthly Trends 1Department of Environment and Planning, CESAM — Centre for Environmental and Marine Studies, University of Aveiro, Aveiro, 3810-193, Portugal; 2Associate Unit CSIC-University of Huelva “Atmospheric Pollution”, Centre for Research in Sustainable Chemistry - CIQSO, ETSI, University of Huelva, 21071 Huelva, Spain; 3LESRA – Separation, Chemical Reaction, and Environmental Engineering Laboratory, Agostinho Neto University, Av. Ho Chi Minh n◦ 201, Luanda, Angola; 4CIMO — Mountain Research Centre, LA SusTEC — Associated Laboratory for Sustainability and Technology in Inland Regions, Polytechnic Institute of Bragança, Campus de Santa Apolónia, Bragança, 5300-253, Portugal Urban air quality is a major challenge in rapidly developing cities such as Luanda, Angola, where traffic and industrial emissions contribute to high PM10 levels, increasing cardiorespiratory risks. This study analysed PM10 composition from June to November 2023, using thermo-optical analysis for carbon fractions, ICP-OES/MS for elements, and ion chromatography for water-soluble ions.PM10 concentrations peaked on weekdays at 62.2 ± 15.5 µg/m³, with major oxides comprising 38%, elemental carbon 18%, and organic matter 27%, reflecting urban activities and climatic influences. The highest PM10 levels occurred during the dry season, highlighting the impact of seasonal pollution dynamics.
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PM2.5 in European Classrooms: A Comparative Study 1Centro de Ciências e Tecnologias Nucleares, Instituto Superior Técnico, Universidade de Lisboa, Bobadela, Portugal; 2Faculdade de Engenharia, Universidade Lusófona – Centro Universitário de Lisboa, 1749-024, Lisbon, Portugal; 3Universidad de Sevilla, Dpto. Ingeniería Energética, Camino de los Descubrimientos s/n, Sevilla, 41092, Spain; 4Universidad de Sevilla, Laboratory of Engineering for Energy and Environmental Sustainability, Seville, 41092, Spain; 5MedaResearch, Pitesti, Romania; 6Finnish Institute for Educational Research,University of Jyväskylä, Jyväskylä, Finland; 7CIEMAT - Departamento de Energía Unidad Análisis Sistemas Energéticos; 8QUE TECΗNOLOGIES, Athens, Greece This study assesses PM2.5 and CO₂ levels in classrooms across Spain, Portugal, Finland, and Romania, analyzing ventilation efficiency in primary, secondary, and university settings. Measurements from sensors in 20 classrooms show higher PM2.5 levels in Portugal (10.74 µg/m³) and Romania (10.11 µg/m³), while Finland had the lowest (2.23 µg/m³). CO₂ levels followed a similar trend, indicating poor ventilation contributes to particulate accumulation. Schools with mechanical ventilation had lower pollutant levels, underscoring its importance. Findings emphasize the need for improved ventilation strategies, particularly in naturally ventilated schools, to reduce exposure risks. This study is part of the ECF4CLIM project.
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Regional and Long-Range Transport Sources of PM2.5 Identified in Seoul, South Korea 1Advanced Institute of Convergence Technology, Korea, Republic of (South Korea); 2Mokpo National University, Korea, Republic of (South Korea) In Seoul, combustion-related components have been continuously observed. however, specific sources have not been clearly identified. In contrast, long-range transported PM2.5 exhibits a sharp increase during winter, accounts for a significant portion of PM2.5 mass, and primarily consists of secondary ionic components
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Supervised Machine Learning Approaches for Black Carbon Estimation in Rural Areas 1University of Nova Gorica, Slovenia; 2University of Ljubljana, Slovenia Black carbon (BC) is an important primary species of particulate matter and a major contributor to air pollution. While BC proxy models have been successfully developed for urban environments, their application in rural areas remains poorly explored. In this study, machine learning models were developed to estimate BC concentrations in rural Slovenia. Using multiple linear regression, decision tree, random forest, and artificial neural networks, we predicted BC concentrations one hour in advance. The results show that the ANN model outperforms the other models, demonstrating its potential for estimating BC concentrations in areas with limited air quality measurements.
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The role of the atmosphere in the contamination of the sea surface microlayer with heavy metals in selected seaports of northern Europe and on transects between them 1University of Gdansk, Poland; 2University of Brest, France The main goal of the research was the determination of heavy metals concentration in aerosols in six size classes (7.2-10 𝜇m; 3.0-7.2 𝜇m; 1.5-3.0 𝜇m; 0.95-1.5 𝜇m; 0.49-0.95 𝜇m; <0.49 𝜇m) at 3 seaports (Bergen and Bodø, Norway and Malmo, Sweden) and at 12 stations between them. During the cruise from Gdynia (Poland) to Bodø (Norway) in the period from June 5 to July 2, 2024, in addition to aerosols, the microlayer and underwater samples were collected. It aimed to compare the degree of SML contamination in heavy metals in every single location under the influence of atmospheric dry deposition.
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Traffic emissions and air quality in Alpine regions: a two-site study on the Mont Blanc Tunnel closure 1Regional Environmental Protection Agency - ARPA Valle d'Aosta, Saint-Christophe, 11020, Italy; 2Université Grenoble Alpes (UGA), CNRS, IRD, Grenoble-INP, INRAE, 38402, Grenoble, France; 3Atmo Auvergne-Rhône-Alpes, 69500 Bron, France The Mont Blanc Tunnel (Italy–France) is undergoing an 18-year renovation plan with scheduled full closures for consecutive months each year. This presents a unique opportunity to investigate the impact of traffic emissions in surrounding Alpine areas. Nearly 180 PM10 samples were collected at both entrances (Courmayeur, Italy; Chamonix, France) between 2023 and 2024. Comprehensive chemical analyses (140 species/sample, including EC/OC, ions, metals, sugars, polyols, and organic acids) and oxidative potential assays were performed. Single-site PMFs identified key sources, but only a combined multi-site PMF approach ensured factor stability. Random forest meteorological normalisation enhanced traffic impact assessment.
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Workplace assessment: inhalable particles formed during the laser ablation of hazardous GaAs materials 1Faculty of Chemistry and Chemical Technology, University of Ljubljana; 2National Institute of Chemistry, Slovenia It is well known that nanoparticles form during laser treatment of solid materials. However, as long as the treated material does not represent a health hazard on its own, the formed aerosol is usually not of worker’s concern and studies of produced particles are relatively scarce. We had a unique opportunity to support a high technology company during the development of laser ablation (LA) systems, investigating aerosols formed during the laser ablation of GaAs wafers and proposing appropiate safety measures accordingly. Particle concentration, size distribution, morphology and chemical composition were studied at the source and behind the filtration unit.
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Acute episodes of particulate matter pollution: the role of day-night atmospheric vertical stratification 1Istituto di BioEconomia IBE-CNR, 50145 Florence, Italy; 2ENEA, SSPT-CLIMAR, 40121 Bologna, Italy; 3Consorzio LaMMa, 50019 Sesto Fiorentino, Florence, Italy; 4Department of Chemistry, University of Florence, 50019 Sesto Fiorentino, Florence, Italy; 5I.N.F.N., Florence, Via Sansone 1, 50019 Sesto F.no, Florence, Italy; 6Department of Physics and Astronomy, University of Florence, 50019 Sesto F.no, Florence, Italy Meteorological conditions favoring PM10 accumulation occur mainly in winter, with high pressure, vertical stability, and weak circulation. Thermal inversions in valleys and lack of precipitation worsen pollution episodes. Strong day-night temperature variations also influence pollutant accumulation. The LaMMA Consortium applied a weather classification method to analyze the correlation between PM10 pollution and recurring meteorological patterns. Critical areas in Tuscany were identified using AirQino network data and WRF model outputs. Particulate matter compositional analyses revealed biomass burning from domestic heating as a major emission source, using techniques like ion chromatography, PIXE, and ICP-AES.
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Aerosol light absorption alleviates particulate pollution during wintertime haze events Institute of Earth Environment, Chinese Academy of Sciences, China, People's Republic of Aerosol light absorption can reduce near-surface PM2.5 during wintertime haze events. Absorbing aerosols create a “warm bubble” above the planetary boundary layer, generating secondary circulations that lower PM2.5. Additionally, aerosol absorption of UV light reduces photolysis, hindering ozone formation and suppressing secondary aerosols. Combined, these interactions decrease PM2.5 by 7.4%. This negative feedback should be considered in weather, climate, and health models.
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Alternative approach to the determination of Cr(VI) in a Cr(III)-rich particulate matter for occupational exposure assessment 11Department of Science and High Technology, University of Insubria, Como, 22100, Italy; 2Department of Theoretical and Applied Sciences, University of Insubria, Varese, 21100, Italy This study aims to assess the performance of official methods in the challenging determination of Cr(VI) in Cr(III)-rich particulate matter and to develop a novel, robust analytical protocol to address this issue. This study involves the application of the developed method in the analysis of Cr(VI) in welding fumes, in occupational environments characterised by the processing of chromium-rich steels. The aim is to verify the reliability of the protocol in complex matrices, ensuring accuracy in chromium speciation and minimising false positives. A previous study was conducted in tannery environments.
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Ammonia and ammonium nitrate in the Po Valley: monitoring, sources, and impacts on Air Quality ARPA Lombardia, Italy Since 2007, ARPA Lombardia has monitored ammonia concentrations, a key precursor of ammonium nitrate, at urban and rural sites. Agriculture and slurry storage account for 96% of ammonia emissions in Lombardy, mainly from livestock farming and fertilizer use. Since 2017, intensive campaigns have analyzed ammonia emissions and particulate composition, studying different slurry spreading techniques. Data on PM10, NH3, NOx, SO2, and meteorological parameters were collected, along with particle size distribution. Measurements at farms and Milan’s urban site (Milano-Pascal) were compared to assess aerosol formation conditions. Findings from 2019-2025 will focus on aerosol size distribution and fertilization phases.
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Assessing chemical PM10 concentrations in school settings over two seasons 1Centre for Environmental and Marine Studies (CESAM), Department of Environment, University of Aveiro, Aveiro, 3810-193, Portugal; 2Center for Research in Sustainable Chemistry-CIQSO, Associate Unit CSIC-University of Huelva “Atmospheric Pollution”, Campus El Carmen s/n, 21071 Huelva, Spain; 3CIMO, LA SusTEC, Instituto Politécnico de Bragança, Campus de Santa Apolónia, 5300-253 Bragança, Portugal This study examines particulate matter (PM10) exposure at a school near an industrial estate in Portugal. Samples from classrooms and the schoolyard were analysed during winter and spring. Indoor PM10 concentrations averaged 24.0 µg/m³ in winter and 29.4 µg/m³ in spring, while outdoor levels were higher in winter (28.2 µg/m³). Major PM10 sources included fuel burning, sea salt, resuspended dust, and industrial activity. The study highlights the importance of identifying these sources to mitigate PM10 exposure, which can negatively impact children's health and academic performance.
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BIOINFO – the internet database on risks associated with exposure to harmful biological aerosols in the work environment Central Institute for Labour Protection – National Research Institute, Poland The BIOINFO database is a unique information platform about biological threats in the work environment. The database contains: information on applicable European laws, information necessary to assess occupational risk related to exposure to biological agents, checklists supporting occupational risk , description of qualitative and quantitative methods used in identification of air microbiological pollutants, characteristics of available measurement methods and the ways of interpreting their results, a list of major biological agents related to the professional activities in different work environments, and methods of protection and prevention against adverse effects of biological agents.
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Chemical Composition of Deposition Particles in the Riotinto Mining District (Huelva, Spain) University of Huelva, Spain This study examines the deposition levels and chemical composition of the insoluble fraction and heavy metals in deposition particles (DP) from the Riotinto Mining District. To achieve this, three monitoring stations were selected, located in La Dehesa and the municipalities of Nerva and Minas de Riotinto, during the period 2022–2023.
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Comparison of statistical spatial modelling and machine learning algorithm to assess population exposure to PM10 and PM2.5 1Italian Institute for Environmental Protection and Research, Italy; 2Department oEpidemiology of the Lazio Regional Health Service, ASL Roma 1, Rome, 00144, Italy; 3ARPAE, Regional Environmental Agency of Emilia-Romagna, 40122 Bologna, Italy; 4Department of Life Sciences. University of Modena and Reggio Emilia, 41125 Modena, Italy; 5Department of Engineering ‘Enzo Ferrari’. University of Modena and Reggio Emilia, 41125 Modena, Italy Our objective is to conduct a sensitivity analysis between spatio-temporal models, based on different methods: Random Forest (RF) models, which have been widely used for exposure estimates in Italy, and statistical models based on the INLA-SPDE approach, in order to evaluate the potential for creating an integrated model (ensemble model). We also aim to demonstrate the capability of both RF and INLA-SPDE methods to improve the surface concentration estimates produced by chemical diffusion and transport models as well as the spatial resolutions of these estimates, while maintaining sufficient temporal resolution for the main application purposes.
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Correction of CAMS PM10 Reanalysis Improves AI-Based Dust Event Forecast Weizmann Institute, Israel Dust storms affect air quality, climate, and health, making early warnings crucial. The Copernicus Atmosphere Monitoring Service (CAMS) provides PM10 estimates for forecasting, but existing discrepancies with ground measurements impact accuracy. AI-based models struggle due to scarce dust event data. This study proposes a machine-learning approach to correct CAMS PM10 fields using in-situ data. A gradient-boosting model predicts CAMS errors across the Eastern Mediterranean, improving accuracy by 12 μg m−3 on average. A deep neural network trained on bias-corrected PM10 fields enhances city-scale dust event forecasting (0–72 h) over the Balkans, improving AI-based predictions across all metrics.
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Determination of Tire-road Wear Particle (TRWP) Emission Factor Under Realistic On-road Driving Conditions Korea Institute of Machinery and Materials, Korea, Republic of (South Korea) This study aims to evaluate the impact of tire wear on airborne PM emissions through real-world on-road driving experiments using actual vehicles. When sampling particles under real driving conditions, particles from various sources are mixed. To selectively analyze tire-road wear particles (TRWPs), pyrolysis gas chromatography-mass spectrometry (GC–MS) was employed, as described in ISO/TS 20593. A tracer gas experiment was conducted to correlate TRWP concentrations obtained using the pyrolysis GC-MS method with an emission factor. The results revealed that 3.1% of tire wear particles fall within the PM10 fraction, of which 14% belong to the PM2.5 fraction.
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Efficient numerical analysis for performance evaluation of an electrostatic precipitator under varied jet flow velocity profiles 1Korea Institute of Science and Technology Europe Forschungsgesellschaft mbH, Germany; 2Department of Mechanical Systems Engineering, Sookmyung Women’s Univeristy, Korea; 3Department of Materials Science and Engineering, Korea University, Korea This study evaluates electrostatic precipitator (ESP) aerosol collection efficiency under different jet flow velocity profiles using a 2D axisymmetric model in COMSOL Multiphysics 6.3. Simulating laminar flow at 0.3 L/min with a 25 kV potential, it compares uniform and fully-developed inlet flows. Results indicate uniform flow enhances collection efficiency. Since real-world inlet pathways are often too short for fully developed flow, the study emphasizes the need to consider velocity variations when assessing ESP performance. These findings align with prior research and commercial applications of ESPs for aerosol sampling.
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HIGH TEMPORAL AND SPATIAL RESOLUTION MONITORING APPROACH FOR INDOOR AIR QUALITY EVALUATION IN NATURALLY VENTILATED CHURCHES Università degli Studi di Bari, Italy This study aims to investigate the time profiles of pollutants concentrations in a church and basilica during the liturgical celebrations in order to estimate the emissions dynamic induced by incense burning and its potential health impacts, so were carried out two high-time and spatial resolved monitoring campaigns. The preliminary results showed that during the hours of greatest crowd of faithful and in correspondence of incense use significant concentrations increment of all investigated pollutants were registered. Therefore, this study allowed to highlight the significant impact of the incense burning on IAQ and, thus, health of priests and altar boys.
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InAPI: Indoor air pollution inventory tool to visualise activity-based concentrations and emission rates of pollutants for the UK 1Cranfield University, United Kingdom; 2Lancaster University, United Kingdom; 3University of Birmingham, United Kingdom Indoor air pollution poses a serious risk to public health. People can encounter different pollutants in places like homes, workplaces, vehicles, and recreational areas. There is a uneed to understand how different sources and activities contribute to air pollution over time in these spaces. The InAPI tool is built on a database of indoor air pollutants in the UK. It organizes information about pollutants, environments, and occupants' activities, and provides data on indoor pollutant concentrations and their emission rates. This is vital for researchers and policymakers to inform interventions as well as guide future research in managing indoor air quality.
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Advancing analytical approaches to improve bioaerosols detection and characterisation Cranfield University, United Kingdom While knowledge about the physico-chemical and biological properties of bioaerosols from various man-made and natural environments is increasing, significant gaps still exist that hinder our understanding of the role and impact of bioaerosols on public health, climate, and ecosystems. This project seeks to harness the advancements in sensing and molecular analysis technologies and data analytics for the real-time detection and characterization of bioaerosols in varied environments, enhancing our understanding of their nature, magnitude, fate, behaviour, and the resultant impact pathways.
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Monitoring of size distribution of ultrafine particles in Tuscany Region ARPAT, Italy The new European Directive for air quality 2024/2881 poses new monitoring needs. Among these there are the Ultrafine Particles (UFP) for which it is recommended the monitoring in sites where high levels are expected. In particular: traffic roads, harbours, airports, sites affected by biomass burning. The study presents results for all the monitored sites. The aim of the study is to characterize the granulometric distribution according to the source, in particular the biomass burning. This work is the starting point for the definition of the new regional network according to the criteria of the new air quality Directive.
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Origin and hourly variation of metals and metalloids in industrial and mining areas of Huelva (SW Europe) University of Huelva, Spain Emissions of metals and metalloids as a result of industrial processes and mining activities, entail a risk to human health. The use of near real-time techniques allows high time resolution (1-h) studies to be carried out to know more precisely their origin and hourly behaviour. In Huelva (SW Spain), two main areas where anthropogenic activities are carried out, are recognized: the Ría of Huelva and the mining district of Riotinto. This study emphasizes the need for continuous monitoring of these elements to control and minimize their exposure to the population.
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PM10 concentrations at different locations in the Dominican Republic 1Department of Applied Physics, Miguel Hernández University, Avda. Universidad S/N, 03203, Elche, Spain; 2Department of Biology, Faculty of Science, Universidad Autónoma de Santo Domingo (UASD), Santo Domingo, 10105, Rep. Dom. This study investigates PM10 concentrations in the Dominican Republic, a region where emission controls are limited and air pollution poses potential health risks. PM10 samples were collected every six days from January to December 2022 at four urban sites using high-volume samplers. Results show that the annual PM10 limit (50 µg/m³) was exceeded at all but one site, with concentrations comparable to other Caribbean coastal cities. A moderate correlation (r = 0.66) was observed between two sites in Santo Domingo, highlighting the influence of local meteorological conditions. These results highlight the need for stricter air quality regulations in the region.
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Potential effect of inhalation exposure to the organic and inorganic constituents of ambient PM2.5 could modulate Amyotrophic Lateral Sclerosis progression Sri Sathya Sai Institute of Higher Learning, India Amyotrophic Lateral Sclerosis (ALS) is a progressive motor neuron disease, with 90% sporadic and 10% genetic cases linked to Single-nucleotide polymorphism. PM2.5 exposure is associated with neurodegenerative diseases, including ALS, by inducing oxidative stress and mitochondrial dysfunction. This study examines TDP43 aggregation in a yeast ALS model using screened PM2.5 constituents from Bangalore, India. Organic and inorganic compounds of PM2.5, including PAHs like B[a]A, B[a]P, B[b]F, D[ah]A, Ind and metals such as Cd²⁺, Fe²⁺, Cr⁶⁺, and Ni²⁺, significantly increased TDP43 aggregation. This study suggests PM2.5 potentially exacerbates ALS, highlighting environmental pollution as a potential risk factor for neurodegeneration.
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Relationship between atmospheric electric field, precipitation and air ions University of Tartu, Estonia The objective of the present study is to understand the influence of meteorological processes on the atmospheric electric field (AEF). We present a dataset of AEF and air ion measurements from a hemiboreal forest region, at Järvselja (SMEAR Estonia) in southeastern Estonia, to investigate the influence of local meteorological and air pollution processes on the AEF.
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Size-resolved condensation sink in different urban environments 1Tampere University, Finland; 2Finnish Meteorological Institute, Finland Condensation of gaseous components on existing particles is important in terms of aerosol health and climate effects. Condensation sink (CS) is a useful parameter, which has been widely utilised to estimate the condensation growth rate of existing particles. Typically, only total CS is considered in atmospheric aerosol studies. In this study, we demonstrate how CS size distribution could be a highly important parameter in terms of both aerosol health and climate effects. We report CS size distributions measured in different urban environments, including road/river traffic sites, airports, detached housing areas and industrial sites, in Finland, Germany, Czechia and India.
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Size-resolved microphysical and optical properties of atmospheric aerosols in an urban area of the northern Tibetan Plateau 1Institute of Atmospheric Physics, Chinese Academy of Sciences, China; 2College of Environment and Climate, Jinan University, China Aerosols at high altitudes on the Tibetan Plateau (TP) influence regional climate and hydrology. This study analyzes the microphysical and optical properties of aerosols in northern TP using a ground-based tandem system. The particle number size distribution follows a lognormal pattern, peaking at ~70 nm. Refractory black carbon (rBC) accounts for 17.7% of particles in the 100–750 nm range, with larger particles showing higher rBC fractions. Most rBC particles are externally mixed, with non-spherical structures. The study provides key insights for improving aerosol radiative forcing estimates and understanding aerosol–climate interactions in high-altitude regions.
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Statistical evaluation of particulate matter (PM1) concentrations in indoor and outdoor air of households in Zagreb, Croatia 1Division of Environmental Hygiene, Institute for Medical Research and Occupational Health, Zagreb, 10000,; 2Division of Toxicology, Institute for Medical Research and Occupational Health, Zagreb, 10000, Croatia Different sources of indoor air pollutants are expected to significantly affect the concentration of indoor air pollutants and therefore make significant differences in PM concentration between households. A pilot study of air quality in households is being conducted in Zagreb (Croatia) as part of the EDIAQI (Evidence Driven Indoor Air Quality Improvement) project, in which one of the key aspects is concentrations of particulate matter with an aerodynamic diameter of less than 1 μm (PM1). This study aims to showcase the differences in measured levels of PM1 in different households.
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The contribution of chemical components and the particle core to the toxicity of diesel exhaust particles 1Norwegian Institute of Public Health, Norway; 2University of Oslo, Norway A key objective of the ULTRHAS project is clarifying which physical and chemical characteristics are the main drivers of the effects of particles from transport mode emissions. The present study found that the harmful effects of diesel exhaust particles (DEP) were mainly due to adsorbed chemical constituents, not the carbon core. Using a 3D airway cell model, RNA sequencing analysis revealed that DEP and its chemical extracts caused significant gene expression changes, while the residual washed particles had minimal impact. These finding emphasize the key role of soluble chemicals in DEP toxicity.
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Utilization of Airmodus Condensation Particle Counters in the Net4Cities Network for Long-Term Air Quality Monitoring 1Airmodus Ltd., Helsinki, 00560, Finland; 2Research Institute for Sustainability at GFZ, Potsdam, Germany; 3Flemish Institute for Technological Research, Mol (VITO), Belgium; 4Climate and Atmosphere Research Center (CARE-C), The Cyprus Institute The Net4Cities project enhances air and noise pollution monitoring in 11 European cities, supporting Zero Pollution Action Plans and the EU Green Deal. With 24 CPCs deployed, the study compares n-butanol and propylene glycol as CPC working fluids, assessing detection performance, stability, and suitability for long-term monitoring. Standardized sampling systems ensure data consistency across diverse environments. Findings contribute to real-time pollution assessments, source apportionment modeling, and policy decisions on transport-related emissions. This research advances air quality monitoring technologies, providing insights into sustainable alternatives for ultrafine particle measurement in urban settings.
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Enhancing Information on COPD Exacerbations Through the Integration of Qualitative Approaches in Non-Hospitalized Patients with Mild COPD 1Chair of Spatial Planning, Faculty of Civil and Geodetic Engineering, University of Ljubljana, Jamova Cesta 2, 1000, Slovenia; 2Dept of Physical Chemistry, School of Industrial and Aerospace Engineering, Inst. Of Nanoscience, Nanotechnology and Molecular Materials, Universidad de Castilla-La Mancha, 45071, Toledo; 3Dept of Pneumology, ASL Salerno-Luigi Curto Hospital, Polla (SA), Italy This study highlights the value of integrating qualitative and quantitative methods in environmental epidemiology, focusing on the progression of COPD in urban areas. By combining social, demographic, and clinical data, the research explores how factors like residential environment influence lung function variability. Through a systematic review using the PRISMA methodology, 15 peer-reviewed articles were selected, demonstrating the importance of contextual and cultural factors in shaping health outcomes. The findings emphasize that qualitative research enhances quantitative analyses, providing a deeper understanding of environmental health challenges and offering insights for personalized, localized interventions to improve air quality and public health.
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Estimating PM2.5 Concentrations in Classrooms Installed with Fresh Air Units Through the Determination of the Indoor PM2.5 Generation Rate and Non-Ventilation Removal Rate National Cheng Kung university, Taiwan This study develope a technique to quantify indoor PM2.5 generation (G) and non-ventilation removal (K) rates in classrooms with Fresh Air Units (FAUs). A well-mixed room modelling approach and first-order Runge-Kutta method were used to assess the PM2.5 exposure concentration. A typical elementary classroom equipped with FAUs was monitored was selected for PM2.5 and CO2 measurements. Results showed significant PM2.5 reductions and acceptable CO2 levels. A first-order Runge-Kutta method minimized differences between measured and predicted PM2.5, yielding G (GM (GSD)) as 10.7 (2.1) and 19.2 (1.2) µg/min respectively for lecture sessions and noon rest periods, and K consistently as 0.
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Air quality assessment on the central campus of the national University of Equatorial Guinea: aerosol monitoring and its impact on the university community 1Universidad de León, Spain; 2National University of Equatorial Guinea; 3Droplet Measurement Technologies, LLC, Longmont, CO, USA The study assesses air quality at the central campus of the National University of Equatorial Guinea (UNGE) in Malabo. Monitoring of PM1, PM2.5, PM10, CO2, and TVOC from August 2023 to January 2025 showed significant variability in pollutant concentrations. PM10 levels exceeded WHO guidelines during the dry season, posing risks to vulnerable populations. A general decline in PM10 was observed over the study period, but concerns remain about data quality for PM2.5 in 2025. The study highlights the importance of continuous air quality monitoring and mitigation strategies.
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Indoor air quality in schools of Malabo, Equatorial Guinea: health risks and environmental factors in the African context 1Universidad de León, Spain; 2National University of Equatorial Guinea; 3Droplet Measurement Technologies, LLC, Longmont, CO, USA The study assesses indoor air quality in four schools in Malabo, Equatorial Guinea, measuring levels of PM₂.₅, PM₁₀, and CO₂. The results reveal that all schools exceeded the air quality guidelines established by the WHO. The "Virgen María de África" school recorded the highest PM₂.₅ concentrations, exceeding the WHO's recommended daily limit by a factor of three. The study highlights the substantial health risks associated with this exposure, including respiratory infections and asthma exacerbation.
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Analysing bioaerosols regarding their impact on human health in freely-ventilated pig and cattle barns Unit Bioaerosols, Federal Institute for Occupational Safety and Health, Berlin, Germany Agricultural employees are constantly exposed to high concentrations of inhalable dust containing microorganisms, toxins and other biological substances, which poses them to a risk for adverse health effects. Freely-ventilated pig and milk cow barns meet higher standards for animal welfare but also change the composition of bioaerosols. Using high volume sampling in the barns as well as at the interface to the environment the subsequent combination of advanced metaproteomic analyses and toxicological in vitro studies on lung epithelial cells together with culture-dependant microbiological and molecular biological screening is aimed to identify main parameters relevant for occupational health.
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Assessment of measures to reduce the impact of climate change on indoor air quality Department of Material Analysis and Indoor Chemistry, Fraunhofer WKI, Braunschweig, 38108, Germany Climate change impacts indoor air quality (IAQ) as changing outdoor conditions are also reflected indoors. This study evaluated preventive measures on a test house using the Indoor Air Quality Climate Change (IAQCC) model under the SSP5-8.5 climate scenario by 2100. Measures studied include natural and mechanical ventilation, shading and smart control. Results show that indoor overheating is significantly reduced by window shading and smart ventilation. Mechanical ventilation with coarse filters could lead to increased indoor PM2.5 and ozone levels. Results underline the need for a balanced approach that considers both thermal comfort and pollution levels in future IAQ improvement strategies.
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Can air purifiers remove radioactive aerosol particles from household air in radiation hazard situations? 1National Defence University, Finland; 2University of Jyväskylä, Finland; 3University of Helsinki, Finland; 4Radiation and Nuclear Safety Authority, Finland This study evaluates air purifiers' effectiveness in reducing radioactive aerosol particles in households during radiation hazards. Using natural radon as a radiation source, air purifiers with activated carbon and HEPA13 filters were tested in a controlled space. Preliminary results show these purifiers efficiently reduce aerosol particle concentrations, especially in the accumulation mode, but have minimal impact on ultrafine particles and unattached radon. The findings suggest that while air purifiers can reduce certain radioactive contaminants indoors, their ability to mitigate all forms of radioactive exposure is limited. Future experiments will explore filter contamination management post-incident.
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Changes in cholesterols profile in THP-1 cells and mice lung tissue after exposure to PbO nanoparticles Institute of Analytical Chemistry of the Czech Academy of Sciences, Czech Republic PbO NPs exposure lead to the accumulation of Pb in the lungs, stimulation of the immune system of exposed mice and caused changes in cholesteryl ester levels in macrophage cells.
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Characteristics of Particle-bounded Air Toxic Emissions and Exposure Risk By Cogeneration System Using Solid Waste Recovered Fuel National Cheng Kung University, Taiwan Cogeneration boilers in Taiwan use Solid Recovered Fuel (SRF) to reduce coal consumption. In 2020, 38.5 thousand metric tons of SRF were co-fired with coal in many boilers. This study analyzed emissions of air toxics (As, Pb, Cd, dioxins) and assessed potential health risks in surrounding areas. Results showed significant variation in PM and air toxic emission factors, influenced by SRF composition, mixing ration, and air pollution control devices. The maximum exposure risk in surrounding areas caused by the case was below 10⁻⁶.
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Citizen Science and Nature-Based Solutions to Reduce Particulate Matter Exposure in Schools 1C2TN, Instituto Superior Técnico, Universidade de Lisboa, Portugal; 2CITUA, Instituto Superior Técnico, Universidade de Lisboa, Portugal Educational spaces must promote sustainability and well-being, especially in polluted areas. This study co-designed a multifunctional space in the Basic School of Camarate, Portugal, integrating Nature-Based Solutions (NBS) for air quality improvement and community well-being. Given the school's proximity to major pollution sources – airport and high-traffic streets – students, teachers, staff and environment and architecture researchers, identified the need for NBS to mitigate exposure to particulate matter (PM₂.₅, PM₁₀), black carbon, and ultrafine particles. Air quality was assessed pre- and post-implementation and results highlight the effectiveness of NBS in mitigating pollution and the value of interdisciplinary collaboration in sustainable school design.
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Comparison of Airborne In-Situ and Ground-/Satellite-Based LIDAR-Derived Aerosol Light Extinction Coefficients During the JATAC/CAVA-AW Campaigns in 2021 and 2022 1Center for Atmospheric Research, University of Nova Gorica, Ajdovščina, 5270, Slovenia; 2Haze Instruments d.o.o., Ljubljana, 1000, Slovenia; 3Aerovizija d.o.o., Vojnik, 3212, Slovenia; 4IAASARS, National Observatory of Athens, Penteli, 15236, Greece; 5Meteorological Institute, Ludwig Maximilian University of Munich, Germany; 6Leibniz Institute for Tropospheric Research, Leipzig, Germany; 7Ocean Science Centre Mindelo, Mindelo, CP 2110, Cape Verde; 8GEOMAR Helmholtz Centre for Ocean Research, Kiel, 24148, Germany; 9ESA/ESTEC, Noordwijk, 2201 AZ, Netherlands Here we compare the optical product of ESA's space-borne ALADIN lidar with the in-situ airborne measurements obtained during the JATAC campaign over Cabo Verde in 2021–2022. In-situ measurements of aerosol optical properties were matched to Aeolus overpasses and extrapolated to 355 nm. Despite the spatial and temporal resolution differences, results of comparison between the in-situ and space-borne aerosol light extinction coefficients show good agreement (regression slope of 0.99, geometric Rg² of 0.54). Additional comparisons of the in-situ aerosol light extinction coefficient with ground-based lidars (PollyXT and eVe) data show regression slopes of 0.69–0.94 and Rg² > 0.74.
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Effect of air purifiers on indoor air pollution in beauty salons 1Institute of Environmental Engineering of the Polish Academy of Sciences, M. Skłodowskiej-Curie 34, 41-819 Zabrze, Poland; 2Fire University, 01-629 Warsaw, Juliusza Słowackiego 52/54, Poland This study compared indoor/outdoor mass ratios (I/O) for respirable particulate matter and its organic (OC) and elemental carbon (EC) components in beauty salons before and after air purifier installation. Measurements from 2015 and 2024 show all I/O ratios exceeding unity, confirming significant indoor pollutant sources. Respirable PM and EC ratios increased in 2024, while OC ratios decreased. Notably, the variability in data diminished with air purifiers, indicating more stable pollutant levels indoors. These findings suggest that air purification improves consistency in air quality. Extended measurements over different seasons are recommended to better establish indoor air quality standards for beauty salons.
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Environmental contamination of antibiotics in Swedish hospitals 1Region Skåne, Sweden; 2Lund University, Sweden Antibiotics are pharmaceuticals used for treatment of bacterial infections. Occupational exposure to antibiotics may cause hypersensitivity reactions and occupational allergy as well as due to risk of bacterial resistance development. The aim of this study was to map the level of environmental contamination of currently used antibiotics in healthcare and to propose hygienic guidance values (HGV)s for antibiotics based on wipe test measurements in Swedish hospitals. A wipe test sampling method combined with mass spectrometric analysis of six antibiotics was developed. A screening campaign was performed at in total 16 wards located at five different public hospitals.
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Experimental study of aerosol emission and flow exiting a wound during mock-up tracheostomy operations 1ASNR - France; 2CERTES . UPEC, University Paris Est; 3Hopital Laveran Following the SARS-CoV-2 pandemic, awareness of indoor aerosols has increased, emphasizing the need to identify aerosol sources. During the pandemic, tracheostomies were performed on patients with respiratory distress. Two types of procedures, Surgical Tracheostomy (ST) and Percutaneous Dilatation Tracheostomy (PDT), are associated with high risks of airborne disease transmission due to aerosolized bronchial secretions. This study compares the emission rates and particle numbers during both procedures and examines the flow exiting the wound. Using a mannequin, aerosol injection, and flow visualization techniques, the study found PDT to be riskier due to its longer duration and higher total particle emission.
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Exploring the Impact of Bioaerosols: Pollen, Cyanobacteria, Microalgae and Fungi in Diverse Environments 1University of Wroclaw; 2University of Gdansk; 3Mount Allison University Bioaerosols are airborne organisms, their excrements, or by-products originating from aquatic and terrestrial environments. Bioaerosols were studied at two sites in Poland: Gdynia (coastal) and Wrocław (inland).This study presents key findings on the presence of pollen, cyanobacteria, microalgae, and fungi in the atmosphere and compares sampling and analytical methods, including Hirsch Trap, TISH Environment impactor, and SWISENS POLENO. The results confirm the year-round presence of bioaerosols, some of which may pose health risks. Understanding bioaerosol composition and improving quantification methods are crucial for assessing their environmental and health impacts. This study highlights the significance of methodological advancements in bioaerosol research
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Exposure to particulate matter during rural, urban and highway asphalt work 1National Research Centre for the Working Environment, Denmark; 2Department of Chemistry, University of Copenhagen, Copenhagen, DK-2100, Denmark; 3Occupational and Environmental Medicine, Lund University, Lund, 22100, Sweden ; 4Occupational and Environmental Medicine, Region Skåne, Lund, 22381, Sweden; 5Ergonomics and Aerosol Technology, Lund University, Lund, SE-22100 Lund, Sweden We attended 20 days of paving rural and urban roads, and highways in the period 2022-2024 and evaluated the max concentrations og particulate matter (PM) in 81 near-field plumes from 11 locations. Bitumen fumes in the submicron particle fraction dominated PM and the highest concentrations were observed near the paving machine. The concentrations were lowest on rural locations and highest during highway work. The observed differences could largely be ascribed to asphalt type and temperature, wind speed and number of paving machines operating in close vicinity.
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Exposure to traffic-related particulate matter in schools and hospitals in a city quarter 1Helmholtz-Zentrum Hereon, Germany; 2Imperial College London, UK Traffic emissions of particulate matter in urban environments are related to higher risk of asthma, lung cancer, and cardiovascular diseases, especially among the vulnerable groups, such as school children and the elderly. In this study, simulations were conducted for 2023 with two urban dispersion models, ADMS-Roads 5 and EPISODE-CityChem, to assess the air quality in an inner-city urban area in Hamburg. Long-term exposure to PM2.5 levels at hospitals, schools and nurseries exceeded the WHO’s recommendation guidelines. We intend to conduct scenario simulations in accordance with the Hamburg mobility strategy for the year 2030.
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Five-year trend of levoglucosan levels in winter at the urban station in Zagreb, Croatia Institute for Medical Research and Occupational Health, Croatia Despite the extansive natural gas infrastructure, biomass burning for residential heating remains common in Zagreb, contributing to poor air quality mostly during wintertime. This study assessed levoglucosan (LG), a biomass burning tracer, in PM1 fraction over a five-year period (2019–2023) to evaluate its long-term trends. LG was quantified using ion chromatography, and results showed strong correlations between LG and PM1 levels. LG concentrations ranged from 0.689 to 1.023 µg/m³, with a slight decreasing trend. The LG/PM ratio remained stable (4.8–6.2%). Findings suggest biomass burning is a significant and persistent source of particulate matter in urban site of Zagreb City.
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How can we determine the level of particles that impact our health? Development of laboratory studies with the PolluRisk platform. 1Université Paris Cité et Univ Paris Est Creteil, CNRS, LISA, F-75013 Paris, France; 2Univ Paris Est Creteil et Université Paris Cité, CNRS, LISA, F-94010 Créteil, France; 3Université Paris Est-Créteil, INSERM, IMRB, F-94010 Créteil, France; 4Laboratoire Hypoxie&Poumon, INSERM, Université Sorbonne Paris-Nord, F-93000 Bobigny, France; 5Service de Physiologie et d’Explorations Fonctionnelles, Hôpital Avicenne, APHP, F-93000 Bobigny, France To estimate the levels of particles that impact health, we conduct exposure studies using the POLLURISK platform. The principle is to expose biological models to a realistic atmosphere simulated in a smog chamber. In this study, the aim was to simulate an atmosphere with PM10 concentration around 20 µg/m3, typical of a European city. The results showed that particulate compounds (NH4 and organic) were representatives of those in a real atmosphere of an urban city in proportion. However, the stability of the concentration can be improved (the coefficient of variation is 22%).
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Impact of Return Air Ratios and Filtration on Airborne Infection Risk in Healthcare Settings 1Tsinghua University, China, People's Republic of; 2School of Building Engineering, Xi’an University of Architecture and Technology, Xi’an, China Efficient ventilation strategies are critical for controlling airborne transmission of respiratory pathogens in healthcare environments. This study investigates the influence of return air ratios and return air filtration on individual exposure risks to infectious aerosols in a full-scale ISO-5 clean chamber. Results reveal that distance to the index patient is the primary factor of the airborne infection risk. Reducing the return air ratio, or implementing of HEPA filters at the return air terminal didn’t lower the inhalation exposure. It indicates that return air from the building ventilation system is not the key to minimize person-to-person transmission of respiratory aerosols.
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In-human performance characterisation of laparoscopic surgical smoke management technologies on the example of sleeve gastrectomy 1Topas GmbH, Dresden, DE-01237, Germany; 2St. Martinus-Krankenhaus, Department of Surgery, Düsseldorf, DE-40219, Germany; 3Fliedner Fachhochschule, University of Applied Science Düsseldorf, Düsseldorf, DE-40489, Germany Cutting of organic tissue by means of modern energy-driven surgical instruments is accompanied by the formation of surgical smoke, i.e., aerosols composed i.a. of water vapour, soot, cell debris, bacteria and viruses. Surgical smoke interferes during laparoscopic interventions not only the surgical view but poses also a health risk for surgical staff. Thus, laparoscopic surgical smoke management technologies were designed to remove surgical smoke. Although the use of surgical smoke management technologies is strongly recommended, only limited performance data for such technologies exist. The present in-human study attempts to confirm the findings of previous studies under realistic conditions.
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Indoor air quality at the Sephardic Museum (Toledo, Spain): PM and bioaerosol study 1Faculty of Environmental Sciences and Biochemistry, Toledo, UCLM, Spain; 2Faculty of Chemical Sciences and Technologies, Ciudad Real, UCLM, Spain; 3Department of Science and Agroforestry Technology and Genetics, Albacete, UCLM, Spain An often overlooked aspect of cultural heritage conservation is the indoor air quality (IAQ) in heritage buildings and museums. IAQ plays an important role in the longevity and integrity of historic materials, as it influences both their chemical stability and their physical state. The objective of the study was to analyse the IAQ in The Transito Synagogue, a significant historical and cultural monument in Toledo, Spain. The level of PM of different sizes were measured, the bioaerosols using culture-dependent and culture-independent analyses were quantified, and the presence of genes which codifying proteins that biodegrade relevant materials was determined using qPCR.
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Indoor air quality in school: Key influencing factors Center of Physical Sciences and Technology, Lithuania Children are particularly susceptible to air pollution as their bodies are still developing. In schools, both indoor and outdoor air pollution is important as children spend their breaks outdoors. The ratio of indoor and outdoor particle number concentrations was analysed, as well as the differences in the lognormal profiles of indoor and outdoor particle number and mass concentrations during different episodes and activities in the classroom. The rate of removal of air pollutants such as PMs from the classroom after school hours was calculated for different episodes, taking into account ventilation options and outdoor air pollution.
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Industrial particulate matter, characterization and collection for an animal-free prediction of nanomaterial-induced adverse outcomes 1Ergonomics and Aerosol Technology, Lund University, Lund, Sweden; 2NanoLund, Lund University, Lund, Sweden; 3Occupational and Environmental Medicine, Lund University, Lund, Sweden; 4Department of Condensed Matter Physics, Jozef Stefan Institute, Ljubljana, Slovenia; 5Work Environment Toxicology, STAMI, Oslo, Norway Airborne particles smaller than 2.5 µm of nine different industrial materials, representing both established high-production materials and advanced nanomaterials for emerging technologies, as well as different life cycle stages, have been collected and characterized in terms of size distribution, size-resolved chemical composition, morphology, and endotoxin levels. The materials will be used to calibrate and validate in-silico models developed for quantitative prediction of adverse outcomes in vivo.
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Investigation of fungal microbiome in indoor environments of public-use facilities in Korea 1Seokyeong University, Korea, Republic of (South Korea); 2Antibacterial Resistance Laboratory, Institut Pasteur Korea, Seongnam-si, 13588, Republic of Korea; 3Institute of Environmentsl Health and Safety, Seoul, 04788, Republic of Korea; 4Department of Agricultural Science Korea, National Open University, Seoul, 03087, Republic of Korea Indoor fungi affect health, requiring constant monitoring. We analyzed fungal compositions in environmental samples from Korean public facilities in 2022. Results showed indoor fungal microbiota are influenced by both environmental and human-originated fungi from occupants. Some samples contained opportunistic pathogenic fungi. This study enhances understanding of indoor fungal microbiota in Korea and highlights the potential of microbiota analysis for pathogen monitoring. Such analysis can help detect emerging pathogens and support effective preventive measures against health risks. Continuous surveillance of indoor fungi is essential for controlling harmful proliferation and ensuring healthier indoor environments for occupant
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Occupational inhalation exposure to welding fumes 1University of Science and Technology Beijing, China, People's Republic of; 2School of Architecture, Tsinghua University, Beijing, China, People's Republic of This study seeks to fill these gaps by measuring welders’ inhalation exposure to welding fumes and assessing associated health impacts. An integrated protocol was developed and implemented among shipyard welders, focusing on: (1) welding fume concentrations in the breathing zone and small airways, (2) chemical analysis of welding fumes, and (3) evaluating health effects through inflammation, oxidative stress, and lung injury biomarkers. This approach establishes a generalizable framework for precision occupational exposure and health risk assessment, guiding targeted exposure control strategies and safety interventions.
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ODESSA: A collaborative WebGIS platform for predicting hospital admissions related to air pollution exposure 1Centro de Ciências e Tecnologias Nucleares, Instituto Superior Técnico, Universidade de Lisboa, 2695-066 Bobadela-LRS, Portugal; 2Centre for Environment and Marine Studies (CESAM), University of Aveiro, 3810-193 Aveiro, Portugal; 3Instituto de Telecomunicações, University of Aveiro, 3810-193 Aveiro, Portugal Artificial intelligence and predictive analytics use the increasing data generated nowadays to enhance business and research activities by enabling the prediction of complex real-world dynamics. Environmental data helps relate variables and predict public health problems, monitor and prevent diseases. The COVID-19 pandemic highlighted the need to anticipate pressure on hospital systems to reduce overcrowding. The ODESSA project addresses these challenges by developing a collaborative open-source WebGIS platform to predict hospital admissions linked to air pollution. By integrating historical data on hospital admissions, meteorology and air quality, the tool will support health authorities, policymakers, and citizens to identify risk areas and allocate resources effectively.
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Assessing the contribution of road traffic to airborne microplastics: the iMPact project 1Centro de Ciências e Tecnologias Nucleares, Instituto Superior Técnico, Universidade de Lisboa, 2695-066 Bobadela-LRS, Portugal; 2Centre for Environment and Marine Studies (CESAM), University of Aveiro, 3810-193 Aveiro, Portugal The growing interest in the effects of particles on human health and local environments has spurred research towards defining and characterising their sources. Road traffic is considered a major source of airborne particles in urban areas. The abrasion of tyres is one of the most dominant sources of microplastics (MPs) in the environment. The iMPact project is investigating the contribution of road traffic as a potential vector of MPs pollution in the environment, extending the knowledge on MPs found in the air and exploring their occurrence to assess the potential personal exposure.
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Overview of indoor air pollution measurements in elementary schools in Denmark: a case study 1Department of Environmental Science, Aarhus University, 4000 Roskilde, Denmark; 2Environment, Occupation and Health, Department of Public Health, Aarhus University, 8000, Aarhus, Denmark; 3Department of Biological and Chemical Engineering - Process and Materials Engineering, Aarhus University, 8000 Aarhus, Denmark Air pollution is a major global health risk, with children spending 90% of their time indoors, making them highly vulnerable. Under the Horizon Europe project LEARN, we measured indoor air quality in Danish schools. We performed measurements of particulate matter (PM) mass, particle number (PN), black carbon (BC), and total volatile organic ocmpounds (TVOCs) using a single-blind crossover design with real and sham interventions. Preliminary data show high PM exposure to children during school hours. Going further, we will analyze pollution sources, mitigation strategies, and the effects of PM on children’s cognitive functions, and test afficacy of purification devices.
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Particle emissions from dry herbs vaping Hellenic Open University, Greece The purpose of this work is to study emissions generated from dry herbs vaping. Four dry herbs were heated using dry herb vaporizer. The results show that more than 99% of the emitted particles have a diameter less than 1 μm. Under the experimental conditions used, Levander was found to emit higher quantities of particles, followed by Chamomile, Eucalyptus and Green tea. Intense vaping and temeprature results to higher Particle emissions The results show that dry herb vaping is not a safe alternative to tobacco, as it emits high concentrations of particles.
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PM-related organic and elemental carbon in hair and nail salons in Poland 1Institute of Environmental Engineering, Polish Academy of Sciences; 2Fite University, Poland; 3Warsaw University of Technology; 4Warsaw University of Life Sciences Analysis of organic matter associated with PM particles is an effective method of identifying specific sources of contamination. We have shown that the differences in air quality between beauty salons and atmospheric air can be attributed to the use of specific beauty salons, ventilation systems, window types and volume. The results presented highlight the need to prioritise the air in beauty salons.
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Pollution Routes: Ship Emissions Impact on Volatile Organic Compounds in the Atmosphere Università degli Studi di Bari, Italy Italy's geographical positioning and abundance of ports render it highly susceptible to air pollution caused by ship emissions. A recent study carried out on the Amerigo Vespucci in the Tyrrhenian Sea utilised low cost, high-resolution instruments to investigate these emissions. The study found that levels of VOCs increased significantly due to motor propulsion and port activities, emphasising the importance of standardised methods for monitoring short-term emission events and suggesting the potential for implementing targeted mitigation strategies within the shipping sector, particularly in variable operating environments.
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Pseudomonas spp. in metalworking fluids – potential bioaerosol contamination of occupational environment in metal industry and phage-based biocontrol method Central Institute for Labour Protection - National Research Institute, Poland This study examines the contamination of metalworking fluids (MWF) with Pseudomonas species, including Pseudomonas aeruginosa, which may be emitted as bioaerosols during manufacturing processes, posing health risks to workers. The analysis of MWF samples revealed that Pseudomonas bacteria constituted up 37.7%, while P. aeruginosa up to 9.2% of the total microbiota. The application of bacteriophage 16 resulted in a significant reduction in P. aeruginosa concentration, achieving a 99.9% decrease after 8 hours. These results suggest that phage-based biocontrol may be an effective method for reducing pathogenic bacteria in MWF and bioaerosols, highlighting the need for further research in occupational environments.
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Real-Time Detection of Dusts from Narcotics using Single-Particle Mass Spectrometry 1Joint Mass Spectrometry Centre, University of Rostock and Helmholtz Munich, Germany; 2Federal Criminal Police Office, Forensic Science Institute & Bavarian State Criminal Police Office, Germany; 3University of New South Wales, Canberra, Australia; 4University of the Bundeswehr, Munich, Germany; 5Parteq GmbH, Malsch, Germany; 6Photonion GmbH, Schwerin, Germany This study addresses the urgent need for real-time detection of hazardous dusts, particularly drugs and explosives, using an integrated approach. The core technology, single-particle mass spectrometry (SPMS), enables chemical characterization of individual particles in complex aerosols. A specialized sampling system, incorporating gas-pulse particle redispersion and aerosol enrichment, facilitates direct surface sampling. Field tests at a DHL hub and a former illegal drug lab demonstrated successful identification of drug residues. Machine learning algorithms, particularly supervised learning, enhanced real-time data analysis, outperforming traditional methods in speed and accuracy. This system offers a robust solution for real-time risk assessment and emergency response.
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Respiratory aerosol emission during various phonatory tasks 1Faculty of Medicine, University of Helsinki/ Helsinki University Hospital, Finland; 2Tampere University of Applied Sciences, Finland; 3Aerosol Physics Laboratory, Physics Unit, Faculty of Engineering and Natural Sciences, Tampere University, Finland; 4VTT Technical Research Centre of Finland, Finland; 5Speech and Voice Research Laboratory, Tampere University, Finland; 6Department of Information and Communications Engineering, Aalto University, Finland; 7Heart and Lung Center, Helsinki University Hospital, Finland Airborne transmission plays a key role in spreading respiratory pathogens. This study investigated how different phones, vocalization types, and individual characteristics affect aerosol emission. Forty-one infection-free singers phonated [a], [o], and [r], spoke, whispered, breathed, and coughed in a controlled setup. Whispering generated more aerosols than speaking, and [o] produced more particles than [a]. The alveolar trill [r] emitted more small particles than vowels. While sound pressure level consistently increased emission, exhaled flow rates showed no significant variation between phones. Age, BMI, and exhaled flow rate influenced emission in some activities, but no consistent link was found across tasks.
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Secondary organic aerosol formation potential from vehicles under real-world driving conditions in a tunnel 1PSI Center for Energy and Environmental Sciences, Paul Scherrer Institute (PSI), Villigen, 5232, Switzerland; 2Department of Chemical Engineering, University of Patras, Patras, 26504, Greece; 3Institute of Chemical Engineering Sciences (FORTH/ICE-HT), Patras, 26504, Greece; 4Laboratory of Atmospheric Processes and their Impacts (LAPI), École Polytechnique Fédérale de Lausanne (EPFL), Lausanne, 1015, Switzerland; 5Universite Claude Bernard Lyon 1, CNRS, IRCELYON, UMR 5256, Villeurbanne F-69100, France We provide a comprehensive investigation on the parimary emissions and secondary aerosol formation from vehicles under real-world driving conditions in the Fréjus tunnel . The VOC composition and volatility in the tunnel and OFR were compared to understand the evolution of SOA formation. The SOA compositions were characterized at molecular formula level. Furthermore, the emission factors of secondary aerosols in the tunnel were reported and compared with the chassis dynamometer measurements. The gap between field measurements and laboratory studies will also be discussed.
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Shape factor characterization of dry powder aerosol drugs 1Environmental Physics Department, Institute for Energy Security and Environmental Safety, HUN-REN Centre for Energy Research, Hungary; 2Thin Film Physics Department, Institute of Technical Physics and Materials Science, HUN-REN Centre for Energy Research, Hungary; 3Department of Applied and Nonlinear Optics, Institute for Solid State Physics and Optics, HUN-REN Wigner Research Centre for Physics, Hungary In the aerosol drug deposition modelling, particles are mainly approximated by regular spheres. However, according to microscope images taken after drug formulation, their shape is irregular in most cases. This work aims to combine experimental measurements and numerical simulations to reveal the shape factors of the particles of 3 different commercialized aerosol drugs and the effect of non-sphericity on the lung deposition distribution of these drugs. The results of computer simulations of deposition distribution suggest that neglecting the irregular shape does not lead to a major distortion of the simulation results unless fiber-shaped particles are also present after the formulation.
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Spatial Distribution and Concentration of BaP in PM10 Across Six Locations in Croatia Institute for Medical research and Occupational Health, Croatia Polycyclic aromatic hydrocarbons (PAHs) are harmful air pollutants, with heavier PAHs bound to PM10 particles and lighter ones existing in the gas phase. Benzo(a)pyrene (baP) indicates PAH presence, with a European limit of 1 ng m-3. The main sources of PAHs include the combustion of wood, waste, and fossil fuels. In Croatia, BaP concentrations were measured across six locations throughout all seasons. The highest levels occurred in winter, particularly in Slavonski Brod (9.030 ng m-3), while the lowest were recorded in summer. Results indicated strong seasonal and spatial variability influenced by emission sources and transport.
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Study of drug exposure during magistral preparation of medicine 1University of Debrecen; 2HUN-REN Institute for Nuclear Research (ATOMKI), Hungary Magistral drug compounding is common practice in Hungarian pharmacies. Pharmacist exposure can be caused by inhaled substances or absorption through the skin during the preparation of the medicine. Drug preparation processes, such as mixing in a mortar or sieving, can generate the formation of airborne particles. The purpose of this study was to investigate the potential occupational health risks of extemporaneous preparation of medicine in Hungarian practice.
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Temporal variability of PM₁₀ and PM2.5 in Puerto Plata, Dominican Republic (2020-2024) 1Miguel Hernández University (Spain).; 2Universidad Autónoma de Santo Domingo (UASD). (Dominican Republic). This study analyzes the temporal variability of PM2.5 and PM₁₀ concentrations in Puerto Plata (located on the north coast of the Dominican Republic) over the past five years. The average concentrations were 8.4 µg/m³ and 31.7 µg/m³, respectively. PM10 levels were generally higher between June and October, possibly due to lower precipitation rates, increased tourism activity, and the higher incidence of Saharan dust transport to the Caribbean during boreal summer. The average PM2.5/PM10 ratio for the whole study period was 0.28, indicating a clear dominance of coarse particles.
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Urban Pollution Island (UPI) for ultrafine particles – characteristics and influencing factors 1Technische Universität Braunschweig, Germany; 2German Environment Agency, Germany This study examines the spatial and temporal variability of fine and ultrafine particles on the urban scale of Dresden, Germany. Continuous measurements of the particle number size distribution (PNSD) were carried out at a total of seven locations during a five-month measurement period. Six of the locations are located in the city of Dresden while one characterizes the rural background concentration level. The aim of this study is to characterize the Urban Pollution Island phenomenon by exploring intra-urban differences of PNSD and to quantify the influence of factors such as meteorological parameters using descriptive and exploratory statistical analysis.
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Use of green infrastructure as filtration panels for biological and mineral aerosols Griffith University, Australia This study explores the potential of plants as natural air filters for indoor spaces, focusing on their ability to remove airborne pollutants, including fungal allergens. Two plant species, Banksia spinulosa (dry flowers) and Tillandsia incarnata (living plants), were assessed in a laboratory setup with an aerosol chamber. The plants were arranged in panels, and their filtration efficiency was tested with various aerosols, including bacteria, fungi, and particles. Results demonstrated significant filtration capabilities, with Tillandsia plants excelling in bacterial removal. These findings suggest that plants can improve indoor air quality and public health by reducing airborne microorganisms in various settings.
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MODIS versus AERONET Aerosol Optical Properties in Central-East Europe Babeș-Bolyai University, Romania This study evaluates MODIS Terra satellite AOD retrievals against AERONET data from 29 stations in 10 Central-East European countries over 2010–2023. Correlation with AERONET improves seasonally, with R² increasing from 0.58 in winter to 0.76 in summer. Mean negative biases are found at 16 out of 29 sites, suggesting that MODIS Terra AOD retrievals are mostly overestimated. Larger deviations in biases are attributed to factors such as limited matching retrievals or site-specific conditions. Aerosol classification reveals mixed types dominate (>30%), followed by polluted (>22%) and continental (22–24%), with the rest from biomass burning, dust, and marine sources.
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Effectively constraining aerosol radiative forcing using remote sensing and in-situ observations 1Babeș-Bolyai University, Romania; 2Scripps Institute, University of California, San Diego, USA; 3AOPP, University of Oxford, Great Britain We use a Perturbed Parameter Ensemble (PPE) to constrain a global aerosol-climate model with respect to black carbon (BC) radiative forcing uncertainties. We perturbed three key parameters: BC number, wet deposition, and the imaginary refractive index. The ensemble was constrained using AERONET AAOD and airborne BC mass concentration . Results show a shift toward more absorbing particles and lower BC emissions. The effective radiative forcing (ERF) constrained from −1.42 ± 0.17 W/m² to −1.47 ± 0.04 W/m². Analyses included Gaussian mixture clustering and Sobol sensitivity analysis to identify dominant sources of uncertainty and the structure of the constrained parameter space.
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Measurement of On-road Brake Wear Particle(BWP) Emissions of Electrification Vehicle and Regenerative Effect Analysis Korea Institute of Machinery and Materials, Korea, Republic of (South Korea) Road transport emissions have declined due to regulations, but non-exhaust emissions (NEE), especially brake wear particles (BWPs), are rising with more and heavier vehicles. From November 2026, Euro 7 will regulate BWP emissions, with UN GTR No.24 providing an indirect estimation method using friction braking ratio. This study developed an on-road BWP measurement method for ICEV, HEV, and PEV, using tracer gas and data filtering. Results showed BWP emissions decrease with higher regenerative braking ratio, and emissions were highest in urban areas, followed by rural and motorways, correlating with regenerative braking usage.
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Biomonitoring of Airborne Particulate Matter Using Plane Tree Bark: Method Development and First Insights into Oxidative Potential measurement 1Center for Energy and Environment, IMT Nord Europe, Institut Mines-Télécom, Université de Lille, Lille, France.; 2Mines Saint-Etienne, Univ Jean Monnet, INSERM, U1059 Sainbiose, Centre CIS, F-42023 Saint-Etienne, France; 3Center of Geosciences and Geoengeneering, Mines Paris - PSL, Fontainebleau, France Exposure to particulate matter (PM) has harmful health effects, but the underlying physiological mechanisms remain poorly understood. A key hypothesis involves oxidative stress induced by reactive oxygen species (ROS). The oxidative potential (OP) of PM, a key indicator of its toxicity, depends on its chemical composition. However, data on PM’s spatial variability are limited. Biomonitoring using trees, such as plane trees in Paris, offers a cost-effective monitoring solution. This study presents an ultrasound-based extraction method to analyze PM composition and assess their toxicity and OP using AA and DTT assays.
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Oxidative potential of PM1 and PM10 at a Mediterranean urban site Miguel Hernández University, Spain PM1 and PM10 samples collected at an urban area close to the Spanish Mediterranean coast were analysed in order to determine their chemical composition and oxidative potential (OP) using the dithiothreitol (DTT) assay. Volume and mass-normalised OP values were higher in winter than in summer, most likely because OP sources vary depending on the season of the year. Although the average OPV values in the submicron and coarse fractions were similar, the mass-normalised DTT activity was considerably higher in PM1 than in PM10-1, which suggests that fine particles are potentially more harmful for human health than coarse particles.
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First results of In-Situ Measurement Campaign for Cloud Studies at the Milešovka Observatory, Czechia Palas GmbH, Germany From Winter 2024 on, the cloud droplet analyser is used Setup of the campaign and first results will be
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Analysis of the nano fraction content in the atmospheric air of the SE part of Warsaw CIOP-PIB, Poland In the context of the nanoparticles impact on human health and the environment, research has been conducted in atmospheric aerosol. The measurements covered different seasons and various weather conditions in the SE part of Warsaw. Due to weather conditions, the particle size distributions for July and August of 2024 are almost identical. The increase in the share of particles below 100 nm in September and October may be the result of increased road traffic and higher exhaust emissions. SEM analysis confirmed the presence of nano-objects in the form of agglomerates in the atmospheric aerosol.
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High-resolution temporal and size-resolved analysis of atmospheric particulate matter using OPC: source apportionment 1ARPA Puglia, Italy; 2Lab Service Analytica srl This study investigates the impact of particulate matter (PM) from biomass combustion, burning during winter in various urban areas of the Apulia region, Italy. Real-time measurements were conducted using Fidas 200s (Palas) optical particle counters (OPC), which is certified according to the UNI EN 16450 standard. This instrument allows to quantify particle number and size distribution in the 0.18–18 µm range. The study was carried out at two different urban sites located in small towns. The investigation aims to identify and characterize PM concentration increase cycles, which are likely associated with the ignition of domestic fireplaces.
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The OASIS 2024 Campaign: The Role of VOCs in the Nucleation Particle Growth 1Ciemat, Spain; 2Universidad de A Coruña The OASIS 2024 campaign studied new particle formation (NPF) in the atmosphere, focusing on the role of volatile organic compounds (VOCs) in particle nucleation and growth. Conducted from April to July 2024 at the CIEMAT site in Madrid, it collected nearly 500 VOC samples and recorded 38 nucleation events. Various atmospheric parameters were measured to assess the relationship between biogenic and anthropogenic VOCs and nucleation. Statistical analyses revealed significant differences in β-pinene concentrations between nucleation and non-nucleation days, with a 95% confidence level, highlighting its potential role in the nucleation process.
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Chemical-physical characterization of atmospheric particulate matter collected in the Lecce area (South Italy) by ED-XRF and ATR-FTIR spectroscopy 1Institute of Atmospheric Sciences and Climate (ISAC), National Research Council of Italy, Lecce, 73100, Italy; 2Department of Environmental and Biological Sciences and Technologies (DISTEBA), University of Salento, Lecce, 73100, Italy In this study a chemical-physical characterization of PM2.5 by means of ED-XRF and ATR-FTIR analysis was performed. The PM2.5 was collected om Teflon filters in the framework of TOX-IN-AIR project during two measurement campaigns in two sites, an urban site and an urban background site in Lecce (Puglia, South Italy). Acquisition and processing of ATR-FTIR spectra of particulate samples were optimized to collect solid and accurate information on functional groups which represent the particulate composition. In addition, ED-XRF investigation allows to determine the elemental composition of the air particulate matter, useful to focus on the role of anthropogenic activities and natural sources.
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Techniques and measurement methods comparison for determination of the water-soluble fraction of atmospheric particulate matter 1CNR-ISAC Lecce, Italy; 2Department DISTEBA - University of Salento, Lecce, Italy This study compares two water-soluble organic carbon measurement methodologies: the method that measures total organic carbon obtained by the difference between total carbon and inorganic carbon, and the method that measures non-volatile organic carbon. The water-soluble nitrogen, measured simultaneously with soluble carbon and without requiring an additional sample, was compared with the inorganic nitrogen fraction measured using a different analytical technique, i.e., ion chromatography. In conclusion, there is an excellent correlation of the values obtained with the two methods used to measure water-soluble organic carbon. Furthermore, the same instrumental technique allows for obtaining the water-soluble nitrogen content in the sample.
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On the use of low-cost PM sensors for controlling ventilation system of production facilities on demand 1Institut für Umwelt & Energie, Technik & Analytik e. V. (IUTA), Germany; 2Invent GmbH, Germany; 3B+T Oberflächentechnik GmbH, Germany; 4Technische Universität Braunschweig, Germany The applicability of low-cost PM sensors for the control of HVAC systems on demand in production facilities has been investigated. Low cost sensors were tested in different industries, including surface treatment by electroplating and the manufacture and processing of carbon fibre-based composite materials. A filter sampler and a scientific-grade optical aerosol spectrometer (Grimm 11-D) were operated in parallel and served as references. It was found that the sensors require workplace-specific calibration in order to provide meaningful estimates of the PM concentration. Upon this calibration, they are well suited to control HVAC systems, based on the actual concentration.
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Suspect and untargeted characterization of total suspended particles collected in Porto Marghera, an industrial site in the Northeast of Italy 1Institute of Polar Sciences, National Research Council of Italy, Italy; 2Department of Environmental Sciences, Ca’ Foscari University of Venice, Italy The Porto Marghera industrial site, in the Venice lagoon, has hosted various manufacturing activities for over a century, heavily impacting the environment and public health. Since the 1980s, deindustrialization has reduced pollution. This study analyzes new contaminants by examining Total Suspended Particles (TSP) collected near the site. Using UHPLC-HRMS analysis, over 130 compounds were identified, including pesticides, pharmaceuticals, biocides, personal care products, and plastic additives. The research aims to characterize the current contamination fingerprint and assess the site's ongoing environmental impact.
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Evaluation of the impact of climate change on air quality in Alpine valleys Arpa Liguria, Italy ARPAL is involved in the ALP'Aerà project, a project funded by the Interreg Italy-France ALCOTRA program 2021-2027. The main objective is to characterize the future impacts of climate change on air quality in the Alpine valleys, to propose new indicators for climate change monitoring and to establish new integrated mitigation strategies. Thhe project faces the cross-border economic and social challenges with deepen study of the evolution of pollutant emissions and climate change in the medium and long term. ARPAL is responsible for air quality diagnostic in the Alpine valleys and for the coordination of the measurement campaigns.
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Intercomparison of online and offline XRF spectrometers for determining the elemental composition of PM10 at an urban site in Milan 1Università degli Studi di Milano, Italy; 2ARPA Lombardia, Milan, Italy; 3Aix Marseille Université, LCE, Marseille, France & Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen PSI, Switzerland; 4Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen PSI, Switzerland This study assessed the Xact 625i Ambient Metals Monitor performance and evaluated the data quality and robustness. Xact data were aggregated to 24-h daily means and compared to 24-h PM10 data retrieved by ARPA Lombardia in the same station in Milan (Italy) and analysed offline by a benchtop ED-XRF spectrometer. The intercomparison focused on Al, Si, S, Cl, K, Ca, Ti, Cr, Mn, Fe, Ni, Cu, Zn, Br, Sr, and Pb. Xact data were found to be highly correlated to the offline XRF analyses (R2 ranging from 0.67 to 0.99) and slopes (online vs offline) ranging from 0.79 to 1.3.
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Impacts of summertime photochemical aging on the physicochemical properties of aerosols in a Paris suburban forest region 1Université Paris Cité and Univ Paris Est Créteil, CNRS, LISA, F-75013 Paris, France; 2IMT Nord Europe, Institut Mines-Télécom, Université de Lille, Centre for Energy and Environment, F-59000, Lille, France; 3Univ Paris Est Créteil and Université Paris Cité, CNRS, LISA, F-94010 Créteil, France; 4Atmospheric Chemistry Department, Max-Planck-Institute for Chemistry, 55128-Mainz, Germany; 5Laboratoire de Physique et Chimie de l’Environnement et de l’Espace (LPC2E), CNRS−Université Orléans−CNES, Orléans Cedex 245071, France; 6Multiphase Chemistry Department, Max-Planck-Institute for Chemistry, 55128-Mainz, Germany; 7CNRM, Universite de Toulouse, Meteo-France, CNRS, Toulouse, France; 8Department of Earth and Environmental Sciences, University of Manchester, Manchester M13 9PL, United Kingdom; 9National Centre for Atmospheric Sciences, University of Manchester, Manchester M13 9PL, United Kingdom; 10Department of Atmospheric Sciences, School of Earth Sciences, Zhejiang University, Zhejiang 310027, China; 11Guangxi Key Laboratory of Theory and Technology for Environmental Pollution Control, Collaborative Innovation Center for Water Pollution Control and Water Safety in Karst Area, Guilin University of Technology, Guilin, China An experiment was conducted in a suburban forest area in the Paris region to systematically study the evolution of OOA. The submicron organic aerosol (OA) and their primary and secondary sources were characterised by an aerosol mass spectrometer (AMS) with positive matrix factorization (PMF) analysis. Our results show that the photochemical processes drove significant increases in OOA derived from both biogenic and anthropogenic emissions. Under elevated pollution and intense solar radiation during continental air mass-dominated periods, rapid formation of More-Oxidized OOA (MO-OOA) occurred. Our findings underscore the dual role of photochemistry in shaping aerosol optical properties and climate impacts.
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A novel laboratory experimental platform to explore jet engine combustion and lubricant oil aerosols interactions ONERA, France This laboratory study investigates the interaction between oil and combustion aerosol emissions from aircraft engines. The experimental setup combines oil aerosol generation and combustion particulate matter (both volatile and non-volatile) using a swirl mixing device. Emission aging is simulated with an oxidation chamber to study vPM formation. Emissions are characterized using a CPC and a SMPS. By varying fuel type, oil concentration, combustion, and aging conditions, the study examines how oil and soot interactions affect aerosol emissions. The preliminary results show the control of particle size distributions, simulating a range of aircraft engine emission scenarios.
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RECETOX Research Infrastructure services offer – Core facility of the Central Laboratories Masaryk University, Czech Republic The RECETOX Research Infrastructure at Masaryk University, Czech Republic, supports advanced environmental and health research focusing on the exposome and persistent organic pollutants. As a key partner of ACTRIS-CZ and contributor to the pan-European ACTRIS initiative, RECETOX provides analytical expertise, long-term POPs monitoring, and support for atmospheric research at the National Atmospheric Observatory Košetice. Its Central Laboratories offer accredited trace analysis, microbiome profiling, and biomarker detection. RECETOX ensures open, merit-based access via schemes such as IRISCC and ATMO-ACCESS, and advances capacity-building through activities like the 2023 ATMO-ACCESS training, promoting interdisciplinary collaboration in atmospheric and environmental sciences.
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RECETOX, ACTRIS_CZ Research infrastructures Masaryk University, Czech Republic ACTRIS-ERIC is a European research infrastructure focused on aerosols, clouds, and trace gases. The Czech node, ACTRIS-CZ, includes Masaryk University (RECETOX), which contributes advanced analytical capacity and long-term POPs monitoring at the Košetice Observatory. RECETOX supports international agreements like the Stockholm Convention and operates the GENASIS database, providing open access to validated environmental data. Monitoring includes active and passive air sampling, deposition, and biota sampling, with comprehensive analysis of organic pollutants and metals. ACTRIS-CZ offers physical, virtual, and remote access, supports capacity building, and provides services to projects like ACTRIS, ATMO-ACCESS, and EIRENE.
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Are low-cost sensors suitable for detecting smoke generated during laser surgery? HUN-REN Wigner Research Centre for Physics, Hungary The question of whether low-cost sensors are suitable for measuring the smoke generated in the operating theatre during laser surgery and thus assessing the risks is a complex, multidisciplinary problem. Indeed, low-cost sensors can be helpful for preliminary or supplementary measurements, such as monitoring trends or general characterisation of smoke generation, but are not a substitute for professional, standardised instrumentation for detailed risk analysis and regulatory compliance.
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High-resolution PM prediction at intra-urban scale: the APEMAIA project in preparation for the MAIA mission 1Institute of Atmospheric Pollution, National Research Council (CNR-IIA), Italy; 2Italian Space Agency; 3Interateneo Physics Department M. Merlin, University of Bari, Italy; 4National Institute for Nuclear Physics, Bari, Italy; 5Regional Environmental Protection Agency, Bari, Italy Air pollution represents one of the greatest contemporary environmental and health threats. The APEMAIA project develops machine learning methodologies to estimate PM concentrations at intra-urban scale (300m), supporting preparatory studies for NASA's MAIA mission (Multi-Angle Imager for Aerosol).The framework integrates multi-source data including satellite AOD, meteorological variables and urban morphological characteristics. The XGBoost model demonstrates good performance in capturing complex relationships between different data sources, obtaining high spatio-temporal resolution maps in the metropolitan city of Bari (2019-2022) identifying the most critical urban areas. This methodology provides a solid foundation for assessing population exposure to atmospheric particulate matter in urban environments.
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Machine Learning-Based Forecasting and Impact Assessment of Black Carbon over Indo-Gangetic Basin City 1Dayalbagh Educational Institute (Deemed to be University) Dayalbagh Agra 282005 (India), India; 2Civil and Environmental Engineering, School of Engineering, Northeastern University, Boston, USA Black carbon (BC), a potent climate forcer and air pollutant, was studied in Agra, India (2022–2024) to assess its seasonal dynamics, radiative impacts, and health risks. BC peaked in winter (20–25 µg/m³) due to biomass burning and shallow boundary layers, while monsoon rains caused declines. Despite a moderate BC–PM₂.₅ correlation (r=0.53), BC–AOD linkage was weak (r=0.12), suggesting vertical decoupling. BC reduced solar (r=-0.30) and thermal radiation (r=-0.41). XGBoost predicted BC accurately (R²=0.88) using AOD and soil temperature. Health analysis showed up to 10% excess winter mortality. Results stress season-specific emission controls and integrated climate-health policies for the Indo-Gangetic Basin.
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A charger-less, pump-less electrostatic precipitator utilizing triboelectric charging for collecting brake-wear-particles 1Korea Institute of Machinery and Materials, Republic of (South Korea); 2Yonsei University, Republic of (South Korea) This study presents an electrostatic precipitator utilizing triboelectric charging for collecting brake wear particles without a particle charger or pump. Experiments using a brake dynamometer and LM, NAO pads showed the device reduced PM₁₀ emissions to 3.3 mg/km and 1.4 mg/km, respectively, meeting EURO 7 limits. Efficiency averaged 61% under WLTC conditions, with 74–75% during acceleration. Simulations guided design optimization, focusing on collector size and voltage. The developed collector presents an energy-efficient and eco-conscious approach to collecting brake wear particle emissions.
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Bioaerosol Sensing for Environmental Health: A Proof-of-Concept Study Cranfield University, United Kingdom This study aims to develop a proof-of-concept for a portable bioaerosols sensor system exploiting novel physical principles where electron-photon interactions within a solid-state device platform is used to mimic this interaction. Absorbed photons can transfer energy to the electrons in the semiconductor device, which can then be used for detection purposes. Our prototype design aims to cover a wide fluorescence spectral range (298–735 nm), capturing key bioaerosol signatures through ultraviolet laser-induced fluorescence (UV-LIF).
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Chemistry in nanometer-sized aerosol particles: Investigating the dependency of peptide formation on particle size using online-APCI-MS Johannes Gutenberg University Mainz, Germany This study investigates the size-dependent formation of peptides in nanometer-sized aerosol particles, serving as a model for condensation reactions relevant to atmospheric growth processes. Laboratory experiments using a flow tube reactor, SMPS, and online APCI-MS analyze how particle size influences reaction rates and product formation. Smaller particles offer unique nanoscale chemical environments that can enhance specific reactions, thereby affecting particle survival and growth. These findings enhance our understanding of size-dependent particle-phase chemistry and how it bridges the gap between initial particle embryos and growth into sizes with higher survival probability.
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Comparison of Aerosol Absorption Ångström Exponent Between Photoacoustic and Filter-Based Methods in a Rural Environment 1Institute for Atmospheric and Environmental Research, University of Wuppertal, Wuppertal, 42119, Germany; 2schnaiTEC GmbH, Wuppertal, 42287, Wuppertal; 3Collaborative Innovation Center on Forecast and Evaluation of Meteorological Disasters, Nanjing University of Information Science & Technology, Nanjing, 210044, China; 4Finnish Meteorological Institute, Helsinki, 00560, Helsinki The aerosol absorption Ångström exponent (AAE) is commonly used to distinguish black and brown carbon sources. However, its reliability is limited due to sensitivity to aerosol microphysics and filter artifacts. We present a long-term intercomparison between a four-wavelength photoacoustic spectrometer (PAAS-4λ) and an AE33 Aethalometer at two Finnish sites: Pallas (sub-Arctic) and Hyytiälä (boreal forest). PAAS-4λ revealed broader AAE distributions, likely reflecting real atmospheric variability, which AE33 underrepresents. We further investigate AAE variability using supporting microphysical data, numerical simulations, and correlations with seasonal, meteorological, and transport patterns to better constrain absorption-based source apportionment.
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Contribution of BTEX on secondary organic aerosol formation potential at a Mediterranean site (Heraklion, Crete, Greece) 1Institute for Environmental Research and Sustainable Development, National Observatory of Athens, P. Penteli, Athens, 15236, Greece; 2Environmental Chemical Processes Laboratory, Department of Chemistry, University of Crete, Heraklion, 71003, Greece BTEX monitoring is challenging in the Eastern Mediterranean area under enhanced photochemistry conditions and regional transport, especially by taking into consideration their increased reactivity and their aerosol formation potential. BTEX were monitored during two years (2023-2024) at Heraklion, Crete, Greece by means of an automatic gas chromatograph with 15 minutes time resolution, along with other gaseous and particulate pollutants and meteorological parameters. The SOA formation potential of the measured BTEX was estimated for winter given the important contributions from local sources, including residential biomass burning sources, and found to account for almost 40% of the locally produced organic mass.
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Delayed respiratory response to wildfire smoke 1Old Dominion University, United States of America; 2Towson University, USA; 3University of Nevada - Reno Wildfires pose significant challenges to public health. This study utilized a retrospective repeat measures cohort study design (n=842) by collecting multiple peak flow measures made by an allergist among his patients before, during, and after two wildfire events in the Dismal Swamp area of North Carolina USA. Changes in peak flow were temporally correlated with the wildfire occurrences by comparing peak flow measures before, during, and after the wildfire. An assessment of wind direction was also assessed to determine if there were differences between peak flow measurements when the wind was blowing directly from the fire to the community affected.
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Electrode material transport and its role in the temporal variation of the composition of Cu/Ag NPs generated by high-frequency spark discharge 11Department of Optics and Quantum Electronics, University of Szeged, Szeged, 6720, Hungary; 2Department of Molecular and Analytical Chemistry, University of Szeged, Szeged, 6720, Hungary Binary Ag/Cu nanoparticles were synthesized using a high-frequency spark discharge generator operating in unipolar mode. This setup enables asymmetric electrode erosion, leading to cross-contamination between the electrodes. By combining ex situ ICP-MS and SEM-EDX analysis, the time evolution of nanoparticle composition and electrode surface coverage was investigated over 10-minute intervals. Results show that copper gradually covers the silver electrode surface, while silver contributes less significantly to the copper side. This asymmetric material transport strongly influences the resulting nanoparticle composition, confirming the key role of electrode surface contamination in spark ablation-based BNP synthesis.
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Evaluation of Particle Collection and Cleaning Performance of an Electrostatic Precipitator Equipped with EDS System 1Department of Urban Environment Research, Korea Institute of Machinery and Materials, Republic of Korea; 2Mechanical Engineering, University of Science and Technology (UST), Republic of Korea Electrostatic precipitators (ESPs) are widely used for fine dust removal due to their high collection efficiency and low pressure drop. However, dust accumulation on collection plates over time reduces efficiency, highlighting the need for improved cleaning methods. In this study, we developed an ESP incorporating an electrodynamic screen (EDS) system, which was fabricated by coating the surface of the collection plates with a dielectric film printed with interdigitated electrodes. Experimental results showed that, after the particle collection efficiency dropped to approximately 70% due to dust accumulation, activation of the EDS system effectively restored the collection efficiency to its original level.
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Evaluation of the Role of Benzo(a)pyrene as Carcinogenic Index of PM10-bound PAHs in Italy and Europe 1Consiglio Nazionale delle Ricerche, Italy; 2ARPA Veneto, Italy A study was conducted in Italy to assess the effectiveness of Benzo(a)pyrene (BaP) as the sole marker of PAH toxicity, as defined by the European directive. The results obtained in Italy were compared with available European data. The study showed that BaP can represent the general behavior of Polycyclic Aromatic Hydrocarbons (PAHs), confirming its role as a suitable indicator. However, its ability to reflect the overall carcinogenicity of PAHs is limited, accounting for approximately 60% of total PAH-related toxicity. These findings suggest that relying solely on BaP may underestimate the health risks associated with PAH exposure in the environment.
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Indoor air quality and health effects in elementary schools: preliminary results of MISSION project 1CNR ISAC, Lecce, Italy; 2CNR ISAC, Lamezia Terme, Italy; 3Laboratorio di Prevenzione-ATS Milano, Italy; 4Medicina del lavoro, Ospedale di Desio, Italy; 5ATS Insubria, Varese, Italy; 6ASST Spedali Civili di Brescia, Italy; 7Medicina del lavoro - Università di Bari, Italy In this contribute, passive sampling results of VOC (Volatile Organic Compounds), ozone, formaldehyde and nitrogen dioxide concentration trends of four elementary schools in Lecce and four in Milan are shown and discussed, also considering their relative outdoor trends. Results shown are referred to the basal monitoring campaign of the project performed during the winter 2024/2025. Children and teachers can be exposed to indoor sources of pollutants which can sometimes be more relevant than outdoor ones. Results of spirometry and FeNO test will be discussed. This work was supported by MISSION project (PREV-A-2022-12377010)-PNC-Salute, Ambiente, Biodiversità e Clima – Ministero della Salute.
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Modelling oxidative potential (OP) of atmospheric particle: A 2-year study over France 1LISA (UPEC-CNRS-UPC), France; 2IGE, France; 3INERIS, France; 4LMD, France; 5Atmo AURA, France; 6Atmo Sud, France; 7Atmo Nouvelle-Aquitaine, France; 8ANDRA, France In this work, OP, a promising indicator of the effects of PM on health, is modelled over France with the CHIMERE model for two years. We described the methodology develloped to simulate OP based on data from field measurements and a PMF approach. Evaluation of the simulation against observations (PM mass, speciation, source modelling and OP) allows to evaluate our method. It highlights the need to get larger OP datasets and improve our capacity to model sources and PM speciation. The analysis of the results do confirm the large differences of source contribution to OP and to PM mass.
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Highly perforated ZnO/PLA nanofibers fabricated via humidity-assisted electrospinning for antimicrobial filtration of bioaerosols 1Korea Institute Machinery & Materials, Korea, Republic of (South Korea); 2Yonsei University, Korea, Republic of (South Korea) We developed highly perforated ZnO/PLA nanofibers (HP-ZnO/PLA NFs) via a one-step, humidity-assisted electrospinning process. This method leverages the breath-figure effect to form porous architectures and simultaneously expose ZnO nanoparticles on the fiber surface without post-treatment. The resulting nanofibers exhibit strong antimicrobial activity against bacteria (E. coli, S. aureus) and viruses (MS2, H1N1, HCoV-229E/-OC43). Their high porosity and surface functionality make them promising antimicrobial filters for bioaerosol control in indoor environments such as schools and healthcare facilities.
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Improving Ultrafine Particle Measurements with an Innovative UFSMPS Dual-CPC System University of Helsinki, Finland We present the University of Helsinki’s ultrafine scanning mobility particle sizer (UFSMPS), developed in collaboration with the ACTRIS Cluster Calibration Centre. The UFSMPS measures aerosol particle size distributions between 2.5-30 nm, using a unique dual-CPC setup (TSI ultrafine and TSI standard CPC) combined with a short Vienna-type DMA. Sampled simultaneously, it improves data reliability by correcting for poor counting statistics common in ultrafine measurements. A non-complex design in combination with a short sampling line and dilution system further minimize uncertainties. This design offers improved precision for long-term ultrafine aerosol measurements under both laboratory and ambient conditions.
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Implementing bioaerosols in the EC-Earth3-AerChem model 1Institute for Environmental Research and Sustainable Development, National Observatory of Athens (NOA), Greece; 2Department of Physical Geography and Ecosystem Science, Lund University, Sweden; 3Environmental Chemical Processes Laboratory (ECPL), University of Crete, Greece; 4Barcelona Supercomputing Center (BSC), Spain This study presents the implementation of primary biological aerosol particles (PBAPs)—bacteria, fungal spores, and pollen—into the EC-Earth3-AerChem model. The model introduces soluble and insoluble PBAPs, simulating aging processes based on ozone and relative humidity. Global PBAP flux is estimated at ~84 Tg yr⁻¹, with a lifetime of ~1.4 days. Results also show strong seasonal patterns and good agreement with site observations. This work demonstrates that including biological aerosol sources improves model accuracy and therefore enhances our understanding of coarse-mode organic aerosol climate effects.
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Long-term monitoring of New Particle Formation influencers in Ny-Ålesund leads to understanding novel nucleation pathways in the Arctic 1Institute for Atmospheric and Earth System Research , INAR, Helsinki, Finland; 2Institute of Polar Sciences (CNR-ISP), National Research Council, CNR, Bologna, Italy The Arctic is rapidly warming, impacting ecosystems and atmospheric processes. To understand new particle formation (NPF), measurements since 2017 at Ny-Ålesund, Svalbard, monitor the particle size distribution and NPF inflencers such as key vapors of sulfuric acid, methane sulfonic acid (MSA), and iodic acid. Since 2024, upgraded instrumentation enables tracking of both neutral molecules and ion clusters, revealing ion-driven clustering on a year-round base. Exracted from this data set, a case study captured the first field evidence of MSA-ammonia nucleation in the arctic field, highlighting the importance of continuous observations of an everchanging Arctic atmosphere.
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Study of Cs-Mo reactivity through RCS transport in PWR accident conditions ASNR, France Understanding fission product (FP) behavior under severe nuclear accident conditions is critical for improving source term models. This work focuses on Cs–Mo interactions, particularly the formation of CsHMoO₄, which could influence iodine transport. A dedicated campaign in the SPARC facility studies experimentally species transport and deposition under a strong thermal gradient. Various Cs–Mo precursors are tested; resulting aerosols, deposits, and gases are analyzed (SEM-EDX, XRD, ICP-MS). Early results confirm CsHMoO₄ formation in predicted zones and highlight molybdenum’s effect on cesium behavior. These findings support improved ASTEC modeling by refining the chemical mechanisms affecting volatile FP transport in reactor coolant systems.
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The LowC-project: Safe and sustainable Low-Carbon fuels for heavy-duty, aviation, and maritime sectors. 1Norwegian Institute of Public health, Norway; 2University of Fribourg, Switzerland; 3University of Eastern Finland, Finland; 4University of Rostock, Germany; 5International Institute for Applied Systems Analysis (IIASA), Austria; 6Norwegian Meteorological Institute, Norway; 7Deutz AG, Germany; 8University of Basel, Switzerland Heavy-duty road and non-road machinery, aircrafts and ships are contributing significantly to emissions of green-house gases and air pollutants, including fine particulate matter (PM2.5) and emerging pollutants. New low or zero carbon fuels (LCF/ZCF) are considered to decarbonize the sector. An important question is how these potential new fuels will influence emissions of air pollutants and climate relevant compounds. LowC will address the impact of LCF/ZCF on the emissions of air pollutants and climate-drivers, evaluate health and environmental impacts and provide guidance and recommendations to ensure that solutions to reduce CO2 emissions and prevent climate change are safe and sustainable.
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Urban Air Quality Hotspot Detection Through High-Resolution Mobile Measurements: Budapest Case Study Department of Meteorology, Institute of Geography and Earth Sciences, Eötvös Loránd University, Budapest, Hungary Traditional air quality monitoring relies on sparse fixed stations, limiting spatial resolution of urban pollution patterns. This study presents a bicycle-based measurement campaign conducted in Budapest using TSI DustTrak II (8532) for PM10/PM2.5, GPS tracking, and meteorological sensors. Over 200 measurement runs across four representative urban routes captured fine-scale concentration variations. Automated data processing pipeline performed quality control, temporal synchronization, and spatial gridding. Statistical analysis identified persistent air quality hotspots using 90th percentile thresholds, revealing distinct pollution patterns associated with traffic corridors, industrial areas, and urban topography. Results demonstrate mobile monitoring potential for urban planning applications and cycling route optimization.
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Study on Cleaning Performance and Dust Emissions of Bag Filters Depending on Surface Treatment 1Korea Institute of Energy Research, Korea, Republic of (South Korea); 2University of Science and Technology, Daejeon, Republic of Korea A baghouse is widely employed as effective particle precipitator from diverse industrial sources such as power plant, steel industry, cement production industry and waste incineration facilities. Eventhough a baghouse shows high particle collection efficiency, the emission is sharply incresing during the cleaning process using pulse jet(Shim et al.,2017; Simon et al., 2014). Many efforts have been made to mitigate this, one of which is the modification of the filter surface. In this stydy, we aimed to investigate the effect of surface treatment of filter media on the performance of bag filters. PO3: 235
Introduction and First Test Results of a Portable Dual Channel Water CPC TSI GmbH, Germany The newly developed OmniCountTM, portable Water-CPC (Model 3002, TSI Incorporated) incorporates two synchronized CPC “engines”. It was originally designed for respiratory protection testing of face masks in the field, allowing for simultaneous determination of particle number concentrations upstream and downstream of a filter or barrier. Due to its compact design, which among others allows operation in any orientation, this WCPC is also well suited for a wide range of additional applications, including the uses on unmanned aerial systems, weather balloons, and mobile measurement platforms PO3: 236
The impact of wildfire emissions on oxidative potential of aerosol particles in Canada 1Environmental and Life Sciences, Trent University, Peterborough, Canada; 2Multiphase Chemistry Department, Max Planck Institute for Chemistry, Mainz, Germany; 3Analysis and Air Quality Section, Environment and Climate Change Canada, Ottawa, Canada; 4Institute of Chemical Engineering Sciences, Foundation for Research and Technology Hellas, Patras, Greece; 5Air Quality Processes Research Section, Environment and Climate Change Canada, Toronto, Canada; 6Laboratory of Atmospheric Processes and their Impacts, School of Architecture, Civil and Environmental Engineering, École Polytechnique Fédérale de Lausanne, Lausanne, Switzerland; 7Department of Chemistry, Trent University, Peterborough, Canada Wildfires are increasing in frequency and magnitude worldwide, and there is growing interest in understanding their impacts on air quality and population health. Here we investigate the impact of 2023 wildfires on oxidative potential (OP) of ambient air across Canada, with the aim to identify molecular carriers of OP. The productions of reactive oxygen species and OP were modelled using KM-SUB-ELF and KM-SUB-OP models, and the aerosol speciation data. Contributions of emission sources, aerosol composition, transformation, and acidity on OP were determined. Significant increases in concentrations of biomass burning markers and reactive species were observed during wildfire season.
PO3: 237
Spectral aerosol light absorption measurements with a self-calibrated photothermal interferometer National Research Council Canada Photothermal interferometry (PTI) is a diagnostic method that provides direct and accurate measurement of aerosol light absorption coefficient. Here, we present a self-calibrating PTI capable of high-resolution multi-wavelength measurements. By combining a supercontinuum light source with an optical wavelength filter, we enable the selection of excitation beams with wavelengths ranging continuously from 405 nm to 850 nm with bandwidth resolution as small as ±5 nm. We developed a calibration procedure for the instrument and demonstrated its applicability by measuring the spectral absorption coefficient of nigrosin aerosol samples and extracting the complex refractive index based on the PTI measurements.
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